File name: Pandora282s1_Ilo-UNAM_20250803_L2Fit_fout2c3d20250118p1-8.txt File generation date: 20250829T105228.7Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 282 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora282_OF_v2d20240118.txt Instrument calibration file used: Pandora282s1_CF_v3d20250118.txt Level 1 file used: Pandora282s1_Ilo-UNAM_20250803_L1_smca1c3d20250118p1-8.txt Full location name: Grupo de Investigacion en Ciencias de la Atmosfera, UNAM, Peru Short location name: Ilo-UNAM Country of location: Peru Location latitude [deg]: -17.6020 Location longitude [deg]: -71.3389 Location altitude [m]: 85 Local noon date: 20250803 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 202 344 Nominal wavelengths inside fitting window [nm]: 305.0533 305.1939 305.3345 305.4751 305.6156 305.7562 305.8968 306.0373 306.1778 306.3184 306.4589 306.5994 306.7399 306.8803 307.0208 307.1613 307.3017 307.4421 307.5825 307.7230 307.8634 308.0037 308.1441 308.2845 308.4248 308.5652 308.7055 308.8458 308.9861 309.1264 309.2667 309.4070 309.5473 309.6875 309.8278 309.9680 310.1082 310.2484 310.3886 310.5288 310.6690 310.8091 310.9493 311.0894 311.2296 311.3697 311.5098 311.6499 311.7900 311.9300 312.0701 312.2102 312.3502 312.4902 312.6302 312.7702 312.9102 313.0502 313.1902 313.3301 313.4701 313.6100 313.7500 313.8899 314.0298 314.1697 314.3095 314.4494 314.5893 314.7291 314.8690 315.0088 315.1486 315.2884 315.4282 315.5680 315.7077 315.8475 315.9872 316.1269 316.2667 316.4064 316.5461 316.6858 316.8254 316.9651 317.1048 317.2444 317.3840 317.5236 317.6632 317.8028 317.9424 318.0820 318.2216 318.3611 318.5006 318.6402 318.7797 318.9192 319.0587 319.1982 319.3376 319.4771 319.6165 319.7560 319.8954 320.0348 320.1742 320.3136 320.4530 320.5923 320.7317 320.8710 321.0104 321.1497 321.2890 321.4283 321.5676 321.7068 321.8461 321.9854 322.1246 322.2638 322.4030 322.5422 322.6814 322.8206 322.9598 323.0990 323.2381 323.3772 323.5164 323.6555 323.7946 323.9337 324.0727 324.2118 324.3509 324.4899 324.6289 324.7679 324.9070 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250803T151113.9Z 9346.632800 245 1 8.28 2 42.77 36.59 117.45 132.31 0.00 1 0.00 1 0 17 8.596e-03 6.904e-03 1.458e-03 1.132e-03 1.627478e-01 5.713708e-04 1.746319e-03 -6.000000e+00 4.788019e-03 226.76 -2.00 3.04 -2.00 314.24 0.00e+00 3.261281e-04 4.397563e-05 2.071505e-05 -6.000000e+00 2.180479e-04 290.18 -2.00 20.00 -2.00 313.64 0.00e+00 1.360 0.000 302.00 328.00 3 3.1481e+00 1.4501e-03 1.5232e-02 -6.0000e+00 1.1850e-02 3.5186e-02 1.6068e-03 7.2688e-03 -6.0000e+00 1.2850e-02 -6.6446e-04 9.2552e-04 3.5520e-03 -6.0000e+00 7.6912e-03 -4.2336e-03 4.1078e-04 1.0087e-03 -6.0000e+00 3.3474e-03 5.0956e-03 -1.1509e-04 2.9562e-05 1.2650e-05 -6.0000e+00 2.1464e-04 -7.0170e-05 0.0000e+00 12 9 1 12 9 1 98.96 25.08 0.41 -0.00007 -0.00093 21 80 1 5 0 376.180 33.25 20.00 25.08 28.54 3.8 1006.07 534 60 130 -1521 -2613 -2409 -388 1309 860 109 -1091 -1025 -638 234 997 616 328 452 426 1235 778 590 886 960 501 507 453 -140 -866 -118 1079 1081 1636 -166 -2597 -2678 -2389 -1821 -534 -77 -695 -786 -442 -741 -520 -160 -414 -356 -708 -418 272 513 449 1194 735 925 779 412 374 276 578 927 1508 1874 898 44 -577 -894 -7 430 687 671 419 436 492 70 -544 -1604 -1160 -1097 -1035 -1168 -1799 -1660 -1000 -555 -78 193 648 552 407 108 -173 -440 -68 56 204 1033 691 247 -65 -616 -990 -548 -782 -765 -727 -604 -261 407 620 604 523 252 -88 -211 -188 -181 260 297 -73 219 272 357 542 514 138 644 308 208 224 -141 -181 -356 -11 2 46 420 162 -147 -179 -548 -701 226 26 57 -666 -1048 -952 -148 552 386 49 -503 -461 -297 115 521 350 182 254 246 728 471 350 524 571 313 327 292 -85 -501 -67 626 633 1019 -104 -1600 -1558 -1495 -1204 -387 -60 -581 -659 -379 -642 -444 -136 -355 -292 -579 -333 222 431 382 1056 670 823 707 374 343 250 518 883 1452 1911 901 43 -524 -793 -7 415 712 708 447 453 496 68 -485 -1371 -1024 -1008 -1000 -1208 -1943 -1802 -1118 -650 -94 235 794 677 476 121 -185 -450 -69 61 229 1234 848 302 -79 -713 -1101 -618 -920 -936 -902 -780 -340 541 845 838 715 328 -110 -255 -222 -216 321 388 -98 293 356 461 675 626 163 752 369 259 285 -185 -231 -467 -15 3 65 603 232 -213 -253 -767 -976 SS 20250803T151610.5Z 9346.636233 248 1 29.99 2 42.08 35.17 116.60 131.58 0.00 1 0.00 1 0 17 8.320e-03 6.712e-03 5.170e-04 4.014e-04 1.612674e-01 2.031141e-04 1.725588e-03 -6.000000e+00 4.634694e-03 226.76 -2.00 3.04 -2.00 314.24 0.00e+00 3.433560e-04 1.564402e-05 1.438172e-05 -6.000000e+00 2.110607e-04 290.18 -2.00 20.00 -2.00 313.63 0.00e+00 1.346 0.000 302.00 328.00 3 2.4305e+00 5.1544e-04 1.5070e-02 -6.0000e+00 1.1470e-02 2.8851e-02 5.7092e-04 7.1970e-03 -6.0000e+00 1.2438e-02 -1.3257e-03 3.2904e-04 3.5155e-03 -6.0000e+00 7.4448e-03 -3.4934e-03 1.4599e-04 1.0043e-03 -6.0000e+00 3.2402e-03 1.0652e-02 -8.5479e-05 1.0494e-05 1.2543e-05 -6.0000e+00 2.0776e-04 -2.5045e-04 0.0000e+00 11 8 0 10 0 0 99.98 25.09 0.38 -0.00025 -0.00089 261 261 1 5 0 114.890 33.50 20.00 25.09 28.41 3.8 1005.53 43 44 192 -1671 -2651 -1819 -226 749 1269 285 -1245 -979 -408 64 780 567 80 615 821 1450 717 477 849 852 633 482 190 -188 -686 163 876 1078 1679 -174 -2367 -2710 -2460 -1315 -529 -274 -669 -690 -532 -811 -239 -236 -536 -566 -861 -461 340 625 740 937 818 883 763 545 326 184 618 1016 1391 1904 765 -170 -616 -975 168 554 547 611 460 689 409 2 -458 -1335 -1000 -996 -1093 -1053 -1890 -1663 -1079 -578 -109 139 726 604 496 221 -130 -280 -172 -88 239 912 592 245 -122 -631 -960 -375 -652 -809 -713 -655 -245 334 598 551 507 279 -88 -146 -152 -167 47 273 12 140 401 387 583 329 -30 475 372 307 223 -17 -114 -182 -47 54 -28 274 211 -75 -266 -567 -698 18 20 88 -720 -1047 -703 -90 312 557 132 -564 -433 -196 32 420 316 45 353 463 835 425 277 493 518 386 305 120 -116 -405 91 499 645 1022 -107 -1422 -1613 -1507 -881 -390 -219 -566 -584 -461 -710 -206 -203 -449 -470 -690 -371 281 530 634 838 727 792 698 499 292 163 559 945 1349 1897 773 -162 -564 -874 153 538 554 630 479 718 415 2 -412 -1150 -861 -923 -1064 -1094 -1996 -1814 -1212 -679 -131 170 891 724 581 248 -135 -288 -176 -95 268 1095 729 301 -146 -733 -1073 -424 -770 -994 -887 -829 -320 445 817 765 695 364 -110 -172 -180 -199 59 359 17 188 526 501 731 404 -36 560 449 384 286 -22 -146 -240 -63 76 -39 395 303 -109 -375 -797 -952 SS 20250803T152013.4Z 9346.639044 251 1 3.79 2 41.53 33.97 115.90 131.00 0.00 1 0.00 1 0 17 8.802e-03 7.124e-03 1.205e-03 9.466e-04 1.600424e-01 4.782619e-04 1.713309e-03 -6.000000e+00 4.902759e-03 226.76 -2.00 3.04 -2.00 314.17 0.00e+00 3.330331e-04 3.637459e-05 2.083506e-05 -6.000000e+00 2.232828e-04 290.18 -2.00 20.00 -2.00 313.57 0.00e+00 1.334 0.000 302.00 328.00 3 2.0714e+00 1.2128e-03 1.4942e-02 -6.0000e+00 1.2134e-02 2.6528e-02 1.3429e-03 7.1356e-03 -6.0000e+00 1.3158e-02 -9.5106e-04 7.7452e-04 3.4848e-03 -6.0000e+00 7.8756e-03 -3.6826e-03 3.4356e-04 9.8956e-04 -6.0000e+00 3.4274e-03 1.5475e-02 -1.3410e-04 2.4727e-05 1.2552e-05 -6.0000e+00 2.1979e-04 3.0057e-04 0.0000e+00 12 9 1 12 1 1 56.55 25.10 0.44 0.00030 -0.00071 28 230 1 5 0 130.370 33.50 20.01 25.10 28.40 3.8 1005.37 336 16 -43 -1604 -2701 -1693 -528 921 1454 327 -1140 -1168 -466 -29 995 596 240 869 1108 1191 943 480 825 760 476 468 240 144 -1215 -86 1055 848 1618 -180 -2365 -3134 -2810 -1500 -669 -162 -468 -702 -636 -815 -170 -325 -452 -606 -999 -505 271 798 803 936 493 836 911 385 403 310 683 1057 1518 2078 910 -130 -544 -970 130 698 605 646 624 721 432 -40 -583 -1440 -1093 -1020 -1045 -1171 -1857 -1626 -1088 -541 -52 110 717 760 404 276 -304 -408 -171 -163 140 898 676 144 -131 -565 -1015 -398 -735 -856 -696 -782 -253 341 588 524 517 335 -15 -196 -157 -207 144 197 80 180 462 376 669 239 178 628 271 384 278 -132 -198 -17 -95 80 -2 281 188 -11 -332 -644 -724 146 7 -19 -718 -1100 -668 -215 395 662 151 -536 -537 -222 -15 539 338 139 506 637 703 570 285 490 473 300 304 157 91 -732 -49 608 516 1005 -114 -1450 -1899 -1763 -998 -496 -128 -392 -593 -551 -711 -146 -279 -389 -499 -818 -401 221 670 686 835 441 752 834 354 362 276 618 990 1488 2100 910 -125 -498 -866 118 682 622 680 663 744 433 -39 -524 -1266 -960 -942 -1024 -1201 -2000 -1764 -1223 -625 -62 133 873 921 466 310 -322 -413 -177 -176 157 1058 842 180 -158 -656 -1129 -448 -872 -1038 -877 -1007 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