File name: Pandora282s1_Ilo-UNAM_20250125_L2Fit_fout2c3d20250118p1-8.txt File generation date: 20250829T094101.9Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 282 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora282_OF_v2d20240118.txt Instrument calibration file used: Pandora282s1_CF_v3d20250118.txt Level 1 file used: Pandora282s1_Ilo-UNAM_20250125_L1_smca1c3d20250118p1-8.txt Full location name: Grupo de Investigacion en Ciencias de la Atmosfera, UNAM, Peru Short location name: Ilo-UNAM Country of location: Peru Location latitude [deg]: -17.6020 Location longitude [deg]: -71.3389 Location altitude [m]: 85 Local noon date: 20250125 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 202 344 Nominal wavelengths inside fitting window [nm]: 305.0533 305.1939 305.3345 305.4751 305.6156 305.7562 305.8968 306.0373 306.1778 306.3184 306.4589 306.5994 306.7399 306.8803 307.0208 307.1613 307.3017 307.4421 307.5825 307.7230 307.8634 308.0037 308.1441 308.2845 308.4248 308.5652 308.7055 308.8458 308.9861 309.1264 309.2667 309.4070 309.5473 309.6875 309.8278 309.9680 310.1082 310.2484 310.3886 310.5288 310.6690 310.8091 310.9493 311.0894 311.2296 311.3697 311.5098 311.6499 311.7900 311.9300 312.0701 312.2102 312.3502 312.4902 312.6302 312.7702 312.9102 313.0502 313.1902 313.3301 313.4701 313.6100 313.7500 313.8899 314.0298 314.1697 314.3095 314.4494 314.5893 314.7291 314.8690 315.0088 315.1486 315.2884 315.4282 315.5680 315.7077 315.8475 315.9872 316.1269 316.2667 316.4064 316.5461 316.6858 316.8254 316.9651 317.1048 317.2444 317.3840 317.5236 317.6632 317.8028 317.9424 318.0820 318.2216 318.3611 318.5006 318.6402 318.7797 318.9192 319.0587 319.1982 319.3376 319.4771 319.6165 319.7560 319.8954 320.0348 320.1742 320.3136 320.4530 320.5923 320.7317 320.8710 321.0104 321.1497 321.2890 321.4283 321.5676 321.7068 321.8461 321.9854 322.1246 322.2638 322.4030 322.5422 322.6814 322.8206 322.9598 323.0990 323.2381 323.3772 323.5164 323.6555 323.7946 323.9337 324.0727 324.2118 324.3509 324.4899 324.6289 324.7679 324.9070 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250125T150811.1Z 9156.630684 339 1 21.94 2 26.03 96.92 25.16 241.11 0.00 1 0.00 1 0 17 8.628e-03 7.083e-03 1.780e-03 1.439e-03 1.336404e-01 7.255437e-04 1.441667e-03 -6.000000e+00 4.786682e-03 225.49 -2.00 3.04 -2.00 313.91 0.00e+00 6.655965e-04 5.402296e-05 1.766086e-05 -6.000000e+00 2.219400e-04 293.43 -2.00 20.00 -2.00 313.33 0.00e+00 1.112 0.000 302.00 328.00 3 4.8844e+00 1.8314e-03 1.2415e-02 -6.0000e+00 1.1799e-02 3.6402e-02 2.0268e-03 6.0286e-03 -6.0000e+00 1.2795e-02 -1.8206e-04 1.1714e-03 2.9165e-03 -6.0000e+00 7.6818e-03 -4.6614e-03 5.2019e-04 9.1835e-04 -6.0000e+00 3.3669e-03 1.2217e-03 -1.9621e-04 3.7477e-05 1.0605e-05 -6.0000e+00 2.1536e-04 -5.3317e-03 0.0000e+00 12 9 1 12 1 1 91.70 25.79 0.45 -0.00533 -0.00681 12 18 1 5 0 1686.990 33.75 20.00 25.79 37.66 3.7 1071.29 352 111 -300 -1335 -2496 -1892 -139 1400 1703 469 -1035 -970 -1036 243 873 218 555 571 483 1296 682 633 655 552 184 770 463 111 -808 -36 1092 1161 1778 -569 -2453 -2624 -2663 -1298 -725 -239 -615 -724 -835 -673 -253 -624 -475 -693 -857 -457 518 817 395 726 902 813 521 413 253 188 469 1414 1542 2129 499 248 -474 -1109 -32 489 507 877 449 684 576 -251 -356 -1739 -1009 -747 -1140 -1214 -1751 -1696 -956 -512 -144 295 756 540 558 148 -388 -87 -21 -182 -14 981 619 451 75 -493 -864 -416 -647 -903 -807 -653 -302 275 619 670 605 353 -70 -371 -369 -220 101 109 -126 256 265 287 743 387 -166 327 250 132 149 -68 -178 -100 -21 111 -25 440 349 5 -286 -726 -517 163 56 -152 -635 -1098 -764 -57 631 800 234 -501 -454 -524 127 505 130 332 344 298 815 441 400 412 362 119 512 309 73 -487 -21 658 731 1116 -378 -1523 -1620 -1665 -871 -549 -201 -540 -629 -744 -603 -223 -551 -426 -594 -737 -379 436 697 353 645 819 743 486 385 231 170 432 1370 1540 2152 513 242 -434 -1000 -29 481 530 922 479 710 590 -244 -320 -1516 -866 -675 -1106 -1241 -1845 -1846 -1056 -586 -174 357 922 668 666 167 -409 -88 -21 -196 -16 1163 765 557 90 -576 -943 -458 -756 -1089 -1011 -822 -391 359 843 927 805 451 -84 -443 -429 -254 124 140 -166 336 341 368 931 463 -195 368 294 159 188 -84 -222 -126 -27 152 -34 613 497 7 -393 -1007 -693 SS 20250125T151300.6Z 9156.634034 342 1 28.91 2 24.89 96.85 26.15 241.87 0.00 1 0.00 1 0 17 9.676e-03 7.804e-03 2.041e-03 1.631e-03 1.348355e-01 8.205190e-04 1.457581e-03 -6.000000e+00 5.368406e-03 225.49 -2.00 3.04 -2.00 313.99 0.00e+00 7.592209e-04 6.186119e-05 2.785386e-05 -6.000000e+00 2.489036e-04 293.43 -2.00 20.00 -2.00 313.39 0.00e+00 1.102 0.000 302.00 328.00 3 5.4567e+00 2.0742e-03 1.2362e-02 -6.0000e+00 1.3232e-02 4.9196e-02 2.2971e-03 6.1168e-03 -6.0000e+00 1.4350e-02 -2.8146e-03 1.3257e-03 2.9519e-03 -6.0000e+00 8.6153e-03 -3.6856e-03 5.8963e-04 9.6868e-04 -6.0000e+00 3.7763e-03 6.9185e-04 -9.4121e-05 4.2501e-05 1.0910e-05 -6.0000e+00 2.4152e-04 -5.7026e-03 0.0000e+00 11 8 0 10 0 0 95.49 25.81 0.36 -0.00570 -0.00641 10 10 1 5 0 2890.500 34.00 20.00 25.81 37.82 3.7 1072.70 185 678 606 -1296 -3858 -2075 -124 451 1015 -414 -1166 -907 -1058 142 949 534 -369 1059 1221 1969 1014 368 532 748 929 933 -66 802 -631 -428 2178 916 1602 -65 -2716 -3147 -2070 -1993 -866 -196 -314 -1008 -801 -273 -623 -486 -342 -840 -911 -406 910 417 705 565 593 907 910 329 84 669 528 824 1348 2030 921 -265 -480 -1439 59 873 577 1009 441 965 698 -66 -393 -1462 -1153 -1244 -1428 -1271 -1835 -1655 -1135 -270 -132 286 878 768 350 -74 -413 -484 -102 33 -20 1030 915 209 -48 -523 -1014 -720 -824 -863 -745 -739 -141 432 750 758 592 76 -88 -363 -416 -520 4 324 -319 342 481 633 674 487 9 616 271 264 80 -9 195 -104 -273 188 -35 613 144 24 -275 -706 -950 84 331 299 -604 -1700 -829 -50 202 469 -203 -551 -414 -523 72 531 324 -215 611 720 1181 627 224 322 469 605 627 -45 502 -387 -248 1252 558 964 -41 -1727 -1882 -1313 -1360 -657 -163 -270 -903 -733 -251 -567 -441 -300 -708 -776 -333 756 350 617 515 554 849 822 299 79 616 497 781 1368 2067 950 -264 -449 -1274 53 832 582 1065 473 1002 723 -62 -345 -1250 -975 -1104 -1419 -1315 -1942 -1807 -1251 -319 -158 355 1097 937 416 -84 -440 -475 -102 36 -22 1213 1112 255 -58 -611 -1108 -796 -957 -1071 -919 -950 -187 570 1035 1018 798 100 -109 -433 -483 -625 5 411 -427 457 628 796 834 575 10 687 317 314 100 -12 247 -135 -359 251 -48 860 206 35 -380 -953 -1298 SS 20250125T151757.2Z 9156.637467 345 1 12.96 2 23.72 96.78 27.17 242.57 0.00 1 0.00 1 0 17 9.200e-03 7.346e-03 2.675e-03 2.178e-03 1.322918e-01 1.098298e-03 1.428992e-03 -6.000000e+00 5.104363e-03 225.49 -2.00 3.04 -2.00 313.86 0.00e+00 7.517144e-04 8.094760e-05 2.101937e-05 -6.000000e+00 2.366629e-04 293.43 -2.00 20.00 -2.00 313.28 0.00e+00 1.092 0.000 302.00 328.00 3 5.0943e+00 2.7715e-03 1.2217e-02 -6.0000e+00 1.2582e-02 4.2791e-02 3.0631e-03 6.0011e-03 -6.0000e+00 1.3644e-02 -1.2680e-03 1.7722e-03 2.8894e-03 -6.0000e+00 8.1916e-03 -4.2990e-03 7.8810e-04 9.3709e-04 -6.0000e+00 3.5905e-03 1.0113e-03 -1.7682e-04 5.6683e-05 1.0736e-05 -6.0000e+00 2.2964e-04 -5.6257e-03 0.0000e+00 12 9 1 12 1 1 92.71 25.83 0.43 -0.00563 -0.00695 5 14 1 5 0 2158.280 34.00 20.00 25.83 37.97 3.7 1073.64 400 578 252 -1060 -2944 -3076 -1277 630 2002 1285 -860 -1582 -158 989 1509 -374 292 205 613 1698 1210 276 643 -134 -148 298 300 -61 -1021 -165 1121 884 1470 -255 -2477 -2446 -1947 -2064 -567 50 -748 -522 -761 -533 -638 -459 -573 -802 -937 -152 406 750 576 1142 930 906 718 703 -61 610 717 1141 1440 2097 815 -255 -674 -697 -169 650 782 569 547 488 950 166 -1062 -1421 -1320 -1158 -941 -1179 -1614 -1757 -1228 -482 -248 316 610 740 465 290 -29 -688 -111 -155 -2 924 885 38 -379 -410 -840 -618 -700 -829 -714 -650 -450 164 768 582 495 273 23 -147 -59 -50 7 38 25 220 569 435 484 452 151 551 297 405 180 -272 154 57 -38 105 99 177 -32 -237 -202 -571 -675 192 280 123 -521 -1262 -1305 -551 277 967 655 -428 -767 -82 527 889 -228 179 127 386 1085 793 178 412 -85 -97 202 203 -38 -627 -101 688 535 939 -172 -1561 -1443 -1225 -1409 -432 42 -659 -474 -677 -476 -565 -404 -514 -689 -808 -126 343 639 513 1053 840 824 664 650 -56 572 654 1102 1428 2191 864 -248 -643 -622 -153 634 807 592 576 523 959 159 -957 -1228 -1131 -1043 -902 -1190 -1748 -1885 -1394 -564 -295 389 759 898 546 322 -30 -692 -113 -164 -2 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