File name: Pandora25s1_HoustonTX_20220714_L2Fit_fout2c6d20220503p1-8.txt File generation date: 20250922T152338.6Z Data description: Level 2 spectral fitting results file Data file version: fout2c6p1-8 Local principal investigator: Jimmy Flynn Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 25 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora25_OF_v7d20190903.txt Instrument calibration file used: Pandora25s1_CF_v6d20220503.txt Level 1 file used: Pandora25s1_HoustonTX_20220714_L1_smca1c6d20220503p1-8.txt Full location name: University Of Houston Short location name: HoustonTX Country of location: United States Location latitude [deg]: 29.7200 Location longitude [deg]: -95.3400 Location altitude [m]: 19 Local noon date: 20220714 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Update session 4 for SO2 First and last pixel inside fitting window: 281 423 Nominal wavelengths inside fitting window [nm]: 305.1116 305.2524 305.3931 305.5338 305.6745 305.8152 305.9558 306.0965 306.2371 306.3777 306.5183 306.6589 306.7995 306.9401 307.0806 307.2212 307.3617 307.5022 307.6427 307.7832 307.9236 308.0641 308.2045 308.3449 308.4853 308.6257 308.7661 308.9065 309.0468 309.1872 309.3275 309.4678 309.6081 309.7484 309.8886 310.0289 310.1691 310.3093 310.4495 310.5897 310.7299 310.8701 311.0102 311.1504 311.2905 311.4306 311.5707 311.7108 311.8509 311.9909 312.1310 312.2710 312.4110 312.5510 312.6910 312.8310 312.9709 313.1109 313.2508 313.3907 313.5306 313.6705 313.8104 313.9503 314.0901 314.2300 314.3698 314.5096 314.6494 314.7892 314.9290 315.0687 315.2085 315.3482 315.4879 315.6276 315.7673 315.9070 316.0466 316.1863 316.3259 316.4656 316.6052 316.7448 316.8843 317.0239 317.1635 317.3030 317.4425 317.5821 317.7216 317.8611 318.0005 318.1400 318.2794 318.4189 318.5583 318.6977 318.8371 318.9765 319.1159 319.2552 319.3946 319.5339 319.6732 319.8125 319.9518 320.0911 320.2304 320.3696 320.5089 320.6481 320.7873 320.9265 321.0657 321.2049 321.3441 321.4832 321.6223 321.7615 321.9006 322.0397 322.1788 322.3178 322.4569 322.5960 322.7350 322.8740 323.0130 323.1520 323.2910 323.4300 323.5689 323.7079 323.8468 323.9857 324.1246 324.2635 324.4024 324.5413 324.6801 324.8190 324.9578 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20220714T130531.6Z 8230.545505 236 1 49.59 2 71.53 75.12 100.15 247.33 0.00 1 0.00 1 0 17 8.764e-02 7.821e-03 2.003e-02 2.127e-03 4.013715e-01 1.083508e-03 4.334384e-03 -6.000000e+00 5.052241e-02 230.09 -2.00 3.24 -2.00 318.98 0.00e+00 7.668813e-04 2.614328e-04 1.279912e-04 -6.000000e+00 2.324001e-03 294.15 -2.00 20.00 -2.00 318.05 0.00e+00 3.116 0.000 302.00 328.00 3 4.1364e+00 3.0312e-03 3.6625e-02 -6.0000e+00 1.2571e-01 1.4041e-03 3.5362e-03 1.9438e-02 -6.0000e+00 1.3606e-01 -8.8088e-03 2.4642e-03 9.4061e-03 -6.0000e+00 8.1464e-02 7.7518e-04 1.2921e-03 2.6972e-03 -6.0000e+00 3.4791e-02 2.3557e-04 -2.9535e-04 6.1223e-05 2.8730e-05 -6.0000e+00 2.3888e-03 -1.6127e-03 6.5292e-05 11 8 0 10 0 0 97.97 24.61 0.38 -0.00161 -0.00383 38 8 1 5 0 1304.850 27.05 19.99 24.61 34.73 26.2 1007.24 -58483 21068 -19173 24836 -36939 -13631 29970 -17733 31976 -11436 -17654 7453 -19704 1796 -5932 871 6514 7478 3440 5171 5548 -659 -12506 1200 -6578 1470 -7461 -2032 -3832 -11348 9675 2335 3160 -1481 -5881 -1917 4912 3801 1813 -2639 -2436 2368 3229 380 1541 925 -1312 -1749 3872 -1776 2396 39 976 1103 1002 1710 2485 -2501 67 -1153 1768 492 1572 737 -669 -801 -135 -298 310 704 982 526 229 185 1419 891 -2132 -520 -849 -636 -1058 -1379 -2184 171 -1369 -961 41 260 361 1224 238 512 240 -393 165 542 41 427 215 -332 -169 -1017 -797 -937 -35 -518 -588 -790 612 62 290 805 491 -305 -390 168 23 7 -384 -241 -414 266 526 286 473 494 -79 686 84 438 320 -200 -3 404 -15 -124 145 400 -157 -315 -32 -700 -295 -3013 571 -769 621 -1503 -450 725 -756 953 -533 -885 325 -1299 115 -475 73 551 667 335 518 561 -71 -1576 143 -893 193 -1055 -260 -483 -1599 1248 359 529 -263 -1032 -329 884 813 470 -813 -811 791 1105 134 544 330 -477 -639 1359 -679 949 17 448 533 500 872 1279 -1335 34 -599 930 281 967 484 -444 -506 -82 -183 205 514 764 422 182 142 1012 587 -1352 -324 -568 -474 -874 -1239 -2076 167 -1419 -1042 46 295 409 1336 248 501 225 -373 165 591 49 548 287 -441 -213 -1215 -917 -1106 -44 -668 -787 -1097 881 95 462 1296 780 -468 -571 238 32 11 -590 -382 -662 418 810 430 689 699 -109 960 124 687 524 -337 -6 713 -28 -236 280 781 -307 -607 -59 -1280 -531 SS 20220714T131509.9Z 8230.552197 242 1 39.32 2 69.51 76.14 101.99 248.36 0.00 1 0.00 1 0 17 1.878e-02 5.050e-03 5.876e-03 1.081e-03 3.650028e-01 5.515847e-04 3.983072e-03 -6.000000e+00 1.082556e-02 230.09 -2.00 3.24 -2.00 318.22 0.00e+00 1.906174e-04 1.063838e-04 9.523763e-05 -6.000000e+00 5.014088e-04 294.15 -2.00 20.00 -2.00 317.26 0.00e+00 2.827 0.000 302.00 328.00 3 3.0794e+00 1.4987e-03 3.3250e-02 -6.0000e+00 2.6935e-02 -1.8063e-02 1.7132e-03 1.7643e-02 -6.0000e+00 2.9157e-02 2.6861e-03 1.1024e-03 8.5152e-03 -6.0000e+00 1.7461e-02 -3.7561e-03 5.7146e-04 2.3321e-03 -6.0000e+00 7.5036e-03 9.4783e-04 -1.0655e-04 3.1104e-05 2.5535e-05 -6.0000e+00 5.1409e-04 -2.1859e-03 4.8967e-05 12 1 1 12 9 1 66.35 24.60 0.27 -0.00219 -0.00299 70 19 1 5 0 551.280 27.05 20.01 24.60 35.05 26.0 1009.31 900000 -3706 -505 -1895 -7265 -7686 3781 -7178 4970 -3001 -6632 1413 -7313 -827 -1221 7315 -1053 1338 -106 1622 -620 -162 -3376 -636 -795 373 -126 -1218 -1280 -2848 2857 457 1418 -1243 -3108 -2475 -662 182 -641 -739 -1197 -161 0 -12 -27 54 -1079 -387 119 -290 654 276 668 640 720 767 1199 -354 783 127 913 753 1284 1274 739 75 -208 -485 569 941 444 432 108 389 478 326 -1112 -432 -599 -757 -1027 -1100 -1714 -1090 -855 -662 -188 147 374 375 701 602 273 247 373 341 209 603 78 -185 -350 -897 -468 -520 -482 -708 -573 -500 100 193 232 341 183 36 -112 54 94 -2 -40 -261 -339 -34 80 199 430 421 249 844 664 572 365 -44 -108 230 12 -70 -96 301 -34 -321 -207 -425 -414 900000 -215 -29 -102 -378 -404 196 -467 319 -216 -499 107 -697 -87 -148 898 -148 194 -16 255 -101 -26 -591 -116 -154 74 -25 -230 -234 -543 567 102 339 -307 -743 -597 -174 55 -229 -297 -517 -72 0 -5 -12 25 -500 -178 55 -138 327 147 374 374 432 470 743 -221 478 78 575 506 918 955 554 54 -145 -341 424 763 382 381 95 330 383 244 -793 -303 -447 -619 -916 -1051 -1716 -1126 -923 -745 -218 173 438 427 760 620 270 245 388 382 253 773 104 -243 -443 -1080 -545 -621 -604 -919 -766 -689 143 288 358 533 281 53 -159 74 130 -3 -60 -401 -524 -52 121 292 613 584 337 1154 953 862 571 -71 -176 383 21 -124 -173 549 -62 -581 -365 -734 -706 SS 20220714T132038.9Z 8230.556006 245 1 49.48 2 68.35 76.71 103.04 248.93 0.00 1 0.00 1 0 17 1.189e-02 4.780e-03 2.853e-03 6.112e-04 3.477623e-01 3.110892e-04 3.802747e-03 -6.000000e+00 6.852924e-03 230.09 -2.00 3.24 -2.00 317.95 0.00e+00 1.887703e-04 5.542184e-05 8.455034e-05 -6.000000e+00 3.152290e-04 294.15 -2.00 20.00 -2.00 316.99 0.00e+00 2.686 0.000 302.00 328.00 3 2.3724e+00 8.3951e-04 3.1606e-02 -6.0000e+00 1.7052e-02 -1.9729e-02 9.5474e-04 1.6777e-02 -6.0000e+00 1.8455e-02 9.9125e-04 5.9579e-04 8.1011e-03 -6.0000e+00 1.1050e-02 -3.2055e-03 3.0455e-04 2.2194e-03 -6.0000e+00 4.7192e-03 2.2591e-03 -2.9155e-05 1.7516e-05 2.4483e-05 -6.0000e+00 3.2401e-04 -2.0402e-03 5.4344e-05 10 0 0 10 0 0 52.34 24.60 0.28 -0.00204 -0.00226 217 46 1 5 0 228.000 27.05 20.00 24.60 35.34 26.0 1011.31 -1851 -2102 -2662 -1806 -4488 -5912 1212 -3005 1099 -2401 -4179 -1354 -2625 -882 -1326 4249 -721 278 -2 1320 488 -157 -1110 35 -644 594 -393 -778 -665 -776 1339 616 1352 -591 -2229 -2405 -1432 -743 -771 -865 -887 -338 -114 -415 63 94 -641 -309 -334 -164 483 753 652 840 739 799 805 441 595 361 696 844 1213 1439 689 -246 -234 -417 535 501 323 296 80 250 322 126 -464 -651 -485 -658 -927 -993 -1765 -1227 -830 -550 -284 126 467 455 467 456 309 512 501 226 356 480 82 -284 -285 -905 -504 -316 -563 -768 -557 -557 -90 470 218 204 136 78 -41 181 197 56 29 -185 -351 -133 151 81 475 356 313 850 571 540 328 -69 -55 157 105 -60 -133 146 -117 -281 -171 -324 -412 -121 -151 -194 -120 -279 -374 79 -232 91 -213 -381 -130 -298 -107 -188 628 -119 48 0 246 93 -30 -226 7 -138 131 -86 -173 -141 -170 294 151 361 -162 -584 -641 -425 -244 -306 -373 -416 -166 -57 -211 32 48 -325 -155 -167 -85 252 424 393 505 460 512 525 287 378 230 462 609 906 1144 546 -183 -166 -297 414 418 280 265 71 222 263 97 -332 -483 -369 -545 -829 -984 -1797 -1311 -908 -615 -332 151 555 517 513 480 303 500 530 256 435 624 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