File name: Pandora66s1_HuntsvilleAL_20200514_L2Fit_fout2c3d20200122p1-8.txt File generation date: 20251117T154744.5Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: Nader Abuhassan Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 66 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora66_OF_v3d20200114.txt Instrument calibration file used: Pandora66s1_CF_v3d20200122.txt Level 1 file used: Pandora66s1_HuntsvilleAL_20200514_L1_smca1c3d20200122p1-8.txt Full location name: The University of Alabama in Huntsville- SWIRLL Short location name: HuntsvilleAL Country of location: United States Location latitude [deg]: 34.7252 Location longitude [deg]: -86.6464 Location altitude [m]: 221 Local noon date: 20200514 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Modification of session 1, fieldcal refday 20200921 First and last pixel inside fitting window: 253 395 Nominal wavelengths inside fitting window [nm]: 305.1019 305.2425 305.3831 305.5238 305.6644 305.8050 305.9456 306.0862 306.2268 306.3673 306.5079 306.6484 306.7890 306.9295 307.0700 307.2105 307.3510 307.4914 307.6319 307.7723 307.9128 308.0532 308.1936 308.3340 308.4744 308.6148 308.7551 308.8955 309.0358 309.1762 309.3165 309.4568 309.5971 309.7374 309.8777 310.0179 310.1582 310.2984 310.4386 310.5789 310.7191 310.8593 310.9994 311.1396 311.2798 311.4199 311.5600 311.7002 311.8403 311.9804 312.1205 312.2605 312.4006 312.5407 312.6807 312.8207 312.9607 313.1007 313.2407 313.3807 313.5207 313.6606 313.8006 313.9405 314.0805 314.2204 314.3603 314.5002 314.6400 314.7799 314.9197 315.0596 315.1994 315.3392 315.4790 315.6188 315.7586 315.8984 316.0381 316.1779 316.3176 316.4573 316.5970 316.7367 316.8764 317.0161 317.1558 317.2954 317.4351 317.5747 317.7143 317.8539 317.9935 318.1331 318.2727 318.4122 318.5518 318.6913 318.8308 318.9703 319.1098 319.2493 319.3888 319.5282 319.6677 319.8071 319.9465 320.0860 320.2254 320.3647 320.5041 320.6435 320.7828 320.9222 321.0615 321.2008 321.3401 321.4794 321.6187 321.7580 321.8972 322.0365 322.1757 322.3149 322.4542 322.5934 322.7325 322.8717 323.0109 323.1500 323.2892 323.4283 323.5674 323.7065 323.8456 323.9847 324.1238 324.2628 324.4019 324.5409 324.6799 324.8189 324.9579 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SU 20200514T120939.4Z 7439.506706 731 1 14.75 2 74.09 77.85 53.22 181.74 0.00 1 0.00 1 0 17 1.964e-01 1.513e-02 1.377e-01 7.066e-03 5.068130e-01 3.674440e-03 5.605045e-03 -6.000000e+00 1.149809e-01 231.18 -2.00 3.38 -2.00 319.55 0.00e+00 2.304211e-03 1.068912e-03 4.397784e-04 -6.000000e+00 5.338872e-03 286.21 -2.00 20.00 -2.00 318.82 0.00e+00 3.586 0.001 302.00 328.00 3 4.4548e+00 1.0533e-02 4.3510e-02 -6.0000e+00 2.8764e-01 1.0959e-01 1.2474e-02 2.5699e-02 -6.0000e+00 3.1127e-01 -4.3656e-02 9.8913e-03 1.2881e-02 -6.0000e+00 1.8527e-01 8.5127e-03 5.1629e-03 4.5625e-03 -6.0000e+00 7.8416e-02 9.6217e-05 8.8123e-04 2.0238e-04 4.8608e-05 -6.0000e+00 5.5620e-03 -1.4482e-02 0.0000e+00 12 9 9 12 41 1 95.14 26.32 -0.11 -0.01448 -0.00786 3 3 1 5 0 3642.470 26.32 20.00 23.03 27.51 24.2 994.90 -86724 -29519 -16772 -38681 -50432 -42232 30083 131995 -12358 20089 900000 -25267 22907 -5788 -30832 -24011 -33546 5979 14736 48951 -12893 -4411 -15618 1019 76449 13334 -14188 10067 -34182 45946 -13754 23990 -4346 4099 -7639 13223 9694 -11082 -3755 -28 1826 9441 -23 8621 -367 5172 3593 604 3839 -6535 5542 -5751 16805 1028 4754 1744 418 -5283 -3059 -3759 -1350 -2433 8009 2601 1536 -3533 -392 -2249 154 626 251 2433 -1523 305 229 656 -1277 -2215 -652 -253 71 -1032 -2809 323 -1768 -660 -322 164 -779 716 -589 1244 6890 992 -1582 -87 943 1711 -613 5 -1205 -632 -102 -2191 -84 -1108 -646 -1146 683 -206 1000 1434 1439 -489 -503 -1707 859 326 3 -780 -206 -571 1443 -1108 873 54 1201 539 1270 -1085 117 -257 -288 -40 -849 79 871 214 734 -42 161 -486 -1011 -2706 -623 -325 -883 -1124 -927 373 909 -277 346 900000 -758 552 -216 -1688 -1415 -2388 330 794 1964 -923 -292 -1220 73 2881 934 -1314 701 -3637 2495 -1474 2020 -546 489 -980 1397 1187 -1877 -718 -6 428 2177 -6 2129 -100 1356 964 169 1070 -2028 1672 -2132 5372 413 1928 752 178 -2357 -1304 -1607 -588 -1173 3884 1453 881 -2039 -214 -1275 89 411 180 1773 -1088 212 146 392 -723 -1267 -404 -173 53 -877 -2515 296 -1772 -669 -341 177 -847 733 -589 1135 5887 911 -1567 -92 1088 2205 -828 6 -1512 -746 -115 -2595 -101 -1414 -832 -1578 959 -308 1599 2362 2332 -767 -765 -2505 1233 492 4 -1274 -334 -906 2249 -1698 1250 77 1646 766 1898 -1761 195 -454 -511 -75 -1639 159 1723 433 1477 -84 307 -919 -1868 SU 20200514T121132.3Z 7439.508013 733 1 16.57 2 73.72 78.10 53.23 182.29 0.00 1 0.00 1 0 17 9.175e-02 5.826e-03 4.402e-02 2.435e-03 4.918334e-01 1.261850e-03 5.479138e-03 -6.000000e+00 5.364818e-02 231.18 -2.00 3.38 -2.00 319.34 0.00e+00 1.313134e-03 3.397480e-04 1.959579e-04 -6.000000e+00 2.377457e-03 286.21 -2.00 20.00 -2.00 318.58 0.00e+00 3.507 0.001 302.00 328.00 3 2.9852e+00 3.5731e-03 4.2462e-02 -6.0000e+00 1.3418e-01 3.1828e-02 4.1911e-03 2.4998e-02 -6.0000e+00 1.4523e-01 -6.6299e-03 3.2415e-03 1.2224e-02 -6.0000e+00 8.6470e-02 -7.3366e-03 1.7009e-03 3.6881e-03 -6.0000e+00 3.6451e-02 4.7826e-04 -6.3423e-04 6.9608e-05 3.8939e-05 -6.0000e+00 2.5816e-03 -6.6067e-03 0.0000e+00 12 1 1 12 9 1 80.16 26.32 0.22 -0.00661 -0.01137 23 15 1 5 0 683.290 26.32 20.00 23.03 27.49 24.2 994.84 -47920 60128 -7531 -27660 -6163 -11584 22166 41869 -21182 -20182 16223 -11151 -12617 -5498 -13563 -9080 -8365 -3017 2423 -2741 8078 -8504 -717 -143 11261 -4573 -5022 934 -7206 5730 210 3056 -1906 -1882 -785 -2025 1934 -2790 -1767 -1535 -1192 479 -136 -999 3518 1003 400 -340 -1463 -649 848 -531 3556 1188 748 709 108 -756 -667 -506 594 732 2239 1600 193 -179 143 529 778 -158 163 1351 -176 339 713 -501 -444 -745 -1182 -536 -1453 -675 -1694 -650 -1441 -699 -453 92 519 410 702 713 884 747 607 968 690 838 -6 -77 -731 -989 -416 -631 -459 -911 -416 -654 245 -220 -76 92 301 -264 477 -282 372 761 66 -411 -261 -1 346 98 395 184 572 640 456 -94 -37 -214 202 -158 -183 -22 94 213 -247 -8 230 -262 -413 -1164 560 -144 -616 -102 -205 308 543 -580 -586 341 -346 -449 -224 -722 -533 -535 -198 162 -202 547 -686 -57 -12 915 -458 -508 85 -698 520 23 348 -256 -263 -104 -275 283 -508 -364 -373 -319 134 -40 -302 1026 304 123 -107 -476 -221 293 -205 1422 524 328 322 51 -355 -306 -231 279 376 1262 939 117 -104 80 303 486 -107 121 1033 -135 246 498 -319 -262 -440 -769 -381 -1197 -590 -1545 -620 -1422 -730 -496 103 577 437 724 683 839 684 608 1049 818 1072 -7 -100 -938 -1211 -472 -732 -572 -1155 -553 -891 356 -339 -121 147 488 -409 713 -404 531 1130 102 -664 -423 -1 527 149 570 265 792 910 685 -150 -62 -376 355 -292 -349 -42 186 431 -486 -16 440 -482 -765 SU 20200514T121334.7Z 7439.509429 735 1 49.36 2 73.31 78.36 53.25 182.88 0.00 1 0.00 1 0 17 4.905e-02 4.605e-03 5.117e-03 4.259e-04 4.815175e-01 2.204001e-04 5.372078e-03 -6.000000e+00 2.867926e-02 231.18 -2.00 3.38 -2.00 319.17 0.00e+00 8.656657e-04 5.583872e-05 1.838708e-04 -6.000000e+00 1.270959e-03 286.21 -2.00 20.00 -2.00 318.40 0.00e+00 3.426 0.001 302.00 328.00 3 8.0944e-01 6.1797e-04 4.1492e-02 -6.0000e+00 7.1732e-02 1.0457e-02 7.1949e-04 2.4410e-02 -6.0000e+00 7.7637e-02 -1.7752e-02 5.3880e-04 1.1888e-02 -6.0000e+00 4.6225e-02 -7.9969e-04 2.8274e-04 3.4296e-03 -6.0000e+00 1.9486e-02 4.6908e-03 -5.8793e-04 1.2230e-05 3.7223e-05 -6.0000e+00 1.3801e-03 -6.4824e-03 0.0000e+00 10 0 0 10 0 0 92.94 26.32 0.21 -0.00648 -0.01090 744 159 1 5 0 66.330 26.32 20.00 23.03 27.47 24.2 995.01 -18294 -11527 -15215 -20926 -22232 -19735 -16769 -13202 -14865 -13852 -10583 -10242 -7948 -4250 -2380 -2090 -2712 -471 560 724 6 -536 -362 -262 498 -1225 -1840 -1778 -2001 392 870 1713 874 -1148 -2247 -1902 -1524 -1049 -306 -787 -1040 -519 -699 -421 280 -196 -469 -528 -494 335 814 625 1406 920 782 798 497 55 242 253 865 1335 1932 1298 295 147 181 96 921 644 296 252 -39 -36 -114 -272 -319 -379 -342 -570 -833 -1058 -1760 -1197 -923 -617 -169 167 300 565 584 644 385 778 569 355 459 523 -64 -341 -377 -545 -112 -126 -722 -931 -581 -572 -128 21 97 41 96 24 207 385 457 243 111 -288 -341 -65 155 102 404 207 538 947 503 118 48 -213 -117 -104 -177 -84 100 252 -138 -69 -16 -249 -327 -413 -273 -391 -539 -536 -468 -424 -367 -472 -466 -358 -351 -322 -203 -134 -134 -192 -35 44 60 1 -47 -33 -26 52 -138 -210 -194 -213 43 100 221 128 -178 -336 -288 -257 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