File name: Pandora66s1_HuntsvilleAL_20200515_L2Fit_fout2c3d20200122p1-8.txt File generation date: 20251117T154936.4Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: Nader Abuhassan Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 66 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora66_OF_v3d20200114.txt Instrument calibration file used: Pandora66s1_CF_v3d20200122.txt Level 1 file used: Pandora66s1_HuntsvilleAL_20200515_L1_smca1c3d20200122p1-8.txt Full location name: The University of Alabama in Huntsville- SWIRLL Short location name: HuntsvilleAL Country of location: United States Location latitude [deg]: 34.7252 Location longitude [deg]: -86.6464 Location altitude [m]: 221 Local noon date: 20200515 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Modification of session 1, fieldcal refday 20200921 First and last pixel inside fitting window: 253 395 Nominal wavelengths inside fitting window [nm]: 305.1019 305.2425 305.3831 305.5238 305.6644 305.8050 305.9456 306.0862 306.2268 306.3673 306.5079 306.6484 306.7890 306.9295 307.0700 307.2105 307.3510 307.4914 307.6319 307.7723 307.9128 308.0532 308.1936 308.3340 308.4744 308.6148 308.7551 308.8955 309.0358 309.1762 309.3165 309.4568 309.5971 309.7374 309.8777 310.0179 310.1582 310.2984 310.4386 310.5789 310.7191 310.8593 310.9994 311.1396 311.2798 311.4199 311.5600 311.7002 311.8403 311.9804 312.1205 312.2605 312.4006 312.5407 312.6807 312.8207 312.9607 313.1007 313.2407 313.3807 313.5207 313.6606 313.8006 313.9405 314.0805 314.2204 314.3603 314.5002 314.6400 314.7799 314.9197 315.0596 315.1994 315.3392 315.4790 315.6188 315.7586 315.8984 316.0381 316.1779 316.3176 316.4573 316.5970 316.7367 316.8764 317.0161 317.1558 317.2954 317.4351 317.5747 317.7143 317.8539 317.9935 318.1331 318.2727 318.4122 318.5518 318.6913 318.8308 318.9703 319.1098 319.2493 319.3888 319.5282 319.6677 319.8071 319.9465 320.0860 320.2254 320.3647 320.5041 320.6435 320.7828 320.9222 321.0615 321.2008 321.3401 321.4794 321.6187 321.7580 321.8972 322.0365 322.1757 322.3149 322.4542 322.5934 322.7325 322.8717 323.0109 323.1500 323.2892 323.4283 323.5674 323.7065 323.8456 323.9847 324.1238 324.2628 324.4019 324.5409 324.6799 324.8189 324.9579 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SU 20200515T114240.1Z 7440.487964 1050 1 8.11 2 79.35 74.12 51.81 159.79 0.00 1 0.00 1 0 25 4.382e-01 2.040e-02 2.415e-01 1.074e-02 7.025292e-01 5.917289e-03 7.839244e-03 -6.000000e+00 2.601537e-01 231.24 -2.00 3.38 -2.00 320.95 0.00e+00 2.325654e-03 2.696736e-03 3.161883e-03 -6.000000e+00 1.286663e-02 286.30 -2.00 20.00 -2.00 320.32 0.00e+00 5.204 0.002 302.00 328.00 3 2.9212e+00 1.9603e-02 6.3995e-02 -6.0000e+00 6.5067e-01 2.2431e-01 2.6021e-02 4.1067e-02 -6.0000e+00 7.0576e-01 -2.6795e-01 2.4341e-02 1.9781e-02 -6.0000e+00 4.1690e-01 1.0539e-01 1.1703e-02 5.1940e-03 -6.0000e+00 1.7661e-01 8.1414e-05 -1.1937e-03 3.0231e-04 8.6221e-05 -6.0000e+00 1.2610e-02 -4.6527e-03 0.0000e+00 12 9 9 12 1 1 -2.36 26.41 -0.01 -0.00465 -0.01362 4 7 1 5 0 1587.950 26.41 20.00 23.12 29.19 23.5 1000.37 -217061 900000 900000 -119809 -127719 900000 -65004 900000 -198397 -182314 900000 -128185 -109707 -41304 -62361 -85602 -61109 -57487 -18535 52628 900000 -30085 -54539 -42316 900000 56800 -4875 21227 -72900 12339 -11992 36367 -18909 27859 44932 -1821 51363 -46719 6863 16685 14207 55358 44302 48082 79593 16719 21651 5252 10664 1830 17328 5270 19351 13346 11465 2406 -6242 -1641 6549 6656 4047 617 18444 15079 2900 -1259 1861 -4548 1565 -1051 -4394 5624 -1113 -564 8534 -1804 953 -6239 -5565 -2499 2645 36 -2667 846 1071 -171 914 -653 -3220 2576 -1647 2732 -7207 155 -121 4461 -925 -467 -1887 -97 -556 -1957 -1804 -3153 -275 -1315 -624 -1411 645 -248 -314 614 1493 228 236 -1782 2401 1382 -1263 122 -96 316 1898 1801 912 -1345 1103 806 1125 35 -141 -172 -56 206 -1179 -21 398 -2 639 -338 320 -168 -1495 -5533 900000 900000 -1420 -1514 900000 -680 900000 -6224 -5243 900000 -2681 -2438 -633 -1386 -2853 -1797 -1803 -424 660 900000 -826 -2032 -1521 900000 911 -137 474 -3677 315 -470 1046 -1024 1056 1380 -90 1678 -4569 481 1262 1232 3405 3188 3401 4422 1676 2118 630 1279 246 2366 857 3002 2396 2225 533 -1545 -384 1370 1373 891 156 4436 4205 904 -402 578 -1574 567 -448 -2019 2554 -531 -251 3147 -663 322 -2335 -2346 -1214 1358 22 -1807 588 758 -130 721 -536 -2703 1957 -1215 1905 -5147 113 -95 3874 -940 -518 -2294 -115 -622 -2101 -1772 -3156 -287 -1460 -697 -1712 843 -352 -475 975 2361 354 363 -2686 3500 2128 -2026 200 -156 491 2915 2664 1304 -1900 1547 1137 1783 61 -260 -327 -112 422 -2611 -48 901 -5 1456 -745 680 -350 -3057 SU 20200515T121858.4Z 7440.513176 1644 1 6.88 2 72.10 78.85 49.83 170.64 0.00 1 0.00 1 0 17 2.891e-01 1.645e-02 1.786e-01 1.033e-02 4.532042e-01 5.341063e-03 5.199630e-03 -6.000000e+00 1.691019e-01 231.24 -2.00 3.38 -2.00 319.07 0.00e+00 -2.288797e-03 1.307779e-03 1.162659e-03 -6.000000e+00 7.494113e-03 286.30 -2.00 20.00 -2.00 318.30 0.00e+00 3.209 0.000 302.00 328.00 3 4.5677e+00 1.4913e-02 3.9465e-02 -6.0000e+00 4.2300e-01 5.0818e-02 1.7331e-02 2.4985e-02 -6.0000e+00 4.5776e-01 -3.5317e-03 1.2740e-02 1.1219e-02 -6.0000e+00 2.7256e-01 -1.1787e-02 6.6721e-03 4.2738e-03 -6.0000e+00 1.1492e-01 1.3578e-04 -1.1404e-03 3.0008e-04 3.7261e-05 -6.0000e+00 8.1335e-03 -8.0408e-03 0.0000e+00 12 9 9 12 33 1 999.00 26.32 -0.45 -0.00804 -0.01661 1 3 1 5 0 3352.440 26.32 20.00 23.10 29.19 23.7 1001.47 -42501 105293 51048 -25807 37241 -15829 1891 154870 13088 6727 248136 -52624 17460 -20205 19184 -30612 12634 -26866 17651 -11174 28643 -11427 -20166 -5775 -22176 1230 -15139 8935 -9326 21240 -2938 4721 7408 6078 -5280 5792 13449 -3563 -9013 4557 1827 4797 3092 13802 11556 -2741 2402 628 -879 -1247 -3230 -1995 -7277 4345 -1530 6447 -6487 1928 -291 3089 -4134 391 3265 1968 967 144 414 3788 623 130 -816 3436 3760 -2157 4009 -87 -681 -4248 -1653 -387 -1493 25 -1619 -789 290 -579 977 -1565 487 -82 1018 2366 -6232 -455 -581 520 153 1482 -1329 1151 -837 -1767 -909 -2381 -541 310 -913 183 -858 697 -262 888 1716 -140 -1398 -817 -237 2439 -762 810 1841 -190 220 314 806 234 95 243 1935 -758 50 -209 95 -752 -52 170 417 281 -272 -728 -20 -459 -300 -1385 1485 857 -780 625 -429 48 1560 387 215 2500 -3269 673 -1278 1023 -2878 834 -2678 1265 -1119 1972 -1190 -2310 -628 -3069 142 -2071 960 -1088 1997 -372 623 1061 915 -851 845 2032 -759 -2356 1233 563 1520 984 4185 3586 -939 818 208 -300 -446 -1285 -858 -3396 1940 -762 3073 -3612 984 -148 1505 -2236 219 1881 1245 626 89 247 2212 409 93 -649 2730 2954 -1713 2875 -59 -424 -2700 -1107 -282 -1205 23 -1524 -778 292 -628 1095 -1784 543 -91 1042 2296 -6208 -428 -592 569 183 1893 -1800 1501 -1083 -2189 -1043 -2823 -678 393 -1231 250 -1225 1066 -422 1414 2745 -216 -2105 -1161 -346 3488 -1159 1275 2891 -297 344 472 1184 331 130 337 2872 -1183 83 -354 166 -1350 -96 320 803 554 -539 -1403 -38 -828 -541 SU 20200515T122110.0Z 7440.514699 1646 1 49.98 2 71.66 79.14 49.76 171.32 0.00 1 0.00 1 0 17 5.550e-02 5.460e-03 1.647e-02 1.422e-03 4.414865e-01 7.359682e-04 4.938408e-03 -6.000000e+00 3.246009e-02 231.24 -2.00 3.38 -2.00 319.17 0.00e+00 8.123086e-04 1.862464e-04 1.664658e-04 -6.000000e+00 1.438691e-03 286.30 -2.00 20.00 -2.00 318.40 0.00e+00 3.136 0.000 302.00 328.00 3 3.3331e+00 2.0628e-03 3.8027e-02 -6.0000e+00 8.1197e-02 2.2222e-02 2.3996e-03 2.2408e-02 -6.0000e+00 8.7874e-02 3.9013e-03 1.7750e-03 1.0903e-02 -6.0000e+00 5.2321e-02 -1.0361e-02 9.2892e-04 3.1190e-03 -6.0000e+00 2.2057e-02 5.0948e-04 -6.2828e-04 4.1628e-05 3.4176e-05 -6.0000e+00 1.5615e-03 -7.0941e-03 0.0000e+00 10 0 0 10 0 0 99.96 26.41 0.23 -0.00709 -0.01182 134 29 1 5 0 370.150 26.41 20.00 23.10 29.15 23.8 1001.62 -31147 16669 -8004 -10006 -29702 -5944 -19747 10395 -25488 -7150 1644 -7892 -14750 800 -8938 -4009 -7565 1059 724 4336 -454 -54 -512 -558 5582 -874 -2622 332 -4487 6593 203 2171 382 -2721 336 -1076 1522 -3920 -896 -3324 -129 3 -7 -386 3134 -694 35 -799 14 -1922 866 -87 3232 736 1109 876 143 -717 180 211 664 1133 2108 1370 279 -420 258 -32 457 299 -426 544 -158 358 180 -2 -98 107 -667 8 -779 -326 -2125 -859 -1250 -618 -245 158 -102 621 731 657 203 958 438 692 543 786 -1 -376 -364 -872 -126 -619 -350 -1056 -459 -724 153 -187 71 52 373 19 89 -99 669 302 111 -296 -327 -75 291 41 473 151 541 794 649 25 31 -320 -64 -94 -223 -38 130 271 55 36 -223 -182 -414 -901 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