File name: Pandora66s1_HuntsvilleAL_20210323_L2Fit_fout2c3d20200122p1-8.txt File generation date: 20251117T165355.8Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: Nader Abuhassan Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 66 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora66_OF_v3d20200114.txt Instrument calibration file used: Pandora66s1_CF_v3d20200122.txt Level 1 file used: Pandora66s1_HuntsvilleAL_20210323_L1_smca1c3d20200122p1-8.txt Full location name: The University of Alabama in Huntsville- SWIRLL Short location name: HuntsvilleAL Country of location: United States Location latitude [deg]: 34.7252 Location longitude [deg]: -86.6464 Location altitude [m]: 221 Local noon date: 20210323 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Modification of session 1, fieldcal refday 20200921 First and last pixel inside fitting window: 253 395 Nominal wavelengths inside fitting window [nm]: 305.1019 305.2425 305.3831 305.5238 305.6644 305.8050 305.9456 306.0862 306.2268 306.3673 306.5079 306.6484 306.7890 306.9295 307.0700 307.2105 307.3510 307.4914 307.6319 307.7723 307.9128 308.0532 308.1936 308.3340 308.4744 308.6148 308.7551 308.8955 309.0358 309.1762 309.3165 309.4568 309.5971 309.7374 309.8777 310.0179 310.1582 310.2984 310.4386 310.5789 310.7191 310.8593 310.9994 311.1396 311.2798 311.4199 311.5600 311.7002 311.8403 311.9804 312.1205 312.2605 312.4006 312.5407 312.6807 312.8207 312.9607 313.1007 313.2407 313.3807 313.5207 313.6606 313.8006 313.9405 314.0805 314.2204 314.3603 314.5002 314.6400 314.7799 314.9197 315.0596 315.1994 315.3392 315.4790 315.6188 315.7586 315.8984 316.0381 316.1779 316.3176 316.4573 316.5970 316.7367 316.8764 317.0161 317.1558 317.2954 317.4351 317.5747 317.7143 317.8539 317.9935 318.1331 318.2727 318.4122 318.5518 318.6913 318.8308 318.9703 319.1098 319.2493 319.3888 319.5282 319.6677 319.8071 319.9465 320.0860 320.2254 320.3647 320.5041 320.6435 320.7828 320.9222 321.0615 321.2008 321.3401 321.4794 321.6187 321.7580 321.8972 322.0365 322.1757 322.3149 322.4542 322.5934 322.7325 322.8717 323.0109 323.1500 323.2892 323.4283 323.5674 323.7065 323.8456 323.9847 324.1238 324.2628 324.4019 324.5409 324.6799 324.8189 324.9579 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SU 20210323T130848.8Z 7752.547788 603 1 7.69 2 73.81 100.01 121.41 353.55 0.00 1 0.00 1 0 17 2.663e-01 1.865e-02 2.012e-01 1.119e-02 4.148025e-01 5.727572e-03 4.683598e-03 -6.000000e+00 1.543915e-01 227.36 -2.00 3.38 -2.00 319.19 0.00e+00 2.977946e-03 1.469358e-03 4.663619e-04 -6.000000e+00 6.928290e-03 281.33 -2.00 20.00 -2.00 318.51 0.00e+00 3.526 0.001 302.00 328.00 3 4.5980e+00 1.5960e-02 4.0033e-02 -6.0000e+00 3.8289e-01 2.7532e-03 1.8592e-02 2.0808e-02 -6.0000e+00 4.1632e-01 4.5058e-02 1.4302e-02 1.0671e-02 -6.0000e+00 2.4727e-01 -3.0036e-02 7.5369e-03 4.0388e-03 -6.0000e+00 1.0465e-01 1.0523e-04 -6.0274e-04 3.3073e-04 4.0958e-05 -6.0000e+00 7.5113e-03 3.6861e-03 0.0000e+00 12 9 9 12 33 1 999.00 26.32 0.49 0.00369 -0.00084 1 3 1 5 0 3757.710 26.32 19.99 23.03 24.03 30.5 991.30 -43136 900000 89875 160047 -19712 900000 136156 30967 -6853 -7647 166811 -53269 5771 -37979 11223 -29767 -12793 3418 20959 15116 16917 -3982 10775 5545 19343 3077 -6665 24652 -4896 34135 -27537 8428 -4831 315 2326 8138 1466 -10090 -14745 -3049 -4196 8565 4889 6299 24999 -4114 -3206 3282 1463 2916 -2605 -2957 19734 -1452 4240 2175 1099 -5988 1770 -1841 1081 -1943 6054 723 -1985 -5174 3430 -1040 -2596 -2550 -1301 432 -1626 158 4211 -847 5066 -4624 -1627 -514 2051 -169 -3445 2151 -3137 -1030 1916 -484 -492 104 -394 2515 -2014 1435 -330 3234 758 2913 687 -1429 -333 -1884 -767 388 -2845 -446 -500 -479 860 -153 370 170 1490 -192 -1747 2281 245 2091 -24 -995 -839 -221 2395 -545 567 -1380 -58 -83 810 -262 -366 286 -1092 -369 -183 -354 -273 -529 559 95 991 947 -906 -1356 900000 980 1746 -493 900000 1485 576 -207 -245 1820 -2938 226 -2647 571 -2598 -1024 251 1372 1099 1230 -360 882 511 1641 321 -768 1987 -519 2607 -4174 1062 -732 46 338 1139 233 -2132 -3945 -805 -1229 2336 1443 1869 6560 -1391 -1077 1040 480 986 -1013 -1256 7180 -664 1905 1026 534 -3101 833 -902 540 -1095 3491 453 -1282 -3263 2008 -616 -1707 -1819 -998 338 -1281 117 2858 -545 2987 -2850 -1064 -383 1621 -146 -3300 2057 -3259 -1118 2037 -542 -549 114 -405 2415 -1907 1321 -323 3443 901 3647 897 -1867 -418 -2286 -867 447 -3516 -567 -670 -656 1244 -234 583 275 2316 -296 -2546 3151 347 3048 -37 -1564 -1325 -352 3608 -811 823 -1957 -82 -116 1214 -417 -603 490 -1892 -665 -339 -669 -530 -1049 1099 181 1850 1699 -1672 SU 20210323T131351.9Z 7752.551295 614 1 25.71 2 72.78 100.78 121.52 354.83 0.00 1 0.00 1 0 25 6.653e-02 8.419e-03 2.928e-02 2.939e-03 4.130876e-01 1.491584e-03 4.700675e-03 -6.000000e+00 3.831037e-02 227.36 -2.00 3.38 -2.00 318.90 0.00e+00 1.017375e-03 3.443209e-04 4.073656e-04 -6.000000e+00 1.689798e-03 281.33 -2.00 20.00 -2.00 318.21 0.00e+00 3.329 0.001 302.00 328.00 3 4.0050e+00 4.0996e-03 3.8382e-02 -6.0000e+00 9.5094e-02 3.8190e-02 4.7258e-03 2.0660e-02 -6.0000e+00 1.0335e-01 -4.3863e-03 3.4148e-03 1.0227e-02 -6.0000e+00 6.1550e-02 -5.9245e-03 1.7981e-03 2.9593e-03 -6.0000e+00 2.5988e-02 2.2858e-04 -6.1826e-04 8.5936e-05 3.4006e-05 -6.0000e+00 1.8710e-03 3.9070e-03 0.0000e+00 12 9 1 12 1 1 99.93 26.32 0.11 0.00391 -0.00074 19 8 1 5 0 1276.620 26.32 20.00 23.03 24.04 30.5 991.35 -34173 26824 18844 -518 -7136 12850 -307 9692 -7745 -18974 37997 -16635 12358 -12078 -4456 -15079 -7457 47 6176 -4453 2583 -6760 -4167 1298 12121 -1687 -3695 4091 -11862 5314 -4796 2919 291 1094 -970 -1037 -196 -3867 -4556 -3865 -2158 2859 1511 1766 4803 1267 -695 -1962 -274 -2368 1415 1411 6480 1072 1316 503 235 -2027 135 135 677 334 3995 1473 363 -669 -117 -282 -103 -970 -322 69 64 111 1296 -410 116 -895 -58 305 -327 -460 -2266 15 -654 -517 -182 -230 201 -762 701 640 -195 1321 -39 1010 -191 1164 -92 -302 -661 -322 -3191 -711 126 -739 -503 -260 242 -61 175 583 709 287 -410 277 700 1049 -340 -768 -295 -199 769 415 933 -206 715 238 501 -75 198 -360 205 -547 -43 -250 200 -43 337 28 85 -436 -492 -1365 687 503 -16 -212 336 -9 304 -322 -931 1154 -906 600 -898 -341 -1447 -714 4 584 -489 268 -776 -491 156 1384 -231 -514 499 -1644 652 -729 461 49 188 -171 -186 -37 -896 -1286 -1199 -721 958 532 628 1669 460 -257 -735 -102 -941 588 606 2838 529 675 268 128 -1118 71 71 371 191 2434 991 247 -434 -73 -178 -71 -730 -262 55 51 87 926 -281 73 -565 -40 228 -267 -419 -2163 15 -668 -563 -207 -269 233 -852 744 628 -190 1272 -40 1098 -229 1477 -124 -402 -859 -383 -3822 -857 156 -937 -670 -366 350 -93 274 929 1137 436 -603 386 976 1524 -515 -1229 -472 -312 1159 624 1327 -294 975 335 738 -117 328 -605 354 -964 -78 -475 387 -83 645 54 155 -794 -877 SU 20210323T131848.8Z 7752.554732 636 1 49.66 2 71.78 101.55 121.60 356.09 0.00 1 0.00 1 0 25 6.601e-02 7.258e-03 2.108e-02 2.143e-03 3.908329e-01 1.088290e-03 4.449889e-03 -6.000000e+00 3.800243e-02 227.36 -2.00 3.38 -2.00 319.08 0.00e+00 9.415878e-04 2.634626e-04 3.033949e-04 -6.000000e+00 1.676811e-03 281.33 -2.00 20.00 -2.00 318.39 0.00e+00 3.158 0.000 302.00 328.00 3 4.0507e+00 3.0163e-03 3.6390e-02 -6.0000e+00 9.4328e-02 1.1943e-02 3.4933e-03 1.9574e-02 -6.0000e+00 1.0253e-01 2.2719e-02 2.5392e-03 9.6736e-03 -6.0000e+00 6.1061e-02 -1.6462e-02 1.3300e-03 2.7891e-03 -6.0000e+00 2.5772e-02 2.6553e-04 -7.2508e-04 6.3704e-05 3.2641e-05 -6.0000e+00 1.8567e-03 6.2061e-03 0.0000e+00 11 8 0 10 0 0 99.99 26.32 0.27 0.00621 0.00076 111 24 1 5 0 447.270 26.32 20.00 23.03 24.04 30.6 991.69 -43176 37428 -410 858 -20382 15184 -19701 15424 -18874 -5831 14507 -10196 4687 -6884 -2436 -11055 -4244 2205 5619 854 4499 -5914 -3238 -1609 8952 -2828 -3188 2637 -6672 5361 -2410 587 452 -1418 1571 -4160 606 -5327 -3135 -2809 -1712 1286 1231 -90 4514 -49 -232 -414 1422 -1408 824 314 5066 528 1351 1160 269 -1871 184 424 520 627 2991 1563 -158 -420 496 -805 -207 -410 -701 856 -166 555 1044 -135 195 -436 -402 -256 62 -941 -2169 -196 -1096 -1000 -185 -355 337 -307 977 903 -256 1078 565 1115 496 883 165 -534 -418 -966 -2529 -625 -428 -927 -230 -573 156 230 413 268 709 -130 39 274 749 756 -387 -624 -237 -206 535 186 626 -178 625 765 550 46 -143 -50 116 -243 -366 -227 171 140 -64 161 -90 -99 -435 -1792 824 -14 26 -704 371 -747 466 -831 -256 532 -490 230 -453 -180 -1002 -386 201 523 87 449 -659 -370 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