File name: Pandora282s1_Ilo-UNAM_20250221_L2Fit_fout2c3d20250118p1-8.txt File generation date: 20250829T094838.1Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 282 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora282_OF_v2d20240118.txt Instrument calibration file used: Pandora282s1_CF_v3d20250118.txt Level 1 file used: Pandora282s1_Ilo-UNAM_20250221_L1_smca1c3d20250118p1-8.txt Full location name: Grupo de Investigacion en Ciencias de la Atmosfera, UNAM, Peru Short location name: Ilo-UNAM Country of location: Peru Location latitude [deg]: -17.6020 Location longitude [deg]: -71.3389 Location altitude [m]: 85 Local noon date: 20250221 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 202 344 Nominal wavelengths inside fitting window [nm]: 305.0533 305.1939 305.3345 305.4751 305.6156 305.7562 305.8968 306.0373 306.1778 306.3184 306.4589 306.5994 306.7399 306.8803 307.0208 307.1613 307.3017 307.4421 307.5825 307.7230 307.8634 308.0037 308.1441 308.2845 308.4248 308.5652 308.7055 308.8458 308.9861 309.1264 309.2667 309.4070 309.5473 309.6875 309.8278 309.9680 310.1082 310.2484 310.3886 310.5288 310.6690 310.8091 310.9493 311.0894 311.2296 311.3697 311.5098 311.6499 311.7900 311.9300 312.0701 312.2102 312.3502 312.4902 312.6302 312.7702 312.9102 313.0502 313.1902 313.3301 313.4701 313.6100 313.7500 313.8899 314.0298 314.1697 314.3095 314.4494 314.5893 314.7291 314.8690 315.0088 315.1486 315.2884 315.4282 315.5680 315.7077 315.8475 315.9872 316.1269 316.2667 316.4064 316.5461 316.6858 316.8254 316.9651 317.1048 317.2444 317.3840 317.5236 317.6632 317.8028 317.9424 318.0820 318.2216 318.3611 318.5006 318.6402 318.7797 318.9192 319.0587 319.1982 319.3376 319.4771 319.6165 319.7560 319.8954 320.0348 320.1742 320.3136 320.4530 320.5923 320.7317 320.8710 321.0104 321.1497 321.2890 321.4283 321.5676 321.7068 321.8461 321.9854 322.1246 322.2638 322.4030 322.5422 322.6814 322.8206 322.9598 323.0990 323.2381 323.3772 323.5164 323.6555 323.7946 323.9337 324.0727 324.2118 324.3509 324.4899 324.6289 324.7679 324.9070 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250221T110924.1Z 9183.464862 250 1 30.99 2 84.42 99.14 9.72 173.07 0.00 1 0.00 1 0 25 4.877e-01 4.213e-02 3.791e-01 2.300e-02 7.882461e-01 1.362806e-02 9.107867e-03 -6.000000e+00 2.870575e-01 225.79 -2.00 3.04 -2.00 321.97 0.00e+00 3.439456e-03 8.348596e-03 1.315657e-02 -6.000000e+00 1.804755e-02 293.53 -2.00 20.00 -2.00 321.44 0.00e+00 9.018 0.002 302.00 328.00 3 1.1775e+00 5.6406e-02 1.1849e-01 -6.0000e+00 7.2195e-01 9.4947e-01 7.6078e-02 9.6557e-02 -6.0000e+00 7.9420e-01 -1.0648e+00 6.4943e-02 3.1487e-02 -6.0000e+00 4.5979e-01 4.0937e-01 3.0861e-02 6.9799e-03 -6.0000e+00 1.9994e-01 1.0606e-05 -1.5997e-03 6.5457e-04 1.9422e-04 -6.0000e+00 1.3674e-02 -1.3177e-03 0.0000e+00 12 8 8 10 0 0 7.06 25.29 1.83 -0.00132 -0.01334 11 11 1 5 0 2816.530 33.50 20.00 25.29 28.80 3.7 1013.00 -105352 900000 -107612 900000 -140818 -26048 900000 900000 900000 900000 900000 -26069 900000 -108879 900000 900000 -66613 900000 8848 239872 900000 92694 900000 -77649 900000 900000 -63305 900000 900000 -68157 900000 900000 900000 -56031 900000 80714 31635 -39514 41445 58874 900000 -34385 109770 900000 900000 -48382 9180 42613 26472 -16855 900000 -37248 11092 10533 47094 -14983 8325 201603 54584 142658 32356 30291 28428 31174 7982 45647 24338 21000 9125 34563 27237 2839 7933 37489 22386 65228 17905 24319 8359 4569 2064 -4078 7510 2424 26534 2028 73 6644 16333 6506 4033 -28293 1657 -1291 -3144 3899 -8534 1857 -1834 -7191 -5182 4255 -6082 -8213 11763 3558 -12070 1551 -3811 -4001 4810 -4184 -43 -1609 -3431 -409 -1441 1801 2132 2588 -280 8606 5161 2718 725 4237 -3977 -1161 475 -3 -2911 1127 2346 368 24 -1234 2467 19 -578 68 -809 403 -2958 -2350 900000 -2837 900000 -3998 -581 900000 900000 900000 900000 900000 -582 900000 -3974 900000 900000 -2567 900000 197 5351 900000 2068 900000 -3622 900000 900000 -2696 900000 900000 -2764 900000 900000 900000 -3636 900000 1800 770 -2244 1261 1791 900000 -3138 2693 900000 900000 -5720 614 2091 1594 -1654 900000 -5567 1113 1151 3782 -2306 1040 4497 4018 4137 2815 2905 3171 3894 1371 5295 3420 3139 1669 5705 5407 754 1982 6523 4095 6838 2756 3526 1585 1091 603 -1474 2714 979 8937 932 36 3172 7104 3033 1799 -16283 680 -559 -1564 2140 -6244 1433 -1665 -7122 -4786 3217 -4504 -5990 7583 2667 -11119 1342 -3834 -4614 5826 -5549 -56 -2341 -4875 -538 -1910 2418 3038 3873 -430 11576 6873 3613 951 5218 -5110 -1468 676 -5 -5136 2084 4552 777 56 -3052 6044 49 -1497 171 -1901 869 -6202 SS 20250221T111942.4Z 9183.472019 253 1 29.83 2 81.99 98.40 9.73 186.41 0.00 1 0.00 1 0 17 4.147e-01 9.877e-03 2.474e-01 4.662e-03 6.354740e-01 2.416329e-03 6.976184e-03 -6.000000e+00 2.302169e-01 225.79 -2.00 3.04 -2.00 320.93 0.00e+00 7.624428e-03 1.135711e-03 4.082093e-03 -6.000000e+00 1.075770e-02 293.53 -2.00 20.00 -2.00 320.23 0.00e+00 6.704 0.001 302.00 328.00 3 1.2923e+00 8.1945e-03 7.2956e-02 -6.0000e+00 5.6783e-01 1.2238e-01 1.1187e-02 3.4961e-02 -6.0000e+00 6.1574e-01 -1.4333e-01 1.0855e-02 2.0888e-02 -6.0000e+00 3.6995e-01 4.6803e-02 5.3135e-03 7.9055e-03 -6.0000e+00 1.6281e-01 1.1486e-04 -1.5895e-04 1.2053e-04 1.1331e-04 -6.0000e+00 1.0357e-02 -1.1271e-03 0.0000e+00 12 8 8 10 0 0 9.37 25.30 0.55 -0.00113 -0.00232 39 39 1 5 0 764.790 33.50 20.00 25.30 29.34 3.7 1017.07 -199373 900000 -168648 -106884 4827 -94385 -164931 -40023 -113192 -119090 -18470 18050 -93755 -81533 224860 26127 -54365 -38547 -17311 -54234 25371 -39936 -33301 -32999 60736 13271 -25293 -4506 -7635 -23574 -20129 14860 -4451 -35500 -20651 -7525 -5828 -3260 1403 2180 -3199 -11285 -4805 2904 -3669 -6827 8291 2557 6780 951 -757 3595 6656 3896 105 1821 4819 4155 -721 2741 0 3576 5304 5162 2156 2610 -1209 1802 -1045 3229 3419 2284 2169 3546 -1187 -390 -2017 -5158 -2252 -2710 -2757 -3429 -496 -366 -499 -31 2265 1580 1470 1931 664 -1674 -766 -2551 -2220 -992 -302 -5 65 -187 -91 -1244 -2201 -1852 -769 -1871 749 -101 8 580 925 943 204 302 -302 -417 -357 141 114 269 206 553 637 507 480 506 -786 26 -89 155 -275 -571 -140 275 3 -294 328 572 410 130 -343 -598 -419 -2719 900000 -2230 -751 22 -558 -2099 -182 -1080 -1299 -84 82 -1193 -1223 1022 214 -1137 -771 -307 -1479 323 -962 -772 -825 635 235 -678 -96 -167 -654 -659 419 -180 -2162 -1032 -318 -265 -170 86 160 -282 -1164 -496 289 -399 -794 855 291 777 123 -111 570 1125 740 22 390 1036 901 -159 577 0 852 1427 1598 675 874 -410 605 -358 1239 1469 1047 995 1524 -492 -143 -763 -2009 -858 -1248 -1503 -2171 -339 -243 -353 -23 1776 1296 1218 1553 506 -1214 -571 -1787 -1724 -889 -313 -6 80 -236 -108 -1357 -2171 -1943 -801 -2106 864 -126 10 815 1456 1491 329 474 -481 -632 -539 221 178 446 344 887 985 818 744 760 -1142 38 -147 270 -501 -1123 -287 560 7 -691 742 1317 959 296 -787 -1293 -862 SS 20250221T113345.5Z 9183.481777 258 1 30.01 2 78.68 97.41 10.60 203.15 0.00 1 0.00 1 0 17 1.205e-01 7.035e-03 2.089e-02 1.383e-03 4.956751e-01 6.898948e-04 5.095167e-03 -6.000000e+00 6.692403e-02 225.79 -2.00 3.04 -2.00 319.49 0.00e+00 7.184294e-03 1.993889e-04 9.102819e-04 -6.000000e+00 3.102228e-03 293.53 -2.00 20.00 -2.00 318.63 0.00e+00 4.917 0.000 302.00 328.00 3 9.9235e-01 1.9721e-03 5.2845e-02 -6.0000e+00 1.6506e-01 2.1341e-02 2.3562e-03 2.2412e-02 -6.0000e+00 1.7899e-01 -4.5587e-02 1.8641e-03 1.3153e-02 -6.0000e+00 1.0744e-01 1.3925e-02 9.9480e-04 7.7098e-03 -6.0000e+00 4.7037e-02 9.5078e-04 -2.2818e-04 3.5949e-05 6.4291e-05 -6.0000e+00 3.0095e-03 -1.8413e-03 0.0000e+00 11 8 0 10 0 0 -15.56 25.30 0.46 -0.00184 -0.00356 134 134 1 5 0 223.880 33.50 20.00 25.30 30.61 3.7 1025.25 -41917 -32442 -38668 -39807 -46184 -48884 -33929 -37260 -38546 -30855 -30743 -33030 -30977 -23834 -3755 -7552 -8996 -4973 -7617 -2179 -5078 -4086 -3639 -4126 -2095 -4082 -7434 -8286 -5929 -9262 -3726 -608 -165 -1507 -4164 -7308 -5454 -2359 174 1673 1282 979 1858 1526 2313 1272 607 1575 479 282 1154 1878 2167 2454 1641 1458 792 639 195 27 57 963 1841 2367 1139 313 -665 -1210 326 923 931 1040 735 832 336 -655 -1515 -3007 -1728 -1313 -1323 -1297 -2003 -1558 -1030 -144 271 622 1118 1068 797 -6 -399 -812 -754 -296 -65 1006 683 -64 -514 -841 -1226 -393 -532 -1304 -743 -575 -92 159 634 544 532 297 -78 -143 21 2 62 246 39 198 655 371 497 298 -219 562 404 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