File name: Pandora282s1_Ilo-UNAM_20250807_L2Fit_fout2c3d20250118p1-8.txt File generation date: 20250829T105104.9Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 282 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora282_OF_v2d20240118.txt Instrument calibration file used: Pandora282s1_CF_v3d20250118.txt Level 1 file used: Pandora282s1_Ilo-UNAM_20250807_L1_smca1c3d20250118p1-8.txt Full location name: Grupo de Investigacion en Ciencias de la Atmosfera, UNAM, Peru Short location name: Ilo-UNAM Country of location: Peru Location latitude [deg]: -17.6020 Location longitude [deg]: -71.3389 Location altitude [m]: 85 Local noon date: 20250807 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 202 344 Nominal wavelengths inside fitting window [nm]: 305.0533 305.1939 305.3345 305.4751 305.6156 305.7562 305.8968 306.0373 306.1778 306.3184 306.4589 306.5994 306.7399 306.8803 307.0208 307.1613 307.3017 307.4421 307.5825 307.7230 307.8634 308.0037 308.1441 308.2845 308.4248 308.5652 308.7055 308.8458 308.9861 309.1264 309.2667 309.4070 309.5473 309.6875 309.8278 309.9680 310.1082 310.2484 310.3886 310.5288 310.6690 310.8091 310.9493 311.0894 311.2296 311.3697 311.5098 311.6499 311.7900 311.9300 312.0701 312.2102 312.3502 312.4902 312.6302 312.7702 312.9102 313.0502 313.1902 313.3301 313.4701 313.6100 313.7500 313.8899 314.0298 314.1697 314.3095 314.4494 314.5893 314.7291 314.8690 315.0088 315.1486 315.2884 315.4282 315.5680 315.7077 315.8475 315.9872 316.1269 316.2667 316.4064 316.5461 316.6858 316.8254 316.9651 317.1048 317.2444 317.3840 317.5236 317.6632 317.8028 317.9424 318.0820 318.2216 318.3611 318.5006 318.6402 318.7797 318.9192 319.0587 319.1982 319.3376 319.4771 319.6165 319.7560 319.8954 320.0348 320.1742 320.3136 320.4530 320.5923 320.7317 320.8710 321.0104 321.1497 321.2890 321.4283 321.5676 321.7068 321.8461 321.9854 322.1246 322.2638 322.4030 322.5422 322.6814 322.8206 322.9598 323.0990 323.2381 323.3772 323.5164 323.6555 323.7946 323.9337 324.0727 324.2118 324.3509 324.4899 324.6289 324.7679 324.9070 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250807T143827.2Z 9350.610037 361 1 29.98 2 47.04 45.88 135.99 195.78 0.00 1 0.00 1 0 17 8.533e-03 6.756e-03 2.713e-04 2.018e-04 1.766329e-01 1.015052e-04 1.884700e-03 -6.000000e+00 4.754066e-03 226.83 -2.00 3.04 -2.00 314.53 0.00e+00 3.618733e-04 8.236749e-06 2.019667e-05 -6.000000e+00 2.164495e-04 290.16 -2.00 20.00 -2.00 313.89 0.00e+00 1.465 0.000 302.00 328.00 3 9.2177e-01 2.5826e-04 1.6426e-02 -6.0000e+00 1.1768e-02 1.3989e-02 2.8648e-04 7.8732e-03 -6.0000e+00 1.2760e-02 -8.7627e-04 1.6476e-04 3.8458e-03 -6.0000e+00 7.6372e-03 -3.5350e-03 7.3670e-05 1.0952e-03 -6.0000e+00 3.3230e-03 4.1772e-02 -8.9290e-05 5.2917e-06 1.3452e-05 -6.0000e+00 2.1308e-04 4.7668e-04 0.0000e+00 11 8 0 10 0 0 99.94 25.05 0.38 0.00048 -0.00019 1024 1024 1 5 0 29.270 33.50 20.00 25.05 28.83 3.9 1009.02 268 62 210 -1768 -2701 -2201 -343 689 1248 197 -1314 -1126 -428 173 929 540 308 675 799 1437 877 512 934 854 527 650 166 -155 -772 36 807 929 1611 -235 -2373 -2830 -2404 -1439 -511 -228 -618 -702 -543 -690 -213 -265 -488 -574 -870 -471 278 556 827 996 696 895 754 493 314 203 674 1060 1439 1961 790 -164 -542 -988 163 576 567 695 471 670 386 0 -490 -1465 -993 -1068 -1145 -1098 -1892 -1684 -1055 -591 -174 164 667 582 462 228 -157 -245 -153 -43 246 943 647 156 -140 -634 -910 -409 -655 -838 -708 -682 -217 337 610 586 499 290 -94 -128 -136 -143 85 218 -83 132 414 399 609 321 90 528 368 293 179 -98 -159 -134 -64 30 8 307 236 -75 -203 -597 -739 104 26 85 -711 -997 -800 -121 270 517 82 -564 -474 -187 81 460 280 163 362 441 778 489 280 511 492 306 390 100 -91 -434 19 442 516 953 -141 -1390 -1644 -1440 -911 -358 -175 -502 -573 -455 -583 -178 -221 -397 -463 -678 -370 217 464 699 853 614 798 666 436 280 180 607 984 1398 1964 782 -158 -485 -867 147 553 571 714 489 694 388 0 -434 -1283 -871 -984 -1116 -1116 -2020 -1811 -1172 -689 -209 199 816 712 538 254 -166 -249 -160 -47 278 1140 807 195 -169 -742 -1019 -464 -779 -1040 -892 -878 -282 449 837 820 688 380 -117 -155 -165 -175 109 289 -112 179 558 519 782 404 109 635 455 369 231 -130 -213 -180 -88 43 12 446 350 -110 -294 -860 -1031 SS 20250807T144841.4Z 9350.617146 364 1 30.05 2 45.32 43.44 136.58 192.72 0.00 1 0.00 1 0 17 8.492e-03 6.719e-03 6.358e-04 4.739e-04 1.716364e-01 2.382822e-04 1.829947e-03 -6.000000e+00 4.731308e-03 226.83 -2.00 3.04 -2.00 314.50 0.00e+00 3.442820e-04 1.920355e-05 2.119279e-05 -6.000000e+00 2.154049e-04 290.16 -2.00 20.00 -2.00 313.86 0.00e+00 1.420 0.000 302.00 328.00 3 2.6582e+00 6.0606e-04 1.5931e-02 -6.0000e+00 1.1711e-02 2.6802e-02 6.7236e-04 7.6421e-03 -6.0000e+00 1.2699e-02 -6.7084e-04 3.8685e-04 3.7324e-03 -6.0000e+00 7.6005e-03 -3.5471e-03 1.7301e-04 1.0619e-03 -6.0000e+00 3.3073e-03 7.7234e-03 -9.2638e-05 1.2406e-05 1.2997e-05 -6.0000e+00 2.1205e-04 1.2923e-04 0.0000e+00 11 8 0 10 0 0 99.97 25.10 0.43 0.00013 -0.00057 250 250 1 5 0 120.190 33.25 20.01 25.10 30.01 3.8 1015.92 155 85 24 -1639 -2825 -2127 -362 661 1389 140 -1470 -1171 -544 162 955 508 390 566 794 1254 702 383 1067 916 577 624 147 -161 -738 64 801 1116 1771 -394 -2188 -2706 -2331 -1542 -516 -139 -764 -624 -568 -615 -173 -256 -490 -529 -951 -422 374 506 758 993 695 944 814 489 230 176 554 1047 1411 1897 763 -198 -571 -1031 188 523 624 667 489 622 364 -72 -504 -1390 -1042 -1094 -1074 -1125 -1867 -1672 -1121 -612 -148 191 697 571 459 257 -110 -268 -156 8 230 949 655 122 -139 -628 -891 -387 -677 -838 -774 -614 -228 306 610 565 506 283 -77 -154 -83 -156 186 228 -67 170 455 376 579 372 88 507 363 307 118 -99 -142 -146 -85 -7 16 299 230 -88 -266 -560 -700 59 35 10 -649 -1034 -770 -126 256 563 60 -619 -482 -244 77 476 263 206 303 437 706 406 218 604 519 344 385 91 -93 -411 35 432 634 1021 -241 -1309 -1538 -1357 -982 -359 -109 -629 -512 -478 -521 -145 -214 -399 -430 -747 -335 293 424 639 874 608 832 732 441 203 153 492 989 1386 1908 779 -192 -518 -921 172 504 644 698 517 639 365 -68 -453 -1202 -903 -1019 -1044 -1166 -2017 -1808 -1247 -710 -176 235 865 690 531 287 -118 -277 -160 9 266 1133 821 153 -170 -728 -995 -438 -818 -1022 -981 -789 -302 414 845 796 688 377 -96 -187 -99 -193 231 300 -90 226 609 499 745 457 105 602 441 386 152 -131 -189 -193 -115 -10 23 430 338 -128 -384 -786 -979 SS 20250807T145724.3Z 9350.623198 367 1 30.48 2 43.92 41.23 136.99 190.04 0.00 1 0.00 1 0 17 8.843e-03 7.040e-03 1.834e-03 1.343e-03 1.681497e-01 6.757855e-04 1.794213e-03 -6.000000e+00 4.926851e-03 226.83 -2.00 3.04 -2.00 314.58 0.00e+00 4.027802e-04 5.537476e-05 2.285791e-05 -6.000000e+00 2.243066e-04 290.16 -2.00 20.00 -2.00 313.94 0.00e+00 1.386 0.000 302.00 328.00 3 4.7329e+00 1.7206e-03 1.5570e-02 -6.0000e+00 1.2195e-02 4.3977e-02 1.9099e-03 7.4979e-03 -6.0000e+00 1.3224e-02 -3.2645e-05 1.0981e-03 3.6607e-03 -6.0000e+00 7.9146e-03 -4.3541e-03 4.9176e-04 1.0483e-03 -6.0000e+00 3.4440e-03 1.0026e-03 -6.8579e-05 3.5240e-05 1.2727e-05 -6.0000e+00 2.2081e-04 9.6237e-05 0.0000e+00 11 8 0 10 0 0 99.42 25.16 0.35 0.00010 -0.00042 19 19 1 5 0 1604.070 33.50 20.00 25.16 30.31 3.7 1017.57 -129 1034 249 -1152 -2793 -2508 -990 847 380 -59 -914 -719 -403 94 878 460 129 560 792 1218 1238 168 591 766 353 703 146 116 -400 275 1081 870 1703 -272 -2739 -2931 -2650 -1688 -831 -181 -486 -805 -504 -473 -453 -447 -638 -547 -906 -309 908 476 837 679 483 937 683 576 309 241 792 1147 1648 1906 962 -50 -615 -1081 30 666 409 645 520 738 339 -54 -300 -1651 -1276 -917 -1281 -1141 -1710 -1871 -1114 -353 -204 311 788 607 638 -79 -177 -278 -213 -109 42 920 720 303 -182 -704 -1122 -500 -422 -905 -791 -678 -275 196 845 686 457 321 -132 -343 -292 -152 371 388 -207 178 607 296 508 435 -196 402 261 96 166 70 -52 -35 54 115 72 237 58 -121 -218 -503 -705 -48 411 101 -439 -1002 -837 -341 320 150 -25 -368 -283 -173 42 438 234 67 294 428 674 700 94 330 447 204 418 87 69 -216 141 567 482 1003 -159 -1600 -1620 -1576 -1080 -598 -137 -401 -657 -421 -397 -377 -371 -543 -446 -712 -248 709 398 696 591 433 843 628 528 278 215 717 1053 1626 1909 975 -48 -567 -945 27 642 418 662 539 774 337 -51 -262 -1409 -1090 -828 -1242 -1164 -1797 -2038 -1284 -419 -247 388 989 744 753 -89 -186 -285 -224 -120 49 1119 908 381 -225 -806 -1251 -564 -501 -1110 -1007 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