File name: Pandora282s1_Ilo-UNAM_20250212_L2Fit_fout2c3d20250118p1-8.txt File generation date: 20250829T094416.1Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 282 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora282_OF_v2d20240118.txt Instrument calibration file used: Pandora282s1_CF_v3d20250118.txt Level 1 file used: Pandora282s1_Ilo-UNAM_20250212_L1_smca1c3d20250118p1-8.txt Full location name: Grupo de Investigacion en Ciencias de la Atmosfera, UNAM, Peru Short location name: Ilo-UNAM Country of location: Peru Location latitude [deg]: -17.6020 Location longitude [deg]: -71.3389 Location altitude [m]: 85 Local noon date: 20250212 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 202 344 Nominal wavelengths inside fitting window [nm]: 305.0533 305.1939 305.3345 305.4751 305.6156 305.7562 305.8968 306.0373 306.1778 306.3184 306.4589 306.5994 306.7399 306.8803 307.0208 307.1613 307.3017 307.4421 307.5825 307.7230 307.8634 308.0037 308.1441 308.2845 308.4248 308.5652 308.7055 308.8458 308.9861 309.1264 309.2667 309.4070 309.5473 309.6875 309.8278 309.9680 310.1082 310.2484 310.3886 310.5288 310.6690 310.8091 310.9493 311.0894 311.2296 311.3697 311.5098 311.6499 311.7900 311.9300 312.0701 312.2102 312.3502 312.4902 312.6302 312.7702 312.9102 313.0502 313.1902 313.3301 313.4701 313.6100 313.7500 313.8899 314.0298 314.1697 314.3095 314.4494 314.5893 314.7291 314.8690 315.0088 315.1486 315.2884 315.4282 315.5680 315.7077 315.8475 315.9872 316.1269 316.2667 316.4064 316.5461 316.6858 316.8254 316.9651 317.1048 317.2444 317.3840 317.5236 317.6632 317.8028 317.9424 318.0820 318.2216 318.3611 318.5006 318.6402 318.7797 318.9192 319.0587 319.1982 319.3376 319.4771 319.6165 319.7560 319.8954 320.0348 320.1742 320.3136 320.4530 320.5923 320.7317 320.8710 321.0104 321.1497 321.2890 321.4283 321.5676 321.7068 321.8461 321.9854 322.1246 322.2638 322.4030 322.5422 322.6814 322.8206 322.9598 323.0990 323.2381 323.3772 323.5164 323.6555 323.7946 323.9337 324.0727 324.2118 324.3509 324.4899 324.6289 324.7679 324.9070 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250212T114934.3Z 9174.492758 267 1 30.31 2 74.26 99.51 107.38 282.67 0.00 1 0.00 1 0 17 5.329e-02 8.071e-03 2.957e-02 3.398e-03 3.929018e-01 1.676648e-03 4.088384e-03 -6.000000e+00 2.957153e-02 225.63 -2.00 3.04 -2.00 318.86 0.00e+00 3.418609e-03 3.962864e-04 5.759853e-04 -6.000000e+00 1.371591e-03 293.54 -2.00 20.00 -2.00 317.96 0.00e+00 3.620 0.000 302.00 328.00 3 3.9504e+00 4.6225e-03 3.9486e-02 -6.0000e+00 7.2907e-02 2.3231e-02 5.3745e-03 1.7653e-02 -6.0000e+00 7.9068e-02 -3.0184e-02 3.8000e-03 9.1135e-03 -6.0000e+00 4.7469e-02 9.8300e-03 2.0458e-03 3.6557e-03 -6.0000e+00 2.0790e-02 1.8600e-04 -3.5805e-04 9.1311e-05 3.3795e-05 -6.0000e+00 1.3305e-03 -2.2052e-03 0.0000e+00 11 8 0 10 0 0 97.86 25.59 0.45 -0.00221 -0.00490 19 19 1 5 0 1595.150 33.75 20.00 25.59 33.61 3.6 1044.57 -31622 6370 -18881 -731 -9477 -13766 -33648 2685 -9863 -98 -2216 3634 -16546 6075 683 -7503 -10208 9191 1232 1622 1770 1937 19 -1134 -1319 972 -245 10381 -4321 -581 -199 -1381 -1474 -3356 -6480 -2453 -4990 -4486 146 -2089 1029 -2606 668 337 -178 -1181 -170 1120 220 1101 4826 27 -325 1646 860 1425 1055 1067 -558 -279 2062 818 2335 2510 1764 747 277 -1302 -382 607 465 1174 668 1102 971 291 -1000 -2521 -1330 -2687 -990 -1857 -1834 -1853 -752 -577 268 363 1207 256 839 -706 -689 -110 -350 -396 -113 1193 843 38 -390 -1428 -1504 -1334 -477 -994 -641 -290 158 625 851 518 843 281 224 -543 -546 -38 456 39 -288 481 230 439 576 86 -29 54 658 -146 349 -50 -28 -401 -278 -209 290 558 429 108 -89 -784 -708 -1289 203 -820 -25 -317 -456 -1439 90 -422 -4 -93 151 -998 356 51 -704 -1062 841 130 178 201 216 2 -141 -175 132 -34 1249 -570 -75 -28 -226 -272 -678 -1267 -439 -994 -1038 36 -624 332 -924 240 125 -67 -453 -65 419 83 421 1909 12 -146 778 429 724 553 561 -291 -143 1058 460 1440 1577 1164 509 177 -828 -255 427 365 966 556 878 723 196 -666 -1627 -890 -1944 -811 -1605 -1730 -1830 -784 -604 294 415 1382 288 876 -736 -662 -101 -345 -410 -132 1457 1137 53 -507 -1709 -1754 -1551 -601 -1262 -847 -404 218 935 1302 832 1334 450 331 -755 -793 -53 686 64 -454 741 364 672 839 129 -41 76 989 -230 556 -84 -48 -718 -502 -402 543 1064 832 206 -172 -1450 -1256 SS 20250212T115917.8Z 9174.499511 270 1 29.98 2 71.97 98.89 109.55 282.07 0.00 1 0.00 1 0 17 1.883e-02 6.296e-03 2.598e-03 6.891e-04 3.498049e-01 3.398518e-04 3.629861e-03 -6.000000e+00 1.045268e-02 225.63 -2.00 3.04 -2.00 317.58 0.00e+00 1.791089e-03 5.516867e-05 1.255274e-04 -6.000000e+00 4.847788e-04 293.54 -2.00 20.00 -2.00 316.66 0.00e+00 3.188 0.000 302.00 328.00 3 1.4968e+00 9.0102e-04 3.4801e-02 -6.0000e+00 2.5771e-02 -1.7253e-02 1.0211e-03 1.5633e-02 -6.0000e+00 2.7947e-02 -8.7493e-03 6.2603e-04 7.6363e-03 -6.0000e+00 1.6778e-02 9.5065e-04 3.2281e-04 2.5312e-03 -6.0000e+00 7.3493e-03 3.5150e-03 -1.3353e-04 1.8293e-05 2.3878e-05 -6.0000e+00 4.7025e-04 -2.8654e-03 0.0000e+00 10 0 0 10 0 0 2.46 25.62 0.37 -0.00287 -0.00387 205 205 1 5 0 146.190 33.75 20.00 25.62 34.59 3.6 1051.95 -5668 -2108 -1607 -5637 -9433 -7412 -6387 -3752 -3368 -3757 -5719 -4718 -3786 -1419 218 684 279 1195 1369 2374 1684 700 2101 1407 1287 902 -149 -546 -1811 -871 636 437 1252 -537 -3150 -3556 -3158 -2448 -879 -30 -393 -193 64 -23 417 219 79 -231 -421 -203 568 807 839 1004 911 1028 774 768 408 280 915 1126 1664 2146 735 206 -404 -977 230 458 628 754 252 518 217 -391 -761 -1809 -1329 -1430 -1213 -1235 -1775 -1697 -1187 -515 -35 238 724 755 449 78 -139 -357 -148 -29 81 983 563 -35 -262 -755 -935 -325 -635 -863 -740 -548 -178 399 673 590 492 243 -90 -83 -72 -31 94 178 -101 147 459 339 635 193 -119 618 374 309 206 -126 -72 -143 -57 8 -98 349 174 -72 -261 -559 -522 -449 -182 -145 -507 -851 -623 -564 -366 -337 -404 -622 -524 -486 -213 38 125 55 245 296 532 392 162 489 353 318 235 -40 -139 -439 -225 164 127 401 -174 -978 -1138 -1015 -913 -367 -14 -191 -99 34 -12 227 121 44 -126 -230 -111 312 485 511 651 587 677 527 524 273 184 614 814 1261 1695 609 161 -309 -731 179 375 549 694 234 464 190 -324 -597 -1359 -1034 -1220 -1085 -1191 -1799 -1797 -1285 -576 -40 282 862 877 505 84 -143 -365 -153 -33 94 1242 733 -46 -337 -922 -1085 -376 -781 -1100 -984 -743 -247 575 1017 903 740 357 -129 -114 -98 -44 137 264 -155 222 692 495 905 273 -165 835 529 451 314 -195 -114 -229 -94 15 -173 615 312 -127 -454 -958 -885 SS 20250212T120542.0Z 9174.503958 274 1 29.71 2 70.47 98.48 110.98 281.69 0.00 1 0.00 1 0 17 1.703e-02 6.408e-03 6.442e-03 1.711e-03 3.268816e-01 8.442785e-04 3.407795e-03 -6.000000e+00 9.450537e-03 225.63 -2.00 3.04 -2.00 317.59 0.00e+00 1.722057e-03 1.375278e-04 1.523596e-04 -6.000000e+00 4.382997e-04 293.54 -2.00 20.00 -2.00 316.67 0.00e+00 2.957 0.000 302.00 328.00 3 3.4706e+00 2.2394e-03 3.2344e-02 -6.0000e+00 2.3300e-02 -1.4647e-04 2.5419e-03 1.4634e-02 -6.0000e+00 2.5268e-02 -6.8225e-03 1.5582e-03 7.1663e-03 -6.0000e+00 1.5170e-02 9.4540e-04 8.0319e-04 2.3574e-03 -6.0000e+00 6.6447e-03 6.1976e-04 -1.3965e-04 4.5591e-05 2.2220e-05 -6.0000e+00 4.2516e-04 -2.8900e-03 0.0000e+00 11 8 0 10 0 0 56.00 25.63 0.37 -0.00289 -0.00394 32 32 1 5 0 928.390 33.75 20.00 25.63 35.47 3.6 1057.52 -5960 -399 -4779 -3293 -6941 -4650 -5434 -4038 -1169 -3662 -4630 -5284 -4836 -500 1678 1749 -621 646 1487 2521 -1220 1742 465 942 427 1047 -402 -125 -1941 1921 -162 1172 1630 -159 -1972 -4120 -3295 -1842 -1326 522 -663 -824 67 546 766 -253 -217 160 -591 -496 790 601 680 1067 746 735 566 904 257 475 509 866 1413 2210 1099 125 -773 -1230 160 763 525 841 650 840 517 -20 -416 -1705 -1313 -1552 -1263 -1430 -1433 -1694 -1119 -627 -52 267 549 531 486 5 -417 -420 -272 -314 1 966 547 156 -268 -793 -1039 -464 -567 -861 -819 -386 -61 668 753 703 412 151 -253 -126 52 -64 192 308 -215 -72 422 443 362 290 133 666 312 405 102 -125 -55 -315 -103 36 90 384 195 -91 -99 -773 -570 -511 -36 -476 -308 -590 -366 -456 -378 -120 -412 -519 -611 -645 -69 266 315 -122 132 316 554 -287 391 107 231 103 262 -103 -30 -490 462 -43 314 483 -51 -601 -1222 -1051 -675 -543 232 -331 -434 36 301 421 -142 -121 87 -323 -272 425 354 426 665 486 490 388 619 173 314 344 630 1061 1799 881 100 -577 -894 121 621 477 760 593 779 451 -17 -313 -1302 -1034 -1318 -1154 -1388 -1435 -1775 -1185 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