File name: Pandora282s1_Ilo-UNAM_20250817_L2Fit_fout2c3d20250118p1-8.txt File generation date: 20250829T105639.8Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 282 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora282_OF_v2d20240118.txt Instrument calibration file used: Pandora282s1_CF_v3d20250118.txt Level 1 file used: Pandora282s1_Ilo-UNAM_20250817_L1_smca1c3d20250118p1-8.txt Full location name: Grupo de Investigacion en Ciencias de la Atmosfera, UNAM, Peru Short location name: Ilo-UNAM Country of location: Peru Location latitude [deg]: -17.6020 Location longitude [deg]: -71.3389 Location altitude [m]: 85 Local noon date: 20250817 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 202 344 Nominal wavelengths inside fitting window [nm]: 305.0533 305.1939 305.3345 305.4751 305.6156 305.7562 305.8968 306.0373 306.1778 306.3184 306.4589 306.5994 306.7399 306.8803 307.0208 307.1613 307.3017 307.4421 307.5825 307.7230 307.8634 308.0037 308.1441 308.2845 308.4248 308.5652 308.7055 308.8458 308.9861 309.1264 309.2667 309.4070 309.5473 309.6875 309.8278 309.9680 310.1082 310.2484 310.3886 310.5288 310.6690 310.8091 310.9493 311.0894 311.2296 311.3697 311.5098 311.6499 311.7900 311.9300 312.0701 312.2102 312.3502 312.4902 312.6302 312.7702 312.9102 313.0502 313.1902 313.3301 313.4701 313.6100 313.7500 313.8899 314.0298 314.1697 314.3095 314.4494 314.5893 314.7291 314.8690 315.0088 315.1486 315.2884 315.4282 315.5680 315.7077 315.8475 315.9872 316.1269 316.2667 316.4064 316.5461 316.6858 316.8254 316.9651 317.1048 317.2444 317.3840 317.5236 317.6632 317.8028 317.9424 318.0820 318.2216 318.3611 318.5006 318.6402 318.7797 318.9192 319.0587 319.1982 319.3376 319.4771 319.6165 319.7560 319.8954 320.0348 320.1742 320.3136 320.4530 320.5923 320.7317 320.8710 321.0104 321.1497 321.2890 321.4283 321.5676 321.7068 321.8461 321.9854 322.1246 322.2638 322.4030 322.5422 322.6814 322.8206 322.9598 323.0990 323.2381 323.3772 323.5164 323.6555 323.7946 323.9337 324.0727 324.2118 324.3509 324.4899 324.6289 324.7679 324.9070 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250817T133334.2Z 9360.564980 297 1 29.66 2 57.31 60.75 53.27 328.61 0.00 1 0.00 1 0 17 9.366e-03 6.709e-03 1.756e-03 1.058e-03 2.241361e-01 5.292221e-04 2.367849e-03 -6.000000e+00 5.221240e-03 227.02 -2.00 3.04 -2.00 315.53 0.00e+00 3.795337e-04 5.186785e-05 4.998056e-05 -6.000000e+00 2.375730e-04 290.15 -2.00 20.00 -2.00 314.79 0.00e+00 1.845 0.000 302.00 328.00 3 3.7150e+00 1.3598e-03 2.0723e-02 -6.0000e+00 1.2930e-02 2.9248e-02 1.5163e-03 9.9724e-03 -6.0000e+00 1.4019e-02 1.1769e-03 8.7263e-04 4.8705e-03 -6.0000e+00 8.3893e-03 -4.4344e-03 4.0281e-04 1.3788e-03 -6.0000e+00 3.6481e-03 1.6046e-03 -3.3047e-05 2.7994e-05 1.5906e-05 -6.0000e+00 2.3389e-04 1.5339e-03 0.0000e+00 11 8 0 10 0 0 98.85 24.95 0.41 0.00153 0.00129 39 39 1 5 0 760.490 33.25 20.00 24.95 27.85 3.9 1003.15 -495 786 -52 -1163 -3268 -3664 -1096 -29 1327 118 -1563 -1732 -969 -6 1357 615 44 427 824 1322 732 427 933 1102 545 364 31 104 -1019 191 1015 1101 1545 -458 -2176 -3328 -2347 -1498 -340 -298 -437 -582 -170 -541 55 -151 -462 -632 -957 -67 631 667 803 748 725 723 565 606 162 337 525 1158 1545 2016 614 98 -870 -1154 30 598 618 757 438 754 491 -222 -555 -1554 -923 -1088 -1016 -1320 -1914 -1546 -1126 -452 -33 162 604 664 539 90 -380 -303 -155 -102 274 970 573 193 -112 -839 -1019 -463 -646 -780 -819 -659 -308 364 749 663 580 259 -57 -330 -51 -228 207 186 -25 262 403 420 618 324 -37 548 466 259 170 -128 -107 -87 -126 -55 24 413 309 -170 -315 -631 -676 -129 221 -15 -318 -789 -906 -279 -8 386 37 -478 -529 -305 -2 506 254 19 176 350 578 330 189 416 518 256 178 15 51 -461 82 457 531 758 -239 -1063 -1660 -1183 -821 -211 -207 -317 -440 -126 -406 40 -112 -353 -468 -691 -47 463 502 636 597 597 604 483 517 136 279 442 996 1439 1925 600 92 -780 -991 26 553 609 782 457 760 485 -207 -482 -1321 -793 -966 -975 -1354 -2041 -1705 -1272 -529 -39 201 751 803 626 99 -408 -305 -163 -113 323 1178 731 246 -139 -996 -1165 -535 -792 -988 -1046 -878 -413 499 1085 955 833 359 -75 -412 -65 -290 271 256 -36 372 558 578 829 417 -46 665 601 348 234 -176 -148 -124 -184 -84 37 634 484 -262 -484 -940 -1002 SS 20250817T133831.2Z 9360.568416 300 1 6.55 2 56.28 59.99 53.88 327.52 0.00 1 0.00 1 0 17 8.939e-03 6.577e-03 9.298e-04 6.101e-04 2.183488e-01 3.057047e-04 2.312976e-03 -6.000000e+00 4.983171e-03 227.02 -2.00 3.04 -2.00 315.21 0.00e+00 3.349188e-04 2.813550e-05 3.395403e-05 -6.000000e+00 2.267444e-04 290.15 -2.00 20.00 -2.00 314.50 0.00e+00 1.796 0.000 302.00 328.00 3 1.2144e+00 7.8259e-04 2.0172e-02 -6.0000e+00 1.2340e-02 9.5206e-03 8.7149e-04 9.7083e-03 -6.0000e+00 1.3380e-02 -1.0928e-03 5.0069e-04 4.7436e-03 -6.0000e+00 8.0068e-03 -2.9288e-03 2.2809e-04 1.3427e-03 -6.0000e+00 3.4817e-03 2.0934e-02 -8.3163e-05 1.6080e-05 1.5715e-05 -6.0000e+00 2.2323e-04 1.6409e-03 0.0000e+00 12 9 1 12 1 1 23.99 24.97 0.39 0.00164 0.00102 94 435 1 5 0 68.920 33.25 20.00 24.97 28.28 3.8 1005.67 406 113 -109 -2292 -3071 -2543 -642 562 771 -304 -1609 -1214 -362 161 999 619 528 803 1157 1474 886 448 969 1162 443 629 215 -273 -997 -7 924 989 1677 -335 -2577 -2856 -2491 -1450 -538 -252 -574 -456 -454 -504 -228 -109 -379 -534 -937 -563 424 595 789 925 633 821 719 461 422 96 686 1124 1340 1943 872 -138 -531 -1037 130 558 619 775 454 630 393 -39 -476 -1538 -997 -1052 -1038 -1047 -1822 -1739 -1028 -545 -123 127 649 566 427 236 -81 -220 -181 -22 235 923 683 118 -222 -621 -929 -390 -567 -832 -698 -678 -197 301 659 595 524 222 -167 -171 -64 -248 100 227 -23 126 477 355 588 264 75 586 284 393 228 -114 -114 -159 -137 5 49 337 239 -45 -315 -498 -764 124 36 -35 -749 -930 -721 -189 173 251 -106 -549 -411 -128 61 429 280 234 365 544 714 423 220 478 579 225 331 114 -142 -500 -3 459 503 880 -187 -1354 -1491 -1346 -864 -342 -176 -427 -341 -350 -392 -175 -84 -287 -404 -690 -421 318 464 627 772 530 697 625 401 359 80 588 997 1219 1835 841 -126 -469 -902 113 523 610 781 462 637 384 -37 -421 -1311 -858 -961 -1011 -1070 -1965 -1898 -1161 -631 -147 154 791 687 493 260 -85 -228 -190 -24 271 1123 861 149 -276 -730 -1064 -452 -690 -1035 -885 -880 -266 411 931 860 735 303 -217 -214 -80 -317 130 307 -31 176 651 478 779 342 94 725 357 520 312 -157 -160 -223 -199 7 74 517 367 -70 -480 -748 -1114 SS 20250817T134243.3Z 9360.571334 303 1 29.98 2 55.42 59.33 54.42 326.62 0.00 1 0.00 1 0 17 9.132e-03 6.654e-03 2.684e-04 1.779e-04 2.133517e-01 8.914220e-05 2.263077e-03 -6.000000e+00 5.090835e-03 227.02 -2.00 3.04 -2.00 315.16 0.00e+00 3.815355e-04 8.139123e-06 3.283507e-05 -6.000000e+00 2.316561e-04 290.15 -2.00 20.00 -2.00 314.45 0.00e+00 1.756 0.000 302.00 328.00 3 3.2923e-01 2.2801e-04 1.9730e-02 -6.0000e+00 1.2607e-02 1.2228e-03 2.5376e-04 9.4970e-03 -6.0000e+00 1.3669e-02 -6.5002e-04 1.4582e-04 4.6390e-03 -6.0000e+00 8.1799e-03 -3.0824e-03 6.6389e-05 1.3166e-03 -6.0000e+00 3.5568e-03 5.3350e-02 -1.1656e-04 4.6804e-06 1.5374e-05 -6.0000e+00 2.2806e-04 1.9772e-03 0.0000e+00 11 8 0 10 0 0 23.67 25.00 0.37 0.00198 0.00110 1277 1277 1 5 0 23.470 33.25 20.01 25.00 28.73 3.9 1009.82 180 30 69 -2058 -3246 -2821 -1014 423 1033 0 -1617 -1466 -671 155 952 668 538 808 966 1626 999 548 1093 1140 663 622 150 -35 -798 6 937 1056 1576 -345 -2549 -2782 -2606 -1491 -481 -101 -591 -696 -394 -691 -192 -211 -472 -552 -936 -524 297 545 785 998 739 913 723 462 276 203 661 1082 1482 1989 815 -141 -572 -963 192 576 605 668 441 621 357 -110 -618 -1436 -973 -1009 -1121 -1124 -1878 -1680 -1110 -560 -146 153 674 638 477 231 -173 -263 -169 -45 228 932 615 134 -209 -676 -949 -418 -639 -799 -695 -613 -167 339 612 581 481 292 -87 -151 -134 -131 127 231 -71 130 447 410 632 335 71 535 360 307 157 -91 -133 -167 -53 21 12 332 234 -104 -248 -604 -704 56 10 23 -680 -998 -812 -302 132 340 0 -557 -501 -253 62 411 303 251 369 456 788 499 269 539 568 350 327 80 -18 -398 3 464 535 859 -192 -1389 -1442 -1401 -883 -315 -72 -436 -534 -301 -534 -146 -162 -365 -414 -705 -388 221 434 635 822 629 764 620 397 232 174 560 949 1366 1903 796 -131 -512 -824 169 546 602 679 453 634 353 -103 -538 -1203 -824 -906 -1073 -1159 -1991 -1844 -1232 -652 -176 186 825 779 554 257 -182 -268 -179 -50 264 1135 778 169 -261 -798 -1093 -487 -782 -998 -884 -797 -226 463 866 824 674 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