File name: Pandora66s1_HuntsvilleAL_20200701_L2Fit_fout2c3d20200122p1-8.txt File generation date: 20251117T155850.1Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: Nader Abuhassan Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 66 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora66_OF_v3d20200114.txt Instrument calibration file used: Pandora66s1_CF_v3d20200122.txt Level 1 file used: Pandora66s1_HuntsvilleAL_20200701_L1_smca1c3d20200122p1-8.txt Full location name: The University of Alabama in Huntsville- SWIRLL Short location name: HuntsvilleAL Country of location: United States Location latitude [deg]: 34.7252 Location longitude [deg]: -86.6464 Location altitude [m]: 221 Local noon date: 20200701 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Modification of session 1, fieldcal refday 20200921 First and last pixel inside fitting window: 253 395 Nominal wavelengths inside fitting window [nm]: 305.1019 305.2425 305.3831 305.5238 305.6644 305.8050 305.9456 306.0862 306.2268 306.3673 306.5079 306.6484 306.7890 306.9295 307.0700 307.2105 307.3510 307.4914 307.6319 307.7723 307.9128 308.0532 308.1936 308.3340 308.4744 308.6148 308.7551 308.8955 309.0358 309.1762 309.3165 309.4568 309.5971 309.7374 309.8777 310.0179 310.1582 310.2984 310.4386 310.5789 310.7191 310.8593 310.9994 311.1396 311.2798 311.4199 311.5600 311.7002 311.8403 311.9804 312.1205 312.2605 312.4006 312.5407 312.6807 312.8207 312.9607 313.1007 313.2407 313.3807 313.5207 313.6606 313.8006 313.9405 314.0805 314.2204 314.3603 314.5002 314.6400 314.7799 314.9197 315.0596 315.1994 315.3392 315.4790 315.6188 315.7586 315.8984 316.0381 316.1779 316.3176 316.4573 316.5970 316.7367 316.8764 317.0161 317.1558 317.2954 317.4351 317.5747 317.7143 317.8539 317.9935 318.1331 318.2727 318.4122 318.5518 318.6913 318.8308 318.9703 319.1098 319.2493 319.3888 319.5282 319.6677 319.8071 319.9465 320.0860 320.2254 320.3647 320.5041 320.6435 320.7828 320.9222 321.0615 321.2008 321.3401 321.4794 321.6187 321.7580 321.8972 322.0365 322.1757 322.3149 322.4542 322.5934 322.7325 322.8717 323.0109 323.1500 323.2892 323.4283 323.5674 323.7065 323.8456 323.9847 324.1238 324.2628 324.4019 324.5409 324.6799 324.8189 324.9579 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SU 20200701T130355.1Z 7487.544388 4007 1 50.21 2 62.56 79.82 152.97 309.20 0.00 1 0.00 1 0 17 7.254e-02 1.760e-02 1.756e-02 4.208e-03 2.930225e-01 2.162312e-03 3.362557e-03 -6.000000e+00 4.258099e-02 232.27 -2.00 3.38 -2.00 317.78 0.00e+00 1.117131e-03 3.612442e-04 1.583028e-04 -6.000000e+00 1.914250e-03 290.49 -2.00 20.00 -2.00 316.89 0.00e+00 2.158 0.000 302.00 328.00 3 6.2767e+00 5.8193e-03 2.5889e-02 -6.0000e+00 1.0663e-01 8.3245e-02 6.5829e-03 1.4913e-02 -6.0000e+00 1.1523e-01 1.1566e-02 4.0208e-03 7.2274e-03 -6.0000e+00 6.8728e-02 -8.3978e-03 2.0120e-03 2.0982e-03 -6.0000e+00 2.9021e-02 8.0211e-05 -2.9197e-04 1.2444e-04 2.3524e-05 -6.0000e+00 2.0423e-03 -4.3127e-03 0.0000e+00 12 9 8 11 8 0 99.97 26.41 -0.18 -0.00431 -0.00651 21 4 1 5 0 2390.650 26.41 20.00 23.17 30.02 28.1 973.26 -16864 47543 11399 10947 -17633 7377 -6297 27828 -5592 -7541 33580 -15328 -4112 626 1678 -15309 -5894 1282 5312 6874 3160 -11773 -7980 -1525 17694 -6219 -3094 2575 -4803 5840 -4333 1193 983 1800 2255 -3902 8885 -5583 -2576 -2119 -1320 4476 356 3074 9185 891 -1672 -384 -721 -5929 -766 -1714 12225 4077 2226 1866 492 -3197 -209 -605 -1053 -1420 5881 1104 -436 -1979 1252 -2325 -809 -1643 -1815 2775 233 -460 3098 -2707 -3036 -4528 -2287 -157 -1738 -1352 -2855 1020 -750 -729 1182 38 -243 1593 847 1512 -935 1305 -1647 2661 210 1705 1360 217 -689 -2200 -1458 -3342 1860 -1556 -378 -694 1447 628 1604 1621 1643 -761 -1757 -1920 1338 -343 -1173 -90 359 -739 1041 -221 1118 -1092 -125 511 735 43 -844 108 694 -1301 -796 -137 647 993 885 791 -414 -859 -938 -1645 2805 919 819 -1588 543 -538 2006 -583 -834 2610 -1943 -533 90 272 -3051 -1122 252 1046 1381 629 -2714 -1834 -347 3682 -1604 -766 598 -1136 1260 -1054 298 267 490 574 -1063 2362 -2008 -1075 -964 -646 2158 184 1560 4384 461 -873 -194 -362 -3193 -417 -1008 6623 2526 1448 1242 337 -2252 -140 -408 -740 -1026 4294 895 -354 -1511 918 -1748 -612 -1412 -1698 2571 220 -418 2507 -2085 -2252 -3293 -1726 -124 -1569 -1340 -2914 1052 -844 -876 1395 47 -299 1925 951 1541 -948 1267 -1751 2856 258 2175 1828 289 -868 -2717 -1693 -4087 2332 -2030 -510 -986 2120 947 2520 2572 2511 -1161 -2493 -2574 1816 -471 -1739 -134 540 -1108 1559 -320 1515 -1508 -163 669 1026 62 -1287 169 1098 -2086 -1346 -241 1160 1737 1554 1409 -717 -1442 -1540 SU 20200701T130543.0Z 7487.545636 4009 1 49.90 2 62.20 80.04 153.24 309.87 0.00 1 0.00 1 0 17 1.038e-02 5.201e-03 3.936e-03 1.050e-03 2.823711e-01 5.410665e-04 3.238850e-03 -6.000000e+00 6.093673e-03 232.27 -2.00 3.38 -2.00 317.70 0.00e+00 1.644255e-04 8.750275e-05 7.176776e-05 -6.000000e+00 2.738629e-04 290.49 -2.00 20.00 -2.00 316.80 0.00e+00 2.133 0.000 302.00 328.00 3 3.7481e+00 1.4536e-03 2.5353e-02 -6.0000e+00 1.5260e-02 1.2900e-02 1.6404e-03 1.4364e-02 -6.0000e+00 1.6489e-02 1.9744e-02 9.9547e-04 6.9166e-03 -6.0000e+00 9.8347e-03 -1.4819e-02 4.9454e-04 1.8765e-03 -6.0000e+00 4.1545e-03 1.0922e-03 -2.4479e-04 3.1305e-05 2.2238e-05 -6.0000e+00 2.9214e-04 -6.8116e-03 0.0000e+00 10 0 0 10 0 0 99.98 26.41 0.22 -0.00681 -0.00865 393 84 1 5 0 125.660 26.41 20.00 23.17 30.11 28.2 973.89 -2113 680 -240 -4310 -751 821 849 4312 3842 -1932 3166 -1872 187 291 1291 -1960 4 -101 380 746 577 -665 235 340 1217 203 -908 728 108 2400 941 1746 1230 -374 -1811 -511 -593 -955 -878 -1111 -1830 -600 -1519 -925 -253 -902 -1305 -706 -1364 62 335 390 1404 1135 745 1042 415 41 315 586 739 1015 1700 751 -106 -559 176 -57 1012 458 54 43 171 50 525 -113 47 -163 305 -382 -849 -1081 -1779 -940 -713 -582 0 28 299 608 506 755 237 840 585 529 559 711 -5 -352 -491 -723 -384 -331 -683 -920 -644 -609 -118 214 62 205 47 -34 -73 86 386 407 -108 -349 -379 -180 75 157 627 184 562 1038 689 206 79 -155 144 -114 -96 -129 145 249 54 -101 -60 -406 -474 -191 65 -23 -403 -61 65 73 403 399 -222 345 -227 25 45 212 -363 1 -20 79 160 126 -147 53 82 305 53 -239 177 25 544 232 463 355 -111 -514 -144 -186 -330 -364 -535 -907 -307 -807 -493 -134 -479 -683 -359 -691 31 181 225 850 728 495 705 288 28 213 396 517 720 1302 615 -87 -424 132 -42 755 388 50 39 155 46 443 -86 35 -116 228 -307 -769 -1026 -1814 -999 -812 -673 0 35 371 720 582 793 231 841 590 591 661 928 -7 -456 -629 -858 -453 -384 -860 -1225 -853 -847 -173 317 97 323 71 -51 -100 116 520 573 -156 -537 -594 -278 113 226 893 252 731 1354 962 294 119 -242 229 -181 -162 -228 250 439 95 -176 -104 -688 -787 SU 20200701T130759.1Z 7487.547211 4013 1 6.14 2 61.74 80.32 153.58 310.75 0.00 1 0.00 1 0 25 9.922e-03 5.658e-03 5.469e-03 2.133e-03 2.788262e-01 1.103888e-03 3.192652e-03 -6.000000e+00 5.825699e-03 232.27 -2.00 3.38 -2.00 316.79 0.00e+00 3.210477e-04 1.417955e-04 5.109623e-05 -6.000000e+00 2.618066e-04 290.49 -2.00 20.00 -2.00 315.93 0.00e+00 2.101 0.000 302.00 328.00 3 3.4068e+00 2.9119e-03 2.4943e-02 -6.0000e+00 1.4589e-02 2.2515e-02 3.2583e-03 1.4064e-02 -6.0000e+00 1.5764e-02 -1.8334e-03 1.9007e-03 6.7820e-03 -6.0000e+00 9.4020e-03 -4.0811e-03 9.0444e-04 1.8545e-03 -6.0000e+00 3.9720e-03 1.5950e-03 -2.7927e-04 6.2058e-05 2.2074e-05 -6.0000e+00 2.7927e-04 -7.2531e-03 0.0000e+00 12 1 1 12 9 1 99.94 26.41 0.22 -0.00725 -0.00935 13 25 1 5 0 425.670 26.41 20.00 23.17 30.19 28.2 974.11 1069 -770 2381 -5478 554 -2174 445 -615 2650 -3055 611 -1466 -803 -41 319 -744 -986 708 -672 381 -1056 1789 -241 1924 742 891 -1421 352 -620 1586 -156 2112 -273 -429 -3075 -383 -1013 172 -220 28 -1052 -428 -750 -1056 193 -222 -930 -747 -451 6 929 288 1346 1181 1172 544 531 -546 660 -141 1200 672 1727 875 440 -160 111 -939 747 541 183 8 136 60 223 -354 -552 -731 -228 -431 -471 -1058 -1913 -981 -916 -869 -24 563 388 239 440 678 311 973 83 787 381 694 -139 -509 -399 -522 -162 -395 -887 -844 -704 -531 -176 220 78 22 224 -54 29 312 426 151 81 -86 -435 -95 376 313 543 354 542 903 762 108 106 -71 -108 -31 -174 19 169 194 14 -10 18 -633 -704 146 -116 350 -804 69 -275 59 -92 425 -540 104 -268 -165 -9 79 -204 -283 208 -195 113 -322 530 -75 624 255 317 -512 117 -195 492 -53 755 -108 -172 -1190 -145 -401 78 -114 16 -652 -275 -471 -670 121 -139 -608 -477 -284 4 589 197 963 848 868 414 410 -424 497 -107 933 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