File name: Pandora66s1_HuntsvilleAL_20210708_L2Fit_fout2c3d20200122p1-8.txt File generation date: 20251117T171948.0Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: Michael Newchurch Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 66 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora66_OF_v5d20200114.txt Instrument calibration file used: Pandora66s1_CF_v3d20200122.txt Level 1 file used: Pandora66s1_HuntsvilleAL_20210708_L1_smca1c3d20200122p1-8.txt Full location name: The University of Alabama in Huntsville- SWIRLL Short location name: HuntsvilleAL Country of location: United States Location latitude [deg]: 34.7252 Location longitude [deg]: -86.6464 Location altitude [m]: 221 Local noon date: 20210708 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Modification of session 1, fieldcal refday 20200921 First and last pixel inside fitting window: 253 395 Nominal wavelengths inside fitting window [nm]: 305.1019 305.2425 305.3831 305.5238 305.6644 305.8050 305.9456 306.0862 306.2268 306.3673 306.5079 306.6484 306.7890 306.9295 307.0700 307.2105 307.3510 307.4914 307.6319 307.7723 307.9128 308.0532 308.1936 308.3340 308.4744 308.6148 308.7551 308.8955 309.0358 309.1762 309.3165 309.4568 309.5971 309.7374 309.8777 310.0179 310.1582 310.2984 310.4386 310.5789 310.7191 310.8593 310.9994 311.1396 311.2798 311.4199 311.5600 311.7002 311.8403 311.9804 312.1205 312.2605 312.4006 312.5407 312.6807 312.8207 312.9607 313.1007 313.2407 313.3807 313.5207 313.6606 313.8006 313.9405 314.0805 314.2204 314.3603 314.5002 314.6400 314.7799 314.9197 315.0596 315.1994 315.3392 315.4790 315.6188 315.7586 315.8984 316.0381 316.1779 316.3176 316.4573 316.5970 316.7367 316.8764 317.0161 317.1558 317.2954 317.4351 317.5747 317.7143 317.8539 317.9935 318.1331 318.2727 318.4122 318.5518 318.6913 318.8308 318.9703 319.1098 319.2493 319.3888 319.5282 319.6677 319.8071 319.9465 320.0860 320.2254 320.3647 320.5041 320.6435 320.7828 320.9222 321.0615 321.2008 321.3401 321.4794 321.6187 321.7580 321.8972 322.0365 322.1757 322.3149 322.4542 322.5934 322.7325 322.8717 323.0109 323.1500 323.2892 323.4283 323.5674 323.7065 323.8456 323.9847 324.1238 324.2628 324.4019 324.5409 324.6799 324.8189 324.9579 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20210708T151340.3Z 7859.634494 230 1 49.95 2 36.57 98.99 21.73 110.36 0.00 1 0.00 1 0 17 2.459e-02 1.265e-02 5.465e-03 3.045e-03 1.790636e-01 1.579654e-03 2.064327e-03 -6.000000e+00 1.442143e-02 232.18 -2.00 3.38 -2.00 315.82 0.00e+00 6.447336e-04 1.639201e-04 7.338092e-05 -6.000000e+00 6.505522e-04 290.99 -2.00 20.00 -2.00 315.02 0.00e+00 1.244 0.000 302.00 328.00 3 6.8218e+00 4.1223e-03 1.5190e-02 -6.0000e+00 3.6097e-02 5.2940e-02 4.5920e-03 8.9901e-03 -6.0000e+00 3.9021e-02 6.2022e-03 2.6251e-03 4.3427e-03 -6.0000e+00 2.3282e-02 -6.1976e-03 1.1840e-03 1.2159e-03 -6.0000e+00 9.8267e-03 1.3976e-04 -4.3510e-05 8.9221e-05 1.5096e-05 -6.0000e+00 6.9261e-04 2.5472e-03 0.0000e+00 12 8 8 10 0 0 99.96 26.41 0.00 0.00255 0.00222 29 6 1 5 0 1722.050 26.41 20.00 23.22 31.36 34.0 989.67 -8071 15451 -3482 -1157 -9722 5587 -3740 7145 -3595 -1205 3378 -2337 -878 586 -2066 -1042 -1766 1345 1906 1888 1595 -681 -976 -911 4433 -611 -20 0 -3180 1750 424 2291 2398 -834 -2323 -2988 1872 -5674 -1504 -877 -1304 1081 1511 368 3378 -341 -647 -597 -215 -1285 901 -623 5868 1169 1206 1505 38 -1683 606 88 -319 790 3097 2131 -606 -1361 -1171 -725 -2148 -1490 -791 1335 -314 333 1764 -566 -1451 -1827 -2004 -643 -669 -1135 -2517 1052 -798 -660 942 44 254 -805 865 550 -1538 207 -272 1394 -164 2303 1108 -387 -650 -1736 -717 -2034 655 -878 -198 -815 1097 -73 1046 718 1385 -997 -1314 -750 790 1543 -187 -764 429 -268 1455 144 1247 -344 301 279 336 -372 -604 -561 328 -575 -646 308 619 703 376 854 -643 -531 -1542 -2184 3485 -937 -276 -2256 1091 -856 1623 -988 -330 862 -651 -266 196 -741 -393 -686 519 752 765 650 -281 -415 -404 1928 -286 -9 0 -1283 706 181 952 1053 -375 -987 -1286 849 -3227 -918 -607 -969 809 1150 284 2511 -260 -480 -426 -148 -897 644 -478 4411 960 1009 1271 33 -1467 508 74 -282 699 2868 2070 -584 -1202 -1010 -608 -1953 -1429 -814 1393 -331 334 1617 -503 -1176 -1415 -1627 -572 -626 -1163 -2763 1169 -921 -812 1197 58 334 -1019 988 602 -1569 201 -278 1534 -192 2880 1457 -502 -793 -2094 -822 -2470 797 -1141 -267 -1097 1512 -107 1573 1078 1965 -1403 -1694 -905 988 1903 -252 -1053 599 -373 2040 194 1578 -443 365 340 431 -482 -816 -773 454 -831 -941 466 959 1113 600 1323 -980 -784 -2258 SS 20210708T153852.5Z 7859.651996 242 1 49.96 2 31.50 104.12 17.11 119.93 0.00 1 0.00 1 0 17 1.627e-02 9.604e-03 4.073e-03 2.477e-03 1.689597e-01 1.288365e-03 1.957711e-03 -6.000000e+00 9.542748e-03 232.18 -2.00 3.38 -2.00 315.47 0.00e+00 2.348033e-04 1.245276e-04 5.559151e-05 -6.000000e+00 4.305509e-04 290.99 -2.00 20.00 -2.00 314.70 0.00e+00 1.172 0.000 302.00 328.00 3 6.6030e+00 3.3491e-03 1.4329e-02 -6.0000e+00 2.3885e-02 4.6405e-02 3.7234e-03 8.4879e-03 -6.0000e+00 2.5821e-02 8.2312e-03 2.1217e-03 4.1066e-03 -6.0000e+00 1.5407e-02 -7.5448e-03 9.4280e-04 1.1154e-03 -6.0000e+00 6.5015e-03 1.9116e-04 -2.0275e-04 7.2144e-05 1.4869e-05 -6.0000e+00 4.5839e-04 3.6255e-03 0.0000e+00 12 8 8 10 0 0 99.99 26.51 0.58 0.00363 0.00210 32 7 1 5 0 1561.000 26.51 20.00 23.23 33.25 33.9 998.72 -6321 6755 1755 -4815 -1169 903 755 2792 493 -4733 6478 -3792 948 -449 -386 -1767 -747 -174 2089 623 2084 -1805 570 -1187 3240 -786 -364 395 -1061 2016 -1869 2553 290 123 -2052 -2465 -623 -2457 -1093 58 -1872 1323 -781 655 1524 86 -1371 -273 -1195 -513 578 158 4173 1341 1366 1853 95 -1488 -21 464 180 825 2293 1084 -253 -715 -356 -1123 -559 -866 -460 246 364 502 1838 -1390 -645 -2204 -1143 -872 -31 -1483 -2232 217 -263 -469 870 -254 485 -1158 975 356 -746 343 -90 1271 78 1045 325 181 -665 -1382 -736 -1088 251 -750 -332 -364 374 220 737 1077 703 -504 -1235 -213 46 1172 -745 -399 189 -135 964 429 711 -68 279 -4 512 -255 -62 -281 629 -762 14 -6 328 327 539 490 121 -946 -1225 -1850 1824 491 -1301 -289 215 192 772 143 -1474 1866 -1171 307 -164 -156 -767 -327 -78 933 274 959 -809 256 -566 1530 -395 -178 187 -474 860 -861 1182 145 61 -969 -1175 -323 -1423 -701 42 -1474 1041 -641 530 1212 69 -1072 -203 -868 -370 431 125 3313 1141 1184 1538 81 -1277 -19 405 156 758 2220 1101 -252 -648 -313 -971 -488 -848 -486 254 373 519 1735 -1279 -532 -1756 -940 -795 -29 -1559 -2377 237 -309 -563 1082 -328 621 -1438 1141 399 -771 338 -93 1423 93 1284 417 226 -825 -1605 -816 -1267 313 -947 -436 -498 529 313 1082 1566 1020 -682 -1610 -258 55 1466 -976 -556 269 -191 1315 561 917 -84 326 -5 630 -333 -84 -372 835 -1060 20 -9 492 502 830 737 177 -1422 -1811 SS 20210708T155127.9Z 7859.660740 252 1 10.43 2 29.01 107.11 14.98 126.47 0.00 1 0.00 1 0 17 7.434e-03 5.923e-03 1.978e-03 1.463e-03 1.582688e-01 7.699600e-04 1.857444e-03 -6.000000e+00 4.359602e-03 232.18 -2.00 3.38 -2.00 314.56 0.00e+00 2.258567e-04 6.208565e-05 1.831830e-05 -6.000000e+00 1.966647e-04 290.99 -2.00 20.00 -2.00 313.89 0.00e+00 1.143 0.000 302.00 328.00 3 4.3781e+00 1.9831e-03 1.3783e-02 -6.0000e+00 1.0912e-02 2.3036e-02 2.1923e-03 7.9873e-03 -6.0000e+00 1.1796e-02 2.1174e-03 1.2527e-03 3.8735e-03 -6.0000e+00 7.0383e-03 -3.8608e-03 5.4223e-04 1.0697e-03 -6.0000e+00 2.9706e-03 1.8836e-03 -2.3565e-04 4.2302e-05 1.4884e-05 -6.0000e+00 2.0938e-04 2.5623e-03 0.0000e+00 12 1 1 12 1 1 99.96 26.51 0.22 0.00256 0.00079 17 19 1 5 0 569.340 26.51 20.00 23.25 34.60 34.1 1003.88 -1575 -481 -1696 -2549 -1490 373 414 2152 747 -582 19 288 -132 249 237 -358 -43 107 904 620 398 360 1678 96 674 166 -427 235 148 1396 1410 1781 1283 -746 -1768 -810 -978 -453 -186 -835 -1330 -871 -1058 -1001 -112 -566 -561 -376 -544 147 417 821 1105 802 672 661 447 242 554 719 728 1081 1194 804 -27 -355 -160 27 461 479 -147 87 110 402 69 -51 -384 -223 191 -509 -834 -1311 -1843 -1318 -884 -636 -640 -170 -99 53 402 455 296 737 972 575 545 420 -40 -137 -242 -378 -335 -271 -422 -685 -445 -775 -49 112 186 41 112 -114 252 177 524 421 42 -140 -466 54 280 160 435 552 948 1042 806 502 169 -77 -72 -30 -39 -162 -73 218 -193 -160 -279 -474 -699 -609 -193 -678 -995 -514 124 146 827 295 -238 8 116 -59 122 120 -193 -23 60 513 340 219 197 928 56 406 103 -259 131 81 743 776 1024 736 -432 -1023 -466 -586 -296 -136 -666 -1140 -730 -906 -857 -95 -473 -475 -305 -427 115 338 700 933 708 605 603 412 222 498 648 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