File name: Pandora282s1_Ilo-UNAM_20250904_L2Fit_fout2c3d20250118p1-8.txt File generation date: 20250905T044921.4Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 282 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora282_OF_v2d20240118.txt Instrument calibration file used: Pandora282s1_CF_v3d20250118.txt Level 1 file used: Pandora282s1_Ilo-UNAM_20250904_L1_smca1c3d20250118p1-8.txt Full location name: Grupo de Investigacion en Ciencias de la Atmosfera, UNAM, Peru Short location name: Ilo-UNAM Country of location: Peru Location latitude [deg]: -17.6020 Location longitude [deg]: -71.3389 Location altitude [m]: 85 Local noon date: 20250904 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 202 344 Nominal wavelengths inside fitting window [nm]: 305.0533 305.1939 305.3345 305.4751 305.6156 305.7562 305.8968 306.0373 306.1778 306.3184 306.4589 306.5994 306.7399 306.8803 307.0208 307.1613 307.3017 307.4421 307.5825 307.7230 307.8634 308.0037 308.1441 308.2845 308.4248 308.5652 308.7055 308.8458 308.9861 309.1264 309.2667 309.4070 309.5473 309.6875 309.8278 309.9680 310.1082 310.2484 310.3886 310.5288 310.6690 310.8091 310.9493 311.0894 311.2296 311.3697 311.5098 311.6499 311.7900 311.9300 312.0701 312.2102 312.3502 312.4902 312.6302 312.7702 312.9102 313.0502 313.1902 313.3301 313.4701 313.6100 313.7500 313.8899 314.0298 314.1697 314.3095 314.4494 314.5893 314.7291 314.8690 315.0088 315.1486 315.2884 315.4282 315.5680 315.7077 315.8475 315.9872 316.1269 316.2667 316.4064 316.5461 316.6858 316.8254 316.9651 317.1048 317.2444 317.3840 317.5236 317.6632 317.8028 317.9424 318.0820 318.2216 318.3611 318.5006 318.6402 318.7797 318.9192 319.0587 319.1982 319.3376 319.4771 319.6165 319.7560 319.8954 320.0348 320.1742 320.3136 320.4530 320.5923 320.7317 320.8710 321.0104 321.1497 321.2890 321.4283 321.5676 321.7068 321.8461 321.9854 322.1246 322.2638 322.4030 322.5422 322.6814 322.8206 322.9598 323.0990 323.2381 323.3772 323.5164 323.6555 323.7946 323.9337 324.0727 324.2118 324.3509 324.4899 324.6289 324.7679 324.9070 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250904T142536.4Z 9378.601116 312 1 31.76 2 42.13 57.34 139.43 174.83 0.00 1 0.00 1 0 17 1.140e-02 8.104e-03 3.995e-03 2.621e-03 1.731812e-01 1.316686e-03 1.802070e-03 -6.000000e+00 6.372437e-03 227.66 -2.00 3.04 -2.00 315.12 0.00e+00 4.688392e-04 1.188188e-04 2.574657e-05 -6.000000e+00 2.894556e-04 290.33 -2.00 20.00 -2.00 314.42 0.00e+00 1.347 0.000 302.00 328.00 3 5.9790e+00 3.3760e-03 1.5324e-02 -6.0000e+00 1.5803e-02 4.8723e-02 3.7529e-03 7.6504e-03 -6.0000e+00 1.7126e-02 4.4190e-04 2.1537e-03 3.7243e-03 -6.0000e+00 1.0244e-02 -5.1963e-03 9.7815e-04 1.0713e-03 -6.0000e+00 4.4499e-03 2.9531e-04 -2.7491e-05 6.9216e-05 1.2284e-05 -6.0000e+00 2.8479e-04 7.5440e-04 0.0000e+00 11 8 0 10 0 0 99.37 24.97 0.59 0.00075 0.00055 8 8 1 5 0 3969.180 33.25 20.00 24.97 28.28 3.9 1004.97 -2155 1454 -1237 -179 -5538 -512 984 931 1595 -729 -354 -2836 -247 425 2196 492 -480 397 1900 1648 841 1392 1767 1249 -132 -202 -1522 1241 -1394 -878 1881 955 2109 -984 -2181 -2918 -2567 -2003 -756 -431 412 -1147 108 76 -623 -1121 -861 -632 -1245 -560 1020 -245 422 250 1016 786 453 1046 653 -190 1159 197 1764 2253 517 -114 -778 -1244 -160 673 685 1387 407 1227 1109 234 -907 -1934 -1485 -1235 -1097 -1365 -1680 -1414 -653 -619 2 529 922 585 1180 -297 -194 -580 -43 -1105 198 1017 294 891 -375 -512 -1663 -911 37 -273 -1001 -756 -408 273 983 787 151 -359 -64 -446 -274 26 34 354 -78 489 527 513 595 512 -196 331 138 -79 92 -250 320 -338 141 205 62 648 186 7 -146 -808 -846 -692 487 -431 -57 -1606 -132 262 277 528 -259 -120 -971 -91 159 908 225 -225 188 912 816 429 690 876 652 -68 -107 -816 653 -686 -410 883 478 1120 -516 -1147 -1461 -1383 -1144 -512 -317 328 -895 85 60 -495 -893 -714 -501 -956 -418 776 -202 337 209 866 678 400 915 560 -163 999 183 1633 2210 518 -111 -688 -1045 -138 653 689 1454 434 1261 1075 220 -818 -1619 -1245 -1076 -1069 -1377 -1817 -1579 -726 -743 2 653 1144 709 1395 -343 -200 -599 -46 -1210 222 1249 370 1108 -470 -591 -1919 -1062 44 -349 -1265 -994 -554 389 1385 1130 210 -491 -84 -539 -324 32 44 472 -109 679 715 671 777 637 -245 399 175 -102 123 -344 440 -453 199 307 90 964 284 11 -212 -1209 -1227 SS 20250904T143052.7Z 9378.604777 315 1 30.01 2 41.08 56.16 139.32 173.07 0.00 1 0.00 1 0 17 8.415e-03 6.718e-03 8.460e-04 6.441e-04 1.684088e-01 3.252885e-04 1.795166e-03 -6.000000e+00 4.702438e-03 227.66 -2.00 3.04 -2.00 314.37 0.00e+00 3.672254e-04 2.567661e-05 1.761668e-05 -6.000000e+00 2.136123e-04 290.33 -2.00 20.00 -2.00 313.75 0.00e+00 1.325 0.000 302.00 328.00 3 3.3839e+00 8.2776e-04 1.5072e-02 -6.0000e+00 1.1662e-02 2.6812e-02 9.1676e-04 7.5226e-03 -6.0000e+00 1.2638e-02 -7.9764e-04 5.2781e-04 3.6704e-03 -6.0000e+00 7.5596e-03 -3.6193e-03 2.3486e-04 1.0446e-03 -6.0000e+00 3.2835e-03 4.1189e-03 -7.4833e-05 1.6870e-05 1.3008e-05 -6.0000e+00 2.1017e-04 1.1489e-03 0.0000e+00 11 8 0 10 0 0 99.95 24.98 0.39 0.00115 0.00059 78 78 1 5 0 384.650 33.25 20.00 24.98 28.51 3.9 1006.72 -30 436 320 -1685 -2658 -1949 -533 735 1084 459 -1238 -1021 -501 53 901 282 169 467 863 1366 670 596 921 888 485 675 50 -60 -519 -106 876 983 1766 -223 -2432 -2736 -2458 -1408 -701 -231 -555 -862 -466 -721 -225 -369 -508 -604 -842 -521 360 466 827 879 686 778 709 586 332 304 534 958 1433 1955 843 -69 -597 -1009 235 508 571 663 490 729 512 -109 -536 -1496 -1185 -1105 -1151 -1114 -1800 -1528 -1026 -513 -154 266 693 516 392 298 -102 -277 -154 -42 193 901 662 133 -72 -663 -1002 -452 -600 -786 -667 -656 -246 355 668 523 468 171 -160 -149 -153 -120 144 211 -64 153 362 376 574 339 0 561 319 311 231 -109 -142 -51 -66 9 -20 353 245 -73 -192 -621 -737 -12 187 139 -693 -1005 -726 -205 294 457 204 -538 -434 -232 26 466 152 93 259 491 796 383 350 541 522 300 412 31 -36 -297 -58 487 576 1050 -140 -1429 -1597 -1476 -924 -505 -180 -456 -735 -392 -612 -189 -309 -429 -489 -682 -411 292 388 719 772 619 709 636 525 302 274 490 903 1404 1965 859 -67 -557 -892 212 488 587 693 517 746 510 -105 -476 -1276 -1013 -1016 -1110 -1146 -1933 -1644 -1137 -595 -183 328 860 625 453 330 -109 -283 -162 -45 222 1072 828 166 -88 -763 -1110 -507 -720 -980 -841 -841 -326 479 924 736 634 226 -198 -180 -180 -146 183 275 -85 203 482 496 731 413 0 657 382 387 293 -143 -186 -67 -89 13 -29 505 357 -105 -275 -866 -1021 SS 20250904T143533.3Z 9378.608024 318 1 30.01 2 40.16 55.08 139.19 171.51 0.00 1 0.00 1 0 17 8.451e-03 6.742e-03 2.137e-04 1.639e-04 1.660757e-01 8.285937e-05 1.769027e-03 -6.000000e+00 4.722363e-03 227.66 -2.00 3.04 -2.00 314.33 0.00e+00 3.759296e-04 6.498196e-06 1.508160e-05 -6.000000e+00 2.145191e-04 290.33 -2.00 20.00 -2.00 313.72 0.00e+00 1.307 0.000 302.00 328.00 3 6.9673e-01 2.1079e-04 1.4863e-02 -6.0000e+00 1.1711e-02 9.4838e-03 2.3340e-04 7.4171e-03 -6.0000e+00 1.2692e-02 -9.7850e-04 1.3441e-04 3.6171e-03 -6.0000e+00 7.5917e-03 -3.7405e-03 5.9710e-05 1.0313e-03 -6.0000e+00 3.2974e-03 6.2285e-02 -6.9474e-05 4.2914e-06 1.2595e-05 -6.0000e+00 2.1106e-04 1.1985e-03 0.0000e+00 11 8 0 10 0 0 99.91 25.00 0.39 0.00120 0.00068 1367 1367 1 5 0 21.950 33.25 20.00 25.00 28.75 3.9 1008.17 249 130 248 -1721 -2700 -2142 -301 841 1308 274 -1217 -1106 -446 136 821 453 228 562 769 1419 838 454 915 930 414 532 128 -248 -771 39 931 1042 1613 -246 -2402 -2764 -2424 -1425 -539 -239 -585 -707 -529 -701 -209 -280 -480 -546 -907 -475 331 599 800 970 698 861 750 512 332 165 610 1025 1417 1895 783 -138 -593 -984 163 537 581 681 532 692 413 -25 -498 -1424 -978 -1027 -1092 -1089 -1851 -1660 -1064 -545 -154 160 691 597 467 253 -153 -232 -137 -45 227 934 655 153 -155 -654 -923 -435 -628 -818 -722 -646 -218 306 584 582 475 284 -82 -136 -155 -149 95 242 -40 129 429 371 608 321 66 534 390 305 213 -51 -134 -165 -74 51 12 281 233 -79 -243 -571 -742 105 57 110 -717 -1080 -796 -115 339 558 124 -536 -477 -210 68 437 252 124 309 434 820 498 265 533 546 256 327 79 -149 -439 22 534 605 959 -155 -1465 -1601 -1454 -942 -382 -186 -481 -586 -449 -600 -177 -236 -406 -444 -734 -374 267 500 677 858 617 768 682 466 296 146 549 953 1379 1902 797 -132 -543 -879 148 512 596 714 564 711 412 -24 -448 -1224 -841 -956 -1077 -1121 -1998 -1806 -1197 -629 -183 193 839 723 550 285 -163 -236 -140 -49 257 1109 820 191 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