File name: Pandora66s1_HuntsvilleAL_20210408_L2Fit_fout2c3d20200122p1-8.txt File generation date: 20251117T165901.8Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: Michael Newchurch Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 66 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora66_OF_v5d20200114.txt Instrument calibration file used: Pandora66s1_CF_v3d20200122.txt Level 1 file used: Pandora66s1_HuntsvilleAL_20210408_L1_smca1c3d20200122p1-8.txt Full location name: The University of Alabama in Huntsville- SWIRLL Short location name: HuntsvilleAL Country of location: United States Location latitude [deg]: 34.7252 Location longitude [deg]: -86.6464 Location altitude [m]: 221 Local noon date: 20210408 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Modification of session 1, fieldcal refday 20200921 First and last pixel inside fitting window: 253 395 Nominal wavelengths inside fitting window [nm]: 305.1019 305.2425 305.3831 305.5238 305.6644 305.8050 305.9456 306.0862 306.2268 306.3673 306.5079 306.6484 306.7890 306.9295 307.0700 307.2105 307.3510 307.4914 307.6319 307.7723 307.9128 308.0532 308.1936 308.3340 308.4744 308.6148 308.7551 308.8955 309.0358 309.1762 309.3165 309.4568 309.5971 309.7374 309.8777 310.0179 310.1582 310.2984 310.4386 310.5789 310.7191 310.8593 310.9994 311.1396 311.2798 311.4199 311.5600 311.7002 311.8403 311.9804 312.1205 312.2605 312.4006 312.5407 312.6807 312.8207 312.9607 313.1007 313.2407 313.3807 313.5207 313.6606 313.8006 313.9405 314.0805 314.2204 314.3603 314.5002 314.6400 314.7799 314.9197 315.0596 315.1994 315.3392 315.4790 315.6188 315.7586 315.8984 316.0381 316.1779 316.3176 316.4573 316.5970 316.7367 316.8764 317.0161 317.1558 317.2954 317.4351 317.5747 317.7143 317.8539 317.9935 318.1331 318.2727 318.4122 318.5518 318.6913 318.8308 318.9703 319.1098 319.2493 319.3888 319.5282 319.6677 319.8071 319.9465 320.0860 320.2254 320.3647 320.5041 320.6435 320.7828 320.9222 321.0615 321.2008 321.3401 321.4794 321.6187 321.7580 321.8972 322.0365 322.1757 322.3149 322.4542 322.5934 322.7325 322.8717 323.0109 323.1500 323.2892 323.4283 323.5674 323.7065 323.8456 323.9847 324.1238 324.2628 324.4019 324.5409 324.6799 324.8189 324.9579 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20210408T133438.8Z 7768.565727 131 1 15.70 2 64.02 99.38 55.54 145.32 0.00 1 0.00 1 0 25 2.955e-02 6.893e-03 1.241e-02 3.125e-03 3.010938e-01 1.586999e-03 3.468018e-03 -6.000000e+00 1.709470e-02 228.60 -2.00 3.38 -2.00 317.74 0.00e+00 7.040615e-05 2.589101e-04 7.963226e-05 -6.000000e+00 7.548783e-04 282.74 -2.00 20.00 -2.00 316.99 0.00e+00 2.269 0.000 302.00 328.00 3 4.0383e+00 4.2326e-03 2.6784e-02 -6.0000e+00 4.2537e-02 1.4266e-02 4.7832e-03 1.5036e-02 -6.0000e+00 4.6177e-02 1.6746e-02 2.9591e-03 7.3487e-03 -6.0000e+00 2.7495e-02 -1.2471e-02 1.4860e-03 2.0370e-03 -6.0000e+00 1.1596e-02 6.9994e-04 -3.3875e-04 9.2278e-05 2.3917e-05 -6.0000e+00 8.3119e-04 3.2432e-03 0.0000e+00 12 9 1 12 1 1 99.99 26.32 0.07 0.00324 0.00070 20 14 2 5 0 738.830 26.32 20.00 23.07 25.11 31.5 993.13 -16001 20924 -2124 1907 -13413 3296 -4232 6081 -3456 -17 7801 -2598 -1032 1038 -247 -3770 -3589 -118 717 -503 633 -965 402 1862 4129 -267 315 763 -3649 924 1061 1873 1478 279 -44 -2198 1189 -3237 -1499 -2677 -1221 -148 -812 -827 2537 -421 -671 -1724 633 143 278 309 2890 631 1380 759 180 -61 1210 804 1358 590 1518 1082 152 -576 232 32 180 -706 -712 357 -806 246 562 -82 -380 -103 -167 -552 -518 -1038 -1688 -1200 -1308 -1043 86 118 257 480 1040 393 600 1093 331 452 960 448 511 40 -297 -1090 -1840 -487 175 -946 -533 -449 355 72 391 133 256 -325 -227 144 521 679 -88 -651 -256 -211 300 90 350 184 80 642 1033 433 66 -120 182 -238 -279 208 -42 452 109 -16 -189 -593 -498 -1477 1534 -186 157 -1173 244 -367 535 -348 -2 780 -290 -130 148 -41 -709 -668 -22 140 -103 130 -202 86 420 959 -67 78 176 -832 205 254 485 416 80 -12 -619 361 -1145 -626 -1243 -606 -76 -432 -442 1312 -224 -352 -898 319 74 154 184 1778 399 895 507 123 -41 795 531 929 440 1164 882 123 -436 172 24 138 -615 -644 332 -750 216 475 -66 -279 -74 -128 -457 -461 -1023 -1710 -1273 -1491 -1217 104 147 318 565 1171 408 603 1077 352 510 1156 577 689 53 -384 -1311 -2210 -575 222 -1228 -722 -616 510 108 611 210 389 -482 -322 192 696 947 -127 -1004 -385 -323 446 129 490 246 106 865 1429 622 100 -188 281 -385 -463 361 -75 792 193 -28 -323 -983 -836 SS 20210408T151459.3Z 7768.635409 193 1 48.68 2 44.52 118.68 48.17 174.50 0.00 1 0.00 1 0 17 2.418e-02 1.036e-02 8.616e-03 3.747e-03 1.876385e-01 1.912050e-03 2.217853e-03 -6.000000e+00 1.399008e-02 228.61 -2.00 3.38 -2.00 316.66 0.00e+00 1.707944e-04 2.323062e-04 3.651084e-05 -6.000000e+00 6.177673e-04 282.75 -2.00 20.00 -2.00 315.93 0.00e+00 1.401 0.000 302.00 328.00 3 5.8485e+00 5.0112e-03 1.6616e-02 -6.0000e+00 3.4812e-02 -8.2355e-04 5.6141e-03 9.4092e-03 -6.0000e+00 3.7790e-02 3.3073e-02 3.2570e-03 4.6162e-03 -6.0000e+00 2.2502e-02 -1.5580e-02 1.5233e-03 1.2913e-03 -6.0000e+00 9.4899e-03 3.1827e-04 -6.0990e-06 1.1196e-04 1.6368e-05 -6.0000e+00 6.8020e-04 3.0476e-03 0.0000e+00 12 8 8 10 0 0 99.99 26.32 0.13 0.00305 0.00300 141 30 2 5 0 345.190 26.32 19.99 23.02 24.70 31.5 992.02 -11199 13649 -984 137 -8022 5538 -2125 7528 -1732 -1150 9306 -1708 1737 3225 379 -1556 -2874 182 2047 -509 268 -3141 -71 -1621 5055 -1440 235 -281 -761 2753 -1416 311 2042 -660 1647 -1320 1847 -5347 -1088 -2320 -1208 -279 -662 -159 2529 -210 -1530 -1080 113 -217 739 690 3526 1651 1286 1895 71 -1504 109 466 42 49 2066 1595 -1119 -437 75 -261 38 -403 -1166 358 -546 1056 1111 -27 686 -696 -199 -278 -243 -505 -2173 210 -604 -2138 494 -692 309 610 533 888 1633 936 -106 1834 796 1035 52 -544 -101 -1489 -4151 -1146 741 -728 -226 -503 94 -66 320 148 770 -847 -1087 22 905 1379 -375 -529 -93 -167 621 -362 807 110 699 1013 1037 212 -62 585 258 -529 -222 164 133 323 111 395 -380 -691 -1071 -2193 2206 -182 23 -1302 775 -345 1236 -341 -231 1649 -351 382 784 106 -471 -904 57 651 -171 90 -1084 -24 -596 1808 -564 89 -99 -250 868 -487 111 763 -252 573 -478 718 -2435 -565 -1394 -769 -182 -444 -106 1638 -138 -992 -673 68 -131 465 460 2395 1194 954 1419 55 -1168 82 351 33 42 1832 1479 -1031 -365 58 -198 31 -369 -1163 364 -557 1019 991 -22 500 -491 -146 -228 -222 -504 -2335 231 -676 -2595 613 -893 394 741 635 958 1600 896 -108 2006 971 1295 68 -698 -121 -1797 -4941 -1384 952 -936 -303 -705 137 -102 509 234 1157 -1193 -1405 29 1152 1830 -510 -769 -138 -245 883 -496 1102 145 866 1258 1359 296 -91 812 365 -781 -346 267 223 553 191 661 -622 -1099 -1681 SS 20210408T160717.2Z 7768.671727 227 1 0.43 2 35.81 133.68 48.52 191.27 0.00 1 0.00 1 0 17 7.737e-03 6.215e-03 2.044e-03 1.533e-03 1.654061e-01 7.976954e-04 1.974291e-03 -6.000000e+00 4.477111e-03 228.61 -2.00 3.38 -2.00 314.50 0.00e+00 2.446264e-04 6.241829e-05 3.398692e-05 -6.000000e+00 1.976738e-04 282.75 -2.00 20.00 -2.00 313.95 0.00e+00 1.232 0.000 302.00 328.00 3 7.4242e-01 2.0387e-03 1.4612e-02 -6.0000e+00 1.1141e-02 6.7932e-03 2.2601e-03 8.2629e-03 -6.0000e+00 1.2093e-02 2.9634e-03 1.2948e-03 4.0532e-03 -6.0000e+00 7.2008e-03 -4.0678e-03 5.5963e-04 1.1464e-03 -6.0000e+00 3.0373e-03 6.5148e-02 -4.3238e-04 4.4345e-05 1.6464e-05 -6.0000e+00 2.1765e-04 2.2895e-03 0.0000e+00 12 1 1 12 1 1 81.11 26.32 0.28 0.00229 -0.00096 11 404 1 5 0 21.100 26.32 20.00 23.05 28.09 31.9 1009.60 -968 -570 -2103 -2743 -1437 -499 6 1727 851 -219 -320 278 -277 309 157 -90 6 669 946 846 426 808 1028 1006 449 377 -35 -213 592 1835 1960 1627 1229 -890 -1054 -1124 -1001 -701 -3 -1223 -1297 -1286 -1108 -1059 -697 -821 -941 -454 -312 262 438 592 577 1006 867 750 477 421 266 691 688 1120 1315 616 -272 -629 -201 366 1023 332 127 -65 -79 144 -241 -151 330 76 338 -358 -754 -972 -1794 -1131 -918 -850 -596 -146 68 359 458 474 618 1206 552 123 664 509 32 -271 -468 -698 87 -39 -646 -717 -649 -732 -283 -121 172 -11 139 -48 230 363 183 124 43 -259 -156 -70 123 177 497 695 1105 1349 694 426 347 -81 26 -9 -86 -89 -7 250 -426 -267 -260 -494 -600 -388 -240 -885 -1053 -518 -175 2 654 354 -94 -134 119 -123 152 81 -49 3 358 518 476 241 452 589 602 266 228 -21 -124 333 1004 1111 921 738 -542 -598 -641 -598 -462 -2 -960 -1091 -1072 -941 -900 -586 -683 -790 -365 -253 211 353 503 491 890 784 687 426 388 242 627 623 1080 1304 616 -275 -603 -185 326 963 327 131 -70 -85 147 -238 -139 296 65 299 -341 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