File name: Pandora282s1_Ilo-UNAM_20250626_L2Fit_fout2c3d20250118p1-8.txt File generation date: 20250829T103627.7Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 282 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora282_OF_v2d20240118.txt Instrument calibration file used: Pandora282s1_CF_v3d20250118.txt Level 1 file used: Pandora282s1_Ilo-UNAM_20250626_L1_smca1c3d20250118p1-8.txt Full location name: Grupo de Investigacion en Ciencias de la Atmosfera, UNAM, Peru Short location name: Ilo-UNAM Country of location: Peru Location latitude [deg]: -17.6020 Location longitude [deg]: -71.3389 Location altitude [m]: 85 Local noon date: 20250626 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 202 344 Nominal wavelengths inside fitting window [nm]: 305.0533 305.1939 305.3345 305.4751 305.6156 305.7562 305.8968 306.0373 306.1778 306.3184 306.4589 306.5994 306.7399 306.8803 307.0208 307.1613 307.3017 307.4421 307.5825 307.7230 307.8634 308.0037 308.1441 308.2845 308.4248 308.5652 308.7055 308.8458 308.9861 309.1264 309.2667 309.4070 309.5473 309.6875 309.8278 309.9680 310.1082 310.2484 310.3886 310.5288 310.6690 310.8091 310.9493 311.0894 311.2296 311.3697 311.5098 311.6499 311.7900 311.9300 312.0701 312.2102 312.3502 312.4902 312.6302 312.7702 312.9102 313.0502 313.1902 313.3301 313.4701 313.6100 313.7500 313.8899 314.0298 314.1697 314.3095 314.4494 314.5893 314.7291 314.8690 315.0088 315.1486 315.2884 315.4282 315.5680 315.7077 315.8475 315.9872 316.1269 316.2667 316.4064 316.5461 316.6858 316.8254 316.9651 317.1048 317.2444 317.3840 317.5236 317.6632 317.8028 317.9424 318.0820 318.2216 318.3611 318.5006 318.6402 318.7797 318.9192 319.0587 319.1982 319.3376 319.4771 319.6165 319.7560 319.8954 320.0348 320.1742 320.3136 320.4530 320.5923 320.7317 320.8710 321.0104 321.1497 321.2890 321.4283 321.5676 321.7068 321.8461 321.9854 322.1246 322.2638 322.4030 322.5422 322.6814 322.8206 322.9598 323.0990 323.2381 323.3772 323.5164 323.6555 323.7946 323.9337 324.0727 324.2118 324.3509 324.4899 324.6289 324.7679 324.9070 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250626T160359.0Z 9308.669433 233 1 27.50 2 42.34 15.21 53.02 34.22 0.00 1 0.00 1 0 17 1.025e-02 7.846e-03 3.797e-03 2.645e-03 1.600594e-01 1.321987e-03 1.695139e-03 -6.000000e+00 5.701615e-03 226.40 -2.00 3.04 -2.00 314.81 0.00e+00 7.155879e-04 1.140299e-04 2.187935e-05 -6.000000e+00 2.604663e-04 290.69 -2.00 20.00 -2.00 314.14 0.00e+00 1.351 0.000 302.00 328.00 3 5.7794e+00 3.3743e-03 1.5074e-02 -6.0000e+00 1.4097e-02 5.4808e-02 3.7562e-03 7.1665e-03 -6.0000e+00 1.5287e-02 -2.0598e-03 2.1546e-03 3.4749e-03 -6.0000e+00 9.1552e-03 -3.5657e-03 9.7298e-04 1.0819e-03 -6.0000e+00 3.9920e-03 3.6945e-04 -1.4014e-04 6.9716e-05 1.1815e-05 -6.0000e+00 2.5581e-04 -3.3622e-03 0.0000e+00 12 9 1 12 1 1 99.97 25.15 0.50 -0.00336 -0.00442 8 10 1 5 0 3055.050 33.50 20.00 25.15 26.51 3.9 994.29 -714 1068 -322 117 -3366 -2735 -354 -1202 459 -360 -1271 -1395 -931 -117 2302 618 202 1250 430 2773 591 727 1107 731 -127 1315 -310 2289 -913 -777 1042 1094 1396 -1018 -2301 -3129 -2292 -1853 -30 -743 -133 -1470 -250 -199 -338 -513 -249 -683 -997 -909 1317 -181 -195 717 1198 204 944 446 42 129 530 884 1359 2142 1022 -249 -1177 -1239 51 403 541 504 904 1427 839 21 -714 -1805 -1528 -1246 -1244 -1656 -1410 -1219 -886 388 128 182 1489 718 824 -221 -736 -548 -94 -423 406 897 596 732 -263 -624 -1386 -805 -415 -910 -621 -1132 34 351 700 720 361 204 -412 -450 -372 -649 8 449 169 456 414 335 754 162 -75 -104 115 72 502 25 -78 -259 -89 159 269 553 260 117 -171 -641 -956 -244 388 -120 40 -1127 -844 -111 -424 163 -135 -463 -496 -359 -50 1081 296 99 613 218 1414 315 378 573 397 -73 765 -183 1230 -461 -403 546 557 757 -587 -1232 -1588 -1240 -1149 -21 -556 -108 -1250 -215 -173 -291 -441 -208 -549 -771 -684 1001 -149 -168 638 1021 177 828 392 36 117 460 813 1344 2104 1020 -243 -1040 -1101 46 386 539 528 951 1453 862 20 -635 -1485 -1253 -1133 -1187 -1746 -1494 -1332 -1027 453 159 223 1819 910 968 -252 -803 -552 -97 -447 469 1074 772 943 -322 -748 -1557 -913 -486 -1143 -810 -1466 45 487 969 1014 517 272 -527 -560 -451 -817 9 582 230 619 550 453 958 198 -91 -122 141 89 648 33 -104 -354 -122 229 400 798 383 170 -256 -929 -1346 SS 20250626T161336.7Z 9308.676119 236 1 0.84 2 41.80 12.01 51.78 32.07 0.00 1 0.00 1 0 17 9.904e-03 7.683e-03 4.407e-03 3.464e-03 1.556862e-01 1.748340e-03 1.677345e-03 -6.000000e+00 5.511320e-03 226.40 -2.00 3.04 -2.00 314.16 0.00e+00 4.750695e-04 1.334117e-04 2.567081e-05 -6.000000e+00 2.517825e-04 290.69 -2.00 20.00 -2.00 313.56 0.00e+00 1.340 0.000 302.00 328.00 3 2.7825e+00 4.4295e-03 1.4893e-02 -6.0000e+00 1.3626e-02 2.5572e-02 4.9035e-03 6.9731e-03 -6.0000e+00 1.4777e-02 1.4626e-03 2.8295e-03 3.3962e-03 -6.0000e+00 8.8497e-03 -5.5704e-03 1.2577e-03 9.7676e-04 -6.0000e+00 3.8586e-03 7.6325e-03 -1.8805e-04 9.0429e-05 1.2324e-05 -6.0000e+00 2.4728e-04 -3.0593e-03 0.0000e+00 12 9 1 12 1 1 999.00 25.16 0.42 -0.00306 -0.00447 2 107 1 5 0 279.500 33.50 20.01 25.16 26.81 3.8 995.22 -127 287 1248 -2592 -2511 -2847 -583 1007 2493 1002 -1135 -2304 -556 -214 681 1171 106 -135 913 1385 1120 1719 774 504 717 602 -734 -768 -771 1530 974 1116 1169 55 -2619 -3074 -2041 -2401 -1226 -182 -188 -682 324 -775 -622 -426 -153 -532 -892 -617 326 335 335 1235 489 462 529 585 488 -185 1171 1086 1512 1827 997 -330 -359 -1006 468 1127 349 860 603 983 452 207 52 -1336 -556 -1088 -1320 -1423 -1931 -1339 -906 -570 -563 571 875 -280 558 -250 -165 -91 71 -190 739 755 353 31 -285 -448 -1083 -579 -940 -983 -733 -1075 -386 414 400 721 287 686 -416 178 263 -231 362 41 110 587 678 403 603 -33 337 632 474 379 414 -191 -168 -477 55 240 239 258 -5 -588 -462 -127 -802 -55 134 584 -1171 -1023 -1137 -237 429 1113 477 -530 -1062 -262 -107 364 675 60 -78 536 831 663 1029 468 307 456 382 -472 -478 -454 870 572 661 710 35 -1637 -1816 -1284 -1617 -911 -147 -156 -588 275 -671 -533 -363 -130 -449 -726 -503 263 280 293 1086 444 423 479 530 445 -168 1071 1029 1457 1817 1004 -323 -334 -913 417 1074 352 907 627 1018 456 200 47 -1162 -480 -986 -1305 -1466 -2082 -1448 -1012 -670 -669 698 1080 -342 657 -276 -176 -92 73 -204 821 904 437 39 -340 -519 -1205 -651 -1110 -1212 -915 -1375 -497 556 541 988 389 898 -523 209 308 -275 448 53 145 771 893 525 757 -40 398 739 567 473 527 -246 -216 -630 75 330 339 367 -7 -850 -646 -176 -1104 SS 20250626T162235.5Z 9308.682355 239 1 20.16 2 41.41 8.96 50.70 29.98 0.00 1 0.00 1 0 17 9.017e-03 7.088e-03 2.562e-03 1.930e-03 1.550331e-01 9.737295e-04 1.652894e-03 -6.000000e+00 5.018093e-03 226.40 -2.00 3.04 -2.00 314.41 0.00e+00 5.427590e-04 7.773679e-05 1.674711e-05 -6.000000e+00 2.292455e-04 290.69 -2.00 20.00 -2.00 313.79 0.00e+00 1.332 0.000 302.00 328.00 3 4.9789e+00 2.4733e-03 1.4803e-02 -6.0000e+00 1.2407e-02 3.9581e-02 2.7419e-03 6.9380e-03 -6.0000e+00 1.3454e-02 4.1152e-04 1.5789e-03 3.3717e-03 -6.0000e+00 8.0577e-03 -3.7544e-03 7.0481e-04 1.0091e-03 -6.0000e+00 3.5133e-03 8.5204e-04 -1.4071e-04 5.0670e-05 1.1835e-05 -6.0000e+00 2.2515e-04 -3.1932e-03 0.0000e+00 12 9 1 12 1 1 99.71 25.18 0.36 -0.00319 -0.00425 7 12 1 5 0 2519.740 33.50 20.00 25.18 26.96 3.8 996.34 -847 332 139 -1192 -2378 -2202 -1105 861 1115 -635 18 347 -1337 90 1745 392 643 972 1043 1235 837 1048 828 958 -736 173 391 503 -758 -287 1247 872 1780 -245 -3001 -3305 -2366 -1646 -720 -111 -304 -973 -256 -602 -450 -442 -693 -879 -718 -405 369 544 199 1082 567 617 384 790 258 313 617 936 1155 2182 740 -412 -346 -1357 110 968 601 615 697 777 547 245 -605 -1899 -1076 -1106 -961 -971 -1271 -1447 -954 -703 -383 208 854 823 546 63 -2 -361 -162 -152 382 818 842 533 -189 -553 -1226 -529 -400 -684 -548 -864 -394 302 472 536 461 383 -352 -225 -417 -74 -39 250 -251 223 396 315 631 229 177 348 436 187 259 -380 -160 11 -110 -201 10 643 320 58 -99 -625 -755 -339 142 60 -486 -907 -778 -403 343 460 -280 8 142 -605 42 894 207 344 525 578 702 488 596 472 570 -438 105 237 302 -419 -160 703 486 1050 -153 -1767 -1835 -1400 -1049 -514 -88 -249 -831 -222 -529 -391 -383 -586 -713 -587 -321 300 447 171 965 497 544 346 708 228 286 547 880 1117 2220 767 -393 -325 -1211 99 939 619 636 728 825 550 233 -540 -1656 -929 -1008 -933 -991 -1329 -1569 -1096 -835 -461 259 1070 1006 647 71 -2 -371 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