File name: Pandora282s1_Ilo-UNAM_20250320_L2Fit_fout2c3d20250118p1-8.txt File generation date: 20250829T100656.8Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 282 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora282_OF_v2d20240118.txt Instrument calibration file used: Pandora282s1_CF_v3d20250118.txt Level 1 file used: Pandora282s1_Ilo-UNAM_20250320_L1_smca1c3d20250118p1-8.txt Full location name: Grupo de Investigacion en Ciencias de la Atmosfera, UNAM, Peru Short location name: Ilo-UNAM Country of location: Peru Location latitude [deg]: -17.6020 Location longitude [deg]: -71.3389 Location altitude [m]: 85 Local noon date: 20250320 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 202 344 Nominal wavelengths inside fitting window [nm]: 305.0533 305.1939 305.3345 305.4751 305.6156 305.7562 305.8968 306.0373 306.1778 306.3184 306.4589 306.5994 306.7399 306.8803 307.0208 307.1613 307.3017 307.4421 307.5825 307.7230 307.8634 308.0037 308.1441 308.2845 308.4248 308.5652 308.7055 308.8458 308.9861 309.1264 309.2667 309.4070 309.5473 309.6875 309.8278 309.9680 310.1082 310.2484 310.3886 310.5288 310.6690 310.8091 310.9493 311.0894 311.2296 311.3697 311.5098 311.6499 311.7900 311.9300 312.0701 312.2102 312.3502 312.4902 312.6302 312.7702 312.9102 313.0502 313.1902 313.3301 313.4701 313.6100 313.7500 313.8899 314.0298 314.1697 314.3095 314.4494 314.5893 314.7291 314.8690 315.0088 315.1486 315.2884 315.4282 315.5680 315.7077 315.8475 315.9872 316.1269 316.2667 316.4064 316.5461 316.6858 316.8254 316.9651 317.1048 317.2444 317.3840 317.5236 317.6632 317.8028 317.9424 318.0820 318.2216 318.3611 318.5006 318.6402 318.7797 318.9192 319.0587 319.1982 319.3376 319.4771 319.6165 319.7560 319.8954 320.0348 320.1742 320.3136 320.4530 320.5923 320.7317 320.8710 321.0104 321.1497 321.2890 321.4283 321.5676 321.7068 321.8461 321.9854 322.1246 322.2638 322.4030 322.5422 322.6814 322.8206 322.9598 323.0990 323.2381 323.3772 323.5164 323.6555 323.7946 323.9337 324.0727 324.2118 324.3509 324.4899 324.6289 324.7679 324.9070 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250320T112405.6Z 9210.475065 253 1 30.20 2 82.55 87.58 32.30 247.92 0.00 1 0.00 1 0 25 4.711e-01 1.686e-02 3.076e-01 8.318e-03 6.557490e-01 4.451032e-03 7.707379e-03 -6.000000e+00 2.647491e-01 226.32 -2.00 3.04 -2.00 321.29 0.00e+00 8.132015e-03 2.317538e-03 6.645524e-03 -6.000000e+00 1.311312e-02 293.38 -2.00 20.00 -2.00 320.64 0.00e+00 7.135 0.001 302.00 328.00 3 1.7318e+00 1.6173e-02 8.1373e-02 -6.0000e+00 6.5440e-01 2.8315e-01 2.2303e-02 4.8729e-02 -6.0000e+00 7.1028e-01 -3.0489e-01 2.0982e-02 2.3993e-02 -6.0000e+00 4.2388e-01 1.0660e-01 1.0051e-02 6.2813e-03 -6.0000e+00 1.8738e-01 4.6296e-05 -6.7779e-04 2.2163e-04 1.4095e-04 -6.0000e+00 1.2048e-02 -7.4135e-04 0.0000e+00 12 8 8 10 0 0 -50.10 25.16 0.62 -0.00074 -0.00583 21 21 1 5 0 1438.020 33.50 20.00 25.16 29.32 3.7 1015.26 -172887 900000 900000 900000 -182439 900000 -108960 131149 900000 -123230 -30163 -145111 -71008 -122963 170035 -17376 -101093 173464 -71998 -43111 51002 -76781 58812 -97104 21971 -6496 40220 95220 -105659 -70451 423 66058 8033 8144 -33034 -16538 29104 -27279 9292 -30263 29174 -18764 40914 27406 6316 -8145 4015 -2484 13425 29730 30719 -12797 6810 6564 6393 3422 7424 19824 6481 7382 2849 6291 4827 12909 3135 1509 4307 6609 1614 9265 92 1020 3059 585 12802 1559 4244 -2909 1502 -4560 -219 -3423 -717 -1725 509 1175 2216 1661 2743 1466 -2911 -3090 -172 -724 -4307 1553 -1899 -527 -994 -712 -408 -967 -3072 -3341 -1254 -1484 -2194 -546 -1398 483 1238 -191 252 -1046 -519 632 -355 175 598 494 1098 2080 1592 1225 253 1039 -1811 1383 635 192 -698 -91 237 181 57 -905 975 359 220 -544 100 -717 -893 -2165 900000 900000 900000 -2823 900000 -883 1063 900000 -1362 -244 -2245 -680 -2627 1378 -225 -3441 1406 -2217 -1048 496 -2614 524 -4407 321 -132 522 772 -5652 -2855 10 1017 260 290 -1687 -684 826 -1592 459 -2673 1608 -1795 2288 1821 527 -812 364 -250 1208 2410 2739 -1991 955 1005 1041 593 1276 3004 1087 1203 499 1173 1048 2971 861 412 1114 1703 475 2951 36 417 1222 227 4036 490 1193 -877 480 -1863 -101 -1892 -390 -1004 309 761 1502 1176 1938 1023 -1984 -1962 -111 -474 -2954 1175 -1735 -552 -1074 -786 -464 -998 -2895 -3094 -1235 -1567 -2453 -643 -1662 634 1820 -308 411 -1683 -787 898 -508 260 946 829 1845 3337 2471 1856 373 1470 -2522 1881 981 342 -1288 -180 490 396 124 -2137 2325 879 546 -1325 229 -1551 -1979 SS 20250320T114030.0Z 9210.486459 258 1 29.90 2 78.65 86.30 35.86 248.78 0.00 1 0.00 1 0 17 1.082e-01 7.412e-03 2.703e-02 1.801e-03 4.882371e-01 9.004441e-04 5.070458e-03 -6.000000e+00 6.017943e-02 226.32 -2.00 3.04 -2.00 319.45 0.00e+00 2.063104e-03 2.550049e-04 1.304160e-03 -6.000000e+00 2.782541e-03 293.38 -2.00 20.00 -2.00 318.58 0.00e+00 4.906 0.000 302.00 328.00 3 1.4961e+00 2.5698e-03 5.2885e-02 -6.0000e+00 1.4862e-01 2.7221e-02 3.0659e-03 2.2826e-02 -6.0000e+00 1.6111e-01 -3.8960e-02 2.4012e-03 1.1337e-02 -6.0000e+00 9.6659e-02 6.1186e-03 1.2801e-03 3.3094e-03 -6.0000e+00 4.2253e-02 5.8975e-04 -1.4428e-04 4.7407e-05 3.5264e-05 -6.0000e+00 2.7014e-03 -8.5205e-04 0.0000e+00 11 8 0 10 0 0 39.78 25.16 0.47 -0.00085 -0.00194 81 81 1 5 0 369.100 33.50 20.01 25.16 30.21 3.7 1019.99 -39614 -21965 -28607 -18792 -44800 -42982 -40388 -38586 -41735 -28960 -23374 -19669 -24898 -23900 -12850 -12404 -10023 -3762 -4297 -1463 -2809 -6763 -5709 -6554 -3832 -2920 -7992 -4733 -10138 -6268 -4401 -3450 1794 -1165 -2634 -3386 -4690 -1577 1313 410 -475 1378 1580 412 1120 1038 1447 -339 31 699 508 -54 1323 1151 1972 505 1855 745 1392 -522 236 1877 2261 3002 1892 503 -155 -1139 220 900 865 1557 964 711 431 -525 -1052 -2972 -1896 -1630 -1408 -1403 -1692 -1367 -914 14 457 705 1295 900 627 -190 -781 -782 -447 -32 -94 616 372 -297 -502 -1303 -1549 -678 -1105 -1177 -816 -763 -364 171 656 717 417 152 -80 -21 -106 512 378 700 248 520 929 426 529 266 -322 283 348 388 -123 -306 -189 -499 -158 -103 -17 422 345 -157 -142 -412 -506 -723 -390 -583 -337 -928 -845 -837 -901 -1151 -763 -591 -515 -839 -995 -589 -669 -581 -223 -275 -96 -194 -482 -416 -526 -324 -259 -765 -421 -910 -557 -440 -398 225 -164 -355 -443 -681 -238 238 90 -119 363 437 118 322 305 428 -103 10 223 163 -20 509 480 863 215 805 329 644 -242 103 875 1181 1744 1089 280 -89 -660 125 592 595 1122 702 498 301 -331 -607 -1828 -1148 -1154 -1080 -1147 -1527 -1294 -866 14 461 737 1360 924 638 -180 -738 -726 -422 -34 -109 766 487 -396 -634 -1585 -1811 -783 -1326 -1511 -1038 -1030 -499 257 1030 1139 663 242 -119 -31 -154 770 581 1096 397 847 1461 653 811 394 -456 397 537 639 -213 -538 -343 -912 -296 -206 -33 851 706 -315 -282 -781 -956 SS 20250320T114550.5Z 9210.490168 261 1 30.05 2 77.38 85.87 37.03 248.98 0.00 1 0.00 1 0 17 7.452e-02 7.059e-03 1.225e-02 1.190e-03 4.486000e-01 5.908836e-04 4.627512e-03 -6.000000e+00 4.145330e-02 226.32 -2.00 3.04 -2.00 318.98 0.00e+00 1.632267e-03 1.439889e-04 8.374729e-04 -6.000000e+00 1.916691e-03 293.38 -2.00 20.00 -2.00 318.09 0.00e+00 4.449 0.000 302.00 328.00 3 1.1878e+00 1.6437e-03 4.7945e-02 -6.0000e+00 1.0237e-01 8.7499e-03 1.9197e-03 2.0442e-02 -6.0000e+00 1.1098e-01 -2.2897e-02 1.3944e-03 1.0111e-02 -6.0000e+00 6.6581e-02 1.4605e-03 7.4717e-04 2.9819e-03 -6.0000e+00 2.9105e-02 1.2917e-03 -1.1437e-04 3.1465e-05 2.9532e-05 -6.0000e+00 1.8608e-03 -8.5712e-04 0.0000e+00 11 8 0 10 0 0 2.93 25.17 0.39 -0.00086 -0.00172 172 172 1 5 0 174.700 33.50 20.00 25.17 30.23 3.6 1020.43 -17024 -17329 -18732 -24504 -30492 -30937 -35271 -13618 -25821 -20576 -19338 -19354 -19678 -8640 -5862 -4082 -5235 -536 -5727 418 592 -4784 -409 -4049 -677 -2951 -2764 -3988 -5821 -4769 -2476 285 181 -2092 -3274 -5579 -3566 -2427 512 1247 1127 653 1558 1084 1258 1392 966 902 -400 478 812 1364 1082 1518 1251 1538 575 984 116 46 631 1321 2047 2416 1260 166 -467 -681 377 457 750 1046 545 514 387 -735 -1068 -2865 -1751 -1421 -1388 -872 -1796 -1693 -1034 -184 203 361 925 882 572 228 -413 -419 -536 -234 -57 735 326 -306 -543 -1015 -1227 -650 -957 -1261 -828 -635 -146 192 793 464 531 142 -61 67 136 94 591 560 201 524 701 571 534 122 -292 565 423 164 97 -239 -360 -284 -275 10 -134 439 341 -45 -187 -535 -532 -413 -485 -567 -759 -891 -876 -1125 -401 -983 -804 -754 -802 -986 -477 -383 -306 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