File name: Pandora282s1_Ilo-UNAM_20250819_L2Fit_fout2c3d20250118p1-8.txt File generation date: 20250829T105743.4Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 282 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora282_OF_v2d20240118.txt Instrument calibration file used: Pandora282s1_CF_v3d20250118.txt Level 1 file used: Pandora282s1_Ilo-UNAM_20250819_L1_smca1c3d20250118p1-8.txt Full location name: Grupo de Investigacion en Ciencias de la Atmosfera, UNAM, Peru Short location name: Ilo-UNAM Country of location: Peru Location latitude [deg]: -17.6020 Location longitude [deg]: -71.3389 Location altitude [m]: 85 Local noon date: 20250819 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 202 344 Nominal wavelengths inside fitting window [nm]: 305.0533 305.1939 305.3345 305.4751 305.6156 305.7562 305.8968 306.0373 306.1778 306.3184 306.4589 306.5994 306.7399 306.8803 307.0208 307.1613 307.3017 307.4421 307.5825 307.7230 307.8634 308.0037 308.1441 308.2845 308.4248 308.5652 308.7055 308.8458 308.9861 309.1264 309.2667 309.4070 309.5473 309.6875 309.8278 309.9680 310.1082 310.2484 310.3886 310.5288 310.6690 310.8091 310.9493 311.0894 311.2296 311.3697 311.5098 311.6499 311.7900 311.9300 312.0701 312.2102 312.3502 312.4902 312.6302 312.7702 312.9102 313.0502 313.1902 313.3301 313.4701 313.6100 313.7500 313.8899 314.0298 314.1697 314.3095 314.4494 314.5893 314.7291 314.8690 315.0088 315.1486 315.2884 315.4282 315.5680 315.7077 315.8475 315.9872 316.1269 316.2667 316.4064 316.5461 316.6858 316.8254 316.9651 317.1048 317.2444 317.3840 317.5236 317.6632 317.8028 317.9424 318.0820 318.2216 318.3611 318.5006 318.6402 318.7797 318.9192 319.0587 319.1982 319.3376 319.4771 319.6165 319.7560 319.8954 320.0348 320.1742 320.3136 320.4530 320.5923 320.7317 320.8710 321.0104 321.1497 321.2890 321.4283 321.5676 321.7068 321.8461 321.9854 322.1246 322.2638 322.4030 322.5422 322.6814 322.8206 322.9598 323.0990 323.2381 323.3772 323.5164 323.6555 323.7946 323.9337 324.0727 324.2118 324.3509 324.4899 324.6289 324.7679 324.9070 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250819T114619.8Z 9362.490507 149 1 30.14 2 80.53 73.45 53.60 30.87 0.00 1 0.00 1 0 25 3.153e-01 8.531e-03 8.702e-02 2.435e-03 6.238741e-01 1.246215e-03 6.293001e-03 -6.000000e+00 1.757724e-01 227.09 -2.00 3.04 -2.00 320.42 0.00e+00 6.389837e-05 4.913765e-04 1.635356e-03 -6.000000e+00 8.000241e-03 290.17 -2.00 20.00 -2.00 319.70 0.00e+00 5.785 0.000 302.00 328.00 3 1.0037e+00 3.8851e-03 6.3824e-02 -6.0000e+00 4.3533e-01 4.9530e-02 5.0205e-03 3.0232e-02 -6.0000e+00 4.7206e-01 -7.6128e-02 4.6751e-03 1.4601e-02 -6.0000e+00 2.8247e-01 2.4121e-02 2.3543e-03 4.1187e-03 -6.0000e+00 1.2275e-01 3.5945e-04 -3.2302e-04 6.2063e-05 4.3269e-05 -6.0000e+00 7.8765e-03 4.5993e-03 0.0000e+00 11 8 0 10 0 0 99.65 24.73 0.52 0.00460 0.00217 86 86 1 5 0 350.390 33.25 20.00 24.73 23.25 3.8 972.16 -127899 -32767 -85750 -60195 -111021 -144546 -91846 -64804 -135202 -89422 -114616 -67276 -67706 -33517 -35297 -21434 -48918 -20220 -24658 -22715 -469 -37596 -7897 -27529 -10766 -21936 -28429 -6986 -9322 -23826 -24368 -3821 -11644 -8917 -7222 -9937 -3516 -7127 2072 -5824 -772 1587 2499 2880 -83 2192 -1561 -162 -1335 3253 2640 2575 1689 3897 3436 2110 4215 5363 1682 1243 2257 804 4919 3218 2254 1459 524 -1029 -354 1290 2174 1074 908 103 -140 133 -2076 -3757 -2896 -1728 -784 -1913 -1367 -1772 -1003 89 137 524 427 1690 335 -445 -705 -414 -881 -681 -462 814 372 -106 -102 -849 -1508 -869 -910 -1009 -943 -480 31 491 907 743 635 -35 -276 -625 73 1 345 87 -24 331 804 523 392 708 -544 388 133 134 -185 -154 -393 -182 -172 13 66 629 335 1 -154 -410 -617 -1336 -156 -753 -400 -1107 -1991 -829 -523 -2568 -1189 -2041 -831 -1061 -478 -645 -412 -1394 -480 -668 -642 -11 -1277 -210 -1000 -366 -896 -1276 -244 -321 -1001 -1227 -188 -727 -595 -451 -621 -228 -574 190 -709 -102 221 365 430 -13 340 -256 -27 -236 583 532 534 389 963 914 596 1218 1542 487 353 647 256 1716 1302 904 624 220 -412 -154 648 1212 639 542 59 -74 63 -916 -1674 -1408 -991 -484 -1376 -1085 -1388 -835 79 129 506 388 1579 296 -369 -556 -328 -777 -650 -508 954 458 -134 -129 -974 -1670 -948 -1015 -1201 -1175 -599 42 696 1433 1194 1031 -56 -437 -937 108 1 537 145 -40 530 1304 825 595 1035 -813 581 211 230 -334 -298 -757 -370 -359 28 144 1387 749 2 -332 -832 -1254 SS 20250819T115429.1Z 9362.496171 154 1 28.89 2 78.67 72.74 52.65 29.04 0.00 1 0.00 1 0 17 2.601e-01 1.397e-02 1.520e-01 6.976e-03 5.459229e-01 3.569866e-03 5.868601e-03 -6.000000e+00 1.449978e-01 227.09 -2.00 3.04 -2.00 320.31 0.00e+00 5.632921e-03 1.323115e-03 2.542732e-03 -6.000000e+00 6.770685e-03 290.17 -2.00 20.00 -2.00 319.57 0.00e+00 4.916 0.000 302.00 328.00 3 3.5386e+00 1.0977e-02 5.4900e-02 -6.0000e+00 3.5916e-01 1.8020e-01 1.3726e-02 2.6928e-02 -6.0000e+00 3.8941e-01 -1.5407e-01 1.1895e-02 1.5378e-02 -6.0000e+00 2.3344e-01 5.2304e-02 6.0910e-03 5.9346e-03 -6.0000e+00 1.0237e-01 6.4057e-05 -6.3574e-04 1.8550e-04 7.5441e-05 -6.0000e+00 6.6074e-03 4.0658e-03 0.0000e+00 12 8 8 10 0 0 94.32 24.73 0.44 0.00407 -0.00071 10 10 1 5 0 2888.190 33.25 20.01 24.73 23.57 3.8 973.83 -155934 900000 -67726 900000 -138595 -52691 -82255 1972 -56212 -79474 12898 -36855 -41976 -34180 8076 -5940 -28137 704 49692 9280 -5608 -16894 4500 -16402 56152 2624 -32123 86084 11775 -25565 -8384 703 -1962 265 14240 301 -4964 -23332 4928 -4345 18050 -10144 3229 19949 -812 -3712 -440 -4102 846 7451 20934 5716 -2086 1865 6841 -437 4993 2256 2865 -717 5595 1904 1227 3892 -73 1810 4238 -7 -961 -157 -1265 2144 288 1409 2447 61 -1011 -6258 170 -4884 -1383 -3497 35 -1419 252 -425 1568 920 2214 1688 546 -3562 304 -1503 -1084 -184 -2001 325 -264 -230 -176 -108 -1988 -2270 -600 -971 -412 -1523 310 166 2350 210 252 -492 -1040 -473 180 329 1363 1155 -242 1391 346 357 352 304 -1007 515 543 -8 -35 656 -58 -885 -857 132 564 474 -193 216 -22 -281 -914 -5013 900000 -1243 900000 -4430 -681 -1510 17 -994 -1892 123 -627 -942 -906 176 -178 -1167 24 1115 328 -236 -781 171 -825 1451 121 -2141 1698 472 -1565 -507 46 -152 22 959 22 -422 -2792 543 -629 2344 -1862 547 2944 -149 -719 -84 -826 167 1434 3858 1368 -586 544 2000 -141 1575 730 894 -228 1712 662 486 1537 -32 743 1787 -3 -419 -79 -717 1234 169 776 1230 28 -471 -3009 83 -2699 -862 -2538 27 -1167 217 -363 1387 850 2031 1513 503 -3158 243 -1212 -952 -168 -2147 391 -326 -287 -225 -125 -2104 -2388 -675 -1170 -516 -1895 408 243 3712 335 401 -817 -1625 -691 258 492 2153 1943 -388 2291 556 555 523 435 -1391 700 820 -14 -61 1201 -112 -1792 -1733 280 1227 1052 -436 474 -45 -593 -1852 SS 20250819T121708.9Z 9362.511909 166 1 30.02 2 73.54 70.60 50.31 23.61 0.00 1 0.00 1 0 25 2.952e-02 6.669e-03 2.571e-03 5.545e-04 3.959940e-01 2.750257e-04 4.083666e-03 -6.000000e+00 1.645695e-02 227.09 -2.00 3.04 -2.00 317.94 0.00e+00 8.373838e-04 4.835947e-05 2.483660e-04 -6.000000e+00 7.489179e-04 290.17 -2.00 20.00 -2.00 317.07 0.00e+00 3.472 0.000 302.00 328.00 3 6.6865e-01 7.3569e-04 3.8445e-02 -6.0000e+00 4.0759e-02 6.3472e-03 8.3532e-04 1.7705e-02 -6.0000e+00 4.4195e-02 -1.9085e-02 5.3007e-04 8.6425e-03 -6.0000e+00 2.6446e-02 5.6279e-03 2.7669e-04 2.4848e-03 -6.0000e+00 1.1495e-02 5.6233e-03 -2.0894e-04 1.4589e-05 2.4416e-05 -6.0000e+00 7.3729e-04 3.5850e-03 0.0000e+00 11 8 0 10 0 0 96.79 24.76 0.39 0.00358 0.00201 315 315 1 5 0 95.280 33.25 20.00 24.76 23.77 3.9 976.52 -9483 -6231 -6113 -8627 -12691 -13535 -10989 -8317 -6317 -6493 -10263 -7801 -5682 -3381 -77 -275 317 575 1642 1876 1544 717 1463 1212 1489 705 -92 15 -1715 -910 58 1052 2099 -37 -3141 -3590 -3302 -1641 -514 238 -126 84 306 113 188 416 163 -40 -432 -258 802 772 980 1221 1311 1249 844 575 235 25 672 1334 1901 2467 1145 177 -501 -926 83 526 597 660 299 549 134 -499 -1039 -1999 -1320 -1319 -1248 -1214 -1880 -1781 -1185 -614 -30 183 727 696 437 267 -247 -249 -229 -233 131 898 549 -29 -351 -813 -1052 -484 -742 -888 -784 -561 -69 397 683 590 538 305 -132 -183 -59 -59 203 258 -26 281 639 564 540 246 5 561 370 289 111 -127 -151 -162 -124 -36 98 371 209 -99 -247 -591 -734 -614 -442 -456 -630 -852 -881 -751 -633 -537 -540 -886 -688 -580 -406 -11 -44 49 96 286 342 292 135 281 252 332 154 -21 3 -377 -200 14 262 582 -11 -917 -1012 -1015 -542 -192 99 -59 39 147 56 93 207 81 -20 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