File name: Pandora282s1_Ilo-UNAM_20250523_L2Fit_fout2c3d20250118p1-8.txt File generation date: 20250829T103113.5Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 282 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora282_OF_v2d20240118.txt Instrument calibration file used: Pandora282s1_CF_v3d20250118.txt Level 1 file used: Pandora282s1_Ilo-UNAM_20250523_L1_smca1c3d20250118p1-8.txt Full location name: Grupo de Investigacion en Ciencias de la Atmosfera, UNAM, Peru Short location name: Ilo-UNAM Country of location: Peru Location latitude [deg]: -17.6020 Location longitude [deg]: -71.3389 Location altitude [m]: 85 Local noon date: 20250523 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 202 344 Nominal wavelengths inside fitting window [nm]: 305.0533 305.1939 305.3345 305.4751 305.6156 305.7562 305.8968 306.0373 306.1778 306.3184 306.4589 306.5994 306.7399 306.8803 307.0208 307.1613 307.3017 307.4421 307.5825 307.7230 307.8634 308.0037 308.1441 308.2845 308.4248 308.5652 308.7055 308.8458 308.9861 309.1264 309.2667 309.4070 309.5473 309.6875 309.8278 309.9680 310.1082 310.2484 310.3886 310.5288 310.6690 310.8091 310.9493 311.0894 311.2296 311.3697 311.5098 311.6499 311.7900 311.9300 312.0701 312.2102 312.3502 312.4902 312.6302 312.7702 312.9102 313.0502 313.1902 313.3301 313.4701 313.6100 313.7500 313.8899 314.0298 314.1697 314.3095 314.4494 314.5893 314.7291 314.8690 315.0088 315.1486 315.2884 315.4282 315.5680 315.7077 315.8475 315.9872 316.1269 316.2667 316.4064 316.5461 316.6858 316.8254 316.9651 317.1048 317.2444 317.3840 317.5236 317.6632 317.8028 317.9424 318.0820 318.2216 318.3611 318.5006 318.6402 318.7797 318.9192 319.0587 319.1982 319.3376 319.4771 319.6165 319.7560 319.8954 320.0348 320.1742 320.3136 320.4530 320.5923 320.7317 320.8710 321.0104 321.1497 321.2890 321.4283 321.5676 321.7068 321.8461 321.9854 322.1246 322.2638 322.4030 322.5422 322.6814 322.8206 322.9598 323.0990 323.2381 323.3772 323.5164 323.6555 323.7946 323.9337 324.0727 324.2118 324.3509 324.4899 324.6289 324.7679 324.9070 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250523T124740.4Z 9274.533106 222 1 29.31 2 69.06 58.78 25.82 20.63 0.00 1 0.00 1 0 17 2.090e-02 7.100e-03 6.850e-03 1.974e-03 3.196224e-01 9.736984e-04 3.331708e-03 -6.000000e+00 1.162726e-02 226.41 -2.00 3.04 -2.00 317.43 0.00e+00 7.933535e-04 1.514061e-04 1.937558e-04 -6.000000e+00 5.336479e-04 291.65 -2.00 20.00 -2.00 316.55 0.00e+00 2.770 0.000 302.00 328.00 3 3.8387e+00 2.5727e-03 3.0685e-02 -6.0000e+00 2.8737e-02 1.8631e-02 2.9104e-03 1.4264e-02 -6.0000e+00 3.1164e-02 -5.0701e-03 1.7731e-03 6.9659e-03 -6.0000e+00 1.8676e-02 4.3552e-04 9.0599e-04 1.9966e-03 -6.0000e+00 8.1442e-03 5.0661e-04 -1.8159e-04 5.2656e-05 2.0338e-05 -6.0000e+00 5.2196e-04 1.5845e-03 0.0000e+00 11 8 0 10 0 0 99.66 25.05 0.34 0.00158 0.00022 19 19 1 5 0 1542.210 33.50 20.00 25.05 28.34 3.8 1006.29 -5949 2394 -4745 -2555 -12183 -12345 -1521 -3057 -477 -3449 -1231 -1898 -7971 -1337 1669 -319 -756 1981 1134 768 2009 115 1157 688 1592 -356 1023 2306 -1092 -1603 1137 523 2040 -1027 -3722 -3075 -1684 -2702 -585 -1037 -338 -534 -271 77 -76 849 -55 -151 -318 -557 1376 561 962 1272 1013 1184 913 227 143 331 794 1033 1765 2058 700 467 -621 -1096 268 527 416 1055 342 723 369 -908 -978 -1943 -1065 -1568 -748 -1897 -2254 -1596 -1069 -88 3 193 757 648 687 105 -97 -386 -84 -465 -170 1116 339 186 -353 -786 -1332 -807 -709 -686 -815 -745 49 487 970 737 343 224 -81 47 -211 -6 354 184 -238 312 514 565 389 327 -256 583 503 281 121 -41 86 -149 -56 -85 -109 474 132 -147 -214 -671 -633 -566 234 -518 -258 -1187 -1145 -135 -313 -54 -428 -147 -234 -1095 -202 287 -63 -159 424 257 182 485 28 283 181 405 -97 277 635 -289 -421 315 148 628 -345 -1194 -936 -550 -1042 -248 -488 -175 -291 -153 44 -43 484 -31 -85 -177 -311 802 335 610 854 710 794 631 158 97 221 540 756 1411 1682 595 370 -488 -839 213 452 376 995 327 665 318 -753 -775 -1465 -825 -1312 -668 -1814 -2343 -1718 -1161 -102 3 234 921 769 795 112 -100 -379 -86 -510 -198 1376 458 252 -453 -970 -1598 -972 -890 -876 -1088 -1000 69 700 1490 1127 516 330 -115 65 -285 -9 506 271 -364 468 750 831 544 458 -341 790 699 409 180 -63 136 -234 -93 -145 -192 813 230 -252 -368 -1107 -1046 SS 20250523T125707.2Z 9274.539667 225 1 23.78 2 67.15 57.59 25.18 15.48 0.00 1 0.00 1 0 17 1.814e-02 7.424e-03 1.095e-02 3.253e-03 2.908622e-01 1.605048e-03 3.038853e-03 -6.000000e+00 1.009125e-02 226.41 -2.00 3.04 -2.00 317.36 0.00e+00 1.309198e-03 2.443382e-04 1.339745e-04 -6.000000e+00 4.630950e-04 291.65 -2.00 20.00 -2.00 316.49 0.00e+00 2.554 0.000 302.00 328.00 3 4.6525e+00 4.2349e-03 2.8221e-02 -6.0000e+00 2.4941e-02 1.7072e-02 4.7864e-03 1.3037e-02 -6.0000e+00 2.7047e-02 1.3381e-02 2.9089e-03 6.3837e-03 -6.0000e+00 1.6208e-02 -9.3703e-03 1.4823e-03 2.0047e-03 -6.0000e+00 7.0690e-03 2.8637e-04 -6.1647e-05 8.7080e-05 1.9040e-05 -6.0000e+00 4.5296e-04 8.4924e-04 0.0000e+00 12 9 1 12 1 1 99.69 25.07 0.48 0.00085 0.00039 7 10 1 5 0 2971.260 33.25 20.00 25.07 28.48 3.7 1007.37 -5067 -1436 -3901 -617 -7208 -8215 -1948 1058 403 3262 -5231 -192 -3336 -2396 835 -1973 -1871 1469 2841 2842 -1410 2261 1357 189 1027 -114 1189 5364 17 -2399 4967 2436 3176 -728 -2895 -4283 -1794 -2823 -934 -397 371 -1687 -989 695 -234 -852 -954 -959 -274 -1565 2557 160 306 1506 -14 784 375 -3 125 582 616 1449 1194 2876 655 -53 254 -1103 225 532 1012 745 6 432 621 -83 -997 -2557 -1662 -1252 -945 -787 -1909 -2011 -1146 -397 239 512 281 893 610 446 187 -29 -129 20 107 1574 524 28 -432 -650 -1446 -860 -736 -406 -1005 -318 -203 284 704 815 594 173 -238 -17 -262 4 370 -182 -91 40 565 313 420 393 -309 71 -116 501 187 -303 218 -162 2 203 -185 184 149 -97 -220 -583 -125 -510 -155 -448 -65 -707 -771 -182 109 47 393 -674 -24 -492 -410 147 -401 -399 316 633 660 -351 534 328 49 282 -33 343 1402 4 -619 1282 708 1010 -254 -958 -1370 -609 -1034 -407 -188 193 -940 -568 398 -135 -499 -552 -544 -152 -879 1460 102 192 986 -10 547 270 -2 88 402 436 1095 926 2381 567 -42 201 -855 180 457 900 699 5 395 566 -69 -796 -1946 -1293 -1029 -881 -765 -2027 -2095 -1263 -468 281 622 346 1064 716 479 195 -29 -135 21 130 1989 689 37 -569 -786 -1720 -1028 -909 -534 -1312 -433 -289 411 1085 1232 922 253 -336 -24 -356 6 526 -267 -138 59 819 462 587 555 -414 93 -163 718 285 -459 333 -257 3 344 -325 313 259 -166 -379 -967 -200 SS 20250523T130345.9Z 9274.544281 229 1 30.01 2 65.82 56.71 24.84 11.73 0.00 1 0.00 1 0 17 1.049e-02 6.658e-03 1.621e-03 7.143e-04 2.811456e-01 3.546065e-04 2.953411e-03 -6.000000e+00 5.836290e-03 226.41 -2.00 3.04 -2.00 316.53 0.00e+00 6.618257e-04 4.324417e-05 1.060109e-04 -6.000000e+00 2.678349e-04 291.65 -2.00 20.00 -2.00 315.67 0.00e+00 2.424 0.000 302.00 328.00 3 2.3286e+00 9.2142e-04 2.6864e-02 -6.0000e+00 1.4425e-02 -2.7081e-03 1.0341e-03 1.2504e-02 -6.0000e+00 1.5643e-02 1.0677e-03 6.0319e-04 6.1137e-03 -6.0000e+00 9.3740e-03 -2.6363e-03 2.9240e-04 1.7566e-03 -6.0000e+00 4.0883e-03 3.4173e-03 -1.8786e-04 1.8949e-05 1.8727e-05 -6.0000e+00 2.6197e-04 9.2647e-04 0.0000e+00 11 8 0 10 0 0 99.41 25.08 0.38 0.00093 -0.00049 140 140 1 5 0 214.290 33.25 20.00 25.08 28.75 3.8 1009.95 60 859 852 -2302 -3521 -3498 -1710 324 50 -174 -2898 -2444 -2199 -117 495 273 220 967 1013 1602 888 256 857 1108 472 566 619 -203 -1291 -720 307 320 1337 -650 -3243 -3368 -2942 -1599 -668 158 -283 -384 -61 -289 275 32 -107 -372 -684 -542 480 322 763 1075 737 1025 533 661 283 83 623 1106 1683 2216 1067 181 -479 -957 294 558 560 757 564 613 160 -201 -670 -1943 -1363 -1177 -1131 -1204 -1926 -1631 -1044 -424 -24 196 684 539 533 47 -260 -407 -219 -149 163 1001 658 52 -181 -859 -1102 -348 -775 -915 -662 -582 -52 405 828 648 640 387 -97 -110 -225 -215 88 300 -168 115 545 401 561 142 -109 615 432 274 228 -109 -179 -143 -149 15 -47 357 248 -57 -177 -592 -662 10 148 152 -401 -541 -555 -259 55 9 -35 -594 -505 -476 -29 141 81 68 310 339 518 297 85 286 394 179 225 248 -77 -458 -249 112 128 545 -285 -1352 -1339 -1265 -744 -353 93 -176 -250 -39 -188 177 21 -68 -246 -445 -352 310 226 540 804 549 776 416 516 217 63 479 873 1446 1971 942 155 -395 -764 243 507 524 743 559 587 150 -177 -552 -1583 -1135 -1022 -1072 -1225 -2056 -1745 -1146 -483 -28 237 832 640 607 52 -274 -423 -229 -167 190 1254 846 67 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