File name: Pandora66s1_HuntsvilleAL_20200801_L2Fit_fout2c3d20200122p1-8.txt File generation date: 20251117T160344.9Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: Nader Abuhassan Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 66 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora66_OF_v3d20200114.txt Instrument calibration file used: Pandora66s1_CF_v3d20200122.txt Level 1 file used: Pandora66s1_HuntsvilleAL_20200801_L1_smca1c3d20200122p1-8.txt Full location name: The University of Alabama in Huntsville- SWIRLL Short location name: HuntsvilleAL Country of location: United States Location latitude [deg]: 34.7252 Location longitude [deg]: -86.6464 Location altitude [m]: 221 Local noon date: 20200801 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Modification of session 1, fieldcal refday 20200921 First and last pixel inside fitting window: 253 395 Nominal wavelengths inside fitting window [nm]: 305.1019 305.2425 305.3831 305.5238 305.6644 305.8050 305.9456 306.0862 306.2268 306.3673 306.5079 306.6484 306.7890 306.9295 307.0700 307.2105 307.3510 307.4914 307.6319 307.7723 307.9128 308.0532 308.1936 308.3340 308.4744 308.6148 308.7551 308.8955 309.0358 309.1762 309.3165 309.4568 309.5971 309.7374 309.8777 310.0179 310.1582 310.2984 310.4386 310.5789 310.7191 310.8593 310.9994 311.1396 311.2798 311.4199 311.5600 311.7002 311.8403 311.9804 312.1205 312.2605 312.4006 312.5407 312.6807 312.8207 312.9607 313.1007 313.2407 313.3807 313.5207 313.6606 313.8006 313.9405 314.0805 314.2204 314.3603 314.5002 314.6400 314.7799 314.9197 315.0596 315.1994 315.3392 315.4790 315.6188 315.7586 315.8984 316.0381 316.1779 316.3176 316.4573 316.5970 316.7367 316.8764 317.0161 317.1558 317.2954 317.4351 317.5747 317.7143 317.8539 317.9935 318.1331 318.2727 318.4122 318.5518 318.6913 318.8308 318.9703 319.1098 319.2493 319.3888 319.5282 319.6677 319.8071 319.9465 320.0860 320.2254 320.3647 320.5041 320.6435 320.7828 320.9222 321.0615 321.2008 321.3401 321.4794 321.6187 321.7580 321.8972 322.0365 322.1757 322.3149 322.4542 322.5934 322.7325 322.8717 323.0109 323.1500 323.2892 323.4283 323.5674 323.7065 323.8456 323.9847 324.1238 324.2628 324.4019 324.5409 324.6799 324.8189 324.9579 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SU 20200801T122431.1Z 7518.517027 624 1 48.29 2 73.64 79.37 132.25 267.23 0.00 1 0.00 1 0 25 1.551e-01 1.496e-02 4.371e-02 3.314e-03 4.310913e-01 1.716130e-03 4.856940e-03 -6.000000e+00 9.076740e-02 231.55 -2.00 3.38 -2.00 319.18 0.00e+00 -1.529574e-04 4.444341e-04 4.677825e-04 -6.000000e+00 4.167338e-03 291.92 -2.00 20.00 -2.00 318.31 0.00e+00 3.490 0.001 302.00 328.00 3 4.6255e+00 4.8502e-03 4.0553e-02 -6.0000e+00 2.2675e-01 5.8349e-02 5.6848e-03 2.2159e-02 -6.0000e+00 2.4521e-01 1.2020e-04 4.1038e-03 1.0586e-02 -6.0000e+00 1.4655e-01 -8.6530e-03 2.1429e-03 2.8754e-03 -6.0000e+00 6.2270e-02 1.0142e-04 -5.3369e-04 9.7244e-05 3.2635e-05 -6.0000e+00 4.3695e-03 3.0805e-03 0.0000e+00 12 9 8 11 32 0 99.45 26.41 0.05 0.00308 -0.00093 14 3 1 5 0 3448.460 26.41 20.00 23.21 32.17 28.6 966.52 -81133 900000 5962 26080 -42427 81813 -27461 -50366 -27472 -14732 77910 -13142 -1762 10229 -16679 -30221 -8923 9036 12144 4899 15084 -18430 6345 -9818 48872 -6762 -9725 4128 -5500 3492 -6541 10396 10334 3968 8568 -8625 -6862 -14275 1500 -5816 1183 3710 -1048 3494 14499 3061 705 -538 188 -1875 1246 -1632 9102 3063 3784 1720 1976 -712 -317 -858 -2440 -1949 5000 4710 -1149 -1015 226 339 74 -1642 -1937 2301 -974 429 3736 -333 -2418 -1346 -1053 -2879 349 -851 -3494 -2151 -811 -1186 1894 -618 36 -1502 1127 867 244 517 -9 1526 1114 1335 175 -529 -275 -2022 -305 -3486 2369 -1094 -610 -1432 1000 -103 798 1144 1495 -851 -824 -933 1370 1686 -726 -192 -893 -576 1617 470 672 -131 -289 843 1308 151 -706 114 97 -641 -806 -64 -152 452 446 1018 -636 -128 -1033 -3787 900000 141 500 -1403 899 -877 -2307 -1123 -563 1290 -564 -80 496 -1180 -2761 -711 646 892 405 1145 -1978 564 -1110 3474 -829 -1225 429 -608 371 -862 1299 1432 600 1178 -1438 -1198 -3195 348 -1703 355 1087 -334 1076 4233 959 225 -175 61 -656 460 -676 3644 1394 1785 814 953 -351 -152 -413 -1244 -1079 2853 2904 -718 -628 133 203 46 -1191 -1468 1733 -749 323 2499 -219 -1502 -821 -699 -2136 273 -752 -3264 -2095 -837 -1258 2041 -701 41 -1637 1152 822 230 488 -9 1674 1331 1711 231 -689 -347 -2478 -345 -4209 2908 -1408 -821 -1985 1449 -158 1253 1834 2330 -1328 -1195 -1339 1932 2479 -1124 -311 -1409 -918 2450 690 972 -183 -404 1199 1943 238 -1159 193 171 -1152 -1495 -124 -301 880 868 1962 -1190 -236 -1879 SU 20200801T122632.2Z 7518.518428 626 1 50.41 2 73.23 79.64 132.64 267.49 0.00 1 0.00 1 0 17 1.756e-01 1.496e-02 4.696e-02 3.504e-03 4.200512e-01 1.805866e-03 4.753609e-03 -6.000000e+00 1.027273e-01 231.55 -2.00 3.38 -2.00 319.13 0.00e+00 4.158985e-04 4.551789e-04 6.240789e-04 -6.000000e+00 4.665982e-03 291.92 -2.00 20.00 -2.00 318.25 0.00e+00 3.411 0.001 302.00 328.00 3 4.7873e+00 5.0832e-03 3.9610e-02 -6.0000e+00 2.5663e-01 8.4032e-02 5.9289e-03 2.1662e-02 -6.0000e+00 2.7756e-01 -3.8099e-02 4.1517e-03 1.0339e-02 -6.0000e+00 1.6580e-01 1.0561e-02 2.1628e-03 2.7877e-03 -6.0000e+00 7.0091e-02 9.3802e-05 -1.2213e-03 1.0276e-04 3.1724e-05 -6.0000e+00 4.9476e-03 6.6047e-03 0.0000e+00 12 8 8 10 0 0 99.99 26.41 0.14 0.00660 -0.00257 17 4 1 5 0 2964.820 26.41 20.00 23.22 32.21 28.6 967.21 -76996 79558 17403 -19899 -27936 17261 -31616 125346 -29559 -37612 56350 -19085 -5254 -5420 -23118 -24462 -12740 131 8315 4120 13940 -19352 2351 -2159 41419 -6017 -10824 2696 -12406 3421 -16251 7662 5728 9133 1799 -3139 12960 -9050 847 -4475 -1104 7354 4480 5437 12307 2166 -1500 -126 910 -3380 1812 -1285 7504 3687 4614 3071 1514 -3467 958 -943 -2248 -2465 6943 4159 870 -1781 727 -153 575 -2656 -2611 1815 -1038 -88 4405 -766 -1435 -2910 -1565 -433 234 -973 -4879 1278 -1343 -935 411 -879 -834 -827 324 788 -234 243 -430 1548 -113 1413 -112 163 -748 -1582 -871 60 1408 -1070 -1095 -1251 1405 -217 400 1270 1605 -846 -859 -1116 1256 1684 -844 -593 173 -137 1641 448 1212 -493 -474 296 1068 -63 -350 -39 144 -845 -547 43 195 279 619 541 -329 -470 -1043 -4364 1178 461 -714 -996 394 -1290 1285 -1402 -2041 1300 -970 -276 -340 -2035 -2453 -1221 12 729 392 1222 -2380 245 -253 3338 -767 -1442 314 -1621 399 -2437 1072 852 1342 270 -503 1983 -2044 210 -1294 -338 2180 1415 1720 3650 715 -511 -42 306 -1240 685 -545 3127 1704 2200 1455 743 -1775 459 -460 -1156 -1384 3914 2595 561 -1114 427 -92 374 -1928 -2064 1422 -827 -66 3047 -502 -876 -1783 -1030 -308 188 -842 -4715 1227 -1358 -1004 457 -1016 -961 -911 326 763 -216 224 -433 1641 -132 1816 -148 219 -953 -1946 -1002 70 1686 -1384 -1489 -1733 2027 -332 650 2094 2571 -1309 -1286 -1595 1761 2458 -1296 -953 278 -217 2470 680 1736 -688 -663 421 1576 -99 -584 -65 248 -1542 -1021 83 376 546 1210 1059 -620 -850 -1922 SU 20200801T122915.4Z 7518.520317 630 1 48.73 2 72.68 80.00 133.17 267.84 0.00 1 0.00 1 0 25 1.656e-01 1.177e-02 3.898e-02 2.897e-03 4.088641e-01 1.493827e-03 4.634833e-03 -6.000000e+00 9.687364e-02 231.55 -2.00 3.38 -2.00 318.96 0.00e+00 8.172970e-04 3.587835e-04 3.667522e-04 -6.000000e+00 4.399173e-03 291.92 -2.00 20.00 -2.00 318.07 0.00e+00 3.309 0.001 302.00 328.00 3 4.5974e+00 4.1754e-03 3.8435e-02 -6.0000e+00 2.4201e-01 5.1047e-02 4.8454e-03 2.0885e-02 -6.0000e+00 2.6173e-01 -8.1926e-03 3.3750e-03 1.0065e-02 -6.0000e+00 1.5634e-01 -2.9187e-03 1.7631e-03 2.7331e-03 -6.0000e+00 6.6108e-02 1.2766e-04 -8.3317e-04 8.5149e-05 3.1563e-05 -6.0000e+00 4.6646e-03 5.2502e-03 0.0000e+00 12 8 8 10 0 0 99.98 26.41 0.14 0.00525 -0.00101 17 4 1 5 0 2865.550 26.41 19.99 23.21 32.34 28.7 968.29 -53865 139405 -44402 8362 -33368 24283 -33244 69615 -16111 -17474 41981 -19295 2371 6518 -8624 -12315 -4876 5111 1937 1668 10103 -9010 1621 -8119 32659 -6646 -3976 8419 -9613 5429 -10074 6903 4037 1884 2962 -9436 6184 -10280 -412 -4770 -1607 2874 4924 1550 -907 2107 2671 -767 2188 -2197 2579 -1533 5973 2416 1972 1464 1550 -1150 819 -733 -1190 -1543 4702 3034 -276 -664 38 -196 424 -778 -1775 1417 -80 361 2868 -677 -1318 -1458 -1124 -224 350 -1278 -3678 740 -1543 -570 716 -802 -427 -476 935 1057 -542 401 -500 1808 79 1475 -125 -478 -872 -930 -696 -2461 1027 -725 -485 -1158 809 -42 678 604 1332 -601 -561 -959 1296 1276 -783 -481 -407 -175 1204 201 1017 -369 312 586 1163 67 -236 -145 287 -599 -337 -29 111 84 268 564 -241 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