File name: Pandora282s1_Ilo-UNAM_20250604_L2Fit_ffus5c3d20250118p1-8.txt File generation date: 20250829T102342.7Z Data description: Level 2 spectral fitting results file Data file version: ffus5c3p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 282 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora282_OF_v2d20240118.txt Instrument calibration file used: Pandora282s1_CF_v3d20250118.txt Level 1 file used: Pandora282s1_Ilo-UNAM_20250604_L1_smca1c3d20250118p1-8.txt Full location name: Grupo de Investigacion en Ciencias de la Atmosfera, UNAM, Peru Short location name: Ilo-UNAM Country of location: Peru Location latitude [deg]: -17.6020 Location longitude [deg]: -71.3389 Location altitude [m]: 85 Local noon date: 20250604 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 327 593 Nominal wavelengths inside fitting window [nm]: 322.5422 322.6814 322.8206 322.9598 323.0990 323.2381 323.3772 323.5164 323.6555 323.7946 323.9337 324.0727 324.2118 324.3509 324.4899 324.6289 324.7679 324.9070 325.0460 325.1849 325.3239 325.4629 325.6018 325.7408 325.8797 326.0186 326.1575 326.2964 326.4353 326.5741 326.7130 326.8518 326.9907 327.1295 327.2683 327.4071 327.5459 327.6847 327.8234 327.9622 328.1009 328.2397 328.3784 328.5171 328.6558 328.7945 328.9331 329.0718 329.2104 329.3491 329.4877 329.6263 329.7649 329.9035 330.0421 330.1806 330.3192 330.4577 330.5963 330.7348 330.8733 331.0118 331.1503 331.2887 331.4272 331.5656 331.7041 331.8425 331.9809 332.1193 332.2577 332.3961 332.5344 332.6728 332.8111 332.9495 333.0878 333.2261 333.3644 333.5027 333.6409 333.7792 333.9174 334.0557 334.1939 334.3321 334.4703 334.6085 334.7467 334.8848 335.0230 335.1611 335.2993 335.4374 335.5755 335.7136 335.8517 335.9897 336.1278 336.2658 336.4039 336.5419 336.6799 336.8179 336.9559 337.0939 337.2318 337.3698 337.5077 337.6456 337.7836 337.9215 338.0593 338.1972 338.3351 338.4730 338.6108 338.7486 338.8864 339.0243 339.1620 339.2998 339.4376 339.5754 339.7131 339.8508 339.9886 340.1263 340.2640 340.4017 340.5394 340.6770 340.8147 340.9523 341.0899 341.2276 341.3652 341.5027 341.6403 341.7779 341.9155 342.0530 342.1905 342.3280 342.4656 342.6031 342.7405 342.8780 343.0155 343.1529 343.2904 343.4278 343.5652 343.7026 343.8400 343.9773 344.1147 344.2521 344.3894 344.5267 344.6640 344.8013 344.9386 345.0759 345.2132 345.3504 345.4877 345.6249 345.7621 345.8993 346.0365 346.1737 346.3109 346.4480 346.5852 346.7223 346.8594 346.9965 347.1336 347.2707 347.4078 347.5449 347.6819 347.8189 347.9560 348.0930 348.2300 348.3670 348.5039 348.6409 348.7778 348.9148 349.0517 349.1886 349.3255 349.4624 349.5993 349.7361 349.8730 350.0098 350.1467 350.2835 350.4203 350.5571 350.6939 350.8306 350.9674 351.1041 351.2408 351.3776 351.5143 351.6510 351.7876 351.9243 352.0610 352.1976 352.3342 352.4708 352.6075 352.7440 352.8806 353.0172 353.1537 353.2903 353.4268 353.5633 353.6999 353.8363 353.9728 354.1093 354.2458 354.3822 354.5186 354.6550 354.7915 354.9279 355.0642 355.2006 355.3370 355.4733 355.6096 355.7460 355.8823 356.0186 356.1548 356.2911 356.4274 356.5636 356.6999 356.8361 356.9723 357.1085 357.2447 357.3808 357.5170 357.6531 357.7893 357.9254 358.0615 358.1976 358.3337 358.4697 358.6058 358.7418 358.8779 359.0139 359.1499 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Bromine oxide slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of bromine oxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of bromine oxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of bromine oxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of bromine oxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Bromine oxide effective temperature [K] Column 28: Independent uncertainty of bromine oxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of bromine oxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of bromine oxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective bromine oxide fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for bromine oxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Formaldehyde slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of formaldehyde slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of formaldehyde slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of formaldehyde slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of formaldehyde slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Formaldehyde effective temperature [K] Column 39: Independent uncertainty of formaldehyde effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of formaldehyde effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of formaldehyde effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective formaldehyde fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for formaldehyde [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Nitrous acid slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of nitrous acid slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of nitrous acid slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of nitrous acid slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of nitrous acid slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Nitrous acid effective temperature [K] Column 50: Independent uncertainty of nitrous acid effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of nitrous acid effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of nitrous acid effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective nitrous acid fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for nitrous acid [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 56: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 57: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 58: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 59: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 60: Nitrogen dioxide effective temperature [K] Column 61: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 62: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 63: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 64: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 65: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 66: Oxygen dimer slant column amount [moles squared per meter to the 5th], -9e99=fitting not successful Column 67: Independent uncertainty of oxygen dimer slant column amount [moles squared per meter to the 5th], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 68: Structured uncertainty of oxygen dimer slant column amount [moles squared per meter to the 5th], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 69: Common uncertainty of oxygen dimer slant column amount [moles squared per meter to the 5th], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 70: rms-based uncertainty of oxygen dimer slant column amount [moles squared per meter to the 5th], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 71: Oxygen dimer effective temperature [K] Column 72: Independent uncertainty of oxygen dimer effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 73: Structured uncertainty of oxygen dimer effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 74: Common uncertainty of oxygen dimer effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 75: Effective oxygen dimer fitting wavelength [nm], -9=fitting not successful Column 76: Diffuse correction applied before fitting at effective fitting wavelength for oxygen dimer [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 77: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 78: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 79: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 80: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 81: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 82: Ozone effective temperature [K] Column 83: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 84: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 85: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 86: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 87: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 88: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 89: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 90: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 91: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 92: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 93: Sulfur dioxide effective temperature [K] Column 94: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 95: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 96: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 97: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 98: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 99: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 100: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 101: Lower limit used for wavelength scaling [nm] Column 102: Upper limit used for wavelength scaling [nm] Column 103: Order of smoothing polynomial Column 104: Smoothing polynomial coefficient, order 0 Column 105: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 106: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 107: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 108: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 109: Smoothing polynomial coefficient, order 1 Column 110: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 111: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 112: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 113: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 114: Smoothing polynomial coefficient, order 2 Column 115: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 116: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 117: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 118: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 119: Smoothing polynomial coefficient, order 3 Column 120: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 121: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 122: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 123: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 124: Smoothing polynomial coefficient, order 4 Column 125: Independent uncertainty of smoothing polynomial coefficient, order 4, -9=fitting not successful Column 126: Structured uncertainty of smoothing polynomial coefficient, order 4, -9=fitting not successful Column 127: Common uncertainty of smoothing polynomial coefficient, order 4, -9=fitting not successful Column 128: rms-based uncertainty of smoothing polynomial coefficient, order 4, -9=fitting not successful Column 129: Mean value of measured data inside fitting window [same units as measurements] Column 130: Offset polynomial coefficient, order 0 Column 131: Independent uncertainty of offset polynomial coefficient, order 0, -9=fitting not successful Column 132: Structured uncertainty of offset polynomial coefficient, order 0, -9=fitting not successful Column 133: Common uncertainty of offset polynomial coefficient, order 0, -9=fitting not successful Column 134: rms-based uncertainty of offset polynomial coefficient, order 0, -9=fitting not successful Column 135: Wavelength change polynomial coefficient, order 0 Column 136: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 137: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 138: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 139: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 140: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 141: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 142: Resolution change polynomial coefficient, order 0 Column 143: Independent uncertainty of resolution change polynomial coefficient, order 0, -9=fitting not successful Column 144: Structured uncertainty of resolution change polynomial coefficient, order 0, -9=fitting not successful Column 145: Common uncertainty of resolution change polynomial coefficient, order 0, -9=fitting not successful Column 146: rms-based uncertainty of resolution change polynomial coefficient, order 0, -9=fitting not successful Column 147: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 148: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 149: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 150: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 151: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 152: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 153: Atmospheric variability [%], 999=no atmospheric variability was determined Column 154: Wavelength effective temperature [°C], 999=no effective temperature given Column 155: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 156: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 157: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 158: Number of bright count cycles Column 159: Number of dark count cycles Column 160: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 161: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 162: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 163: Integration time [ms] Column 164: Temperature at electronics board [°C], 999=no temperature signal Column 165: Spectrometer control temperature [°C], 999=no temperature signal Column 166: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 167: Temperature in head sensor [°C], 999=no temperature signal Column 168: Humidity in head sensor [%], -9=no humidity signal Column 169: Pressure in head sensor [hPa], -9=no pressure signal Columns 170-436: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 437-703: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250604T164909.9Z 9286.700809 290 1 30.80 2 40.14 358.08 106.49 96.48 0.00 1 0.00 1 0 33 6.904e-03 6.718e-03 4.745e-03 4.580e-03 -1.430598e-07 1.404355e-06 1.938990e-07 3.979290e-07 2.150784e-06 226.39 -2.00 3.04 -2.00 338.69 0.00e+00 -4.762763e-04 3.795719e-04 4.584191e-05 1.611373e-05 5.790204e-04 291.28 -2.00 20.00 -2.00 336.00 0.00e+00 -2.406015e-04 6.576518e-05 4.935402e-06 2.629609e-05 1.068954e-04 291.28 -2.00 20.00 -2.00 344.95 0.00e+00 2.373818e-05 1.907999e-04 1.874707e-05 9.587724e-06 2.978187e-04 291.28 -2.00 20.00 -2.00 343.27 0.00e+00 -1.391839e+05 3.713271e+05 7.016606e+04 2.101181e+05 5.528104e+05 271.89 -2.00 10.04 -2.00 351.13 0.00e+00 1.509744e-01 4.914834e-03 1.204549e-03 1.906335e-03 6.909782e-03 226.39 -2.00 3.04 -2.00 329.75 0.00e+00 -4.940351e-03 7.996146e-03 2.650815e-03 1.210301e-04 9.654835e-03 291.28 -2.00 20.00 -2.00 327.64 0.00e+00 1.307 0.000 319.50 362.20 4 8.0488e+00 6.1496e-03 9.1547e-03 1.4960e-03 9.5735e-03 9.9402e-02 1.4285e-03 1.4435e-03 2.6723e-04 2.1839e-03 -1.6895e-02 2.7193e-03 5.7991e-04 7.1177e-05 4.1214e-03 -3.2254e-03 1.4295e-03 4.5085e-04 4.6914e-05 1.8483e-03 7.9684e-03 2.1753e-03 6.3916e-04 5.8366e-05 3.0527e-03 1.3036e-04 -3.4130e-02 3.5934e-03 8.9857e-05 6.1049e-05 5.6525e-03 -2.9168e-06 6.3016e-05 1.6360e-06 5.5900e-07 9.4991e-05 -9.0704e-04 0.0000e+00 3.6439e-01 3.7775e-01 6.3034e-03 3.2790e-03 5.6978e-01 12 8 8 10 0 0 -96.69 25.22 0.55 -0.00091 -0.00094 14 14 1 5 0 2199.890 33.50 19.99 25.22 30.21 3.8 1018.85 -249 -795 -326 560 -453 -46 582 631 -105 155 32 -153 948 -620 -390 -965 658 -251 -108 -865 -7 1107 -112 31 520 405 -190 234 -771 -428 -150 -519 -3 439 -760 2129 1433 -236 -199 -526 1002 -248 -77 -1177 -78 -151 -541 -732 138 132 1111 585 -368 184 -617 -205 -733 -515 1367 503 -329 486 -52 -21 347 488 198 -620 7 203 -946 167 -487 18 -1005 1254 584 225 -865 -581 117 424 -839 -822 392 -118 -70 153 -169 245 -65 448 -481 -1119 553 -37 981 -1217 2634 35 -438 616 244 627 -789 -332 587 40 593 -507 1007 -700 446 -297 544 -1099 -770 789 677 161 57 191 552 -643 -306 -497 112 -25 60 -1079 212 289 450 -566 -519 -41 -185 -560 781 541 391 186 -247 66 296 -27 183 -955 -1099 767 738 -127 484 19 67 -423 -705 -125 1458 -738 -1090 169 1896 431 -326 938 521 -1168 92 -164 791 -1280 -733 -397 71 814 408 194 -805 707 -1272 -1110 371 -2 -169 138 -802 733 -287 356 -629 442 681 -831 917 1471 -121 427 565 -226 -168 353 1379 -548 14 611 -614 138 560 -519 55 -955 -577 -603 459 194 -1525 -484 -865 -628 986 -93 182 495 -154 -29 285 225 -330 -757 179 142 -47 87 -8 -1099 350 535 266 1316 -329 219 -644 415 -81 -618 17 1637 -1555 2 656 -734 -275 1367 -846 1899 652 233 140 -63 -922 -1209 -501 -204 -1429 650 250 -164 -498 -196 350 -303 -32 413 449 -77 108 24 -117 730 -494 -307 -741 485 -181 -79 -664 -6 962 -104 30 527 416 -196 233 -773 -433 -154 -538 -3 432 -751 2060 1394 -228 -187 -490 918 -234 -72 -1083 -71 -144 -550 -737 145 141 1191 634 -406 205 -678 -218 -799 -515 1316 492 -333 505 -54 -21 349 501 210 -681 7 209 -970 172 -513 19 -1068 1289 607 236 -887 -565 110 400 -834 -850 414 -129 -72 171 -180 255 -68 484 -513 -1236 587 -39 896 -990 2231 31 -433 629 238 558 -661 -271 502 38 618 -560 1058 -705 429 -290 566 -1227 -866 819 759 172 59 192 561 -709 -334 -572 130 -29 66 -1160 236 314 486 -625 -569 -43 -188 -567 813 566 430 205 -265 69 327 -28 198 -1077 -1247 841 792 -134 500 19 67 -368 -560 -95 1164 -663 -1083 181 1940 453 -349 995 548 -1233 91 -165 767 -1319 -720 -403 74 857 443 214 -867 700 -1271 -1066 362 -2 -173 143 -817 728 -294 368 -644 431 678 -756 844 1349 -115 423 594 -260 -191 403 1529 -612 16 689 -686 145 556 -523 58 -1082 -630 -653 503 194 -1417 -426 -787 -619 1046 -97 192 527 -166 -32 323 256 -374 -870 203 163 -55 102 -10 -1294 400 587 282 1360 -343 229 -689 447 -89 -659 17 1460 -1400 1 563 -646 -234 1243 -822 1773 580 200 108 -46 -650 -871 -368 -157 -1177 600 233 SS 20250604T175550.9Z 9286.747117 327 1 28.68 2 43.82 335.64 91.02 91.65 0.00 1 0.00 1 0 33 2.354e-03 2.272e-03 1.965e-03 1.910e-03 -1.015903e-07 5.901590e-07 9.734311e-08 3.978573e-07 7.336820e-07 226.39 -2.00 3.04 -2.00 338.92 0.00e+00 1.873981e-04 1.602213e-04 2.002195e-05 1.612235e-05 1.986508e-04 291.28 -2.00 20.00 -2.00 336.32 0.00e+00 -5.788727e-05 2.708185e-05 4.169462e-06 2.629659e-05 3.607295e-05 291.28 -2.00 20.00 -2.00 345.22 0.00e+00 7.001480e-05 7.875908e-05 1.456687e-05 9.537371e-06 1.015721e-04 291.28 -2.00 20.00 -2.00 343.62 0.00e+00 -9.930582e+04 1.545428e+05 5.394424e+04 2.101615e+05 1.891437e+05 271.89 -2.00 10.04 -2.00 351.41 0.00e+00 1.571928e-01 2.067785e-03 1.211792e-03 1.906243e-03 2.363775e-03 226.39 -2.00 3.04 -2.00 329.71 0.00e+00 3.377873e-04 3.327932e-03 3.585303e-03 1.210919e-04 3.284748e-03 291.28 -2.00 20.00 -2.00 327.56 0.00e+00 1.384 0.000 319.50 362.20 4 6.5643e+00 2.5435e-03 9.6859e-03 1.4960e-03 3.2587e-03 6.7601e-02 5.9856e-04 1.5174e-03 2.6733e-04 7.4624e-04 -6.0761e-03 1.1397e-03 3.7573e-04 7.2123e-05 1.4119e-03 -1.6399e-03 5.9614e-04 5.2057e-04 4.6428e-05 6.3058e-04 2.9837e-03 9.1178e-04 5.6128e-04 5.8501e-05 1.0488e-03 5.3098e-04 -1.3145e-02 1.4984e-03 8.8821e-05 6.1509e-05 1.8828e-03 7.7688e-05 2.6055e-05 1.8087e-06 5.4871e-07 3.2405e-05 -3.7467e-03 0.0000e+00 2.4897e-01 1.5613e-01 7.0500e-03 3.3728e-03 1.9343e-01 12 9 8 11 8 0 99.69 25.33 0.67 -0.00375 -0.00279 9 9 1 5 0 3186.460 33.50 20.00 25.33 32.43 3.7 1030.27 -12 -502 -48 -93 -299 305 340 280 -732 152 45 43 249 -10 161 268 -45 40 -440 -348 348 418 15 44 -129 905 54 146 -438 -241 115 -308 -75 -470 -253 189 228 -274 -277 -102 -74 -150 -92 235 358 23 17 58 -201 -207 71 544 -298 -95 -253 -14 134 -248 301 383 216 -94 -175 347 73 166 -43 154 -120 203 2 -95 -108 -121 -102 300 167 -173 11 -177 171 -108 -326 182 -96 -17 129 -437 122 109 -94 417 -47 -134 -183 72 -2 -557 -202 382 -59 -52 -112 108 -10 53 495 -322 202 -75 -105 40 378 -86 563 29 -150 -65 -49 -190 80 37 -84 -291 -91 230 131 -161 51 -6 248 -324 -35 -55 107 -188 205 -209 41 15 -63 74 -103 180 85 156 -253 -425 -103 166 -192 108 40 67 -93 -290 -65 -107 514 181 -467 32 345 116 174 235 304 -88 181 -144 35 -375 -76 -191 165 36 227 -55 -28 -84 275 -169 -247 -361 -315 -46 17 172 192 56 -159 -64 76 -6 467 292 -123 193 -269 -141 -116 108 208 -84 -17 319 168 -387 302 -237 -246 172 -317 -62 295 98 37 267 -189 -494 -8 269 44 75 21 58 -114 -14 -57 -86 365 -1 -40 -24 45 -278 -83 1 -102 267 -91 -27 -363 402 -288 -29 58 372 -643 -130 309 -212 67 -121 -1 294 18 268 245 -94 112 -537 29 -34 302 -51 -39 -8 -325 -30 -61 -208 206 237 195 -527 115 36 33 196 -8 128 207 -36 31 -347 -269 289 372 13 42 -127 892 51 140 -423 -236 114 -291 -73 -451 -241 180 218 -257 -253 -92 -67 -137 -84 208 317 21 17 58 -214 -224 74 564 -315 -102 -265 -15 135 -243 287 368 213 -91 -169 345 72 169 -43 157 -122 207 2 -97 -106 -121 -101 309 163 -171 11 -170 159 -101 -321 186 -96 -17 137 -465 123 107 -93 426 -52 -144 -203 73 -2 -479 -169 355 -59 -54 -110 103 -9 46 452 -310 202 -79 -106 40 367 -85 560 30 -161 -71 -53 -195 79 38 -87 -307 -98 261 152 -185 57 -6 266 -342 -37 -58 112 -191 201 -215 41 15 -70 82 -111 197 91 170 -276 -480 -116 184 -209 114 42 72 -89 -260 -56 -89 451 165 -449 34 362 124 188 254 325 -93 191 -142 34 -375 -79 -197 176 38 251 -62 -30 -85 266 -158 -237 -372 -329 -49 17 175 200 60 -165 -64 75 -6 465 292 -126 196 -292 -158 -133 125 235 -94 -20 352 182 -402 308 -244 -266 188 -349 -71 317 101 36 253 -185 -500 -9 296 50 81 23 65 -131 -17 -66 -100 420 -2 -45 -28 51 -315 -93 2 -111 284 -96 -29 -396 442 -312 -31 58 360 -597 -115 276 -193 61 -120 -1 286 17 240 207 -76 85 -421 24 -27 263 -49 -38