File name: Pandora66s1_HuntsvilleAL_20210628_L2Fit_fout2c3d20200122p1-8.txt File generation date: 20251117T171204.8Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: Michael Newchurch Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 66 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora66_OF_v5d20200114.txt Instrument calibration file used: Pandora66s1_CF_v3d20200122.txt Level 1 file used: Pandora66s1_HuntsvilleAL_20210628_L1_smca1c3d20200122p1-8.txt Full location name: The University of Alabama in Huntsville- SWIRLL Short location name: HuntsvilleAL Country of location: United States Location latitude [deg]: 34.7252 Location longitude [deg]: -86.6464 Location altitude [m]: 221 Local noon date: 20210628 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Modification of session 1, fieldcal refday 20200921 First and last pixel inside fitting window: 253 395 Nominal wavelengths inside fitting window [nm]: 305.1019 305.2425 305.3831 305.5238 305.6644 305.8050 305.9456 306.0862 306.2268 306.3673 306.5079 306.6484 306.7890 306.9295 307.0700 307.2105 307.3510 307.4914 307.6319 307.7723 307.9128 308.0532 308.1936 308.3340 308.4744 308.6148 308.7551 308.8955 309.0358 309.1762 309.3165 309.4568 309.5971 309.7374 309.8777 310.0179 310.1582 310.2984 310.4386 310.5789 310.7191 310.8593 310.9994 311.1396 311.2798 311.4199 311.5600 311.7002 311.8403 311.9804 312.1205 312.2605 312.4006 312.5407 312.6807 312.8207 312.9607 313.1007 313.2407 313.3807 313.5207 313.6606 313.8006 313.9405 314.0805 314.2204 314.3603 314.5002 314.6400 314.7799 314.9197 315.0596 315.1994 315.3392 315.4790 315.6188 315.7586 315.8984 316.0381 316.1779 316.3176 316.4573 316.5970 316.7367 316.8764 317.0161 317.1558 317.2954 317.4351 317.5747 317.7143 317.8539 317.9935 318.1331 318.2727 318.4122 318.5518 318.6913 318.8308 318.9703 319.1098 319.2493 319.3888 319.5282 319.6677 319.8071 319.9465 320.0860 320.2254 320.3647 320.5041 320.6435 320.7828 320.9222 321.0615 321.2008 321.3401 321.4794 321.6187 321.7580 321.8972 322.0365 322.1757 322.3149 322.4542 322.5934 322.7325 322.8717 323.0109 323.1500 323.2892 323.4283 323.5674 323.7065 323.8456 323.9847 324.1238 324.2628 324.4019 324.5409 324.6799 324.8189 324.9579 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20210628T165049.8Z 7849.701965 5 1 50.01 2 17.26 127.77 116.10 266.86 0.00 1 0.00 1 0 17 6.950e-03 5.775e-03 1.081e-04 8.493e-05 1.433372e-01 4.494434e-05 1.682883e-03 -6.000000e+00 4.080507e-03 232.32 -2.00 3.38 -2.00 314.19 0.00e+00 2.364903e-04 3.381937e-06 2.125981e-05 -6.000000e+00 1.831622e-04 290.17 -2.00 20.00 -2.00 313.57 0.00e+00 1.047 0.000 302.00 328.00 3 4.5945e-01 1.1541e-04 1.2572e-02 -6.0000e+00 1.0221e-02 -1.1058e-04 1.2733e-04 7.2309e-03 -6.0000e+00 1.1046e-02 -9.0188e-05 7.2976e-05 3.5034e-03 -6.0000e+00 6.5863e-03 -3.2712e-03 3.1233e-05 9.7316e-04 -6.0000e+00 2.7798e-03 1.0839e-01 -4.0845e-04 2.4526e-06 1.4238e-05 -6.0000e+00 1.9568e-04 -4.2310e-03 0.0000e+00 10 0 0 10 0 0 99.98 27.05 0.30 -0.00423 -0.00730 4234 904 1 5 0 11.150 27.05 20.00 23.92 43.75 35.2 1034.87 -609 -918 -1388 -2423 -1270 -168 639 1302 855 -370 -495 239 5 330 390 -177 -98 529 598 857 302 870 1126 587 456 220 -226 -217 360 1348 1514 1678 1195 -869 -1367 -713 -958 -395 -260 -899 -1130 -1001 -1001 -1108 -580 -754 -816 -754 -584 280 612 546 960 760 672 794 499 300 464 642 949 1103 1185 707 -266 -271 -181 -54 797 456 56 43 43 140 81 65 85 -7 164 -419 -851 -1138 -1768 -1230 -928 -774 -411 -90 1 201 296 431 358 812 698 371 483 523 0 -275 -291 -445 -15 33 -584 -826 -557 -592 -218 -7 80 -27 53 21 245 411 414 269 224 -157 -318 -50 107 234 586 520 757 1136 676 354 219 -137 -70 18 -84 -144 15 67 -262 -172 -181 -435 -556 -268 -426 -638 -1020 -501 -64 255 570 384 -172 -223 109 2 169 220 -100 -56 308 356 521 185 526 694 358 288 142 -144 -135 205 785 855 988 744 -549 -806 -417 -617 -278 -195 -743 -958 -874 -892 -989 -511 -658 -687 -636 -474 223 508 477 833 687 620 740 451 270 428 593 868 1075 1183 736 -271 -261 -167 -48 746 441 59 46 45 147 80 62 77 -6 144 -392 -847 -1189 -1889 -1369 -1064 -915 -492 -111 1 245 344 472 370 833 716 400 550 629 -1 -338 -337 -500 -17 37 -689 -1030 -698 -747 -285 -9 110 -37 72 26 295 481 483 328 284 -207 -419 -66 141 296 721 630 870 1344 811 432 279 -172 -89 24 -112 -196 21 96 -368 -244 -251 -606 -761 SS 20210628T165636.2Z 7849.705975 8 1 50.70 2 16.35 131.09 117.23 267.64 0.00 1 0.00 1 0 17 6.913e-03 5.720e-03 1.155e-04 9.035e-05 1.424625e-01 4.780740e-05 1.674818e-03 -6.000000e+00 4.058674e-03 232.32 -2.00 3.38 -2.00 314.22 0.00e+00 2.415505e-04 3.598780e-06 1.981019e-05 -6.000000e+00 1.821769e-04 290.17 -2.00 20.00 -2.00 313.59 0.00e+00 1.042 0.000 302.00 328.00 3 5.7443e-01 1.2278e-04 1.2511e-02 -6.0000e+00 1.0166e-02 7.6105e-04 1.3539e-04 7.1990e-03 -6.0000e+00 1.0987e-02 3.0767e-04 7.7640e-05 3.4881e-03 -6.0000e+00 6.5510e-03 -3.4005e-03 3.3300e-05 9.6765e-04 -6.0000e+00 2.7650e-03 9.7222e-02 -3.9950e-04 2.6116e-06 1.4080e-05 -6.0000e+00 1.9462e-04 -4.4377e-03 0.0000e+00 10 0 0 10 0 0 99.99 27.05 0.30 -0.00444 -0.00744 4293 917 1 5 0 10.990 27.05 20.00 23.93 43.53 35.2 1031.63 -606 -890 -1295 -2438 -1307 -109 659 1318 841 -379 -483 267 -9 405 396 -140 -112 542 593 904 322 840 1108 569 437 210 -223 -211 335 1366 1494 1677 1180 -870 -1361 -740 -962 -407 -256 -906 -1110 -990 -980 -1085 -536 -736 -825 -734 -563 257 618 543 945 760 702 802 504 296 461 628 969 1102 1179 726 -270 -283 -208 -52 775 441 78 50 33 156 54 57 33 -30 131 -429 -850 -1119 -1757 -1222 -942 -744 -396 -64 30 225 299 429 334 799 680 380 501 535 32 -276 -284 -444 -31 8 -591 -848 -566 -571 -182 16 123 12 81 30 224 388 390 238 229 -159 -303 -50 108 239 578 491 731 1109 676 328 188 -160 -76 7 -95 -118 30 94 -242 -150 -160 -438 -578 -275 -398 -574 -1057 -497 -43 253 556 388 -170 -224 125 -4 213 215 -81 -65 321 340 529 191 489 657 353 280 138 -144 -126 194 765 860 1005 707 -528 -817 -440 -596 -275 -195 -753 -945 -868 -877 -973 -474 -644 -698 -623 -459 207 515 455 822 689 649 717 457 267 427 582 887 1075 1176 755 -274 -272 -192 -47 727 444 82 52 35 164 53 54 30 -26 115 -401 -845 -1165 -1868 -1354 -1074 -873 -487 -78 36 273 345 467 344 819 696 407 567 637 40 -337 -340 -515 -35 9 -718 -1048 -703 -738 -236 22 166 16 107 38 268 452 451 289 288 -207 -408 -67 142 310 704 590 867 1303 805 396 237 -205 -99 8 -125 -164 41 133 -347 -210 -225 -602 -781 SS 20210628T170846.8Z 7849.714431 17 1 2.65 2 14.58 139.24 119.60 269.32 0.00 1 0.00 1 0 17 6.994e-03 5.847e-03 5.494e-04 4.389e-04 1.405931e-01 2.326389e-04 1.657575e-03 -6.000000e+00 4.106058e-03 232.32 -2.00 3.38 -2.00 314.07 0.00e+00 2.283523e-04 1.707528e-05 2.324569e-05 -6.000000e+00 1.843114e-04 290.17 -2.00 20.00 -2.00 313.47 0.00e+00 1.033 0.000 302.00 328.00 3 7.7023e-01 5.9710e-04 1.2387e-02 -6.0000e+00 1.0285e-02 2.0041e-03 6.5761e-04 7.1073e-03 -6.0000e+00 1.1115e-02 7.1215e-04 3.7728e-04 3.4474e-03 -6.0000e+00 6.6276e-03 -3.4596e-03 1.6173e-04 9.5989e-04 -6.0000e+00 2.7972e-03 8.0913e-02 -5.1073e-04 1.2647e-05 1.3967e-05 -6.0000e+00 1.9690e-04 -4.1814e-03 0.0000e+00 12 1 1 12 1 1 85.30 27.05 0.30 -0.00418 -0.00802 125 501 1 5 0 18.700 27.05 20.00 23.95 42.26 34.3 1021.56 -686 -893 -1193 -2489 -1356 -123 697 1426 734 -269 -513 325 -11 367 472 -195 -48 599 529 867 335 763 998 565 389 182 -247 -198 557 1392 1553 1750 1314 -786 -1282 -772 -874 -468 -267 -905 -1115 -1042 -1015 -1162 -611 -880 -814 -772 -554 302 533 609 819 753 595 662 481 310 489 650 863 1086 1149 714 -286 -241 -168 -72 786 552 14 102 -1 192 106 75 61 69 259 -359 -741 -1090 -1713 -1281 -951 -789 -436 -163 1 214 301 490 375 901 742 393 515 508 13 -303 -248 -473 33 29 -555 -851 -603 -615 -256 -72 36 -117 63 6 272 408 429 254 207 -145 -317 -87 82 251 643 575 780 1152 762 333 261 -134 -66 26 -54 -104 -45 -17 -281 -170 -190 -402 -583 -315 -431 -570 -1092 -555 -48 287 645 342 -129 -240 153 -6 195 262 -115 -29 362 328 520 203 480 607 359 256 123 -164 -121 328 792 908 1065 845 -487 -781 -466 -552 -325 -209 -746 -947 -912 -906 -1040 -539 -769 -715 -650 -467 250 440 528 710 679 548 616 453 290 450 599 822 1059 1151 746 -292 -232 -154 -64 730 554 15 108 -1 202 108 71 55 60 225 -333 -733 -1135 -1829 -1427 -1095 -938 -526 -202 1 253 352 536 387 917 758 423 587 612 16 -363 -289 -532 37 33 -656 -1030 -760 -783 -337 -96 49 -156 82 8 328 477 499 299 254 -185 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