File name: Pandora66s1_HuntsvilleAL_20211005_L2Fit_fout2c3d20200122p1-8.txt File generation date: 20251117T174032.6Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: Michael Newchurch Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 66 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora66_OF_v5d20200114.txt Instrument calibration file used: Pandora66s1_CF_v3d20200122.txt Level 1 file used: Pandora66s1_HuntsvilleAL_20211005_L1_smca1c3d20200122p1-8.txt Full location name: The University of Alabama in Huntsville- SWIRLL Short location name: HuntsvilleAL Country of location: United States Location latitude [deg]: 34.7252 Location longitude [deg]: -86.6464 Location altitude [m]: 221 Local noon date: 20211005 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Modification of session 1, fieldcal refday 20200921 First and last pixel inside fitting window: 253 395 Nominal wavelengths inside fitting window [nm]: 305.1019 305.2425 305.3831 305.5238 305.6644 305.8050 305.9456 306.0862 306.2268 306.3673 306.5079 306.6484 306.7890 306.9295 307.0700 307.2105 307.3510 307.4914 307.6319 307.7723 307.9128 308.0532 308.1936 308.3340 308.4744 308.6148 308.7551 308.8955 309.0358 309.1762 309.3165 309.4568 309.5971 309.7374 309.8777 310.0179 310.1582 310.2984 310.4386 310.5789 310.7191 310.8593 310.9994 311.1396 311.2798 311.4199 311.5600 311.7002 311.8403 311.9804 312.1205 312.2605 312.4006 312.5407 312.6807 312.8207 312.9607 313.1007 313.2407 313.3807 313.5207 313.6606 313.8006 313.9405 314.0805 314.2204 314.3603 314.5002 314.6400 314.7799 314.9197 315.0596 315.1994 315.3392 315.4790 315.6188 315.7586 315.8984 316.0381 316.1779 316.3176 316.4573 316.5970 316.7367 316.8764 317.0161 317.1558 317.2954 317.4351 317.5747 317.7143 317.8539 317.9935 318.1331 318.2727 318.4122 318.5518 318.6913 318.8308 318.9703 319.1098 319.2493 319.3888 319.5282 319.6677 319.8071 319.9465 320.0860 320.2254 320.3647 320.5041 320.6435 320.7828 320.9222 321.0615 321.2008 321.3401 321.4794 321.6187 321.7580 321.8972 322.0365 322.1757 322.3149 322.4542 322.5934 322.7325 322.8717 323.0109 323.1500 323.2892 323.4283 323.5674 323.7065 323.8456 323.9847 324.1238 324.2628 324.4019 324.5409 324.6799 324.8189 324.9579 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20211005T141637.9Z 7948.594883 139 1 18.96 2 61.21 120.07 49.46 120.11 0.00 1 0.00 1 0 17 9.483e-03 5.442e-03 2.873e-03 1.257e-03 2.658764e-01 6.412042e-04 3.095545e-03 -6.000000e+00 5.465105e-03 227.57 -2.00 3.38 -2.00 316.52 0.00e+00 1.145232e-04 7.808335e-05 4.529859e-05 -6.000000e+00 2.481786e-04 288.43 -2.00 20.00 -2.00 315.72 0.00e+00 2.066 0.000 302.00 328.00 3 3.6469e+00 1.6707e-03 2.4051e-02 -6.0000e+00 1.3538e-02 2.4137e-02 1.8745e-03 1.3165e-02 -6.0000e+00 1.4695e-02 -1.0142e-03 1.0874e-03 6.4415e-03 -6.0000e+00 8.7881e-03 -3.8258e-03 5.1411e-04 1.7891e-03 -6.0000e+00 3.7333e-03 1.3377e-03 -1.9440e-04 3.6657e-05 2.1998e-05 -6.0000e+00 2.6681e-04 6.2391e-03 0.0000e+00 12 1 1 12 1 1 99.71 26.41 0.23 0.00624 0.00478 31 18 1 5 0 587.170 26.41 20.00 23.23 30.33 35.0 984.91 -3817 1325 -3196 -2965 -3943 -495 -40 1361 -679 -2204 1047 -1845 644 -531 -315 -1060 314 479 1186 798 1128 635 147 744 1290 -537 -63 11 159 1695 1612 1517 925 -1554 -1667 -1126 -566 -568 -155 -768 -1091 -666 -932 -782 194 -411 -774 -776 -545 145 610 576 1402 1006 721 974 321 268 561 514 792 1131 1533 774 -201 -119 -5 3 234 492 172 138 54 71 211 -12 26 -189 -13 -660 -944 -1228 -2022 -1047 -844 -702 -321 -160 134 166 314 361 393 870 598 398 476 772 -140 -526 -409 -561 -485 -181 -485 -605 -491 -622 23 128 227 134 51 257 86 499 350 165 -8 -374 -347 7 184 115 589 343 543 1251 657 249 202 -85 -16 2 -170 -107 271 -37 -231 -152 -152 -346 -551 -628 221 -558 -472 -622 -75 -6 227 -127 -432 198 -380 147 -130 -87 -320 97 154 395 275 391 221 50 265 479 -209 -24 4 57 604 574 583 384 -662 -667 -455 -253 -280 -86 -464 -712 -450 -615 -517 126 -269 -524 -514 -355 95 403 406 1037 746 551 758 255 211 432 397 636 929 1358 694 -177 -101 -4 3 201 453 165 137 53 69 190 -10 21 -150 -11 -601 -921 -1263 -2134 -1151 -954 -846 -390 -199 165 203 353 387 406 881 648 457 584 1002 -185 -675 -511 -675 -558 -216 -605 -795 -650 -835 32 185 343 197 75 360 115 655 462 220 -11 -531 -499 11 263 156 786 454 687 1594 865 352 289 -126 -24 3 -264 -169 436 -62 -384 -246 -244 -538 -843 SS 20211005T142043.2Z 7948.597722 142 1 10.12 2 60.48 120.90 48.76 121.06 0.00 1 0.00 1 0 17 8.089e-03 5.384e-03 2.155e-03 1.014e-03 2.608057e-01 5.170200e-04 3.033843e-03 -6.000000e+00 4.662080e-03 227.57 -2.00 3.38 -2.00 316.34 0.00e+00 1.364198e-04 6.040062e-05 4.049192e-05 -6.000000e+00 2.116966e-04 288.43 -2.00 20.00 -2.00 315.54 0.00e+00 2.021 0.000 302.00 328.00 3 2.6746e+00 1.3439e-03 2.3529e-02 -6.0000e+00 1.1549e-02 2.4336e-02 1.5076e-03 1.2888e-02 -6.0000e+00 1.2535e-02 -3.3252e-03 8.7071e-04 6.3112e-03 -6.0000e+00 7.4966e-03 -2.7466e-03 4.0660e-04 1.7556e-03 -6.0000e+00 3.1849e-03 3.7261e-03 -2.6347e-04 2.9464e-05 2.2096e-05 -6.0000e+00 2.2759e-04 5.7705e-03 0.0000e+00 12 1 1 12 1 1 99.75 26.41 0.22 0.00577 0.00379 45 48 1 5 0 216.250 26.41 20.00 23.23 30.60 35.1 986.84 -2085 1371 -2213 -2770 -3423 -310 -435 1787 243 -1105 21 293 -262 536 -218 -542 -425 427 503 1033 508 415 1050 693 680 61 -489 -633 480 1004 1362 1353 1069 -1320 -1290 -1391 -917 -644 211 -983 -857 -729 -810 -899 -172 -682 -725 -881 -496 369 571 524 1023 1039 869 734 493 516 309 852 1024 1293 1346 988 -118 -99 -327 86 585 502 -193 40 -36 136 -134 65 -319 -70 84 -642 -709 -1045 -1865 -1265 -896 -657 -325 -47 82 435 326 538 479 650 858 454 460 447 97 -389 -332 -589 -158 -252 -647 -893 -574 -506 -61 -58 192 27 103 49 160 290 393 224 221 -305 -455 -10 168 263 594 455 679 1191 579 198 105 -133 25 99 -82 -104 135 75 -201 -146 -234 -326 -544 -373 254 -423 -487 -594 -52 -79 326 50 -236 4 65 -66 142 -66 -178 -145 140 171 360 179 146 382 267 274 26 -202 -244 172 362 523 559 446 -564 -552 -604 -413 -320 117 -635 -565 -499 -569 -635 -120 -477 -495 -589 -325 244 401 372 764 816 670 577 394 408 240 662 826 1121 1205 892 -105 -85 -278 72 503 465 -186 40 -35 134 -122 56 -262 -55 71 -585 -692 -1077 -1976 -1402 -1021 -769 -398 -59 102 515 370 579 497 661 927 523 545 563 128 -503 -416 -712 -182 -303 -813 -1141 -767 -684 -84 -84 283 41 151 69 216 369 501 300 305 -434 -660 -14 234 361 797 582 861 1521 765 270 151 -190 37 145 -128 -164 219 121 -325 -237 -367 -510 -837 SS 20211005T142539.5Z 7948.601151 145 1 49.56 2 59.62 121.91 47.93 122.23 0.00 1 0.00 1 0 17 8.647e-03 5.460e-03 2.195e-03 9.556e-04 2.559002e-01 4.874541e-04 2.982537e-03 -6.000000e+00 4.984089e-03 227.57 -2.00 3.38 -2.00 316.55 0.00e+00 2.197452e-04 5.980880e-05 4.359675e-05 -6.000000e+00 2.263123e-04 288.43 -2.00 20.00 -2.00 315.74 0.00e+00 1.969 0.000 302.00 328.00 3 4.1420e+00 1.2700e-03 2.2997e-02 -6.0000e+00 1.2347e-02 3.1564e-02 1.4248e-03 1.2688e-02 -6.0000e+00 1.3401e-02 9.4581e-05 8.2801e-04 6.2131e-03 -6.0000e+00 8.0144e-03 -4.8915e-03 3.9095e-04 1.7329e-03 -6.0000e+00 3.4050e-03 9.0480e-04 -2.2628e-04 2.7949e-05 2.1903e-05 -6.0000e+00 2.4330e-04 5.5976e-03 0.0000e+00 11 1 0 11 8 0 99.97 26.51 0.23 0.00560 0.00390 80 17 1 5 0 619.480 26.51 20.00 23.23 30.97 35.2 988.39 -3181 1834 -2447 -2944 -3614 663 161 1481 146 -1084 973 -1010 -44 195 -371 -1273 -252 113 1032 710 634 -91 666 -6 1041 -185 78 -421 445 1719 757 1900 1011 -1395 -936 -977 -378 -854 -503 -1006 -960 -548 -537 -481 460 -590 -776 -808 -531 205 489 433 1503 945 754 954 484 -269 162 499 798 1159 1397 1122 -332 -354 -335 101 587 265 -69 97 -11 177 340 -137 58 -270 -118 -392 -679 -1165 -1982 -1093 -757 -742 -261 -149 140 387 564 658 403 742 656 604 462 735 -27 -327 -521 -651 -916 -277 -602 -863 -473 -534 125 154 262 41 240 -57 76 387 353 296 -36 -304 -427 -152 230 282 511 266 798 982 745 234 105 -37 129 64 -113 -121 97 127 -176 -49 -173 -507 -546 -538 316 -439 -484 -541 94 25 253 28 -215 187 -210 -10 48 -104 -388 -79 37 321 229 206 -30 224 -2 385 -71 30 -149 147 564 268 715 412 -582 -365 -385 -165 -412 -272 -627 -609 -360 -361 -325 307 -396 -509 -517 -334 130 328 310 1123 707 580 747 385 -214 126 387 644 953 1239 998 -307 -302 -282 84 498 241 -68 99 -11 171 319 -116 47 -212 -98 -350 -648 -1170 -2129 -1224 -867 -870 -320 -187 175 460 642 715 425 765 687 668 546 953 -35 -418 -653 -788 -1062 -332 -752 -1137 -625 -740 175 228 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