File name: Pandora282s1_Ilo-UNAM_20250922_L2Fit_fout2c3d20250118p1-8.txt File generation date: 20250929T200034.4Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 282 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora282_OF_v2d20240118.txt Instrument calibration file used: Pandora282s1_CF_v3d20250118.txt Level 1 file used: Pandora282s1_Ilo-UNAM_20250922_L1_smca1c3d20250118p1-8.txt Full location name: Grupo de Investigacion en Ciencias de la Atmosfera, UNAM, Peru Short location name: Ilo-UNAM Country of location: Peru Location latitude [deg]: -17.6020 Location longitude [deg]: -71.3389 Location altitude [m]: 85 Local noon date: 20250922 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 202 344 Nominal wavelengths inside fitting window [nm]: 305.0533 305.1939 305.3345 305.4751 305.6156 305.7562 305.8968 306.0373 306.1778 306.3184 306.4589 306.5994 306.7399 306.8803 307.0208 307.1613 307.3017 307.4421 307.5825 307.7230 307.8634 308.0037 308.1441 308.2845 308.4248 308.5652 308.7055 308.8458 308.9861 309.1264 309.2667 309.4070 309.5473 309.6875 309.8278 309.9680 310.1082 310.2484 310.3886 310.5288 310.6690 310.8091 310.9493 311.0894 311.2296 311.3697 311.5098 311.6499 311.7900 311.9300 312.0701 312.2102 312.3502 312.4902 312.6302 312.7702 312.9102 313.0502 313.1902 313.3301 313.4701 313.6100 313.7500 313.8899 314.0298 314.1697 314.3095 314.4494 314.5893 314.7291 314.8690 315.0088 315.1486 315.2884 315.4282 315.5680 315.7077 315.8475 315.9872 316.1269 316.2667 316.4064 316.5461 316.6858 316.8254 316.9651 317.1048 317.2444 317.3840 317.5236 317.6632 317.8028 317.9424 318.0820 318.2216 318.3611 318.5006 318.6402 318.7797 318.9192 319.0587 319.1982 319.3376 319.4771 319.6165 319.7560 319.8954 320.0348 320.1742 320.3136 320.4530 320.5923 320.7317 320.8710 321.0104 321.1497 321.2890 321.4283 321.5676 321.7068 321.8461 321.9854 322.1246 322.2638 322.4030 322.5422 322.6814 322.8206 322.9598 323.0990 323.2381 323.3772 323.5164 323.6555 323.7946 323.9337 324.0727 324.2118 324.3509 324.4899 324.6289 324.7679 324.9070 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250922T130813.2Z 9396.547375 121 1 29.63 2 54.51 76.81 60.03 84.99 0.00 1 0.00 1 0 17 1.301e-02 7.933e-03 5.096e-03 2.689e-03 2.116486e-01 1.345037e-03 2.214273e-03 -6.000000e+00 7.285483e-03 228.16 -2.00 3.04 -2.00 315.96 0.00e+00 6.740985e-04 1.445578e-04 6.141657e-05 -6.000000e+00 3.307186e-04 290.63 -2.00 20.00 -2.00 315.17 0.00e+00 1.718 0.000 302.00 328.00 3 5.5294e+00 3.4864e-03 1.9377e-02 -6.0000e+00 1.8087e-02 5.1879e-02 3.8918e-03 9.4641e-03 -6.0000e+00 1.9592e-02 -5.2887e-03 2.2476e-03 4.5996e-03 -6.0000e+00 1.1717e-02 -2.8317e-03 1.0550e-03 1.3340e-03 -6.0000e+00 5.0860e-03 3.0005e-04 -1.6371e-05 7.1667e-05 1.4323e-05 -6.0000e+00 3.2500e-04 3.1721e-04 0.0000e+00 11 8 0 10 0 0 99.96 25.01 0.32 0.00032 0.00019 16 16 1 5 0 1851.220 33.50 20.00 25.01 27.16 3.9 997.04 -3078 2712 -794 1159 -6102 -3659 -2612 1211 363 -1569 -2504 -3180 -2204 1272 684 476 321 1062 1860 1518 1022 1407 1424 -266 383 431 525 932 -1082 78 1136 878 1387 -922 -2118 -3551 -4630 -1674 409 -108 -430 -1296 -349 136 106 -184 -678 -981 -1160 654 1818 479 754 745 831 185 966 1190 757 209 779 867 1346 1696 686 -604 -379 -1650 -121 823 624 695 762 399 1203 -232 -1014 -1614 -1339 -1825 -1400 -1097 -1689 -1728 -1049 -161 -107 137 1185 803 783 -415 -618 -862 -352 -719 265 897 490 504 -129 -891 -1516 -949 -655 -810 -911 -119 -56 443 1099 536 856 94 -489 -229 -328 97 71 514 44 451 730 196 479 542 -408 490 514 646 -238 -60 47 -238 -230 258 42 356 64 118 -367 -465 -1029 -676 612 -189 253 -1236 -746 -554 253 86 -397 -618 -784 -598 379 233 178 113 382 686 580 402 540 549 -110 165 193 235 388 -421 31 475 361 613 -435 -929 -1497 -2134 -868 231 -72 -292 -924 -254 99 77 -133 -485 -679 -839 457 1310 349 575 597 685 156 822 1009 630 173 654 725 1216 1636 674 -549 -334 -1401 -105 755 636 696 767 391 1173 -206 -866 -1282 -1075 -1652 -1327 -1145 -1783 -1892 -1216 -188 -133 176 1517 1004 909 -470 -633 -883 -372 -785 316 1114 623 638 -164 -1045 -1763 -1114 -792 -1047 -1226 -157 -76 641 1583 793 1220 132 -668 -288 -404 123 97 713 64 648 1022 267 648 699 -500 615 642 864 -339 -82 65 -340 -347 391 65 566 104 189 -569 -697 -1583 SS 20250922T132310.4Z 9396.557759 132 1 23.30 2 51.05 75.03 56.54 83.74 0.00 1 0.00 1 0 17 1.094e-02 8.115e-03 4.769e-03 2.881e-03 1.947051e-01 1.446717e-03 2.044413e-03 -6.000000e+00 6.123527e-03 228.16 -2.00 3.04 -2.00 315.47 0.00e+00 5.913202e-04 1.397432e-04 5.287772e-05 -6.000000e+00 2.780244e-04 290.63 -2.00 20.00 -2.00 314.72 0.00e+00 1.587 0.000 302.00 328.00 3 5.4708e+00 3.7295e-03 1.7881e-02 -6.0000e+00 1.5202e-02 4.4536e-02 4.1510e-03 8.6952e-03 -6.0000e+00 1.6468e-02 2.1815e-03 2.3839e-03 4.2249e-03 -6.0000e+00 9.8486e-03 -5.4087e-03 1.0969e-03 1.2136e-03 -6.0000e+00 4.2741e-03 3.7299e-04 -2.2380e-04 7.6429e-05 1.3706e-05 -6.0000e+00 2.7321e-04 1.5814e-03 0.0000e+00 12 9 1 12 1 1 93.02 25.05 0.47 0.00158 -0.00010 5 8 1 5 0 3881.690 33.25 20.01 25.05 27.96 4.0 1003.46 -377 2052 -1178 -1999 -1046 834 -1946 460 2007 -727 -1261 -1638 -148 1042 2522 -687 610 256 203 1658 102 618 703 1139 303 894 -776 1869 -1145 -2085 2130 -167 2468 -593 -2612 -2992 -4457 -1432 -483 37 -303 -1436 -446 -438 -415 256 -1252 -550 -923 -443 1614 -104 -53 794 1164 432 1086 855 -365 -420 1176 1120 1414 1779 970 -198 -287 -1510 -151 1207 773 983 544 1106 508 415 -567 -1438 -1150 -1020 -1410 -1152 -2003 -1663 -624 -165 26 486 1369 936 746 -259 -197 -954 299 -1139 -148 672 1022 335 -160 -982 -1457 -602 -945 -630 -1064 -906 -335 343 488 674 558 281 -283 -642 -322 -75 319 894 -190 417 466 470 833 333 -765 385 496 268 -32 -9 -13 -194 119 36 76 599 106 -80 -181 -528 -977 -104 599 -332 -576 -258 189 -475 123 593 -232 -390 -502 -45 357 962 -296 266 105 87 718 46 271 310 525 148 450 -397 870 -502 -959 977 -77 1194 -308 -1269 -1382 -2258 -814 -304 26 -228 -1136 -336 -333 -313 205 -993 -416 -679 -318 1180 -83 -41 647 972 368 937 738 -312 -355 999 1017 1305 1748 967 -182 -254 -1281 -131 1109 790 994 557 1156 503 392 -482 -1213 -976 -908 -1333 -1199 -2125 -1822 -721 -194 33 595 1678 1181 874 -294 -212 -969 310 -1239 -177 832 1293 425 -202 -1146 -1677 -698 -1144 -811 -1359 -1207 -461 472 708 996 797 392 -361 -798 -390 -94 425 1222 -274 596 651 632 1108 425 -927 472 608 352 -42 -12 -18 -271 176 53 116 937 162 -120 -277 -783 -1408 SS 20250922T132822.5Z 9396.561372 135 1 30.01 2 49.85 74.37 55.32 83.29 0.00 1 0.00 1 0 17 8.641e-03 6.679e-03 5.245e-04 3.774e-04 1.897069e-01 1.904578e-04 2.006581e-03 -6.000000e+00 4.838591e-03 228.16 -2.00 3.04 -2.00 314.71 0.00e+00 3.942103e-04 1.591532e-05 2.172948e-05 -6.000000e+00 2.196286e-04 290.63 -2.00 20.00 -2.00 314.04 0.00e+00 1.548 0.000 302.00 328.00 3 2.0838e+00 4.8652e-04 1.7439e-02 -6.0000e+00 1.2013e-02 2.4867e-02 5.3985e-04 8.4743e-03 -6.0000e+00 1.3012e-02 -2.1046e-03 3.1008e-04 4.1241e-03 -6.0000e+00 7.7814e-03 -3.3996e-03 1.3890e-04 1.1704e-03 -6.0000e+00 3.3781e-03 1.1697e-02 -7.2685e-05 9.9057e-06 1.4019e-05 -6.0000e+00 2.1583e-04 -2.8227e-04 0.0000e+00 11 9 0 11 8 0 99.90 25.08 0.38 -0.00028 -0.00083 257 257 1 5 0 116.740 33.50 20.00 25.08 28.25 3.9 1004.91 223 82 52 -1830 -2712 -2282 -613 693 1103 181 -1517 -1230 -534 13 966 704 296 678 777 1451 800 559 1033 876 555 616 240 -164 -670 -149 872 1080 1680 -225 -2340 -2821 -2527 -1448 -527 -145 -530 -774 -448 -629 -253 -125 -499 -566 -840 -534 342 622 794 966 780 879 796 454 316 202 604 1066 1420 1947 842 -187 -730 -1000 123 537 592 706 481 695 415 -99 -552 -1507 -1022 -1112 -1083 -1037 -1782 -1710 -1080 -533 -179 195 663 659 454 245 -214 -222 -220 -56 163 915 689 208 -169 -648 -939 -466 -636 -763 -703 -613 -252 289 613 604 493 293 -75 -244 -169 -110 109 267 22 152 450 428 532 343 79 441 329 273 172 -80 -164 -181 -74 53 59 265 209 -53 -266 -550 -685 81 31 20 -698 -953 -747 -207 245 435 72 -591 -497 -224 6 460 350 151 352 416 761 432 297 548 490 313 360 141 -94 -353 -78 470 590 941 -134 -1360 -1559 -1441 -907 -364 -109 -425 -624 -370 -525 -208 -103 -402 -453 -652 -418 267 502 672 829 669 762 705 403 275 179 529 962 1344 1902 837 -176 -662 -889 108 508 603 734 505 708 411 -93 -496 -1299 -884 -1012 -1044 -1071 -1883 -1871 -1220 -615 -213 241 823 797 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