File name: Pandora66s1_HuntsvilleAL_20210503_L2Fit_fout2c3d20200122p1-8.txt File generation date: 20251117T165916.2Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: Michael Newchurch Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 66 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora66_OF_v5d20200114.txt Instrument calibration file used: Pandora66s1_CF_v3d20200122.txt Level 1 file used: Pandora66s1_HuntsvilleAL_20210503_L1_smca1c3d20200122p1-8.txt Full location name: The University of Alabama in Huntsville- SWIRLL Short location name: HuntsvilleAL Country of location: United States Location latitude [deg]: 34.7252 Location longitude [deg]: -86.6464 Location altitude [m]: 221 Local noon date: 20210503 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Modification of session 1, fieldcal refday 20200921 First and last pixel inside fitting window: 253 395 Nominal wavelengths inside fitting window [nm]: 305.1019 305.2425 305.3831 305.5238 305.6644 305.8050 305.9456 306.0862 306.2268 306.3673 306.5079 306.6484 306.7890 306.9295 307.0700 307.2105 307.3510 307.4914 307.6319 307.7723 307.9128 308.0532 308.1936 308.3340 308.4744 308.6148 308.7551 308.8955 309.0358 309.1762 309.3165 309.4568 309.5971 309.7374 309.8777 310.0179 310.1582 310.2984 310.4386 310.5789 310.7191 310.8593 310.9994 311.1396 311.2798 311.4199 311.5600 311.7002 311.8403 311.9804 312.1205 312.2605 312.4006 312.5407 312.6807 312.8207 312.9607 313.1007 313.2407 313.3807 313.5207 313.6606 313.8006 313.9405 314.0805 314.2204 314.3603 314.5002 314.6400 314.7799 314.9197 315.0596 315.1994 315.3392 315.4790 315.6188 315.7586 315.8984 316.0381 316.1779 316.3176 316.4573 316.5970 316.7367 316.8764 317.0161 317.1558 317.2954 317.4351 317.5747 317.7143 317.8539 317.9935 318.1331 318.2727 318.4122 318.5518 318.6913 318.8308 318.9703 319.1098 319.2493 319.3888 319.5282 319.6677 319.8071 319.9465 320.0860 320.2254 320.3647 320.5041 320.6435 320.7828 320.9222 321.0615 321.2008 321.3401 321.4794 321.6187 321.7580 321.8972 322.0365 322.1757 322.3149 322.4542 322.5934 322.7325 322.8717 323.0109 323.1500 323.2892 323.4283 323.5674 323.7065 323.8456 323.9847 324.1238 324.2628 324.4019 324.5409 324.6799 324.8189 324.9579 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20210503T130616.5Z 7793.546024 228 1 0.93 2 64.22 88.05 60.15 199.41 0.00 1 0.00 1 0 25 1.219e-02 6.741e-03 1.550e-02 5.112e-03 3.093736e-01 2.622421e-03 3.554398e-03 -6.000000e+00 7.102697e-03 230.37 -2.00 3.38 -2.00 317.12 0.00e+00 -1.009318e-04 3.644063e-04 8.832967e-05 -6.000000e+00 3.145543e-04 285.07 -2.00 20.00 -2.00 316.35 0.00e+00 2.285 0.000 302.00 328.00 3 2.5938e+00 6.9271e-03 2.7225e-02 -6.0000e+00 1.7735e-02 8.8651e-03 7.7737e-03 1.5484e-02 -6.0000e+00 1.9218e-02 5.9070e-03 4.6229e-03 7.5176e-03 -6.0000e+00 1.1443e-02 -8.5137e-03 2.2506e-03 2.0586e-03 -6.0000e+00 4.8198e-03 2.8993e-03 -1.2938e-04 1.4863e-04 2.4235e-05 -6.0000e+00 3.4317e-04 1.5647e-03 0.0000e+00 12 9 1 12 1 1 999.00 26.41 0.26 0.00156 0.00059 2 42 1 5 0 252.370 26.41 20.00 23.13 29.23 31.8 986.41 -1118 3618 2480 -5614 -2078 -2069 -950 1470 857 -292 2062 -1290 1360 1443 3322 -2671 -1489 705 -358 390 2472 1176 468 2401 1749 -256 -61 -2766 -1886 539 1091 145 -1866 -3421 1238 -378 -641 -1024 -841 -1709 769 -2540 -612 -301 1364 -647 161 -1090 -456 1231 -1276 1261 981 212 -182 1192 -308 1414 -664 976 957 983 1357 333 803 -419 -339 -31 -401 673 -259 707 -419 142 435 204 385 -499 397 -483 -511 -732 -1197 -1292 -1382 -425 -423 321 271 942 763 588 1004 1120 1211 365 1170 600 379 -781 -263 -968 -1075 -697 -883 -583 -885 -1000 -487 -392 -271 10 -267 82 17 366 232 363 380 32 290 -169 -303 -216 853 381 978 684 595 932 814 -153 -270 -16 -131 217 174 -13 -214 -616 -78 -427 -296 -120 402 281 -637 -224 -223 -111 174 113 -41 281 -194 229 281 675 -633 -366 178 -96 107 673 325 127 682 527 -82 -19 -837 -536 152 332 49 -692 -1218 423 -133 -237 -448 -416 -932 444 -1500 -365 -180 802 -388 94 -635 -262 714 -812 840 661 152 -136 854 -228 1020 -480 728 709 787 1124 283 698 -342 -275 -25 -335 602 -243 682 -405 130 383 169 306 -389 329 -436 -476 -754 -1268 -1387 -1536 -499 -503 389 328 1122 873 642 1015 1163 1292 419 1436 763 507 -1032 -336 -1191 -1259 -844 -1118 -749 -1195 -1375 -682 -569 -414 14 -397 117 23 489 310 491 533 47 423 -252 -441 -310 1150 509 1290 888 830 1343 1201 -228 -413 -25 -208 360 289 -22 -366 -1026 -127 -698 -473 SS 20210503T154712.4Z 7793.657782 336 1 8.72 2 32.14 118.55 78.96 232.57 0.00 1 0.00 1 0 17 7.246e-03 5.703e-03 1.844e-03 1.315e-03 1.647144e-01 6.855555e-04 1.928391e-03 -6.000000e+00 4.221774e-03 230.38 -2.00 3.38 -2.00 314.75 0.00e+00 2.144716e-04 5.640045e-05 2.099246e-05 -6.000000e+00 1.869186e-04 285.08 -2.00 20.00 -2.00 314.13 0.00e+00 1.180 0.000 302.00 328.00 3 3.8846e+00 1.7630e-03 1.4207e-02 -6.0000e+00 1.0542e-02 3.0179e-02 1.9547e-03 8.2208e-03 -6.0000e+00 1.1422e-02 1.5695e-03 1.1165e-03 4.0058e-03 -6.0000e+00 6.8009e-03 -4.3271e-03 4.8460e-04 1.1129e-03 -6.0000e+00 2.8656e-03 2.9308e-03 -2.2554e-04 3.8143e-05 1.5642e-05 -6.0000e+00 2.0391e-04 -5.1441e-04 0.0000e+00 12 1 1 12 1 1 99.98 26.41 0.14 -0.00051 -0.00221 33 44 1 5 0 237.220 26.41 20.01 23.22 31.85 32.5 1000.15 -1227 -534 -1949 -2653 -1963 140 499 896 663 -689 -335 23 -484 70 461 -314 -205 458 857 947 348 915 1265 717 842 609 -67 -150 406 1503 1150 2096 1137 -780 -1106 -257 -686 -736 -439 -863 -1016 -907 -938 -982 -412 -723 -703 -773 -477 256 304 516 953 770 367 860 614 85 581 391 1017 983 1443 972 -325 -350 -209 -175 563 413 70 -42 -104 244 126 -86 101 -171 226 -581 -661 -1137 -1836 -1164 -910 -726 -621 -98 35 464 170 307 480 1024 527 393 521 659 171 -296 -350 -509 -135 106 -454 -827 -492 -639 -131 43 37 40 196 -182 195 341 454 388 33 -60 -196 28 176 91 563 479 672 1073 641 139 150 -82 -28 -107 -124 -245 207 243 -155 -240 -115 -517 -570 -442 -201 -735 -913 -641 44 166 328 247 -266 -125 9 -204 31 221 -161 -107 243 464 494 184 505 671 399 484 359 -39 -81 213 768 611 1158 630 -437 -615 -142 -395 -466 -310 -666 -840 -773 -816 -855 -354 -615 -579 -612 -383 203 240 429 824 662 323 762 551 76 509 344 922 953 1422 1000 -327 -336 -185 -159 512 402 74 -44 -109 256 122 -79 88 -141 194 -529 -638 -1202 -1976 -1304 -1046 -855 -767 -124 44 558 196 335 498 1017 550 430 600 796 216 -366 -424 -599 -152 125 -556 -1028 -637 -830 -176 58 52 56 272 -233 247 404 537 479 43 -78 -266 38 230 118 718 581 807 1282 776 179 192 -108 -37 -141 -173 -345 298 359 -231 -351 -162 -741 -801 SS 20210503T155614.5Z 7793.664057 342 1 49.09 2 30.53 121.35 80.39 234.04 0.00 1 0.00 1 0 17 7.407e-03 5.330e-03 7.683e-04 4.576e-04 1.623916e-01 2.367959e-04 1.898989e-03 -6.000000e+00 4.315834e-03 230.38 -2.00 3.38 -2.00 315.58 0.00e+00 7.990045e-05 2.291215e-05 2.032471e-05 -6.000000e+00 1.910762e-04 285.08 -2.00 20.00 -2.00 314.90 0.00e+00 1.160 0.000 302.00 328.00 3 3.1710e+00 6.1412e-04 1.3993e-02 -6.0000e+00 1.0777e-02 1.4925e-02 6.8276e-04 8.1226e-03 -6.0000e+00 1.1677e-02 8.7822e-03 3.8936e-04 3.9596e-03 -6.0000e+00 6.9523e-03 -8.0128e-03 1.7429e-04 1.0914e-03 -6.0000e+00 2.9296e-03 6.1499e-03 -1.9046e-04 1.3436e-05 1.4665e-05 -6.0000e+00 2.0845e-04 -7.7692e-04 0.0000e+00 10 0 0 10 0 0 100.00 26.41 0.29 -0.00078 -0.00221 2138 457 1 5 0 22.070 26.41 20.00 23.22 32.75 32.6 1003.70 -986 -1246 -1598 -2935 -725 -178 1552 1434 1538 -511 422 331 592 111 361 -753 -260 -1 558 351 263 527 920 375 398 191 -137 6 788 1912 1775 2018 1115 -579 -1106 -112 -829 -77 -352 -886 -1409 -963 -1238 -1148 -721 -856 -988 -780 -737 400 329 502 929 834 697 799 459 400 546 701 1014 1100 1223 736 -248 -350 -141 -53 870 401 177 13 151 53 203 78 190 16 325 -457 -621 -1133 -1636 -1170 -802 -767 -267 3 170 246 416 481 -263 796 615 413 518 641 110 -253 -402 -514 -207 -53 -624 -820 -585 -486 -129 154 222 116 47 14 46 308 182 174 95 -91 -296 -46 67 215 543 337 604 941 515 206 62 -151 -57 -56 -18 -66 128 198 -51 -152 -115 -403 -537 -272 -363 -461 -778 -168 -40 366 376 439 -152 121 97 191 40 143 -320 -112 0 250 162 122 241 430 170 187 92 -65 3 342 805 775 923 543 -285 -509 -51 -421 -42 -226 -654 -1040 -731 -962 -891 -553 -650 -726 -592 -541 290 249 371 715 670 573 664 386 335 448 576 862 998 1187 745 -245 -314 -117 -43 739 383 183 13 162 55 195 68 159 13 268 -390 -589 -1178 -1806 -1258 -922 -942 -343 3 224 309 481 540 -270 780 632 464 598 809 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