File name: Pandora282s1_Ilo-UNAM_20250831_L2Fit_fout2c3d20250118p1-8.txt File generation date: 20250904T094102.8Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 282 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora282_OF_v2d20240118.txt Instrument calibration file used: Pandora282s1_CF_v3d20250118.txt Level 1 file used: Pandora282s1_Ilo-UNAM_20250831_L1_smca1c3d20250118p1-8.txt Full location name: Grupo de Investigacion en Ciencias de la Atmosfera, UNAM, Peru Short location name: Ilo-UNAM Country of location: Peru Location latitude [deg]: -17.6020 Location longitude [deg]: -71.3389 Location altitude [m]: 85 Local noon date: 20250831 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 202 344 Nominal wavelengths inside fitting window [nm]: 305.0533 305.1939 305.3345 305.4751 305.6156 305.7562 305.8968 306.0373 306.1778 306.3184 306.4589 306.5994 306.7399 306.8803 307.0208 307.1613 307.3017 307.4421 307.5825 307.7230 307.8634 308.0037 308.1441 308.2845 308.4248 308.5652 308.7055 308.8458 308.9861 309.1264 309.2667 309.4070 309.5473 309.6875 309.8278 309.9680 310.1082 310.2484 310.3886 310.5288 310.6690 310.8091 310.9493 311.0894 311.2296 311.3697 311.5098 311.6499 311.7900 311.9300 312.0701 312.2102 312.3502 312.4902 312.6302 312.7702 312.9102 313.0502 313.1902 313.3301 313.4701 313.6100 313.7500 313.8899 314.0298 314.1697 314.3095 314.4494 314.5893 314.7291 314.8690 315.0088 315.1486 315.2884 315.4282 315.5680 315.7077 315.8475 315.9872 316.1269 316.2667 316.4064 316.5461 316.6858 316.8254 316.9651 317.1048 317.2444 317.3840 317.5236 317.6632 317.8028 317.9424 318.0820 318.2216 318.3611 318.5006 318.6402 318.7797 318.9192 319.0587 319.1982 319.3376 319.4771 319.6165 319.7560 319.8954 320.0348 320.1742 320.3136 320.4530 320.5923 320.7317 320.8710 321.0104 321.1497 321.2890 321.4283 321.5676 321.7068 321.8461 321.9854 322.1246 322.2638 322.4030 322.5422 322.6814 322.8206 322.9598 323.0990 323.2381 323.3772 323.5164 323.6555 323.7946 323.9337 324.0727 324.2118 324.3509 324.4899 324.6289 324.7679 324.9070 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250831T143522.1Z 9374.607895 186 1 29.62 2 41.36 53.68 109.17 127.90 0.00 1 0.00 1 0 17 9.545e-03 7.527e-03 2.765e-03 1.951e-03 1.650570e-01 9.825010e-04 1.740986e-03 -6.000000e+00 5.331760e-03 227.52 -2.00 3.04 -2.00 314.77 0.00e+00 4.069907e-04 8.270219e-05 2.569837e-05 -6.000000e+00 2.422574e-04 290.29 -2.00 20.00 -2.00 314.09 0.00e+00 1.331 0.000 302.00 328.00 3 5.4409e+00 2.5097e-03 1.5022e-02 -6.0000e+00 1.3218e-02 4.6615e-02 2.7872e-03 7.3394e-03 -6.0000e+00 1.4326e-02 -6.4317e-04 1.6014e-03 3.5759e-03 -6.0000e+00 8.5700e-03 -4.3797e-03 7.1818e-04 1.0212e-03 -6.0000e+00 3.7239e-03 5.2401e-04 1.3772e-05 5.1332e-05 1.2130e-05 -6.0000e+00 2.3839e-04 3.1470e-04 0.0000e+00 11 8 0 10 0 0 99.81 24.98 0.32 0.00031 0.00042 15 15 1 5 0 1974.510 33.25 20.01 24.98 25.46 3.9 987.86 -288 1322 280 -101 -2983 -2560 -702 377 1286 -331 -1446 -968 -831 -634 950 316 -255 713 1084 1146 510 965 1022 992 498 476 -56 -25 -1250 -391 1172 812 1362 -1025 -2707 -3388 -2809 -1111 -335 430 -370 -823 -435 -483 -139 24 -711 -440 -944 -365 760 333 742 1081 654 613 860 646 480 238 363 1084 1659 2104 820 -216 -939 -1868 -211 605 527 1045 499 859 1017 2 -737 -2097 -1457 -1359 -922 -1282 -1548 -1671 -680 -172 -58 312 525 979 621 -312 -488 -801 -439 -676 347 955 539 672 -118 -565 -1041 -891 -791 -766 -845 -467 -136 411 764 857 479 463 -187 -428 -338 -351 -58 256 55 147 299 399 716 423 195 597 231 113 169 -23 -261 -137 74 204 -52 601 268 -127 -297 -773 -775 -104 506 110 -37 -961 -766 -216 128 485 -133 -563 -368 -345 -272 449 152 -125 351 547 594 272 500 531 540 285 282 -33 -14 -636 -202 615 419 748 -597 -1466 -1880 -1554 -698 -234 327 -291 -673 -363 -406 -115 20 -576 -362 -750 -281 599 282 615 934 582 551 785 589 429 210 328 979 1608 2159 809 -207 -860 -1629 -186 573 552 1082 523 873 1027 2 -640 -1798 -1246 -1219 -870 -1337 -1639 -1831 -786 -203 -69 385 652 1180 730 -354 -524 -802 -451 -719 402 1155 671 830 -145 -675 -1164 -1013 -939 -970 -1060 -609 -183 554 1078 1228 663 621 -241 -508 -412 -421 -74 339 77 203 403 519 918 518 236 698 285 142 221 -32 -353 -181 102 287 -76 888 405 -190 -431 -1092 -1110 SS 20250831T144537.9Z 9374.615022 189 1 30.13 2 39.42 51.15 107.29 126.72 0.00 1 0.00 1 0 17 8.566e-03 6.832e-03 7.350e-04 5.737e-04 1.598368e-01 2.900182e-04 1.702140e-03 -6.000000e+00 4.784876e-03 227.52 -2.00 3.04 -2.00 314.21 0.00e+00 2.829748e-04 2.223873e-05 2.344089e-05 -6.000000e+00 2.174006e-04 290.29 -2.00 20.00 -2.00 313.61 0.00e+00 1.293 0.000 302.00 328.00 3 3.2093e+00 7.3714e-04 1.4595e-02 -6.0000e+00 1.1863e-02 3.1572e-02 8.1578e-04 7.1233e-03 -6.0000e+00 1.2856e-02 -2.1158e-03 4.6971e-04 3.4772e-03 -6.0000e+00 7.6909e-03 -3.2387e-03 2.0824e-04 9.8084e-04 -6.0000e+00 3.3421e-03 5.1523e-03 -7.1786e-05 1.4981e-05 1.2334e-05 -6.0000e+00 2.1393e-04 -7.7944e-06 0.0000e+00 11 8 0 10 0 0 99.89 25.02 0.42 -0.00001 -0.00055 96 96 1 5 0 313.750 33.25 20.00 25.02 26.38 3.8 992.18 243 197 168 -1777 -2781 -1945 -286 867 1086 346 -1446 -1260 -885 88 876 654 428 604 723 1510 896 537 859 925 485 528 143 -75 -696 -69 925 985 1588 -309 -2454 -2890 -2432 -1399 -431 -159 -570 -742 -305 -616 -280 -267 -393 -589 -959 -339 231 476 861 1046 653 881 689 637 381 167 610 1060 1431 1840 677 -79 -705 -1055 81 495 607 695 427 640 487 -68 -580 -1496 -1238 -1185 -1008 -1067 -1777 -1539 -1010 -505 -151 220 627 592 524 247 -169 -271 -208 -156 204 941 617 170 -198 -646 -873 -507 -713 -806 -733 -639 -189 308 594 596 527 337 -49 -231 -171 -190 74 367 32 251 512 443 594 367 52 457 288 365 141 -143 -179 -98 -91 15 18 327 201 -28 -276 -634 -728 103 90 77 -775 -1110 -760 -115 365 483 162 -663 -564 -430 45 474 366 244 349 428 872 532 313 500 564 297 335 91 -47 -412 -39 526 590 966 -198 -1472 -1719 -1486 -936 -316 -127 -480 -626 -263 -535 -241 -229 -339 -487 -791 -271 190 402 732 928 596 784 626 578 350 152 547 1008 1418 1872 678 -77 -640 -936 73 477 626 729 453 659 489 -65 -516 -1320 -1093 -1086 -1000 -1094 -1903 -1653 -1119 -585 -181 271 780 717 605 274 -179 -275 -217 -167 232 1111 766 210 -238 -738 -986 -565 -851 -999 -919 -815 -248 413 816 812 708 442 -62 -275 -198 -228 93 472 43 330 674 577 749 454 62 528 340 447 181 -184 -231 -130 -124 21 26 472 289 -40 -390 -894 -996 SS 20250831T145449.9Z 9374.621411 192 1 30.19 2 37.74 48.68 105.59 125.71 0.00 1 0.00 1 0 17 8.376e-03 6.852e-03 8.033e-04 6.316e-04 1.566994e-01 3.198857e-04 1.670537e-03 -6.000000e+00 4.678649e-03 227.52 -2.00 3.04 -2.00 314.15 0.00e+00 3.345374e-04 2.421715e-05 1.549431e-05 -6.000000e+00 2.125697e-04 290.29 -2.00 20.00 -2.00 313.56 0.00e+00 1.263 0.000 302.00 328.00 3 3.4319e+00 8.1290e-04 1.4275e-02 -6.0000e+00 1.1599e-02 3.4202e-02 8.9954e-04 6.9946e-03 -6.0000e+00 1.2571e-02 -2.5780e-03 5.1795e-04 3.4112e-03 -6.0000e+00 7.5201e-03 -2.9433e-03 2.2911e-04 9.6842e-04 -6.0000e+00 3.2680e-03 4.2688e-03 -1.0498e-04 1.6475e-05 1.2105e-05 -6.0000e+00 2.0918e-04 -1.7681e-04 0.0000e+00 11 8 0 10 0 0 99.87 25.06 0.36 -0.00018 -0.00097 82 82 1 5 0 368.050 33.25 20.00 25.06 27.20 3.9 998.52 193 131 151 -1408 -2509 -1992 -321 718 950 131 -1058 -1089 -839 351 947 533 198 517 779 1422 845 636 964 820 584 585 88 -284 -742 130 830 1001 1576 -119 -2287 -2939 -2482 -1383 -462 -65 -712 -786 -432 -709 -261 -290 -521 -509 -807 -374 428 303 668 929 794 869 780 704 362 201 647 964 1415 1893 727 -130 -678 -1063 -11 516 574 720 459 719 528 -85 -571 -1470 -1127 -1133 -1181 -985 -1816 -1629 -1094 -538 -50 218 650 590 536 268 -166 -347 -148 -135 208 936 653 181 -67 -640 -1039 -538 -559 -845 -696 -620 -207 371 684 558 552 219 -64 -137 -108 -196 133 223 20 115 493 369 611 314 34 415 305 362 113 -111 -235 -126 -19 110 -17 305 198 -51 -225 -541 -764 86 60 69 -642 -1051 -773 -128 300 442 61 -478 -507 -402 177 504 309 111 294 454 845 516 380 575 513 366 379 57 -180 -430 74 484 585 979 -74 -1398 -1787 -1546 -940 -344 -53 -605 -668 -375 -621 -225 -249 -453 -423 -669 -301 353 257 591 827 725 800 708 638 332 183 600 917 1399 1918 746 -126 -634 -941 -10 493 588 750 483 758 526 -82 -525 -1295 -991 -1032 -1164 -999 -1925 -1783 -1232 -632 -60 265 796 725 628 302 -174 -348 -152 -147 233 1118 796 227 -82 -741 -1159 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