File name: Pandora282s1_Ilo-UNAM_20250318_L2Fit_fout2c3d20250118p1-8.txt File generation date: 20250829T100127.6Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 282 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora282_OF_v2d20240118.txt Instrument calibration file used: Pandora282s1_CF_v3d20250118.txt Level 1 file used: Pandora282s1_Ilo-UNAM_20250318_L1_smca1c3d20250118p1-8.txt Full location name: Grupo de Investigacion en Ciencias de la Atmosfera, UNAM, Peru Short location name: Ilo-UNAM Country of location: Peru Location latitude [deg]: -17.6020 Location longitude [deg]: -71.3389 Location altitude [m]: 85 Local noon date: 20250318 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 202 344 Nominal wavelengths inside fitting window [nm]: 305.0533 305.1939 305.3345 305.4751 305.6156 305.7562 305.8968 306.0373 306.1778 306.3184 306.4589 306.5994 306.7399 306.8803 307.0208 307.1613 307.3017 307.4421 307.5825 307.7230 307.8634 308.0037 308.1441 308.2845 308.4248 308.5652 308.7055 308.8458 308.9861 309.1264 309.2667 309.4070 309.5473 309.6875 309.8278 309.9680 310.1082 310.2484 310.3886 310.5288 310.6690 310.8091 310.9493 311.0894 311.2296 311.3697 311.5098 311.6499 311.7900 311.9300 312.0701 312.2102 312.3502 312.4902 312.6302 312.7702 312.9102 313.0502 313.1902 313.3301 313.4701 313.6100 313.7500 313.8899 314.0298 314.1697 314.3095 314.4494 314.5893 314.7291 314.8690 315.0088 315.1486 315.2884 315.4282 315.5680 315.7077 315.8475 315.9872 316.1269 316.2667 316.4064 316.5461 316.6858 316.8254 316.9651 317.1048 317.2444 317.3840 317.5236 317.6632 317.8028 317.9424 318.0820 318.2216 318.3611 318.5006 318.6402 318.7797 318.9192 319.0587 319.1982 319.3376 319.4771 319.6165 319.7560 319.8954 320.0348 320.1742 320.3136 320.4530 320.5923 320.7317 320.8710 321.0104 321.1497 321.2890 321.4283 321.5676 321.7068 321.8461 321.9854 322.1246 322.2638 322.4030 322.5422 322.6814 322.8206 322.9598 323.0990 323.2381 323.3772 323.5164 323.6555 323.7946 323.9337 324.0727 324.2118 324.3509 324.4899 324.6289 324.7679 324.9070 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250318T153537.8Z 9208.649743 422 1 30.40 2 25.52 50.51 108.26 241.19 0.00 1 0.00 1 0 17 1.063e-02 8.718e-03 3.918e-03 2.975e-03 1.315639e-01 1.498516e-03 1.380786e-03 -6.000000e+00 5.915883e-03 226.30 -2.00 3.04 -2.00 314.31 0.00e+00 6.863697e-04 1.188188e-04 1.136134e-05 -6.000000e+00 2.734938e-04 293.41 -2.00 20.00 -2.00 313.67 0.00e+00 1.108 0.000 302.00 328.00 3 6.4891e+00 3.8041e-03 1.2308e-02 -6.0000e+00 1.4609e-02 6.6697e-02 4.2126e-03 5.8576e-03 -6.0000e+00 1.5835e-02 -5.1962e-03 2.4241e-03 2.8181e-03 -6.0000e+00 9.5005e-03 -3.5357e-03 1.0860e-03 8.7425e-04 -6.0000e+00 4.1557e-03 2.4595e-04 -1.2479e-04 7.7920e-05 9.6553e-06 -6.0000e+00 2.6547e-04 -4.0842e-03 0.0000e+00 11 8 0 10 0 0 99.57 25.61 0.73 -0.00408 -0.00502 8 8 1 5 0 3798.890 33.75 20.00 25.61 36.71 3.6 1062.29 -1089 95 1629 -73 -1341 -1861 -931 1560 1953 -420 -1432 -1933 624 -948 766 373 -83 1219 192 1602 375 -82 1879 -28 553 288 -556 1725 -1804 -641 1886 -261 2091 -1795 -3142 -3097 -2477 -2246 -792 -691 -37 -716 -206 -162 -10 -379 -866 -304 -818 -78 1339 -744 733 835 903 235 975 764 1310 554 431 1094 1225 2321 1069 -195 -382 -2046 216 569 414 629 689 569 1151 -234 -1059 -1962 -1382 -1572 -1893 -1152 -1561 -1209 -715 -56 -313 641 1049 1025 1230 -569 -1157 -1162 -710 -521 192 727 1363 666 -53 -855 -1221 -987 -207 -636 -1038 -783 -643 161 1214 763 630 -41 -543 -269 -733 -106 374 152 283 681 687 688 741 15 -572 531 204 -87 -620 -56 193 -66 -184 84 327 786 125 184 -277 -795 -903 -439 41 692 -32 -507 -653 -335 609 846 -179 -641 -841 286 -449 397 209 -47 689 112 944 228 -49 1096 -17 353 176 -341 1042 -1023 -339 991 -146 1214 -1120 -1817 -1678 -1431 -1487 -570 -539 -31 -628 -184 -145 -9 -336 -748 -249 -693 -64 1103 -616 624 739 817 215 900 706 1177 495 394 1057 1187 2355 1099 -197 -345 -1758 185 553 416 663 732 589 1202 -223 -971 -1654 -1150 -1449 -1815 -1203 -1630 -1298 -813 -64 -382 804 1326 1264 1497 -639 -1249 -1156 -717 -570 214 885 1663 814 -65 -981 -1312 -1075 -246 -811 -1293 -1015 -859 223 1646 1053 890 -54 -692 -313 -834 -124 465 193 378 908 898 866 937 18 -655 619 232 -106 -791 -73 250 -88 -242 117 466 1144 187 271 -399 -1115 -1229 SS 20250318T164519.2Z 9208.698139 459 1 20.89 2 17.06 6.81 121.53 231.86 0.00 1 0.00 1 0 17 8.873e-03 7.372e-03 2.252e-03 1.862e-03 1.217256e-01 9.449951e-04 1.304935e-03 -6.000000e+00 4.937419e-03 226.30 -2.00 3.04 -2.00 313.73 0.00e+00 3.691420e-04 6.776609e-05 1.002674e-05 -6.000000e+00 2.282512e-04 293.41 -2.00 20.00 -2.00 313.17 0.00e+00 1.046 0.000 302.00 328.00 3 5.3428e+00 2.3876e-03 1.1588e-02 -6.0000e+00 1.2193e-02 4.2152e-02 2.6367e-03 5.4388e-03 -6.0000e+00 1.3215e-02 -3.5871e-03 1.5253e-03 2.6475e-03 -6.0000e+00 7.9291e-03 -2.9113e-03 6.7348e-04 7.6518e-04 -6.0000e+00 3.4685e-03 8.4803e-04 -6.9031e-05 4.8548e-05 9.6521e-06 -6.0000e+00 2.2155e-04 -4.3321e-03 0.0000e+00 12 9 1 12 1 1 90.47 25.79 0.43 -0.00433 -0.00485 7 11 1 5 0 2610.930 33.75 20.00 25.79 37.43 3.6 1066.33 1 499 564 -1175 -2974 -1701 -203 712 939 381 -1437 -852 -938 183 1460 338 -107 819 156 1125 955 352 997 593 403 161 210 95 151 -193 1581 952 1631 -689 -2207 -3004 -2689 -1764 -424 -605 -163 -564 -401 -673 -489 -272 -313 -373 -676 -623 829 105 610 717 795 975 142 798 492 18 841 896 1327 2553 762 -114 -684 -1473 66 522 706 801 556 471 863 -165 -647 -1744 -1129 -1401 -1130 -1025 -1882 -1624 -780 -503 -11 94 702 565 681 147 -430 -221 -366 -282 -147 862 682 411 76 -483 -949 -644 -817 -486 -613 -676 -350 340 897 418 533 208 -171 -235 -448 40 221 383 216 101 513 282 558 301 -181 677 18 -53 -83 182 134 73 -212 31 127 679 257 -151 -411 -734 -715 0 263 299 -586 -1382 -721 -88 340 466 199 -729 -415 -492 105 858 216 -69 527 97 710 616 223 625 389 276 114 147 62 95 -115 937 591 1065 -448 -1413 -1817 -1740 -1223 -327 -518 -144 -515 -374 -633 -453 -250 -280 -317 -579 -515 694 94 537 657 744 916 136 761 461 17 793 854 1354 2599 789 -113 -637 -1361 62 497 742 843 593 489 887 -162 -595 -1475 -994 -1294 -1103 -1044 -1968 -1750 -886 -590 -13 115 871 686 799 164 -451 -224 -377 -301 -164 999 816 491 89 -551 -1064 -699 -935 -592 -745 -856 -456 443 1216 577 705 266 -206 -272 -507 47 263 475 283 133 658 350 677 365 -207 774 21 -64 -101 226 166 92 -271 42 170 928 360 -210 -557 -1008 -952 SS 20250318T165052.9Z 9208.702001 463 1 29.78 2 16.96 2.07 122.52 230.95 0.00 1 0.00 1 0 17 8.389e-03 7.015e-03 1.021e-03 8.607e-04 1.208056e-01 4.376011e-04 1.300151e-03 -6.000000e+00 4.667967e-03 226.30 -2.00 3.04 -2.00 313.60 0.00e+00 3.807004e-04 3.062996e-05 6.880269e-06 -6.000000e+00 2.158088e-04 293.41 -2.00 20.00 -2.00 313.05 0.00e+00 1.045 0.000 302.00 328.00 3 4.3499e+00 1.1037e-03 1.1568e-02 -6.0000e+00 1.1527e-02 3.3034e-02 1.2171e-03 5.4123e-03 -6.0000e+00 1.2495e-02 -3.0617e-03 7.0618e-04 2.6317e-03 -6.0000e+00 7.4966e-03 -3.3028e-03 3.1149e-04 7.6497e-04 -6.0000e+00 3.2789e-03 2.3011e-03 -1.0700e-04 2.2370e-05 9.7430e-06 -6.0000e+00 2.0948e-04 -3.7399e-03 0.0000e+00 11 8 0 10 0 0 99.80 25.80 0.44 -0.00374 -0.00454 35 35 1 5 0 850.630 34.00 20.00 25.80 37.54 3.6 1068.08 47 441 170 -1466 -2527 -1536 164 978 1493 331 -1448 -1025 -616 151 791 197 -219 822 648 1387 732 474 996 656 805 575 24 -66 -749 46 1184 949 1644 -319 -2437 -2558 -2381 -1499 -580 -331 -588 -753 -532 -730 -335 -259 -658 -530 -880 -264 396 234 909 1033 571 952 813 523 299 296 714 986 1385 1983 756 -39 -566 -1029 56 422 495 776 409 741 535 -41 -557 -1586 -995 -1132 -1344 -1183 -1830 -1590 -1028 -515 -144 374 655 528 413 250 -217 -124 -207 -63 90 871 674 214 -30 -506 -800 -582 -589 -773 -638 -761 -263 295 667 498 652 241 -31 -72 -60 -215 116 307 -59 160 384 290 661 299 -81 522 310 410 140 -194 -92 -145 -127 -11 49 289 222 -39 -184 -627 -673 25 236 92 -784 -1236 -688 75 493 789 185 -787 -535 -344 88 481 124 -138 518 418 909 493 312 651 447 570 402 17 -45 -489 28 725 607 1105 -215 -1609 -1586 -1583 -1081 -452 -277 -516 -683 -492 -681 -307 -237 -585 -466 -740 -222 339 205 823 936 532 887 772 497 278 273 670 943 1368 2060 794 -39 -523 -930 51 403 505 830 428 781 555 -40 -503 -1372 -849 -1025 -1309 -1215 -1945 -1742 -1151 -600 -171 461 790 642 483 274 -229 -125 -213 -67 98 1003 810 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