File name: Pandora25s1_HoustonTX_20221008_L2Fit_fout2c6d20220503p1-8.txt File generation date: 20250922T160857.6Z Data description: Level 2 spectral fitting results file Data file version: fout2c6p1-8 Local principal investigator: Jimmy Flynn Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 25 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora25_OF_v7d20190903.txt Instrument calibration file used: Pandora25s1_CF_v6d20220503.txt Level 1 file used: Pandora25s1_HoustonTX_20221008_L1_smca1c6d20220503p1-8.txt Full location name: University Of Houston Short location name: HoustonTX Country of location: United States Location latitude [deg]: 29.7200 Location longitude [deg]: -95.3400 Location altitude [m]: 19 Local noon date: 20221008 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Update session 4 for SO2 First and last pixel inside fitting window: 281 423 Nominal wavelengths inside fitting window [nm]: 305.1116 305.2524 305.3931 305.5338 305.6745 305.8152 305.9558 306.0965 306.2371 306.3777 306.5183 306.6589 306.7995 306.9401 307.0806 307.2212 307.3617 307.5022 307.6427 307.7832 307.9236 308.0641 308.2045 308.3449 308.4853 308.6257 308.7661 308.9065 309.0468 309.1872 309.3275 309.4678 309.6081 309.7484 309.8886 310.0289 310.1691 310.3093 310.4495 310.5897 310.7299 310.8701 311.0102 311.1504 311.2905 311.4306 311.5707 311.7108 311.8509 311.9909 312.1310 312.2710 312.4110 312.5510 312.6910 312.8310 312.9709 313.1109 313.2508 313.3907 313.5306 313.6705 313.8104 313.9503 314.0901 314.2300 314.3698 314.5096 314.6494 314.7892 314.9290 315.0687 315.2085 315.3482 315.4879 315.6276 315.7673 315.9070 316.0466 316.1863 316.3259 316.4656 316.6052 316.7448 316.8843 317.0239 317.1635 317.3030 317.4425 317.5821 317.7216 317.8611 318.0005 318.1400 318.2794 318.4189 318.5583 318.6977 318.8371 318.9765 319.1159 319.2552 319.3946 319.5339 319.6732 319.8125 319.9518 320.0911 320.2304 320.3696 320.5089 320.6481 320.7873 320.9265 321.0657 321.2049 321.3441 321.4832 321.6223 321.7615 321.9006 322.0397 322.1788 322.3178 322.4569 322.5960 322.7350 322.8740 323.0130 323.1520 323.2910 323.4300 323.5689 323.7079 323.8468 323.9857 324.1246 324.2635 324.4024 324.5413 324.6801 324.8190 324.9578 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20221008T130652.3Z 8316.546439 221 1 49.62 2 80.55 102.54 117.58 281.26 0.00 1 0.00 1 0 25 4.045e-01 8.559e-03 1.887e-01 2.843e-03 6.653838e-01 1.561110e-03 7.006754e-03 -6.000000e+00 2.348386e-01 227.33 -2.00 3.24 -2.00 321.22 0.00e+00 4.106481e-03 8.081155e-04 4.091996e-04 -6.000000e+00 1.163174e-02 291.85 -2.00 20.00 -2.00 320.56 0.00e+00 5.793 0.002 302.00 328.00 3 1.7896e+00 5.6263e-03 6.6050e-02 -6.0000e+00 5.8415e-01 -5.1601e-02 8.0266e-03 3.3762e-02 -6.0000e+00 6.3605e-01 -1.3845e-02 8.0765e-03 1.7817e-02 -6.0000e+00 3.7756e-01 2.7624e-03 3.8067e-03 8.5836e-03 -6.0000e+00 1.6389e-01 1.5522e-04 -8.9311e-04 8.1308e-05 8.0088e-05 -6.0000e+00 1.1492e-02 -6.8654e-03 1.2372e-04 11 8 0 10 0 0 97.65 25.05 0.50 -0.00687 -0.01358 89 19 1 5 0 557.440 27.45 20.00 25.05 27.19 26.7 962.72 900000 900000 -162970 900000 -217999 -25218 900000 -140722 900000 23217 -178430 900000 -113577 900000 -42646 -26063 86380 900000 50911 30866 66754 -13206 -26207 63430 -27301 452 -51091 -29056 -17185 -75424 127412 46269 9088 -10259 -17948 45748 -5524 116175 -4705 -1997 -6913 17440 20583 6048 13902 11575 -6727 -13207 11357 -7070 15449 -1934 2483 4332 2267 2558 3920 -9699 2897 -4163 1562 -3405 -1040 1753 -2036 539 2450 618 1480 2943 2454 2775 1234 483 3288 647 -6263 -43 -1213 762 702 -1588 -1880 1655 -585 -1900 119 -148 -218 1395 1334 600 348 -288 -1117 603 777 314 -485 -191 461 -1191 -928 -1404 158 -1071 -997 -948 288 142 229 559 518 -46 388 715 141 -205 -856 -749 -610 260 609 127 363 495 68 824 288 333 249 -75 -172 415 -245 -240 -268 253 -101 -336 472 -461 98 900000 900000 -1135 900000 -2373 -70 900000 -948 900000 64 -2297 900000 -1217 900000 -383 -239 302 900000 310 244 383 -168 -405 453 -509 7 -1295 -589 -317 -2722 798 769 249 -357 -651 927 -205 1633 -255 -125 -506 1097 1330 461 1013 891 -635 -1388 1007 -806 1603 -264 357 666 376 443 689 -1932 504 -771 288 -730 -248 456 -573 146 652 175 463 1035 945 1106 492 184 1128 207 -2038 -14 -440 318 339 -881 -1133 1023 -392 -1364 88 -112 -165 1010 913 392 223 -192 -837 507 738 335 -555 -218 497 -1198 -873 -1342 158 -1137 -1110 -1118 363 197 342 871 812 -71 571 1022 204 -309 -1355 -1221 -988 408 929 191 527 699 94 1178 454 573 460 -146 -348 874 -543 -552 -626 598 -239 -779 1046 -987 204 SS 20221008T131542.9Z 8316.552580 226 1 49.41 2 78.68 103.72 119.36 282.56 0.00 1 0.00 1 0 25 2.682e-01 5.847e-03 1.115e-01 1.423e-03 5.760233e-01 7.441163e-04 6.116093e-03 -6.000000e+00 1.531295e-01 227.33 -2.00 3.24 -2.00 320.55 0.00e+00 2.452574e-03 3.071320e-04 2.626872e-04 -6.000000e+00 7.036460e-03 291.85 -2.00 20.00 -2.00 319.81 0.00e+00 4.918 0.001 302.00 328.00 3 1.4528e+00 2.3708e-03 5.6106e-02 -6.0000e+00 3.7886e-01 -4.8733e-02 3.0728e-03 2.8090e-02 -6.0000e+00 4.1089e-01 3.4988e-03 2.8183e-03 1.4276e-02 -6.0000e+00 2.4622e-01 -8.3128e-03 1.4077e-03 5.4764e-03 -6.0000e+00 1.0566e-01 5.3611e-04 -3.3606e-04 3.9972e-05 5.3678e-05 -6.0000e+00 7.2980e-03 -7.4772e-03 1.6174e-04 10 0 0 10 0 0 17.28 25.06 0.36 -0.00748 -0.01000 206 44 1 5 0 239.810 27.45 20.00 25.06 27.82 27.1 966.66 -142622 -35541 -47039 -40006 -77926 -80506 67484 -80042 175752 -73192 -75033 -48564 -32410 -15191 -14192 -8833 -2315 21840 -14789 8298 -18630 -9625 -19205 -4628 -14351 -2828 -17852 -6601 -8006 -20701 7208 -110 4994 -5913 -5504 -2696 1858 10952 -3452 -3949 -2097 1819 1823 82 3072 3233 -2005 -806 -91 -761 1411 1698 8 2619 78 1348 1549 -1813 1312 -1031 981 -292 974 1297 886 256 976 -281 1153 1018 1391 1057 850 683 848 790 -2566 -496 -1085 -342 -1243 -1110 -1643 -542 -1018 -671 186 141 704 1057 1247 681 859 -294 -82 -53 2 402 206 -312 -167 -847 -834 -742 -749 -1053 -907 -783 -137 1404 220 260 300 208 67 238 72 -129 -362 -339 -522 -50 100 21 258 435 317 683 290 456 343 110 -61 231 -373 -89 -190 171 -82 -94 95 -225 -179 -2142 -211 -332 -252 -669 -721 153 -919 244 -961 -1061 -613 -442 -222 -256 -178 -49 402 -390 201 -556 -266 -624 -143 -530 -98 -731 -234 -288 -929 291 -6 280 -386 -344 -167 124 808 -335 -458 -267 239 252 12 438 473 -316 -129 -15 -137 278 372 2 627 20 361 425 -513 352 -282 276 -93 345 510 361 101 379 -114 516 490 732 580 461 351 399 359 -1132 -218 -540 -186 -792 -752 -1218 -422 -855 -600 164 127 632 964 1058 542 656 -234 -73 -51 2 475 262 -397 -198 -971 -889 -806 -829 -1238 -1125 -1038 -187 2092 346 427 491 327 100 355 108 -194 -580 -568 -872 -81 156 32 392 635 449 1000 452 793 620 211 -117 468 -780 -195 -428 391 -189 -208 199 -471 -365 SS 20221008T132144.2Z 8316.556762 229 1 49.47 2 77.41 104.53 120.57 283.47 0.00 1 0.00 1 0 25 1.006e-01 4.888e-03 2.606e-02 1.002e-03 5.294381e-01 5.166944e-04 5.665561e-03 -6.000000e+00 5.742209e-02 227.33 -2.00 3.24 -2.00 320.11 0.00e+00 1.578418e-03 1.838141e-04 2.605618e-04 -6.000000e+00 2.656126e-03 291.85 -2.00 20.00 -2.00 319.31 0.00e+00 4.459 0.001 302.00 328.00 3 1.3156e+00 1.5658e-03 5.1009e-02 -6.0000e+00 1.4206e-01 -4.4750e-02 1.9491e-03 2.5557e-02 -6.0000e+00 1.5411e-01 4.5154e-03 1.6724e-03 1.2733e-02 -6.0000e+00 9.2364e-02 -8.4610e-03 8.5847e-04 4.1529e-03 -6.0000e+00 3.9885e-02 9.9108e-04 -2.9355e-04 2.8274e-05 4.3365e-05 -6.0000e+00 2.7504e-03 -7.4533e-03 1.3156e-04 10 0 0 10 0 0 1.49 25.06 0.32 -0.00745 -0.00966 294 62 1 5 0 168.210 27.45 20.01 25.06 28.30 26.9 968.67 900000 -35258 -33713 -13842 -46422 -52239 -24077 -35066 3601 -28370 -39618 -14771 -27378 -3389 -15900 856 -2830 6110 -9941 -560 -6402 -6941 -6489 -3459 -3659 -3094 -8151 -7328 -117 -13190 3924 773 200 -3975 -5628 -2010 -3311 4283 -3256 -1399 -2611 1135 283 310 227 1028 -1103 -1116 35 -336 1518 655 1180 1438 416 603 1012 -1017 1053 -269 567 161 995 1642 928 747 384 151 473 1180 677 859 254 486 600 19 -1196 -920 -733 -622 -831 -1159 -1401 -937 -657 -621 176 52 669 790 1116 745 438 169 25 235 254 387 69 -232 -366 -734 -835 -845 -876 -1146 -714 -705 -20 1005 350 337 411 179 81 175 119 -157 -240 -430 -463 -112 181 126 292 409 140 754 418 391 193 36 -127 97 -5 -160 -180 79 -3 -117 34 -257 -122 900000 -371 -367 -127 -548 -612 -257 -445 38 -409 -670 -223 -584 -71 -465 25 -94 202 -416 -23 -280 -309 -284 -161 -185 -164 -458 -393 -6 -802 235 56 16 -355 -489 -171 -323 467 -439 -219 -461 206 54 61 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