File name: Pandora282s1_Ilo-UNAM_20250801_L2Fit_fout2c3d20250118p1-8.txt File generation date: 20250829T105210.0Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 282 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora282_OF_v2d20240118.txt Instrument calibration file used: Pandora282s1_CF_v3d20250118.txt Level 1 file used: Pandora282s1_Ilo-UNAM_20250801_L1_smca1c3d20250118p1-8.txt Full location name: Grupo de Investigacion en Ciencias de la Atmosfera, UNAM, Peru Short location name: Ilo-UNAM Country of location: Peru Location latitude [deg]: -17.6020 Location longitude [deg]: -71.3389 Location altitude [m]: 85 Local noon date: 20250801 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 202 344 Nominal wavelengths inside fitting window [nm]: 305.0533 305.1939 305.3345 305.4751 305.6156 305.7562 305.8968 306.0373 306.1778 306.3184 306.4589 306.5994 306.7399 306.8803 307.0208 307.1613 307.3017 307.4421 307.5825 307.7230 307.8634 308.0037 308.1441 308.2845 308.4248 308.5652 308.7055 308.8458 308.9861 309.1264 309.2667 309.4070 309.5473 309.6875 309.8278 309.9680 310.1082 310.2484 310.3886 310.5288 310.6690 310.8091 310.9493 311.0894 311.2296 311.3697 311.5098 311.6499 311.7900 311.9300 312.0701 312.2102 312.3502 312.4902 312.6302 312.7702 312.9102 313.0502 313.1902 313.3301 313.4701 313.6100 313.7500 313.8899 314.0298 314.1697 314.3095 314.4494 314.5893 314.7291 314.8690 315.0088 315.1486 315.2884 315.4282 315.5680 315.7077 315.8475 315.9872 316.1269 316.2667 316.4064 316.5461 316.6858 316.8254 316.9651 317.1048 317.2444 317.3840 317.5236 317.6632 317.8028 317.9424 318.0820 318.2216 318.3611 318.5006 318.6402 318.7797 318.9192 319.0587 319.1982 319.3376 319.4771 319.6165 319.7560 319.8954 320.0348 320.1742 320.3136 320.4530 320.5923 320.7317 320.8710 321.0104 321.1497 321.2890 321.4283 321.5676 321.7068 321.8461 321.9854 322.1246 322.2638 322.4030 322.5422 322.6814 322.8206 322.9598 323.0990 323.2381 323.3772 323.5164 323.6555 323.7946 323.9337 324.0727 324.2118 324.3509 324.4899 324.6289 324.7679 324.9070 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250801T123629.6Z 9344.525342 83 1 3.96 2 72.08 63.84 132.54 136.87 0.00 1 0.00 1 0 17 5.097e-02 1.119e-02 4.899e-02 8.970e-03 3.756449e-01 4.444920e-03 3.851396e-03 -6.000000e+00 2.838679e-02 226.73 -2.00 3.04 -2.00 318.13 0.00e+00 2.581242e-03 8.294637e-04 1.491819e-04 -6.000000e+00 1.293152e-03 290.19 -2.00 20.00 -2.00 317.27 0.00e+00 3.206 0.000 302.00 328.00 3 3.6198e+00 1.1938e-02 3.5704e-02 -6.0000e+00 7.0248e-02 6.2331e-02 1.3609e-02 1.6915e-02 -6.0000e+00 7.6182e-02 -3.5350e-02 8.8883e-03 8.3441e-03 -6.0000e+00 4.5600e-02 1.0604e-02 4.6881e-03 3.2306e-03 -6.0000e+00 1.9844e-02 3.7512e-04 7.0424e-05 2.3843e-04 2.7643e-05 -6.0000e+00 1.2728e-03 1.1239e-03 0.0000e+00 12 9 9 12 1 1 999.00 24.86 0.53 0.00112 0.00165 1 15 1 5 0 1978.460 33.25 20.00 24.86 24.94 3.9 983.93 4075 -1197 5219 -9596 -11291 -27470 -14563 12969 10812 11352 -13878 -25707 -3365 8734 2932 1882 8628 10342 2656 4495 2783 -448 7245 -11153 874 -10064 -2212 4905 2864 295 3356 -2779 1687 -3774 -7199 -10466 -3133 -1778 -2841 -2027 2740 1585 -593 -369 -1311 3501 1949 -137 -1455 1856 5214 193 249 -1097 3401 -816 2116 1552 417 1868 1036 2080 250 3386 609 -306 -1367 -1411 -202 213 -219 489 -359 2006 61 923 -1120 -3833 -186 -3171 -1113 -1016 -720 -2905 -1217 777 161 1065 -549 102 206 -758 -1011 84 698 -285 -332 1470 1212 16 138 -548 -1747 -202 -66 -157 -1219 -609 476 478 15 141 1897 -126 45 -179 -1773 -8 534 -552 284 -29 1217 1255 78 -115 -203 261 -239 -33 482 -374 -283 -46 -231 202 1007 279 230 -941 253 276 -1397 207 -72 310 -630 -662 -1802 -892 681 653 725 -1129 -2451 -303 840 357 241 1105 1382 405 704 456 -74 1135 -2244 165 -2225 -457 897 503 54 654 -647 421 -1059 -1947 -2796 -847 -508 -998 -841 1110 685 -273 -173 -621 1602 902 -64 -691 866 2519 108 138 -655 2025 -519 1341 988 262 1138 653 1404 178 2563 459 -232 -978 -988 -148 168 -193 423 -314 1751 51 724 -809 -2709 -133 -2526 -995 -959 -736 -2994 -1316 840 185 1261 -666 120 224 -805 -1048 83 730 -319 -398 1852 1593 21 182 -662 -2057 -235 -79 -203 -1580 -827 677 702 23 225 2909 -195 64 -249 -2473 -12 771 -864 432 -46 1832 1825 114 -162 -284 359 -341 -49 767 -600 -464 -75 -400 355 1806 515 431 -1744 442 481 -2376 SS 20250801T124116.9Z 9344.528668 86 1 30.08 2 71.06 63.31 131.77 135.83 0.00 1 0.00 1 0 17 1.942e-02 6.446e-03 5.977e-03 1.315e-03 3.548495e-01 6.501290e-04 3.675415e-03 -6.000000e+00 1.081295e-02 226.73 -2.00 3.04 -2.00 317.89 0.00e+00 8.398073e-04 1.128037e-04 2.340887e-04 -6.000000e+00 4.926360e-04 290.19 -2.00 20.00 -2.00 317.02 0.00e+00 3.043 0.000 302.00 328.00 3 2.7378e+00 1.7356e-03 3.3860e-02 -6.0000e+00 2.6758e-02 2.2528e-02 1.9731e-03 1.5862e-02 -6.0000e+00 2.9020e-02 -1.7895e-02 1.2483e-03 7.7691e-03 -6.0000e+00 1.7370e-02 3.9972e-03 6.4939e-04 2.2494e-03 -6.0000e+00 7.5580e-03 1.1140e-03 -1.2776e-04 3.4943e-05 2.1903e-05 -6.0000e+00 4.8489e-04 1.8065e-03 0.0000e+00 11 9 0 11 8 0 99.98 24.87 0.33 0.00181 0.00085 129 129 1 5 0 233.120 33.25 20.00 24.87 25.37 3.9 987.04 -5379 -1898 -3329 -5654 -9920 -5996 -7232 -883 -4251 -1595 -9396 -2558 -4632 -2602 176 1821 396 1074 -12 1820 1893 13 490 -469 -33 116 481 -777 -2344 -632 -318 894 875 -486 -2482 -3020 -2634 -2305 -1051 -379 -338 -620 709 496 17 376 71 198 -775 -733 570 606 1029 975 962 1040 744 750 371 135 711 1482 1815 2063 1097 5 -398 -1076 145 824 425 1033 432 605 62 -299 -1046 -2429 -1189 -1101 -1370 -1332 -1746 -1655 -1159 -496 224 343 789 624 629 177 -52 -344 18 -260 -6 807 539 -23 -420 -763 -1103 -573 -688 -956 -958 -569 -87 309 690 562 506 268 -45 -231 -48 1 199 184 66 161 638 304 553 404 -253 633 488 232 372 -87 -223 -201 -100 -8 -32 383 310 -166 -285 -661 -513 -361 -138 -257 -425 -683 -379 -495 -65 -365 -143 -901 -237 -510 -334 24 273 64 182 -2 338 362 3 95 -99 -7 28 115 -177 -508 -134 -74 228 249 -137 -723 -846 -735 -751 -412 -163 -161 -290 341 243 8 186 35 96 -378 -362 297 345 624 589 607 671 496 500 242 87 466 1040 1314 1633 850 3 -289 -766 108 662 381 915 387 551 53 -245 -776 -1732 -874 -929 -1247 -1284 -1737 -1719 -1278 -557 265 400 925 713 701 191 -51 -347 18 -280 -7 1037 724 -31 -537 -937 -1309 -681 -854 -1211 -1267 -789 -122 445 1067 868 768 401 -65 -324 -66 2 291 278 102 246 942 455 783 575 -342 836 697 349 573 -140 -352 -329 -168 -15 -56 687 566 -299 -509 -1134 -881 SS 20250801T124956.9Z 9344.534686 92 1 29.96 2 69.22 62.32 130.35 134.01 0.00 1 0.00 1 0 17 1.320e-02 6.473e-03 1.359e-03 4.964e-04 3.257902e-01 2.461049e-04 3.396300e-03 -6.000000e+00 7.351582e-03 226.73 -2.00 3.04 -2.00 317.02 0.00e+00 5.446163e-04 3.377217e-05 1.364014e-04 -6.000000e+00 3.349263e-04 290.19 -2.00 20.00 -2.00 316.17 0.00e+00 2.791 0.000 302.00 328.00 3 1.1839e+00 6.4496e-04 3.1033e-02 -6.0000e+00 1.8193e-02 9.5841e-03 7.2567e-04 1.4486e-02 -6.0000e+00 1.9730e-02 -1.0714e-02 4.2995e-04 7.0695e-03 -6.0000e+00 1.1810e-02 1.3070e-03 2.1360e-04 2.0069e-03 -6.0000e+00 5.1387e-03 7.0222e-03 -1.2754e-04 1.3134e-05 2.0859e-05 -6.0000e+00 3.2966e-04 1.6197e-03 0.0000e+00 11 8 0 10 0 0 36.88 24.89 0.35 0.00162 0.00066 298 298 1 5 0 100.510 33.25 20.00 24.89 26.12 3.9 992.37 -2079 -909 -1078 -4191 -6082 -5366 -3666 -1566 -1352 -1524 -3617 -3521 -1580 38 1336 1201 922 940 882 1733 1074 196 1015 718 842 596 -53 -726 -1634 -783 251 959 1506 -504 -2923 -3551 -2708 -1522 -434 334 -210 -390 78 -206 345 373 -22 -288 -780 -273 454 766 942 1057 667 1127 685 500 249 117 564 1188 1656 2214 988 -256 -552 -929 134 526 722 728 386 611 285 -227 -710 -1680 -1230 -1208 -1182 -1113 -1882 -1753 -1157 -542 -111 119 629 737 406 215 -284 -267 -274 -72 132 901 588 92 -289 -755 -1088 -382 -725 -872 -772 -606 -137 394 631 553 461 324 -85 -164 -14 -69 148 305 -44 207 585 498 617 278 27 578 355 320 151 -72 -235 -133 -80 3 -12 346 230 -115 -275 -626 -673 -262 -126 -143 -594 -769 -642 -460 -219 -196 -237 -566 -565 -287 7 300 305 230 246 243 494 317 58 301 214 267 199 -18 -235 -495 -249 80 336 545 -197 -1088 -1271 -1047 -640 -208 179 -119 -222 46 -124 205 223 -13 -169 -455 -160 280 491 642 732 483 798 500 367 179 87 406 915 1342 1871 836 -212 -440 -723 108 453 666 682 364 576 262 -195 -573 -1344 -976 -1053 -1091 -1109 -1979 -1859 -1261 -614 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