File name: Pandora282s1_Ilo-UNAM_20250124_L2Fit_fout2c3d20250118p1-8.txt File generation date: 20250829T094041.9Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 282 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora282_OF_v2d20240118.txt Instrument calibration file used: Pandora282s1_CF_v3d20250118.txt Level 1 file used: Pandora282s1_Ilo-UNAM_20250124_L1_smca1c3d20250118p1-8.txt Full location name: Grupo de Investigacion en Ciencias de la Atmosfera, UNAM, Peru Short location name: Ilo-UNAM Country of location: Peru Location latitude [deg]: -17.6020 Location longitude [deg]: -71.3389 Location altitude [m]: 85 Local noon date: 20250124 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 202 344 Nominal wavelengths inside fitting window [nm]: 305.0533 305.1939 305.3345 305.4751 305.6156 305.7562 305.8968 306.0373 306.1778 306.3184 306.4589 306.5994 306.7399 306.8803 307.0208 307.1613 307.3017 307.4421 307.5825 307.7230 307.8634 308.0037 308.1441 308.2845 308.4248 308.5652 308.7055 308.8458 308.9861 309.1264 309.2667 309.4070 309.5473 309.6875 309.8278 309.9680 310.1082 310.2484 310.3886 310.5288 310.6690 310.8091 310.9493 311.0894 311.2296 311.3697 311.5098 311.6499 311.7900 311.9300 312.0701 312.2102 312.3502 312.4902 312.6302 312.7702 312.9102 313.0502 313.1902 313.3301 313.4701 313.6100 313.7500 313.8899 314.0298 314.1697 314.3095 314.4494 314.5893 314.7291 314.8690 315.0088 315.1486 315.2884 315.4282 315.5680 315.7077 315.8475 315.9872 316.1269 316.2667 316.4064 316.5461 316.6858 316.8254 316.9651 317.1048 317.2444 317.3840 317.5236 317.6632 317.8028 317.9424 318.0820 318.2216 318.3611 318.5006 318.6402 318.7797 318.9192 319.0587 319.1982 319.3376 319.4771 319.6165 319.7560 319.8954 320.0348 320.1742 320.3136 320.4530 320.5923 320.7317 320.8710 321.0104 321.1497 321.2890 321.4283 321.5676 321.7068 321.8461 321.9854 322.1246 322.2638 322.4030 322.5422 322.6814 322.8206 322.9598 323.0990 323.2381 323.3772 323.5164 323.6555 323.7946 323.9337 324.0727 324.2118 324.3509 324.4899 324.6289 324.7679 324.9070 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SU 20250124T111854.2Z 9155.471461 711 1 6.43 2 79.47 106.85 18.79 117.88 0.00 1 0.00 1 0 25 3.527e-01 2.406e-02 3.346e-01 2.029e-02 5.141727e-01 1.058022e-02 6.604204e-03 -6.000000e+00 1.972808e-01 225.49 -2.00 3.04 -2.00 320.37 0.00e+00 3.434505e-03 4.018122e-03 5.684769e-03 -6.000000e+00 1.017376e-02 293.42 -2.00 20.00 -2.00 319.59 0.00e+00 5.253 0.000 302.00 328.00 3 3.4004e+00 3.3001e-02 6.2528e-02 -6.0000e+00 4.8776e-01 6.5322e-02 4.1698e-02 4.3893e-02 -6.0000e+00 5.2999e-01 -1.1096e-01 3.6006e-02 1.5187e-02 -6.0000e+00 3.1625e-01 5.3690e-02 1.8483e-02 4.2237e-03 -6.0000e+00 1.4020e-01 6.1090e-05 -1.0786e-03 5.6175e-04 6.2868e-05 -6.0000e+00 9.1520e-03 -4.7223e-03 0.0000e+00 12 9 9 12 1 1 999.00 25.42 0.63 -0.00472 -0.01283 1 9 1 5 0 3212.420 33.50 20.00 25.42 31.30 3.8 1029.73 -102009 900000 -131957 900000 -1530 -138844 900000 -158834 93504 900000 900000 -70140 -65300 900000 900000 40938 51204 140704 78946 -2295 100979 -55464 -8230 4535 2232 -12744 10218 107871 -18232 -41476 39133 10957 28725 -3808 -24588 -16189 76488 15018 -23096 11342 12751 6976 -9033 19319 9778 -1835 13304 5299 3457 11547 6547 536 262 -5912 8154 1347 989 -10718 2081 2038 3441 2533 11681 1957 -10480 7093 7955 4808 -7720 303 60 -423 11184 8061 8036 172 -3788 3188 -3905 -202 -3193 -4115 1493 30 -3693 1389 4933 1645 3535 -1075 -146 -6814 -2829 -3246 -1949 -2467 -1887 -2199 881 1759 -854 -1476 -6496 -4734 1017 -3162 -260 -878 -169 1706 4919 1438 1890 2374 -152 -1650 1532 -747 -1660 2865 -1169 1786 383 828 151 220 -455 918 -244 -1032 -175 574 -1217 -198 269 -339 -12 -727 1443 -125 -269 -685 -24 -2016 900000 -4031 900000 -30 -3742 900000 -6279 1848 900000 900000 -1664 -1807 900000 900000 809 1012 2781 1560 -86 1996 -3618 -342 179 97 -680 444 2132 -973 -2869 1392 606 1533 -309 -2333 -1344 2721 1158 -3195 1345 1689 1048 -1678 2787 1565 -337 2130 932 635 2031 1320 128 68 -1776 2256 413 315 -3505 642 616 1047 846 4017 759 -4915 2689 2844 1771 -3440 145 33 -243 5747 4099 3798 79 -1641 1374 -1754 -103 -1957 -2906 1102 24 -2962 1141 4152 1490 3179 -990 -125 -5747 -2338 -2642 -1695 -2263 -1973 -2640 1055 2131 -1007 -1727 -7212 -5084 1122 -3901 -302 -1088 -223 2438 7531 2255 2964 3566 -236 -2441 2164 -1124 -2493 4392 -1905 2756 580 1304 230 321 -637 1255 -371 -1651 -304 1052 -2352 -370 535 -723 -26 -1634 3226 -277 -569 -1376 -45 SU 20250124T112139.5Z 9155.473374 714 1 29.38 2 78.84 106.67 18.23 118.61 0.00 1 0.00 1 0 17 3.666e-01 1.448e-02 2.078e-01 8.231e-03 5.167160e-01 4.203483e-03 5.459336e-03 -6.000000e+00 2.033446e-01 225.49 -2.00 3.04 -2.00 320.30 0.00e+00 4.707935e-03 1.561719e-03 1.720888e-03 -6.000000e+00 1.013150e-02 293.42 -2.00 20.00 -2.00 319.50 0.00e+00 4.982 0.000 302.00 328.00 3 3.8270e+00 1.3008e-02 5.4137e-02 -6.0000e+00 5.0143e-01 1.5986e-01 1.6293e-02 2.4224e-02 -6.0000e+00 5.4398e-01 -1.5783e-01 1.3842e-02 1.3477e-02 -6.0000e+00 3.2697e-01 6.2498e-02 7.1436e-03 5.2047e-03 -6.0000e+00 1.4501e-01 4.8711e-05 -8.6071e-04 2.2207e-04 5.7337e-05 -6.0000e+00 9.4011e-03 -2.9280e-03 0.0000e+00 12 8 8 10 0 0 99.67 25.43 0.65 -0.00293 -0.00940 13 13 1 5 0 2259.460 33.75 20.01 25.43 31.38 3.8 1030.31 -101760 900000 -19496 900000 -118010 -70813 -104786 -74198 91283 -96494 900000 20289 -35262 33670 31790 -33802 -16282 -11936 213072 -17236 -6128 12903 14387 9319 1446 6196 -11194 236301 30543 39 33637 -763 29526 3737 -42797 -6081 7702 -17400 -6844 -7982 6992 -10828 762 25755 -6216 -7642 6887 2158 10144 12327 23460 -5130 2331 1252 3067 1263 3232 4083 -83 3041 -2938 743 -328 5651 1691 1205 -22 982 2627 3785 1306 -1851 2695 1513 2965 348 -3284 -3247 -597 -2411 -187 -3270 -201 -542 -751 863 1664 994 2156 1881 659 -2264 -1332 -349 -2318 -2259 -2180 -870 -697 -853 -524 268 -2346 -1159 -938 -1506 -476 393 -1436 189 1502 228 874 677 37 -1187 -47 -439 778 653 -565 1572 -126 -126 968 1025 -1057 1717 414 127 107 483 337 95 -93 -3 404 -172 347 -40 -924 -485 -668 -2301 900000 -242 900000 -3356 -1307 -2858 -1667 732 -3251 900000 228 -849 513 612 -1491 -666 -508 1709 -871 -285 486 542 396 71 303 -665 1896 1103 2 1403 -53 1729 309 -5321 -498 593 -2010 -867 -1229 1043 -2059 136 3678 -1232 -1569 1238 412 1831 2255 4178 -1354 619 363 920 397 1027 1287 -27 922 -966 256 -129 2353 779 536 -9 415 1163 1922 693 -1068 1490 809 1591 171 -1523 -1461 -280 -1354 -109 -2239 -147 -419 -619 753 1526 953 2063 1760 583 -1902 -1036 -264 -1935 -2158 -2385 -984 -874 -1091 -632 317 -2571 -1237 -1087 -1720 -563 490 -1955 279 2419 365 1393 1039 58 -1763 -68 -664 1240 1026 -915 2625 -206 -201 1456 1483 -1485 2327 625 215 185 879 636 189 -197 -6 865 -378 768 -87 -1921 -1022 -1345 SU 20250124T113433.1Z 9155.482328 741 1 30.46 2 75.89 105.89 15.64 122.81 0.00 1 0.00 1 0 25 1.605e-01 1.055e-02 9.224e-02 4.928e-03 4.303669e-01 2.452807e-03 4.460334e-03 -6.000000e+00 8.902832e-02 225.49 -2.00 3.04 -2.00 319.37 0.00e+00 3.008436e-03 6.801645e-04 7.938815e-04 -6.000000e+00 4.128843e-03 293.42 -2.00 20.00 -2.00 318.51 0.00e+00 4.010 0.000 302.00 328.00 3 4.1261e+00 6.9630e-03 4.3676e-02 -6.0000e+00 2.1944e-01 7.2548e-02 8.2752e-03 1.9434e-02 -6.0000e+00 2.3799e-01 -4.5541e-02 6.2866e-03 1.0087e-02 -6.0000e+00 1.4289e-01 1.2731e-02 3.3552e-03 3.6554e-03 -6.0000e+00 6.2604e-02 1.0094e-04 -5.2176e-04 1.3244e-04 3.6539e-05 -6.0000e+00 4.0070e-03 -3.3019e-03 0.0000e+00 12 8 8 10 0 0 99.81 25.47 0.37 -0.00330 -0.00722 12 12 1 5 0 2537.830 33.75 20.00 25.47 31.29 3.8 1030.05 -38762 118976 -15080 63849 -75484 -24908 18690 -6701 49170 -29671 74 -16642 -37208 -11753 -5402 -19724 6278 15646 8285 3357 3511 2618 -4796 -6099 21255 -5056 4438 25872 -4684 667 -177 8979 15172 -2799 -19620 -9566 -4064 -7376 -4719 145 4406 -7062 376 3056 -1208 -3735 -3497 1175 2950 2105 9880 -839 -666 -55 3110 719 241 1893 817 738 -49 1858 1332 3642 -346 1522 88 184 -143 1023 235 1832 1134 826 1735 -75 500 -3277 -370 -2906 -1209 -1423 -1876 -1138 -763 242 -60 1083 885 429 1455 -787 -442 -1360 10 -1100 -849 512 394 630 -486 -751 -2349 -1070 -438 -1274 -822 -300 -241 -408 894 753 165 -188 147 -1076 -143 -287 791 649 385 514 351 533 463 819 -449 878 275 458 215 53 105 -617 -58 -268 331 549 122 448 -211 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