File name: Pandora282s1_Ilo-UNAM_20250601_L2Fit_fout2c3d20250118p1-8.txt File generation date: 20250829T103300.2Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 282 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora282_OF_v2d20240118.txt Instrument calibration file used: Pandora282s1_CF_v3d20250118.txt Level 1 file used: Pandora282s1_Ilo-UNAM_20250601_L1_smca1c3d20250118p1-8.txt Full location name: Grupo de Investigacion en Ciencias de la Atmosfera, UNAM, Peru Short location name: Ilo-UNAM Country of location: Peru Location latitude [deg]: -17.6020 Location longitude [deg]: -71.3389 Location altitude [m]: 85 Local noon date: 20250601 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 202 344 Nominal wavelengths inside fitting window [nm]: 305.0533 305.1939 305.3345 305.4751 305.6156 305.7562 305.8968 306.0373 306.1778 306.3184 306.4589 306.5994 306.7399 306.8803 307.0208 307.1613 307.3017 307.4421 307.5825 307.7230 307.8634 308.0037 308.1441 308.2845 308.4248 308.5652 308.7055 308.8458 308.9861 309.1264 309.2667 309.4070 309.5473 309.6875 309.8278 309.9680 310.1082 310.2484 310.3886 310.5288 310.6690 310.8091 310.9493 311.0894 311.2296 311.3697 311.5098 311.6499 311.7900 311.9300 312.0701 312.2102 312.3502 312.4902 312.6302 312.7702 312.9102 313.0502 313.1902 313.3301 313.4701 313.6100 313.7500 313.8899 314.0298 314.1697 314.3095 314.4494 314.5893 314.7291 314.8690 315.0088 315.1486 315.2884 315.4282 315.5680 315.7077 315.8475 315.9872 316.1269 316.2667 316.4064 316.5461 316.6858 316.8254 316.9651 317.1048 317.2444 317.3840 317.5236 317.6632 317.8028 317.9424 318.0820 318.2216 318.3611 318.5006 318.6402 318.7797 318.9192 319.0587 319.1982 319.3376 319.4771 319.6165 319.7560 319.8954 320.0348 320.1742 320.3136 320.4530 320.5923 320.7317 320.8710 321.0104 321.1497 321.2890 321.4283 321.5676 321.7068 321.8461 321.9854 322.1246 322.2638 322.4030 322.5422 322.6814 322.8206 322.9598 323.0990 323.2381 323.3772 323.5164 323.6555 323.7946 323.9337 324.0727 324.2118 324.3509 324.4899 324.6289 324.7679 324.9070 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250601T115533.0Z 9283.496910 60 1 30.79 2 80.80 63.15 149.42 86.69 0.00 1 0.00 1 0 17 4.290e-01 1.903e-02 2.695e-01 9.485e-03 6.331722e-01 5.051506e-03 7.071544e-03 -6.000000e+00 2.408587e-01 226.39 -2.00 3.04 -2.00 321.06 0.00e+00 5.655073e-03 2.377159e-03 4.881697e-03 -6.000000e+00 1.205732e-02 291.38 -2.00 20.00 -2.00 320.40 0.00e+00 5.933 0.001 302.00 328.00 3 3.0135e+00 1.7132e-02 6.8169e-02 -6.0000e+00 5.9690e-01 2.5647e-01 2.2855e-02 3.9747e-02 -6.0000e+00 6.4855e-01 -3.3678e-01 2.0903e-02 1.9408e-02 -6.0000e+00 3.8620e-01 1.3435e-01 1.0192e-02 5.1450e-03 -6.0000e+00 1.6920e-01 3.9465e-05 -8.5273e-04 2.5361e-04 1.0180e-04 -6.0000e+00 1.1200e-02 5.8696e-04 0.0000e+00 12 8 8 10 0 0 99.34 24.89 0.80 0.00059 -0.00582 14 14 1 5 0 2198.570 33.25 20.00 24.89 24.88 3.8 983.98 -213696 900000 -190715 900000 -111394 -201757 -71668 900000 179482 900000 -53011 -126292 -57917 -11306 74179 -58885 -22833 -34943 59458 31497 -30037 63359 50638 -29725 900000 -70355 -48483 900000 -21689 25885 -6508 -13500 6087 12985 50980 -11320 18743 -27890 6528 8172 26332 -15975 2575 62345 1196 9718 -119 17163 8315 661 25902 3622 11841 7516 7823 -417 4410 24228 14536 17782 8662 11205 4413 9480 -1475 3720 5500 3820 200 4758 1239 -114 3613 1713 6387 -5449 -518 -5291 -1019 -3711 -27 -4104 -793 -1313 -1522 2922 132 -185 1449 224 -154 -5880 -2370 2559 -942 -1513 -2149 76 -776 1952 -1098 -593 -3602 -3488 -410 -2099 -2857 -104 778 -1757 1989 -480 -277 -344 -972 850 -346 -51 687 376 129 3228 2330 926 1501 1022 -651 545 -221 588 -40 472 500 -241 -151 23 -700 385 825 -290 -688 -798 -662 -7000 900000 -6247 900000 -1403 -5931 -662 900000 1658 900000 -490 -2652 -778 -136 685 -1741 -527 -1001 714 524 -944 761 702 -989 900000 -3900 -2195 900000 -701 550 -228 -611 264 576 1460 -575 762 -2113 428 634 1922 -1904 269 3687 132 1006 -14 1728 953 86 2896 569 1871 1347 1482 -89 921 4141 2646 3056 1665 2298 1105 2575 -481 1120 1575 1129 66 1758 531 -52 1589 728 2378 -2034 -168 -1789 -362 -1622 -13 -2445 -508 -812 -1005 1981 97 -142 1101 168 -108 -4060 -1646 1698 -651 -1224 -2031 81 -936 2339 -1285 -623 -3489 -3311 -410 -2280 -3280 -124 1000 -2382 2915 -776 -452 -546 -1468 1192 -488 -74 1067 621 214 5036 3530 1382 2138 1414 -955 793 -333 1003 -76 884 979 -501 -338 56 -1600 886 1911 -712 -1598 -1740 -1369 SS 20250601T120502.0Z 9283.503495 65 1 22.91 2 78.79 62.24 147.26 86.27 0.00 1 0.00 1 0 17 2.595e-01 1.102e-02 1.638e-01 5.512e-03 5.444340e-01 2.805776e-03 5.732528e-03 -6.000000e+00 1.443388e-01 226.39 -2.00 3.04 -2.00 320.23 0.00e+00 1.519028e-03 1.028838e-03 2.056047e-03 -6.000000e+00 6.618228e-03 291.38 -2.00 20.00 -2.00 319.48 0.00e+00 4.963 0.000 302.00 328.00 3 2.9644e+00 8.5350e-03 5.5191e-02 -6.0000e+00 3.5675e-01 5.3004e-02 1.0721e-02 2.7455e-02 -6.0000e+00 3.8692e-01 -9.0239e-02 9.3338e-03 1.3020e-02 -6.0000e+00 2.3184e-01 3.6554e-02 4.7876e-03 3.5032e-03 -6.0000e+00 1.0106e-01 1.1803e-04 -5.0979e-04 1.4555e-04 4.4877e-05 -6.0000e+00 6.4807e-03 2.4240e-03 0.0000e+00 12 9 9 12 1 1 99.97 24.90 0.66 0.00242 -0.00141 16 22 1 5 0 1347.320 33.25 20.01 24.90 25.37 3.8 987.86 -127337 79881 -111973 -31070 -69949 -106768 -89620 51254 -44986 -80634 -68538 -40058 -79802 -13674 -7229 39699 -6002 -34012 -4357 -18378 -7098 -9540 -5948 -25603 -22209 -17934 -13678 26260 -12054 -7337 466 -7984 -10600 5510 -11398 -1580 6152 -16555 12170 -3957 1406 -7391 7173 5970 -1645 -670 817 1168 3358 5642 1637 -355 2507 -1 1401 205 2370 5778 1468 2831 2387 4760 1890 4586 3660 2018 1787 1893 -2704 1003 1601 1971 2351 569 1091 -904 316 -5699 -2715 -1178 -1571 -2859 -1324 -1282 -1312 176 375 -95 1461 1538 856 -2055 -1329 50 -956 -1464 851 757 -529 -235 -837 -1430 -1535 -1110 -794 -740 -1692 -761 -122 -475 1168 1399 914 184 124 16 -805 -163 613 393 -344 335 1595 347 602 -2 -241 383 665 350 277 -77 30 -344 -493 78 -518 859 249 -87 -105 -811 -426 -2551 429 -2648 -317 -940 -2009 -1542 275 -653 -1820 -1400 -667 -2445 -272 -167 683 -181 -1481 -152 -780 -279 -379 -237 -1362 -1242 -1022 -765 946 -609 -367 25 -549 -866 418 -968 -117 463 -1851 1263 -585 223 -1371 1211 1046 -313 -129 157 227 659 1131 376 -93 697 0 413 64 746 1765 455 847 732 1556 719 1914 1636 882 750 799 -1291 538 956 1237 1473 346 611 -462 145 -2726 -1364 -688 -987 -2078 -1046 -1067 -1168 153 345 -91 1392 1425 807 -1845 -1113 41 -864 -1411 919 871 -683 -306 -1038 -1740 -1688 -1207 -938 -866 -2095 -992 -170 -687 1843 2341 1541 301 191 23 -1160 -244 969 661 -591 555 2523 539 892 -3 -355 559 1002 596 484 -144 59 -660 -1015 170 -1103 1838 544 -185 -224 -1649 -824 SS 20250601T121345.9Z 9283.509559 71 1 12.99 2 76.96 61.37 145.27 85.89 0.00 1 0.00 1 0 25 2.356e-01 1.466e-02 1.419e-01 8.160e-03 4.810673e-01 4.101129e-03 5.162671e-03 -6.000000e+00 1.309880e-01 226.39 -2.00 3.04 -2.00 319.74 0.00e+00 3.737910e-03 1.249550e-03 1.852006e-03 -6.000000e+00 6.008050e-03 291.38 -2.00 20.00 -2.00 318.93 0.00e+00 4.315 0.000 302.00 328.00 3 3.6966e+00 1.1901e-02 4.7974e-02 -6.0000e+00 3.2375e-01 1.0145e-01 1.4248e-02 2.3164e-02 -6.0000e+00 3.5116e-01 -1.2815e-01 1.1048e-02 1.1732e-02 -6.0000e+00 2.1041e-01 5.5807e-02 5.8248e-03 3.5838e-03 -6.0000e+00 9.1687e-02 1.0841e-04 -1.1253e-03 2.1767e-04 4.6867e-05 -6.0000e+00 5.8839e-03 4.6451e-03 0.0000e+00 12 9 9 12 9 1 99.97 24.91 0.42 0.00465 -0.00381 5 14 1 5 0 2163.440 33.25 20.00 24.91 25.94 3.8 991.58 -47380 -22900 -89520 170485 -67262 -97822 -103705 -28041 43071 -16430 27506 -13485 -42425 -34934 -14675 -22186 -13237 -13272 -10194 3092 -9565 -3511 -7475 -17886 -18038 6232 -13360 25114 -113 -3880 -6542 6427 2411 -713 -10129 7485 -2167 -10748 3194 2026 4619 1296 8083 6952 2132 -499 5374 -483 -749 8192 7400 4756 1870 -1557 4670 4543 236 -618 4698 2644 2861 -642 5990 2837 3168 2389 -1444 1578 45 1731 3418 -1770 2682 174 45 -3906 -766 -5679 -5168 -3417 -1762 -4866 -2302 185 -470 -948 -1131 1284 2094 1301 -107 -2558 -2130 -2131 -2519 558 323 1437 -304 1257 -1091 -1054 -1781 -578 -1606 -680 -1357 535 907 1035 1325 876 830 242 35 -691 -901 187 -195 205 179 919 718 1184 1113 986 -1679 629 -142 -113 38 251 -88 -247 -717 -246 284 379 483 213 -615 -13 -1172 -1131 -492 -3989 1357 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