File name: Pandora25s1_HoustonTX_20220923_L2Fit_fout2c6d20220503p1-8.txt File generation date: 20250922T155157.7Z Data description: Level 2 spectral fitting results file Data file version: fout2c6p1-8 Local principal investigator: Jimmy Flynn Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 25 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora25_OF_v7d20190903.txt Instrument calibration file used: Pandora25s1_CF_v6d20220503.txt Level 1 file used: Pandora25s1_HoustonTX_20220923_L1_smca1c6d20220503p1-8.txt Full location name: University Of Houston Short location name: HoustonTX Country of location: United States Location latitude [deg]: 29.7200 Location longitude [deg]: -95.3400 Location altitude [m]: 19 Local noon date: 20220923 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Update session 4 for SO2 First and last pixel inside fitting window: 281 423 Nominal wavelengths inside fitting window [nm]: 305.1116 305.2524 305.3931 305.5338 305.6745 305.8152 305.9558 306.0965 306.2371 306.3777 306.5183 306.6589 306.7995 306.9401 307.0806 307.2212 307.3617 307.5022 307.6427 307.7832 307.9236 308.0641 308.2045 308.3449 308.4853 308.6257 308.7661 308.9065 309.0468 309.1872 309.3275 309.4678 309.6081 309.7484 309.8886 310.0289 310.1691 310.3093 310.4495 310.5897 310.7299 310.8701 311.0102 311.1504 311.2905 311.4306 311.5707 311.7108 311.8509 311.9909 312.1310 312.2710 312.4110 312.5510 312.6910 312.8310 312.9709 313.1109 313.2508 313.3907 313.5306 313.6705 313.8104 313.9503 314.0901 314.2300 314.3698 314.5096 314.6494 314.7892 314.9290 315.0687 315.2085 315.3482 315.4879 315.6276 315.7673 315.9070 316.0466 316.1863 316.3259 316.4656 316.6052 316.7448 316.8843 317.0239 317.1635 317.3030 317.4425 317.5821 317.7216 317.8611 318.0005 318.1400 318.2794 318.4189 318.5583 318.6977 318.8371 318.9765 319.1159 319.2552 319.3946 319.5339 319.6732 319.8125 319.9518 320.0911 320.2304 320.3696 320.5089 320.6481 320.7873 320.9265 321.0657 321.2049 321.3441 321.4832 321.6223 321.7615 321.9006 322.0397 322.1788 322.3178 322.4569 322.5960 322.7350 322.8740 323.0130 323.1520 323.2910 323.4300 323.5689 323.7079 323.8468 323.9857 324.1246 324.2635 324.4024 324.5413 324.6801 324.8190 324.9578 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20220923T130642.8Z 8301.546328 122 1 49.33 2 78.63 96.83 51.22 94.75 0.00 1 0.00 1 0 25 1.860e-01 6.806e-03 9.581e-02 1.915e-03 5.767074e-01 1.014427e-03 6.127691e-03 -6.000000e+00 1.076804e-01 228.10 -2.00 3.24 -2.00 320.58 0.00e+00 1.008943e-03 4.215387e-04 2.567142e-04 -6.000000e+00 5.111577e-03 292.96 -2.00 20.00 -2.00 319.81 0.00e+00 4.896 0.001 302.00 328.00 3 2.0348e+00 3.2701e-03 5.5947e-02 -6.0000e+00 2.6760e-01 -4.4732e-02 4.2647e-03 2.8043e-02 -6.0000e+00 2.9067e-01 6.2187e-03 3.9009e-03 1.3972e-02 -6.0000e+00 1.7257e-01 -1.0387e-02 1.9415e-03 4.3619e-03 -6.0000e+00 7.4201e-02 3.0553e-04 -5.1834e-04 5.4791e-05 4.7702e-05 -6.0000e+00 5.2553e-03 -4.1068e-03 9.1613e-05 11 9 0 11 8 0 2.67 24.71 0.40 -0.00411 -0.00800 116 25 1 5 0 425.140 27.15 20.00 24.71 34.08 27.4 999.56 900000 14866 -52311 900000 -138722 3496 900000 13317 900000 20308 -75211 37972 -53476 -8546 -26884 84120 3833 -7281 4400 -4332 3468 -28742 -6389 -18944 4441 -6448 -14214 -12840 -11167 -33356 18314 16710 1301 4054 -13035 12447 -3583 27478 -2531 -801 -7117 2832 3369 3894 3037 2360 -183 -5390 7364 -4981 4060 -1572 2799 1331 1789 674 1687 -3280 -117 -1292 -606 395 -824 2720 -246 1358 -454 659 807 1017 733 1156 601 -171 1703 -1103 -2349 -1825 -249 -818 -134 -1606 -1426 48 -596 -525 647 328 207 943 1160 1045 23 207 -405 554 -64 354 -65 -263 -82 -1068 -717 -1167 -231 -1243 -461 -1272 -98 1985 303 263 468 217 291 382 -332 -24 -601 -250 -920 254 -105 178 73 719 223 653 246 165 148 -193 -2 113 -99 -157 -157 91 78 -27 53 -150 -130 900000 52 -373 900000 -2032 13 900000 60 900000 106 -1041 205 -870 -114 -521 660 72 -167 97 -110 84 -957 -185 -680 139 -236 -564 -489 -417 -1669 665 718 73 231 -839 648 -244 1681 -248 -91 -947 367 454 533 427 341 -28 -879 1113 -902 749 -338 628 326 460 182 464 -941 -32 -356 -173 123 -290 1018 -97 512 -172 256 346 491 384 623 322 -88 800 -485 -992 -782 -117 -443 -82 -1103 -1047 36 -484 -450 572 297 187 821 954 815 18 162 -349 529 -69 414 -81 -323 -96 -1171 -745 -1238 -258 -1458 -561 -1636 -133 2868 472 423 749 337 434 554 -487 -36 -955 -409 -1510 405 -164 271 108 1034 316 946 386 279 265 -362 -3 226 -207 -340 -346 203 175 -59 112 -306 -261 SS 20220923T131245.0Z 8301.550521 125 1 49.36 2 77.33 97.62 49.95 95.60 0.00 1 0.00 1 0 25 2.549e-01 1.206e-02 4.722e-02 1.308e-03 5.227907e-01 6.756265e-04 5.661502e-03 -6.000000e+00 1.458827e-01 228.10 -2.00 3.24 -2.00 320.13 0.00e+00 3.773062e-03 2.390675e-04 9.452669e-04 -6.000000e+00 6.722745e-03 292.96 -2.00 20.00 -2.00 319.31 0.00e+00 4.431 0.001 302.00 328.00 3 1.8351e+00 2.0562e-03 5.0668e-02 -6.0000e+00 3.6142e-01 -1.0574e-02 2.5510e-03 2.5321e-02 -6.0000e+00 3.9179e-01 -5.1331e-02 2.1248e-03 1.3343e-02 -6.0000e+00 2.3479e-01 1.9705e-02 1.0877e-03 5.0340e-03 -6.0000e+00 1.0061e-01 6.0406e-04 -4.0844e-04 3.6963e-05 5.6090e-05 -6.0000e+00 6.9416e-03 -3.8611e-03 7.5728e-05 12 9 8 11 8 0 1.25 24.71 0.31 -0.00386 -0.00693 176 37 1 5 0 280.410 27.15 19.99 24.71 34.57 27.3 1002.34 -206288 20562 -2762 28132 -44542 -12957 85649 -32983 54899 -26489 -29069 -5239 -2389 7554 -6432 165508 16551 10727 11402 20835 6842 3332 -2040 6134 -1541 6527 -4653 2194 1454 -10466 11312 8397 12009 4868 1579 5810 2786 9678 2190 313 -365 1021 3335 920 4069 4115 1777 1449 3782 1480 3560 2830 2221 3044 1654 1828 682 -1385 405 268 983 683 1665 2752 1845 1273 958 -32 1187 672 330 636 257 310 210 -570 -2335 -1171 -1043 -766 -1360 -1053 -2043 -893 -1327 -1007 -392 194 319 368 782 631 248 -272 -548 -97 -86 111 73 -442 -276 -1097 -958 -1029 -944 -1136 -920 -626 -34 1300 340 512 265 331 189 284 237 -43 -49 -187 -561 177 460 538 616 518 392 1002 611 446 271 -11 -81 165 -53 -214 -258 188 -158 -201 -245 -300 -405 -11923 165 -29 206 -620 -132 358 -513 395 -455 -533 -87 -48 159 -191 1113 500 375 424 742 285 145 -98 295 -85 349 -279 118 79 -695 708 630 909 408 130 467 260 1011 301 52 -67 182 609 176 768 793 356 298 785 335 872 772 662 967 558 638 246 -507 143 95 362 261 710 1276 880 586 432 -15 610 373 201 399 159 182 120 -297 -1160 -583 -580 -466 -962 -788 -1670 -765 -1225 -935 -381 192 315 348 726 545 205 -232 -520 -99 -95 139 93 -560 -343 -1247 -1073 -1124 -1112 -1419 -1150 -832 -49 1936 531 829 424 529 283 408 343 -66 -79 -305 -918 279 735 829 908 771 565 1486 961 744 490 -19 -154 317 -108 -445 -552 408 -343 -424 -511 -596 -784 SS 20220923T131823.6Z 8301.554439 128 1 49.54 2 76.11 98.36 48.76 96.41 0.00 1 0.00 1 0 25 8.296e-02 4.807e-03 1.746e-02 9.419e-04 4.864131e-01 4.829410e-04 5.221140e-03 -6.000000e+00 4.748298e-02 228.10 -2.00 3.24 -2.00 319.74 0.00e+00 1.240579e-03 1.509741e-04 1.871638e-04 -6.000000e+00 2.188105e-03 292.96 -2.00 20.00 -2.00 318.89 0.00e+00 4.070 0.001 302.00 328.00 3 1.6425e+00 1.4151e-03 4.6670e-02 -6.0000e+00 1.1764e-01 -3.8221e-02 1.7132e-03 2.3549e-02 -6.0000e+00 1.2752e-01 8.8054e-04 1.3676e-03 1.1506e-02 -6.0000e+00 7.6421e-02 -6.3769e-03 7.1177e-04 3.6414e-03 -6.0000e+00 3.2749e-02 1.0802e-03 -2.5762e-04 2.6780e-05 3.7128e-05 -6.0000e+00 2.2593e-03 -4.2062e-03 7.1054e-05 10 0 0 10 0 0 8.46 24.70 0.31 -0.00421 -0.00614 252 53 1 5 0 196.490 27.15 19.99 24.70 35.08 27.3 1006.13 -63446 6962 -23934 -1681 -46547 -20564 -1849 -28609 2125 -19363 -18853 -10812 -12675 -5279 -3477 -447 3367 921 1083 -798 -1519 -4319 -4157 -2783 -3378 349 -5860 -2399 -3519 -5401 1753 2630 1978 1948 -4010 -1066 -2152 2867 -825 -1847 -1332 -556 482 -1221 1327 324 -438 -1123 737 -510 1173 507 506 1049 477 785 98 -215 -121 585 58 896 975 1790 754 396 119 -192 792 495 622 592 404 424 883 -104 -857 -1391 -758 -599 -1006 -1041 -1590 -909 -840 -588 -77 429 476 945 885 682 590 464 244 174 168 405 119 -390 -262 -946 -519 -760 -487 -948 -615 -545 -94 786 245 338 314 242 -68 265 67 -95 -225 -361 -555 -107 44 47 301 392 235 717 413 350 289 -64 104 91 -5 -124 -140 187 -65 -132 -103 -213 -199 -1302 87 -422 -22 -894 -309 -26 -597 37 -441 -444 -266 -358 -171 -134 -19 152 46 58 -46 -90 -265 -271 -195 -257 27 -480 -181 -264 -443 154 244 208 211 -439 -115 -266 407 -149 -367 -291 -128 115 -301 322 81 -111 -291 193 -143 357 171 185 383 184 313 40 -88 -49 232 24 410 499 930 402 201 63 -98 444 318 411 406 273 289 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