File name: Pandora282s1_Ilo-UNAM_20250215_L2Fit_fout2c3d20250118p1-8.txt File generation date: 20250829T094615.4Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 282 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora282_OF_v2d20240118.txt Instrument calibration file used: Pandora282s1_CF_v3d20250118.txt Level 1 file used: Pandora282s1_Ilo-UNAM_20250215_L1_smca1c3d20250118p1-8.txt Full location name: Grupo de Investigacion en Ciencias de la Atmosfera, UNAM, Peru Short location name: Ilo-UNAM Country of location: Peru Location latitude [deg]: -17.6020 Location longitude [deg]: -71.3389 Location altitude [m]: 85 Local noon date: 20250215 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 202 344 Nominal wavelengths inside fitting window [nm]: 305.0533 305.1939 305.3345 305.4751 305.6156 305.7562 305.8968 306.0373 306.1778 306.3184 306.4589 306.5994 306.7399 306.8803 307.0208 307.1613 307.3017 307.4421 307.5825 307.7230 307.8634 308.0037 308.1441 308.2845 308.4248 308.5652 308.7055 308.8458 308.9861 309.1264 309.2667 309.4070 309.5473 309.6875 309.8278 309.9680 310.1082 310.2484 310.3886 310.5288 310.6690 310.8091 310.9493 311.0894 311.2296 311.3697 311.5098 311.6499 311.7900 311.9300 312.0701 312.2102 312.3502 312.4902 312.6302 312.7702 312.9102 313.0502 313.1902 313.3301 313.4701 313.6100 313.7500 313.8899 314.0298 314.1697 314.3095 314.4494 314.5893 314.7291 314.8690 315.0088 315.1486 315.2884 315.4282 315.5680 315.7077 315.8475 315.9872 316.1269 316.2667 316.4064 316.5461 316.6858 316.8254 316.9651 317.1048 317.2444 317.3840 317.5236 317.6632 317.8028 317.9424 318.0820 318.2216 318.3611 318.5006 318.6402 318.7797 318.9192 319.0587 319.1982 319.3376 319.4771 319.6165 319.7560 319.8954 320.0348 320.1742 320.3136 320.4530 320.5923 320.7317 320.8710 321.0104 321.1497 321.2890 321.4283 321.5676 321.7068 321.8461 321.9854 322.1246 322.2638 322.4030 322.5422 322.6814 322.8206 322.9598 323.0990 323.2381 323.3772 323.5164 323.6555 323.7946 323.9337 324.0727 324.2118 324.3509 324.4899 324.6289 324.7679 324.9070 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250215T113152.5Z 9177.480468 249 1 30.32 2 78.66 99.67 69.45 276.95 0.00 1 0.00 1 0 17 1.085e-01 7.263e-03 5.571e-02 2.713e-03 5.014452e-01 1.361573e-03 5.151032e-03 -6.000000e+00 6.021503e-02 225.66 -2.00 3.04 -2.00 319.75 0.00e+00 3.012186e-03 4.298176e-04 1.064971e-03 -6.000000e+00 2.792765e-03 293.55 -2.00 20.00 -2.00 318.91 0.00e+00 4.911 0.000 302.00 328.00 3 2.2528e+00 3.9778e-03 5.2983e-02 -6.0000e+00 1.4847e-01 2.9416e-02 4.8354e-03 2.2817e-02 -6.0000e+00 1.6101e-01 -6.1256e-02 3.9636e-03 1.1915e-02 -6.0000e+00 9.6663e-02 1.9518e-02 2.0946e-03 4.1921e-03 -6.0000e+00 4.2330e-02 2.7271e-04 -1.1331e-04 7.1743e-05 4.3256e-05 -6.0000e+00 2.7090e-03 -1.8592e-03 0.0000e+00 11 8 0 10 0 0 80.46 25.48 0.53 -0.00186 -0.00271 43 43 1 5 0 705.030 33.75 20.01 25.48 32.32 3.7 1036.36 -17191 -6655 -36901 -68267 -18073 -6089 -35276 -23836 -26317 -26659 -34087 -47344 -28530 -5770 15465 -15397 -7235 -15340 -1702 -8136 3588 -15655 -3411 -903 -3482 -5028 -4898 -381 -12536 -8077 -11157 3243 -1469 -3796 -4808 -8772 -7166 -3515 459 242 -2207 555 1156 825 -23 -479 1289 -964 348 -322 2568 153 1035 1738 1215 1238 1996 1802 434 153 1761 1625 2597 3767 1567 696 127 -1632 -217 1721 1043 502 345 1131 1394 -839 -1082 -2515 -2240 -1973 -894 -1517 -1084 -939 -1222 -621 96 586 1042 1247 1040 -78 -308 -548 -1166 151 126 698 133 -105 -367 -1056 -1635 -772 -1108 -951 -808 -626 -243 184 635 725 503 379 -668 -130 -152 -50 246 421 -83 462 766 364 435 300 -217 293 336 196 284 -74 -37 -396 -203 -101 271 319 440 -105 75 -586 -772 -200 -81 -654 -1607 -230 -66 -551 -378 -487 -536 -748 -1278 -785 -159 425 -684 -327 -820 -86 -461 187 -977 -194 -54 -232 -360 -359 -26 -915 -583 -959 282 -154 -444 -537 -979 -861 -480 74 47 -453 118 258 190 -6 -116 309 -240 88 -85 718 49 356 642 477 503 764 694 180 63 726 671 1197 1928 867 372 65 -850 -120 1000 683 349 241 750 855 -511 -601 -1379 -1317 -1255 -655 -1184 -927 -844 -1099 -598 97 615 1097 1278 996 -75 -277 -486 -1131 154 138 869 174 -139 -461 -1289 -1817 -846 -1330 -1146 -1019 -838 -329 273 980 1184 822 595 -1046 -190 -219 -76 374 682 -138 742 1188 550 663 441 -305 433 516 320 481 -134 -69 -740 -405 -204 563 677 906 -223 149 -1175 -1484 SS 20250215T113651.3Z 9177.483927 252 1 30.04 2 77.49 99.33 70.60 276.51 0.00 1 0.00 1 0 17 8.060e-02 6.449e-03 1.764e-02 1.479e-03 4.641923e-01 7.349140e-04 4.763063e-03 -6.000000e+00 4.473310e-02 225.66 -2.00 3.04 -2.00 319.16 0.00e+00 3.150859e-03 1.901901e-04 6.352420e-04 -6.000000e+00 2.074682e-03 293.55 -2.00 20.00 -2.00 318.27 0.00e+00 4.486 0.000 302.00 328.00 3 1.5828e+00 2.0649e-03 4.8453e-02 -6.0000e+00 1.1030e-01 6.8157e-03 2.4341e-03 2.0860e-02 -6.0000e+00 1.1961e-01 -3.3578e-02 1.8252e-03 1.0741e-02 -6.0000e+00 7.1809e-02 8.6248e-03 9.7717e-04 4.0487e-03 -6.0000e+00 3.1447e-02 8.2696e-04 -2.7368e-04 3.8984e-05 3.7680e-05 -6.0000e+00 2.0125e-03 -1.9881e-03 0.0000e+00 11 8 0 10 0 0 63.79 25.50 0.42 -0.00199 -0.00404 101 101 1 5 0 297.370 33.75 20.01 25.50 32.68 3.6 1039.13 -28481 -20549 -11103 -22818 -40967 -23201 -38327 -15675 -27588 -24312 -19491 -20782 -18392 -13889 -9468 -2882 -3154 270 -2488 773 -2723 -3100 283 -2658 -717 453 -2244 -3911 -4918 -2730 -2393 712 2605 -591 -2630 -5089 -3990 -2550 615 930 -1109 561 1400 340 679 682 230 -223 351 531 619 1187 785 668 1150 909 1239 694 491 -32 135 1020 2347 2777 1427 350 -260 -1044 178 843 583 1220 276 942 23 -368 -1170 -2738 -1519 -1756 -1519 -1061 -1789 -1202 -989 -292 420 313 871 986 702 103 -337 -415 -358 -405 216 868 328 -63 -490 -779 -1288 -495 -866 -1036 -836 -561 15 297 743 668 368 368 -118 -293 -59 21 304 137 -136 57 552 485 564 286 -113 496 253 71 46 -174 -137 -65 -136 -121 157 293 233 -108 -152 -408 -494 -653 -504 -266 -596 -1140 -519 -1067 -396 -891 -820 -632 -728 -767 -689 -552 -185 -223 20 -204 65 -244 -276 25 -261 -74 49 -255 -435 -528 -294 -293 98 366 -93 -399 -759 -642 -475 136 247 -311 165 429 108 217 223 76 -75 119 186 236 461 332 305 551 450 632 357 247 -16 69 521 1329 1633 896 212 -161 -645 108 592 431 944 217 705 16 -248 -722 -1778 -969 -1312 -1233 -916 -1613 -1132 -993 -297 451 332 928 1077 718 103 -316 -380 -353 -432 247 1071 430 -84 -619 -939 -1489 -566 -1033 -1323 -1064 -756 20 445 1165 1063 585 582 -175 -425 -85 31 461 215 -218 88 866 738 854 418 -165 714 382 115 78 -300 -243 -116 -250 -238 305 580 471 -215 -297 -760 -916 SS 20250215T114158.7Z 9177.487485 255 1 30.02 2 76.29 98.99 71.78 276.06 0.00 1 0.00 1 0 17 5.860e-02 6.342e-03 9.968e-03 1.188e-03 4.311371e-01 5.878292e-04 4.436788e-03 -6.000000e+00 3.252381e-02 225.66 -2.00 3.04 -2.00 318.76 0.00e+00 2.125660e-03 1.343236e-04 4.240061e-04 -6.000000e+00 1.508391e-03 293.55 -2.00 20.00 -2.00 317.85 0.00e+00 4.118 0.000 302.00 328.00 3 1.5580e+00 1.6193e-03 4.4575e-02 -6.0000e+00 8.0192e-02 -5.7599e-03 1.8768e-03 1.9335e-02 -6.0000e+00 8.6966e-02 -2.4693e-02 1.3154e-03 9.6045e-03 -6.0000e+00 5.2210e-02 6.4677e-03 7.0635e-04 3.1898e-03 -6.0000e+00 2.2865e-02 1.2487e-03 -1.9371e-04 3.1355e-05 3.0229e-05 -6.0000e+00 1.4631e-03 -2.1723e-03 0.0000e+00 10 0 0 10 0 0 6.23 25.51 0.43 -0.00217 -0.00363 124 124 1 5 0 242.070 33.75 20.00 25.51 33.28 3.7 1042.96 -19509 -7848 -11950 -24720 -25380 -24428 -22379 -23463 -17176 -11360 -14334 -11347 -13583 -8305 -5102 -986 -2852 1332 -2198 1806 1610 -3160 1161 673 3192 -368 -125 -296 -2903 -1163 -705 301 1985 7 -3099 -2878 -2445 -1732 83 956 -210 -254 6 271 959 -124 -502 428 -614 -507 908 954 921 1297 1199 1044 1254 471 159 -520 799 1409 1819 2173 1153 98 -189 -691 394 667 775 831 713 692 82 -245 -1029 -1845 -1609 -1543 -1272 -814 -1996 -1721 -1096 -438 -24 254 864 930 534 158 -105 -478 -628 -271 124 749 629 -206 -451 -739 -995 -387 -708 -1124 -792 -359 -85 293 669 669 399 170 -46 -117 13 -63 154 212 -144 179 558 508 537 153 -153 610 255 197 255 10 -165 -247 -218 11 -4 434 245 -114 -183 -496 -551 -642 -264 -446 -1011 -926 -846 -814 -984 -770 -518 -677 -549 -807 -574 -414 -90 -287 138 -230 210 177 -359 143 82 406 -51 -18 -40 -385 -154 -104 51 372 1 -622 -552 -509 -421 22 306 -70 -91 2 104 365 -49 -199 168 -246 -209 399 430 448 677 615 553 685 260 86 -279 432 823 1109 1467 775 67 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