File name: Pandora282s1_Ilo-UNAM_20250513_L2Fit_fout2c3d20250118p1-8.txt File generation date: 20250829T102211.0Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 282 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora282_OF_v2d20240118.txt Instrument calibration file used: Pandora282s1_CF_v3d20250118.txt Level 1 file used: Pandora282s1_Ilo-UNAM_20250513_L1_smca1c3d20250118p1-8.txt Full location name: Grupo de Investigacion en Ciencias de la Atmosfera, UNAM, Peru Short location name: Ilo-UNAM Country of location: Peru Location latitude [deg]: -17.6020 Location longitude [deg]: -71.3389 Location altitude [m]: 85 Local noon date: 20250513 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 202 344 Nominal wavelengths inside fitting window [nm]: 305.0533 305.1939 305.3345 305.4751 305.6156 305.7562 305.8968 306.0373 306.1778 306.3184 306.4589 306.5994 306.7399 306.8803 307.0208 307.1613 307.3017 307.4421 307.5825 307.7230 307.8634 308.0037 308.1441 308.2845 308.4248 308.5652 308.7055 308.8458 308.9861 309.1264 309.2667 309.4070 309.5473 309.6875 309.8278 309.9680 310.1082 310.2484 310.3886 310.5288 310.6690 310.8091 310.9493 311.0894 311.2296 311.3697 311.5098 311.6499 311.7900 311.9300 312.0701 312.2102 312.3502 312.4902 312.6302 312.7702 312.9102 313.0502 313.1902 313.3301 313.4701 313.6100 313.7500 313.8899 314.0298 314.1697 314.3095 314.4494 314.5893 314.7291 314.8690 315.0088 315.1486 315.2884 315.4282 315.5680 315.7077 315.8475 315.9872 316.1269 316.2667 316.4064 316.5461 316.6858 316.8254 316.9651 317.1048 317.2444 317.3840 317.5236 317.6632 317.8028 317.9424 318.0820 318.2216 318.3611 318.5006 318.6402 318.7797 318.9192 319.0587 319.1982 319.3376 319.4771 319.6165 319.7560 319.8954 320.0348 320.1742 320.3136 320.4530 320.5923 320.7317 320.8710 321.0104 321.1497 321.2890 321.4283 321.5676 321.7068 321.8461 321.9854 322.1246 322.2638 322.4030 322.5422 322.6814 322.8206 322.9598 323.0990 323.2381 323.3772 323.5164 323.6555 323.7946 323.9337 324.0727 324.2118 324.3509 324.4899 324.6289 324.7679 324.9070 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SU 20250513T131524.5Z 9264.552367 1986 1 30.05 2 62.26 57.07 108.32 235.40 0.00 1 0.00 1 0 17 1.689e-01 3.832e-02 1.201e-01 2.506e-02 2.252404e-01 1.236188e-02 2.744828e-03 -6.000000e+00 9.397275e-02 226.44 -2.00 3.04 -2.00 317.68 0.00e+00 -8.788990e-05 1.993720e-03 1.266155e-03 -6.000000e+00 4.316474e-03 291.96 -2.00 20.00 -2.00 316.77 0.00e+00 2.137 0.000 302.00 328.00 3 8.0196e+00 3.2910e-02 2.3618e-02 -6.0000e+00 2.3226e-01 8.0783e-02 3.7274e-02 1.2350e-02 -6.0000e+00 2.5181e-01 4.3044e-02 2.2613e-02 4.7938e-03 -6.0000e+00 1.5093e-01 -1.3199e-02 1.1532e-02 2.1951e-03 -6.0000e+00 6.5867e-02 1.5782e-05 -1.4301e-03 6.9416e-04 2.1202e-05 -6.0000e+00 4.2165e-03 -1.4188e-03 0.0000e+00 12 8 8 10 0 0 22.67 25.10 6.89 -0.00142 -0.01216 12 12 1 5 0 2503.930 33.25 20.00 25.10 30.60 3.8 1020.96 -23576 147187 -9101 49679 -33753 25506 -12124 25499 32838 -20778 50516 -26753 4121 27764 25647 -12621 -9028 5901 15368 -922 5852 -519 29221 1378 8040 -12911 23830 16734 4943 -7671 3909 2004 7420 -13794 -10922 -6517 -1679 1101 5135 -8382 18402 -7937 994 5517 3036 -4773 -1568 -2474 -266 325 21180 -2275 -4282 -7334 -2883 -684 -5173 2497 10092 318 -1332 823 93 5326 3047 4953 2446 -3046 -3059 5202 2878 2728 2039 -879 4643 -496 -7146 -3693 934 -251 -3543 -4760 815 -2294 4852 -796 -1 4685 4709 -3430 6577 -8547 -5029 -3905 -2024 -4848 -2794 382 -694 3405 -1176 3613 -4036 -7285 1928 2970 -4662 -216 2395 732 3674 2123 1982 1626 -2793 190 -2643 -3622 -2852 966 6497 6703 900 1141 2128 -6299 -2382 1142 -1754 -2753 -514 4709 -2682 -3729 2533 1215 1507 1010 -2107 1075 1784 -170 -3201 -3143 3925 -1193 3422 -4650 1814 -1320 2153 2919 -3370 3929 -4458 559 3393 3647 -2917 -2086 1206 2971 -217 1326 -123 5194 343 1983 -4103 5295 3755 1142 -1926 912 512 1946 -4720 -3374 -1810 -477 352 1906 -4228 7851 -4603 543 2918 1633 -2779 -868 -1336 -136 163 8989 -1314 -2664 -4954 -1928 -455 -3679 1648 6032 206 -894 576 71 4166 2484 3654 1674 -2092 -2161 3861 2437 2437 1853 -798 3766 -381 -5224 -2645 642 -195 -2921 -4400 768 -2314 4840 -907 -1 5580 5672 -4375 7059 -9705 -5470 -3914 -2048 -5534 -3141 461 -920 4351 -1481 4380 -4873 -9117 2408 3928 -6288 -291 3272 1077 5568 3354 3048 2341 -4212 255 -3553 -5073 -4225 1490 9893 10141 1409 1717 2996 -9191 -3144 1404 -2337 -3983 -768 6883 -4255 -6116 4118 2127 2712 1865 -4084 1989 3157 -296 -5524 SU 20250513T141402.0Z 9264.593079 2856 1 31.21 2 51.22 46.94 118.77 227.45 0.00 1 0.00 1 0 17 1.226e-02 8.365e-03 6.074e-03 3.466e-03 1.820580e-01 1.726940e-03 1.914894e-03 -6.000000e+00 6.820171e-03 226.44 -2.00 3.04 -2.00 315.68 0.00e+00 1.008752e-03 1.763938e-04 3.629632e-05 -6.000000e+00 3.133355e-04 291.96 -2.00 20.00 -2.00 314.90 0.00e+00 1.593 0.000 302.00 328.00 3 6.1506e+00 4.4420e-03 1.7597e-02 -6.0000e+00 1.6856e-02 5.1303e-02 4.9583e-03 8.1519e-03 -6.0000e+00 1.8277e-02 1.8951e-03 2.8563e-03 3.9438e-03 -6.0000e+00 1.0955e-02 -6.4005e-03 1.3362e-03 1.2524e-03 -6.0000e+00 4.7793e-03 1.9321e-04 -2.3677e-04 9.2374e-05 1.2791e-05 -6.0000e+00 3.0608e-04 3.1254e-04 0.0000e+00 11 8 0 10 0 0 99.97 25.21 0.46 0.00031 -0.00147 10 10 1 5 0 3120.000 33.50 20.00 25.21 31.87 3.8 1030.49 -1619 102 276 2475 -2635 -566 -3768 -799 -437 -932 -1816 -2209 -197 1566 685 1158 -486 446 1326 1932 537 1014 331 452 562 600 -347 4717 1206 173 133 672 2812 -1831 -2777 -4718 -2986 -1973 -673 -954 -67 -2035 -146 289 -1637 143 -1021 -819 -798 -1175 2297 606 329 1023 886 8 213 624 343 348 819 1381 1127 2400 779 391 -693 -912 -52 165 651 574 341 965 1416 128 -1004 -1626 -1599 -1904 -674 -825 -1837 -1625 -1040 442 320 702 1178 629 522 -910 -527 -801 326 -742 404 954 67 484 110 -1048 -1228 -783 -426 -705 -766 -537 -500 -38 911 623 395 433 -458 -487 -393 -525 566 390 438 1002 745 253 323 15 -844 -104 350 126 -15 -259 31 -194 -167 208 388 483 285 -33 49 -936 -748 -394 27 73 595 -631 -124 -890 -205 -113 -255 -483 -580 -56 494 246 452 -197 183 556 829 239 439 145 207 269 296 -173 2091 506 70 56 299 1317 -934 -1311 -2145 -1440 -1087 -403 -672 -47 -1515 -109 218 -1249 107 -756 -581 -592 -857 1677 444 253 820 731 7 182 529 285 286 686 1229 1010 2267 752 372 -601 -749 -44 157 637 590 355 968 1333 118 -833 -1354 -1340 -1651 -648 -813 -1958 -1789 -1213 513 393 894 1509 789 608 -1045 -541 -828 343 -802 476 1156 88 633 135 -1289 -1407 -907 -505 -893 -1010 -738 -668 -53 1337 934 573 621 -602 -589 -498 -643 734 550 605 1463 1067 351 422 18 -1072 -128 449 162 -21 -360 44 -277 -236 311 597 761 458 -52 76 -1405 -1085 SU 20250513T142422.3Z 9264.600259 2877 1 29.68 2 49.46 44.73 120.48 225.78 0.00 1 0.00 1 0 17 9.317e-03 6.896e-03 2.105e-03 1.436e-03 1.719828e-01 7.192519e-04 1.827082e-03 -6.000000e+00 5.184456e-03 226.44 -2.00 3.04 -2.00 314.94 0.00e+00 3.685734e-04 6.374766e-05 4.779085e-05 -6.000000e+00 2.381641e-04 291.96 -2.00 20.00 -2.00 314.23 0.00e+00 1.535 0.000 302.00 328.00 3 4.6698e+00 1.8356e-03 1.6883e-02 -6.0000e+00 1.2813e-02 2.4300e-02 2.0408e-03 7.6491e-03 -6.0000e+00 1.3893e-02 4.3331e-03 1.1729e-03 3.7289e-03 -6.0000e+00 8.3270e-03 -4.6602e-03 5.3276e-04 1.0571e-03 -6.0000e+00 3.6335e-03 9.2803e-04 -3.8942e-05 3.7853e-05 1.2791e-05 -6.0000e+00 2.3265e-04 -4.8828e-04 0.0000e+00 11 8 0 10 0 0 99.97 25.25 0.37 -0.00049 -0.00078 44 44 1 5 0 674.440 33.50 20.00 25.25 32.63 3.8 1036.22 -920 1639 77 -1492 -2722 -2331 -1959 1261 708 -171 -2122 -1008 -1384 192 1513 233 85 1100 386 1108 647 233 852 1379 1029 877 724 121 -618 -461 618 1218 2122 -137 -2741 -2699 -2326 -1473 -529 -411 -431 -1106 -717 -537 -292 65 -507 -586 -929 -532 627 102 649 893 637 752 682 541 564 180 605 1339 1263 1705 931 148 -469 -1239 119 860 661 593 610 651 483 -389 -379 -1544 -1011 -1189 -1299 -866 -1740 -1737 -1200 -694 -9 201 730 669 415 176 -336 -306 -284 36 -59 929 591 104 -194 -671 -1048 -247 -680 -914 -687 -532 -74 427 681 605 600 344 -160 -30 -199 -215 218 328 63 221 526 447 446 77 -219 565 282 148 157 -169 -136 -258 -23 77 27 390 350 -339 -146 -562 -621 -319 553 27 -489 -842 -671 -589 412 240 -61 -749 -374 -522 80 650 110 41 535 195 572 343 121 443 749 548 485 401 67 -316 -225 307 637 1179 -76 -1522 -1416 -1312 -889 -356 -306 -331 -885 -587 -442 -238 53 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