File name: Pandora282s1_Ilo-UNAM_20250724_L2Fit_fout2c3d20250118p1-8.txt File generation date: 20250829T104448.4Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 282 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora282_OF_v2d20240118.txt Instrument calibration file used: Pandora282s1_CF_v3d20250118.txt Level 1 file used: Pandora282s1_Ilo-UNAM_20250724_L1_smca1c3d20250118p1-8.txt Full location name: Grupo de Investigacion en Ciencias de la Atmosfera, UNAM, Peru Short location name: Ilo-UNAM Country of location: Peru Location latitude [deg]: -17.6020 Location longitude [deg]: -71.3389 Location altitude [m]: 85 Local noon date: 20250724 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 202 344 Nominal wavelengths inside fitting window [nm]: 305.0533 305.1939 305.3345 305.4751 305.6156 305.7562 305.8968 306.0373 306.1778 306.3184 306.4589 306.5994 306.7399 306.8803 307.0208 307.1613 307.3017 307.4421 307.5825 307.7230 307.8634 308.0037 308.1441 308.2845 308.4248 308.5652 308.7055 308.8458 308.9861 309.1264 309.2667 309.4070 309.5473 309.6875 309.8278 309.9680 310.1082 310.2484 310.3886 310.5288 310.6690 310.8091 310.9493 311.0894 311.2296 311.3697 311.5098 311.6499 311.7900 311.9300 312.0701 312.2102 312.3502 312.4902 312.6302 312.7702 312.9102 313.0502 313.1902 313.3301 313.4701 313.6100 313.7500 313.8899 314.0298 314.1697 314.3095 314.4494 314.5893 314.7291 314.8690 315.0088 315.1486 315.2884 315.4282 315.5680 315.7077 315.8475 315.9872 316.1269 316.2667 316.4064 316.5461 316.6858 316.8254 316.9651 317.1048 317.2444 317.3840 317.5236 317.6632 317.8028 317.9424 318.0820 318.2216 318.3611 318.5006 318.6402 318.7797 318.9192 319.0587 319.1982 319.3376 319.4771 319.6165 319.7560 319.8954 320.0348 320.1742 320.3136 320.4530 320.5923 320.7317 320.8710 321.0104 321.1497 321.2890 321.4283 321.5676 321.7068 321.8461 321.9854 322.1246 322.2638 322.4030 322.5422 322.6814 322.8206 322.9598 323.0990 323.2381 323.3772 323.5164 323.6555 323.7946 323.9337 324.0727 324.2118 324.3509 324.4899 324.6289 324.7679 324.9070 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250724T150910.0Z 9336.631365 185 1 29.72 2 45.04 35.22 48.66 30.49 0.00 1 0.00 1 0 17 1.051e-02 7.942e-03 3.421e-03 2.354e-03 1.614751e-01 1.180592e-03 1.697373e-03 -6.000000e+00 5.851054e-03 226.60 -2.00 3.04 -2.00 314.89 0.00e+00 1.014204e-03 1.021567e-04 2.765749e-05 -6.000000e+00 2.666453e-04 290.22 -2.00 20.00 -2.00 314.22 0.00e+00 1.413 0.000 302.00 328.00 3 5.6937e+00 3.0152e-03 1.5643e-02 -6.0000e+00 1.4475e-02 5.0860e-02 3.3511e-03 7.2859e-03 -6.0000e+00 1.5698e-02 1.2074e-03 1.9259e-03 3.4879e-03 -6.0000e+00 9.3973e-03 -5.1879e-03 8.7005e-04 1.1847e-03 -6.0000e+00 4.0919e-03 3.7764e-04 6.4151e-05 6.2119e-05 1.2266e-05 -6.0000e+00 2.6243e-04 -6.0033e-04 0.0000e+00 11 9 0 11 8 0 98.93 25.02 0.47 -0.00060 -0.00012 8 8 1 5 0 3714.310 33.25 20.00 25.02 28.00 3.8 1003.10 -580 1858 234 -185 -3248 -3200 838 612 1478 -1819 -2079 -704 1160 1508 689 539 -1156 587 1102 910 370 1689 1271 209 -55 388 -481 1166 -835 -551 1296 1060 2191 -1408 -2298 -3096 -1915 -1809 -782 190 -480 -1471 -358 -587 370 -785 -722 -1272 -1362 -539 1592 96 950 844 857 857 646 735 666 175 -62 1156 1297 2274 1044 -367 -1151 -1358 276 154 870 1163 717 1101 885 223 -639 -1722 -1451 -1770 -1698 -1283 -1470 -1488 -994 -166 366 -18 973 1137 612 -711 -107 -796 347 -402 -299 981 474 382 34 -455 -1171 -869 -538 -527 -1113 -396 -80 135 932 737 476 268 -396 -266 -697 -265 280 374 -116 575 313 393 588 -76 -544 585 250 347 -191 -433 380 210 -153 -109 50 402 190 61 -241 -574 -563 -195 658 85 -63 -1064 -977 256 209 512 -681 -747 -245 434 632 301 256 -569 288 553 471 197 865 654 113 -31 227 -282 628 -419 -263 626 542 1184 -817 -1230 -1577 -1040 -1131 -539 142 -393 -1178 -291 -482 298 -639 -611 -1037 -1067 -409 1222 80 818 713 741 748 575 651 577 151 -55 1078 1228 2268 1056 -363 -1031 -1150 237 151 881 1232 769 1143 869 211 -577 -1440 -1215 -1553 -1668 -1299 -1593 -1668 -1117 -200 441 -22 1221 1387 735 -784 -111 -822 365 -436 -338 1207 598 480 43 -525 -1344 -1012 -649 -642 -1419 -523 -109 184 1324 1066 664 365 -492 -320 -824 -323 364 500 -163 801 427 517 769 -95 -643 702 299 442 -243 -564 493 279 -215 -156 73 600 290 92 -353 -816 -815 SS 20250724T151422.2Z 9336.634979 188 1 29.15 2 44.34 33.80 48.04 29.17 0.00 1 0.00 1 0 17 9.215e-03 7.353e-03 2.407e-03 1.744e-03 1.611754e-01 8.766057e-04 1.709642e-03 -6.000000e+00 5.129876e-03 226.60 -2.00 3.04 -2.00 314.62 0.00e+00 8.164885e-04 7.279523e-05 1.914524e-05 -6.000000e+00 2.337855e-04 290.22 -2.00 20.00 -2.00 313.98 0.00e+00 1.396 0.000 302.00 328.00 3 5.1654e+00 2.2325e-03 1.5499e-02 -6.0000e+00 1.2691e-02 4.9439e-02 2.4774e-03 7.2554e-03 -6.0000e+00 1.3763e-02 -2.4592e-03 1.4241e-03 3.5009e-03 -6.0000e+00 8.2391e-03 -4.0041e-03 6.4000e-04 1.1097e-03 -6.0000e+00 3.5874e-03 6.5337e-04 -1.3247e-06 4.6001e-05 1.2289e-05 -6.0000e+00 2.3008e-04 -3.8620e-04 0.0000e+00 11 8 0 10 0 0 99.61 25.03 0.30 -0.00039 -0.00040 15 15 1 5 0 1942.890 33.25 19.99 25.03 27.84 3.8 1001.65 70 1025 158 -1474 -2381 -2675 -38 561 718 14 -1267 -1623 -89 -294 1076 34 -295 770 566 1393 1156 882 817 789 1017 1299 -29 -225 -869 -265 1286 987 1422 13 -2486 -3231 -2524 -1492 -882 -383 -614 -930 -792 -478 142 -165 -478 -501 -962 -822 976 645 766 572 332 970 841 969 199 132 493 920 1539 1979 523 -71 -672 -918 -17 757 716 772 698 798 852 -211 -810 -1806 -985 -1328 -881 -1240 -1830 -1818 -1148 -212 91 256 727 711 670 -242 -531 -577 -50 -316 185 1149 730 350 -228 -846 -960 -622 -852 -634 -463 -767 -438 361 796 350 578 328 -111 -23 -350 -401 -257 379 83 279 593 430 723 288 -54 504 314 276 -1 -170 171 -393 212 56 -2 392 215 -93 -337 -379 -898 26 399 63 -552 -837 -879 -13 208 273 6 -493 -621 -37 -137 513 18 -157 411 312 730 620 497 460 434 582 766 -17 -125 -476 -137 677 549 786 8 -1450 -1793 -1499 -944 -623 -297 -491 -771 -673 -408 119 -139 -393 -417 -774 -643 777 519 643 503 300 878 776 890 180 118 451 845 1518 1963 528 -69 -622 -803 -15 724 721 815 743 824 873 -197 -711 -1556 -845 -1202 -843 -1243 -1973 -2027 -1290 -255 110 323 921 878 804 -266 -549 -584 -52 -340 208 1410 924 443 -272 -981 -1091 -717 -1031 -779 -590 -980 -578 498 1101 494 783 431 -138 -27 -412 -490 -321 510 112 376 780 571 902 360 -64 601 375 352 -2 -223 224 -530 287 81 -3 570 319 -136 -481 -546 -1260 SS 20250724T151916.5Z 9336.638386 191 1 30.02 2 43.70 32.41 47.49 27.91 0.00 1 0.00 1 0 17 8.369e-03 6.746e-03 2.451e-04 1.911e-04 1.571155e-01 9.633082e-05 1.682669e-03 -6.000000e+00 4.658662e-03 226.60 -2.00 3.04 -2.00 314.22 0.00e+00 6.634799e-04 7.412214e-06 1.834619e-05 -6.000000e+00 2.123248e-04 290.22 -2.00 20.00 -2.00 313.62 0.00e+00 1.381 0.000 302.00 328.00 3 9.3821e-01 2.4441e-04 1.5293e-02 -6.0000e+00 1.1525e-02 1.3420e-02 2.7075e-04 7.0820e-03 -6.0000e+00 1.2499e-02 -2.9889e-04 1.5594e-04 3.4266e-03 -6.0000e+00 7.4825e-03 -3.9688e-03 6.9194e-05 1.0503e-03 -6.0000e+00 3.2577e-03 4.6417e-02 -1.0486e-04 4.9969e-06 1.2278e-05 -6.0000e+00 2.0896e-04 1.7701e-04 0.0000e+00 11 8 0 10 0 0 99.64 25.04 0.40 0.00018 -0.00061 852 852 1 5 0 35.230 33.25 20.00 25.04 27.73 3.9 1001.86 225 91 266 -1730 -2529 -2025 -197 838 1263 241 -1136 -955 -580 75 806 442 327 597 761 1437 826 540 923 915 448 548 162 -240 -692 56 969 1062 1646 -282 -2368 -2642 -2440 -1482 -570 -264 -608 -753 -552 -765 -199 -299 -482 -550 -920 -496 300 512 799 929 664 858 750 523 298 232 644 1060 1415 1896 763 -141 -563 -989 210 525 591 708 491 722 415 -31 -537 -1421 -1007 -1048 -1126 -1082 -1873 -1645 -1050 -558 -145 158 659 596 468 263 -97 -211 -130 -48 237 923 635 154 -147 -637 -881 -401 -666 -842 -719 -689 -217 318 590 572 484 302 -79 -163 -148 -165 88 214 -71 106 408 375 598 329 86 560 367 328 175 -102 -122 -146 -91 49 1 315 225 -77 -240 -566 -704 96 42 124 -762 -1061 -788 -78 352 563 114 -521 -428 -271 38 429 246 185 342 447 831 491 315 536 557 276 349 103 -148 -406 32 549 633 1004 -175 -1426 -1564 -1498 -968 -414 -210 -500 -642 -468 -655 -173 -260 -408 -460 -741 -399 241 425 691 816 599 780 677 472 271 209 591 980 1371 1896 773 -138 -509 -872 188 507 600 736 516 755 421 -30 -491 -1236 -875 -959 -1093 -1098 -1998 -1769 -1169 -653 -171 194 814 718 548 293 -102 -211 -134 -51 272 1106 787 190 -175 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