File name: Pandora282s1_Ilo-UNAM_20250731_L2Fit_fout2c3d20250118p1-8.txt File generation date: 20250829T104831.3Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 282 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora282_OF_v2d20240118.txt Instrument calibration file used: Pandora282s1_CF_v3d20250118.txt Level 1 file used: Pandora282s1_Ilo-UNAM_20250731_L1_smca1c3d20250118p1-8.txt Full location name: Grupo de Investigacion en Ciencias de la Atmosfera, UNAM, Peru Short location name: Ilo-UNAM Country of location: Peru Location latitude [deg]: -17.6020 Location longitude [deg]: -71.3389 Location altitude [m]: 85 Local noon date: 20250731 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 202 344 Nominal wavelengths inside fitting window [nm]: 305.0533 305.1939 305.3345 305.4751 305.6156 305.7562 305.8968 306.0373 306.1778 306.3184 306.4589 306.5994 306.7399 306.8803 307.0208 307.1613 307.3017 307.4421 307.5825 307.7230 307.8634 308.0037 308.1441 308.2845 308.4248 308.5652 308.7055 308.8458 308.9861 309.1264 309.2667 309.4070 309.5473 309.6875 309.8278 309.9680 310.1082 310.2484 310.3886 310.5288 310.6690 310.8091 310.9493 311.0894 311.2296 311.3697 311.5098 311.6499 311.7900 311.9300 312.0701 312.2102 312.3502 312.4902 312.6302 312.7702 312.9102 313.0502 313.1902 313.3301 313.4701 313.6100 313.7500 313.8899 314.0298 314.1697 314.3095 314.4494 314.5893 314.7291 314.8690 315.0088 315.1486 315.2884 315.4282 315.5680 315.7077 315.8475 315.9872 316.1269 316.2667 316.4064 316.5461 316.6858 316.8254 316.9651 317.1048 317.2444 317.3840 317.5236 317.6632 317.8028 317.9424 318.0820 318.2216 318.3611 318.5006 318.6402 318.7797 318.9192 319.0587 319.1982 319.3376 319.4771 319.6165 319.7560 319.8954 320.0348 320.1742 320.3136 320.4530 320.5923 320.7317 320.8710 321.0104 321.1497 321.2890 321.4283 321.5676 321.7068 321.8461 321.9854 322.1246 322.2638 322.4030 322.5422 322.6814 322.8206 322.9598 323.0990 323.2381 323.3772 323.5164 323.6555 323.7946 323.9337 324.0727 324.2118 324.3509 324.4899 324.6289 324.7679 324.9070 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250731T135630.1Z 9343.580904 142 1 31.46 2 55.96 52.58 111.85 113.09 0.00 1 0.00 1 0 17 1.265e-02 8.337e-03 6.137e-03 3.149e-03 2.092734e-01 1.566955e-03 2.197364e-03 -6.000000e+00 7.045857e-03 226.71 -2.00 3.04 -2.00 316.01 0.00e+00 8.248240e-04 1.715015e-04 7.655035e-05 -6.000000e+00 3.209157e-04 290.19 -2.00 20.00 -2.00 315.23 0.00e+00 1.781 0.000 302.00 328.00 3 5.7724e+00 4.0492e-03 1.9835e-02 -6.0000e+00 1.7436e-02 5.9597e-02 4.5295e-03 9.3153e-03 -6.0000e+00 1.8907e-02 -1.8082e-03 2.6176e-03 4.5369e-03 -6.0000e+00 1.1317e-02 -4.2927e-03 1.2396e-03 1.3543e-03 -6.0000e+00 4.9267e-03 2.2165e-04 3.9262e-04 8.3909e-05 1.3974e-05 -6.0000e+00 3.1588e-04 -8.4135e-04 0.0000e+00 11 8 0 10 0 0 99.51 24.95 0.38 -0.00084 0.00211 9 9 1 5 0 3494.920 33.25 19.99 24.95 27.85 3.8 1001.86 -3287 2017 -465 -2297 -5566 1149 2371 -377 1334 -8 -1975 -648 1322 -472 1658 -351 921 665 1333 2217 1508 707 -21 -1000 -232 838 1323 1156 -713 -1078 1127 -2 957 -421 -2524 -3980 -4647 -2679 -851 408 672 -2022 -914 -996 376 -256 -108 -786 -926 -9 2287 -68 538 655 824 760 980 1018 393 668 183 570 1509 2111 543 -33 -316 -1057 218 794 973 626 958 611 1939 -448 -602 -2914 -1691 -1188 -1292 -1574 -1303 -1827 -463 168 -87 113 110 1068 741 -479 -834 -840 -536 -441 -374 1176 802 756 -504 -173 -1576 -1045 -729 -49 -1166 -451 130 420 1274 818 120 113 -455 -883 -426 -556 315 374 216 792 572 514 670 -163 -662 542 228 144 16 -56 205 331 13 -115 68 251 97 116 -580 -325 -679 -685 433 -104 -489 -1164 211 452 -83 294 -2 -456 -147 327 -135 528 -125 333 247 509 866 606 281 -9 -428 -103 351 602 492 -283 -414 444 -1 437 -186 -1138 -1728 -2199 -1319 -495 254 457 -1467 -675 -743 274 -188 -77 -548 -626 -6 1540 -50 416 530 685 595 781 809 331 554 145 481 1368 2036 535 -30 -260 -898 190 730 989 625 959 595 1876 -398 -514 -2358 -1372 -1077 -1224 -1652 -1364 -1994 -532 194 -107 144 141 1319 851 -540 -849 -859 -567 -478 -448 1441 1064 999 -633 -212 -1819 -1220 -873 -63 -1555 -624 175 598 1904 1253 179 156 -612 -1101 -518 -702 423 511 308 1114 788 725 891 -208 -854 672 300 190 23 -80 296 461 19 -181 109 391 154 181 -932 -503 -1020 SS 20250731T140605.9Z 9343.587569 145 1 29.69 2 54.17 50.86 109.79 112.11 0.00 1 0.00 1 0 25 9.750e-03 7.167e-03 3.201e-03 1.943e-03 2.005987e-01 9.699645e-04 2.116892e-03 -6.000000e+00 5.429674e-03 226.71 -2.00 3.04 -2.00 315.46 0.00e+00 3.850126e-04 9.424750e-05 5.849447e-05 -6.000000e+00 2.473436e-04 290.19 -2.00 20.00 -2.00 314.73 0.00e+00 1.703 0.000 302.00 328.00 3 5.0075e+00 2.4916e-03 1.8978e-02 -6.0000e+00 1.3436e-02 4.6886e-02 2.7765e-03 8.9076e-03 -6.0000e+00 1.4571e-02 -2.0675e-03 1.5967e-03 4.3468e-03 -6.0000e+00 8.7218e-03 -3.6806e-03 7.3840e-04 1.2309e-03 -6.0000e+00 3.7960e-03 5.2560e-04 -5.8131e-05 5.1400e-05 1.4184e-05 -6.0000e+00 2.4346e-04 5.4190e-04 0.0000e+00 11 8 0 10 0 0 99.69 24.96 0.36 0.00054 0.00011 14 14 1 5 0 2120.390 33.25 20.00 24.96 28.30 3.8 1005.46 -841 1101 -1343 -1663 -2505 -2690 -996 236 74 -1021 -944 -2552 -1080 538 872 1143 24 1077 682 1340 1891 601 1077 685 328 680 12 1000 -1043 -743 1176 504 1913 -63 -2769 -2704 -2594 -1505 -360 -229 -217 -1186 -336 179 -262 -197 -469 -867 -905 -1057 1232 492 643 871 177 503 520 515 696 330 940 971 1519 2329 791 -324 -489 -1636 79 790 474 822 565 620 741 152 -835 -1794 -1079 -1545 -1159 -1281 -1780 -1611 -1016 -143 108 289 666 743 492 41 -67 -703 -174 -272 -186 980 380 272 -172 -867 -966 -888 -676 -765 -1021 -359 -14 345 739 727 480 174 -44 -254 -186 -104 219 680 -53 225 313 317 612 204 5 536 143 287 35 77 30 -49 -86 22 284 292 268 -363 -303 -655 -687 -220 307 -391 -452 -646 -652 -249 66 21 -311 -277 -754 -348 193 326 466 10 461 303 609 876 276 495 333 156 335 6 494 -480 -328 530 244 983 -32 -1425 -1317 -1365 -842 -224 -157 -162 -932 -253 135 -197 -148 -367 -656 -663 -762 904 390 503 713 150 431 454 450 592 279 805 840 1416 2302 758 -302 -438 -1407 69 742 468 850 589 627 744 138 -721 -1534 -927 -1406 -1116 -1291 -1933 -1720 -1149 -165 131 366 847 919 594 45 -70 -730 -176 -303 -217 1191 479 343 -214 -1047 -1085 -1012 -804 -972 -1352 -472 -19 474 1067 1072 685 243 -59 -311 -234 -129 291 929 -76 321 435 425 809 259 6 648 183 375 49 104 41 -68 -122 32 439 442 413 -555 -466 -979 -992 SS 20250731T141604.1Z 9343.594492 152 1 30.01 2 52.35 48.97 107.64 111.14 0.00 1 0.00 1 0 17 9.700e-03 7.103e-03 2.198e-03 1.417e-03 1.910518e-01 7.096065e-04 2.023606e-03 -6.000000e+00 5.402020e-03 226.71 -2.00 3.04 -2.00 315.20 0.00e+00 5.063291e-04 6.491391e-05 3.075601e-05 -6.000000e+00 2.460754e-04 290.19 -2.00 20.00 -2.00 314.48 0.00e+00 1.633 0.000 302.00 328.00 3 4.5029e+00 1.8159e-03 1.8175e-02 -6.0000e+00 1.3368e-02 4.0155e-02 2.0215e-03 8.5115e-03 -6.0000e+00 1.4497e-02 -2.4161e-03 1.1627e-03 4.1501e-03 -6.0000e+00 8.6772e-03 -2.5326e-03 5.3131e-04 1.1996e-03 -6.0000e+00 3.7768e-03 9.5150e-04 -3.1546e-05 3.7453e-05 1.3790e-05 -6.0000e+00 2.4221e-04 2.3246e-04 0.0000e+00 11 9 0 11 8 0 99.96 24.98 0.28 0.00023 -0.00000 50 50 1 5 0 599.980 33.25 20.00 24.98 28.70 3.8 1007.59 -37 1153 291 -1989 -3234 -2624 -1592 420 379 -178 -1952 -1556 -1145 205 524 1004 113 1639 497 1630 1315 371 609 1211 164 1027 544 177 -606 54 128 776 1497 -907 -2884 -3081 -2863 -1081 -611 -63 -697 -575 -279 -574 -305 -250 -124 -398 -698 -476 603 311 895 815 856 642 643 501 314 125 547 1394 1581 2047 914 33 -939 -1515 150 571 351 874 507 800 614 -34 -800 -2097 -1342 -1203 -1133 -1165 -1765 -1591 -1258 -307 20 202 641 796 434 112 -263 -168 -228 128 114 1012 540 295 -288 -597 -998 -502 -797 -893 -753 -647 -164 232 896 844 503 305 -317 -115 -319 -156 82 385 60 385 274 432 450 290 -72 361 162 273 236 -119 21 -83 -100 77 -141 314 251 16 -405 -564 -593 -11 372 96 -625 -888 -670 -422 123 124 -62 -661 -518 -387 77 222 430 50 728 231 771 638 178 292 608 88 562 299 91 -287 24 60 384 792 -511 -1520 -1540 -1543 -618 -392 -45 -541 -437 -218 -452 -238 -195 -99 -308 -523 -349 455 252 716 683 738 561 573 446 274 108 481 1230 1508 1972 897 31 -858 -1320 133 545 354 920 540 824 597 -32 -701 -1816 -1164 -1101 -1104 -1190 -1850 -1725 -1449 -361 24 249 795 961 509 125 -279 -175 -233 143 134 1245 689 376 -363 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