File name: Pandora282s1_Ilo-UNAM_20250327_L2Fit_fout2c3d20250118p1-8.txt File generation date: 20250829T101032.5Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 282 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora282_OF_v2d20240118.txt Instrument calibration file used: Pandora282s1_CF_v3d20250118.txt Level 1 file used: Pandora282s1_Ilo-UNAM_20250327_L1_smca1c3d20250118p1-8.txt Full location name: Grupo de Investigacion en Ciencias de la Atmosfera, UNAM, Peru Short location name: Ilo-UNAM Country of location: Peru Location latitude [deg]: -17.6020 Location longitude [deg]: -71.3389 Location altitude [m]: 85 Local noon date: 20250327 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 202 344 Nominal wavelengths inside fitting window [nm]: 305.0533 305.1939 305.3345 305.4751 305.6156 305.7562 305.8968 306.0373 306.1778 306.3184 306.4589 306.5994 306.7399 306.8803 307.0208 307.1613 307.3017 307.4421 307.5825 307.7230 307.8634 308.0037 308.1441 308.2845 308.4248 308.5652 308.7055 308.8458 308.9861 309.1264 309.2667 309.4070 309.5473 309.6875 309.8278 309.9680 310.1082 310.2484 310.3886 310.5288 310.6690 310.8091 310.9493 311.0894 311.2296 311.3697 311.5098 311.6499 311.7900 311.9300 312.0701 312.2102 312.3502 312.4902 312.6302 312.7702 312.9102 313.0502 313.1902 313.3301 313.4701 313.6100 313.7500 313.8899 314.0298 314.1697 314.3095 314.4494 314.5893 314.7291 314.8690 315.0088 315.1486 315.2884 315.4282 315.5680 315.7077 315.8475 315.9872 316.1269 316.2667 316.4064 316.5461 316.6858 316.8254 316.9651 317.1048 317.2444 317.3840 317.5236 317.6632 317.8028 317.9424 318.0820 318.2216 318.3611 318.5006 318.6402 318.7797 318.9192 319.0587 319.1982 319.3376 319.4771 319.6165 319.7560 319.8954 320.0348 320.1742 320.3136 320.4530 320.5923 320.7317 320.8710 321.0104 321.1497 321.2890 321.4283 321.5676 321.7068 321.8461 321.9854 322.1246 322.2638 322.4030 322.5422 322.6814 322.8206 322.9598 323.0990 323.2381 323.3772 323.5164 323.6555 323.7946 323.9337 324.0727 324.2118 324.3509 324.4899 324.6289 324.7679 324.9070 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250327T112527.8Z 9217.476016 110 1 29.54 2 82.58 84.66 56.25 89.42 0.00 1 0.00 1 0 17 4.505e-01 1.904e-02 3.107e-01 1.141e-02 6.621474e-01 6.257914e-03 6.860182e-03 -6.000000e+00 2.572709e-01 226.41 -2.00 3.04 -2.00 321.45 0.00e+00 5.281514e-03 3.468630e-03 3.763684e-03 -6.000000e+00 1.372900e-02 293.25 -2.00 20.00 -2.00 320.81 0.00e+00 7.155 0.001 302.00 328.00 3 2.1945e+00 2.3809e-02 7.7585e-02 -6.0000e+00 6.4188e-01 2.3136e-01 3.3754e-02 3.6507e-02 -6.0000e+00 7.0026e-01 -2.9945e-01 3.2399e-02 2.0423e-02 -6.0000e+00 4.1186e-01 1.1803e-01 1.5203e-02 6.8965e-03 -6.0000e+00 1.7975e-01 2.9277e-05 -4.0565e-04 3.1806e-04 1.0600e-04 -6.0000e+00 1.2162e-02 -5.0113e-04 0.0000e+00 12 8 8 10 0 0 -67.19 25.24 0.60 -0.00050 -0.00355 14 14 1 5 0 2109.690 33.50 20.00 25.24 29.18 3.7 1014.73 -9030 900000 -192305 900000 -169526 -198018 900000 900000 900000 -146186 900000 -125001 900000 900000 -121930 -131900 -98048 55076 900000 900000 900000 900000 140969 -121501 -42972 -12002 -3776 900000 -2956 -2646 10498 29995 65743 -21950 11986 30125 29137 -40465 9054 33393 -25988 17351 10730 65063 10361 -2833 3793 533 -11491 70818 44319 3353 8976 -10198 4929 -18455 -4510 22013 17962 19034 13124 -2453 6458 10242 3236 -1730 9691 10513 -2506 717 3640 5380 11515 2576 6113 3079 12664 -802 -1210 -4526 -2901 -3296 432 1568 -2695 -1010 3139 3846 438 2741 153 -8112 448 -2137 1888 -2242 -2590 2157 -544 49 672 -1474 -5094 -2083 -1221 3139 -3186 1410 -1154 -1274 1105 -590 -1426 -542 -1389 -1197 631 607 674 130 362 2762 1374 960 1454 811 -1788 270 -311 515 -534 1454 1083 -1038 -590 -52 103 1097 -104 368 55 -881 -1456 -100 900000 -3105 900000 -1882 -2798 900000 900000 900000 -1770 900000 -1388 900000 900000 -2830 -4126 -2474 611 900000 900000 900000 900000 1565 -5517 -954 -226 -67 900000 -49 -47 198 566 1022 -902 333 669 712 -2336 392 1371 -2192 1021 715 2600 725 -233 299 45 -1148 3302 3001 387 1076 -1619 717 -3524 -776 2908 2393 2451 1836 -441 1219 2137 783 -430 2098 2311 -684 222 1228 1881 3783 878 1846 854 2938 -213 -357 -1663 -1243 -1639 231 877 -1681 -606 1910 2414 287 1709 100 -5403 261 -1293 1224 -1611 -2177 2007 -583 54 690 -1395 -4472 -1745 -1103 2902 -3299 1496 -1371 -1709 1495 -878 -2175 -799 -1957 -1743 899 906 983 202 565 4050 2146 1465 2125 1155 -2503 374 -490 845 -985 2831 2223 -2128 -1296 -122 247 2648 -257 881 124 -1889 -3233 SS 20250327T114158.9Z 9217.487487 115 1 30.17 2 78.66 83.34 52.43 88.06 0.00 1 0.00 1 0 17 1.300e-01 6.891e-03 3.495e-02 1.978e-03 4.973520e-01 9.905215e-04 5.187676e-03 -6.000000e+00 7.232429e-02 226.41 -2.00 3.04 -2.00 319.70 0.00e+00 8.137926e-03 3.080102e-04 1.242793e-03 -6.000000e+00 3.341040e-03 293.25 -2.00 20.00 -2.00 318.86 0.00e+00 4.912 0.000 302.00 328.00 3 1.6538e+00 2.8865e-03 5.2948e-02 -6.0000e+00 1.7865e-01 7.4899e-03 3.4799e-03 2.2546e-02 -6.0000e+00 1.9366e-01 -5.2588e-02 2.8361e-03 1.4189e-02 -6.0000e+00 1.1617e-01 1.7902e-02 1.5058e-03 8.6629e-03 -6.0000e+00 5.0766e-02 4.9435e-04 -7.3120e-05 5.1970e-05 7.6469e-05 -6.0000e+00 3.2456e-03 -8.5552e-04 0.0000e+00 11 8 0 10 0 0 67.28 25.26 0.48 -0.00086 -0.00140 75 75 1 5 0 402.180 33.50 20.00 25.26 30.62 3.6 1022.97 -34164 -37902 -26244 -57784 -58225 -41349 -40018 -40575 -40711 -41791 -30288 -26814 -33711 -14967 -23439 -11896 -14495 -5938 -11433 3597 -433 -6700 -423 -5592 -769 -6545 -668 -7632 -7911 -6470 -3675 1633 -831 -418 -4266 -5186 -5604 -4862 -1649 2389 -1670 2241 1893 1713 958 1062 1400 1247 1539 -658 566 1650 913 1080 844 726 868 738 380 248 510 776 2681 3223 1488 637 -346 -1094 -26 291 727 1377 1204 1124 374 -690 -1490 -3265 -2383 -1717 -1314 -1046 -1625 -1633 -673 84 383 748 1177 1317 411 24 -552 -696 -417 -117 80 643 292 143 -149 -1153 -1523 -640 -646 -1183 -849 -519 -131 283 745 467 304 264 -36 -208 -238 -159 160 341 10 373 722 366 504 296 -305 374 334 50 93 -218 -62 -265 -28 -21 191 352 251 -86 -259 -428 -454 -481 -651 -435 -1282 -1157 -662 -664 -751 -840 -927 -602 -559 -949 -450 -967 -525 -732 -302 -666 191 -25 -401 -24 -357 -49 -465 -46 -546 -555 -473 -307 153 -92 -50 -503 -592 -700 -706 -282 427 -349 481 433 408 234 268 359 327 414 -188 175 561 311 397 327 289 355 302 152 99 210 350 1345 1673 832 344 -180 -573 -14 174 484 959 842 753 234 -422 -838 -1824 -1425 -1118 -994 -839 -1441 -1429 -622 83 377 763 1208 1318 412 22 -514 -639 -390 -118 92 796 380 189 -187 -1401 -1780 -738 -768 -1512 -1074 -697 -179 425 1169 743 484 421 -54 -308 -350 -244 249 539 15 614 1146 565 781 443 -437 530 500 81 163 -388 -114 -491 -55 -43 396 717 520 -174 -521 -852 -867 SS 20250327T114719.7Z 9217.491200 118 1 29.94 2 77.40 82.90 51.19 87.60 0.00 1 0.00 1 0 17 8.778e-02 6.602e-03 1.906e-02 1.480e-03 4.594251e-01 7.375593e-04 4.687363e-03 -6.000000e+00 4.884835e-02 226.42 -2.00 3.04 -2.00 319.28 0.00e+00 6.355454e-03 1.992903e-04 4.967701e-04 -6.000000e+00 2.256590e-03 293.24 -2.00 20.00 -2.00 318.42 0.00e+00 4.455 0.000 302.00 328.00 3 1.5661e+00 2.0866e-03 4.8185e-02 -6.0000e+00 1.2066e-01 -7.8077e-03 2.4636e-03 2.1114e-02 -6.0000e+00 1.3080e-01 -2.8979e-02 1.8741e-03 1.1642e-02 -6.0000e+00 7.8464e-02 7.8771e-03 1.0041e-03 6.9372e-03 -6.0000e+00 3.4287e-02 8.6431e-04 -1.3935e-04 3.9100e-05 5.6066e-05 -6.0000e+00 2.1921e-03 -7.5020e-04 0.0000e+00 11 8 0 10 0 0 32.34 25.27 0.41 -0.00075 -0.00180 134 134 1 5 0 223.410 33.50 20.00 25.27 30.81 3.6 1023.73 -30709 -25756 -22410 -39911 -38187 -33818 -26508 -10053 -26816 -20376 -24118 -12615 -27142 -11266 -11642 -10291 -5366 -962 -4360 -4711 262 -6642 -2066 -3241 -366 -995 -4931 -4380 -5900 -3697 -4468 254 289 -2053 -4796 -5039 -2860 -648 -461 976 -530 904 1768 1862 2241 1190 858 1153 673 1622 1429 1095 1284 1548 1426 797 724 854 160 -139 232 1548 1742 2320 1217 125 -794 -1219 99 835 765 922 731 512 14 -518 -1203 -2435 -1845 -1795 -1207 -1371 -2147 -1808 -1196 -376 205 578 1156 819 539 147 -301 -478 -414 -56 118 964 808 -109 -86 -753 -1093 -353 -590 -905 -836 -611 -46 234 720 545 338 59 -129 -140 -94 92 -122 -68 -110 408 488 436 528 316 -258 576 182 83 160 -114 -128 -82 -30 -38 -33 392 256 -92 -81 -544 -502 -661 -614 -556 -1147 -959 -776 -597 -215 -759 -577 -710 -355 -1093 -490 -630 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