File name: Pandora282s1_Ilo-UNAM_20250923_L2Fit_fout2c3d20250118p1-8.txt File generation date: 20250929T200050.7Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 282 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora282_OF_v2d20240118.txt Instrument calibration file used: Pandora282s1_CF_v3d20250118.txt Level 1 file used: Pandora282s1_Ilo-UNAM_20250923_L1_smca1c3d20250118p1-8.txt Full location name: Grupo de Investigacion en Ciencias de la Atmosfera, UNAM, Peru Short location name: Ilo-UNAM Country of location: Peru Location latitude [deg]: -17.6020 Location longitude [deg]: -71.3389 Location altitude [m]: 85 Local noon date: 20250923 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 202 344 Nominal wavelengths inside fitting window [nm]: 305.0533 305.1939 305.3345 305.4751 305.6156 305.7562 305.8968 306.0373 306.1778 306.3184 306.4589 306.5994 306.7399 306.8803 307.0208 307.1613 307.3017 307.4421 307.5825 307.7230 307.8634 308.0037 308.1441 308.2845 308.4248 308.5652 308.7055 308.8458 308.9861 309.1264 309.2667 309.4070 309.5473 309.6875 309.8278 309.9680 310.1082 310.2484 310.3886 310.5288 310.6690 310.8091 310.9493 311.0894 311.2296 311.3697 311.5098 311.6499 311.7900 311.9300 312.0701 312.2102 312.3502 312.4902 312.6302 312.7702 312.9102 313.0502 313.1902 313.3301 313.4701 313.6100 313.7500 313.8899 314.0298 314.1697 314.3095 314.4494 314.5893 314.7291 314.8690 315.0088 315.1486 315.2884 315.4282 315.5680 315.7077 315.8475 315.9872 316.1269 316.2667 316.4064 316.5461 316.6858 316.8254 316.9651 317.1048 317.2444 317.3840 317.5236 317.6632 317.8028 317.9424 318.0820 318.2216 318.3611 318.5006 318.6402 318.7797 318.9192 319.0587 319.1982 319.3376 319.4771 319.6165 319.7560 319.8954 320.0348 320.1742 320.3136 320.4530 320.5923 320.7317 320.8710 321.0104 321.1497 321.2890 321.4283 321.5676 321.7068 321.8461 321.9854 322.1246 322.2638 322.4030 322.5422 322.6814 322.8206 322.9598 323.0990 323.2381 323.3772 323.5164 323.6555 323.7946 323.9337 324.0727 324.2118 324.3509 324.4899 324.6289 324.7679 324.9070 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250923T113503.6Z 9397.482681 67 1 5.80 2 76.25 85.85 89.52 100.11 0.00 1 0.00 1 0 17 9.882e-02 9.237e-03 6.966e-02 5.584e-03 4.798223e-01 2.799727e-03 4.912357e-03 -6.000000e+00 5.532740e-02 228.18 -2.00 3.04 -2.00 319.20 0.00e+00 1.398837e-03 7.256495e-04 1.021172e-03 -6.000000e+00 2.512135e-03 290.66 -2.00 20.00 -2.00 318.36 0.00e+00 4.108 0.000 302.00 328.00 3 2.6280e+00 7.8471e-03 4.5894e-02 -6.0000e+00 1.3736e-01 3.9286e-02 9.2270e-03 2.2060e-02 -6.0000e+00 1.4880e-01 -5.3464e-02 6.9784e-03 1.0903e-02 -6.0000e+00 8.8986e-02 2.1505e-02 3.7177e-03 3.1377e-03 -6.0000e+00 3.8618e-02 3.8814e-04 9.1753e-05 1.4630e-04 3.1613e-05 -6.0000e+00 2.4684e-03 1.5788e-03 0.0000e+00 12 9 1 12 1 1 50.81 24.89 0.33 0.00158 0.00227 5 31 1 5 0 965.330 33.25 20.00 24.89 24.71 3.9 979.95 -26633 2976 -15743 11331 -29300 -51245 -55739 -23742 -35196 -14057 -27928 -22689 -32086 -2760 -968 11751 -945 -4522 -1137 5453 10095 -3173 -8985 -11211 -927 -5776 -3 9245 -12206 -7253 -5779 -5779 -2938 -4320 -9620 -6027 -6242 -773 -747 -2155 4209 1378 789 1791 4497 291 521 255 107 595 4320 929 827 382 -88 1634 663 2104 557 -7 647 1616 3624 2031 2301 152 159 -1902 938 1809 -257 1389 101 -221 440 -1052 -1092 -2039 -710 -2268 -1625 -1994 -1212 -1808 -868 -427 125 693 734 2030 1351 2 -586 -803 -1353 -767 603 798 458 -275 -836 -1139 -1097 -819 -423 -1574 -1894 -590 -103 753 476 929 359 276 -60 -331 -100 -254 775 886 -14 492 1546 774 -140 306 -243 -58 585 -77 -240 -164 -192 80 -96 467 -450 469 -29 -81 206 -711 -647 -595 57 -386 204 -702 -1479 -1821 -646 -1227 -429 -988 -815 -1537 -122 -51 640 -64 -342 -89 422 770 -273 -846 -1178 -95 -657 0 881 -1369 -794 -711 -821 -464 -678 -1495 -958 -992 -137 -163 -576 1186 425 235 540 1326 91 164 81 35 198 1511 374 360 167 -41 767 325 1020 267 -3 311 837 2062 1216 1440 92 92 -1116 575 1277 -193 1079 79 -167 307 -713 -673 -1229 -452 -1602 -1322 -1732 -1145 -1698 -863 -455 133 757 808 2143 1415 2 -571 -770 -1330 -806 712 1013 611 -372 -1072 -1400 -1292 -962 -512 -2054 -2463 -802 -142 1130 749 1467 567 436 -88 -480 -143 -380 1169 1423 -23 787 2367 1155 -211 442 -351 -83 875 -123 -399 -288 -333 145 -179 883 -882 929 -58 -160 399 -1320 -1197 SS 20250923T114531.0Z 9397.489942 70 1 29.97 2 73.76 85.01 87.12 99.40 0.00 1 0.00 1 0 25 5.026e-02 7.585e-03 1.986e-02 2.413e-03 4.162162e-01 1.204694e-03 4.263921e-03 -6.000000e+00 2.813598e-02 228.18 -2.00 3.04 -2.00 318.67 0.00e+00 1.611216e-03 2.626795e-04 4.080419e-04 -6.000000e+00 1.277949e-03 290.66 -2.00 20.00 -2.00 317.81 0.00e+00 3.516 0.000 302.00 328.00 3 3.3755e+00 3.3042e-03 3.9333e-02 -6.0000e+00 6.9851e-02 3.2840e-02 3.8094e-03 1.8776e-02 -6.0000e+00 7.5674e-02 -2.0294e-02 2.6604e-03 9.2838e-03 -6.0000e+00 4.5256e-02 4.5947e-03 1.4171e-03 2.8835e-03 -6.0000e+00 1.9633e-02 3.4366e-04 -1.8693e-04 6.3978e-05 2.7105e-05 -6.0000e+00 1.2558e-03 3.8265e-03 0.0000e+00 11 8 0 10 0 0 99.87 24.90 0.43 0.00383 0.00242 25 25 1 5 0 1198.410 33.25 20.00 24.90 24.68 3.9 979.62 -28540 3858 -13511 2232 -29110 -14651 -12131 -9522 -6901 -6509 -21370 -10326 -9885 2526 3509 -186 -3987 1713 311 4182 1379 -4623 -1942 545 2931 -4222 -2222 956 -5742 -3048 1056 -561 -453 -1974 -4833 -5892 -6924 -3384 363 21 -601 -1552 2170 270 1058 -278 24 733 -938 150 1476 965 579 1632 1392 821 837 786 651 482 1275 1795 2226 1939 1759 432 -676 -846 -58 976 917 978 179 1430 530 -889 -1066 -2279 -1483 -1863 -1840 -1070 -1985 -1931 -1233 -420 261 502 1185 896 1030 -175 -2 -563 -582 -669 -8 654 514 56 -524 -723 -1486 -425 -696 -1138 -948 -624 -148 213 695 522 560 356 -456 -313 -51 123 161 604 185 332 614 180 364 426 -299 420 696 369 442 23 -171 -94 -150 -115 -64 457 325 -81 -334 -676 -725 -1135 126 -556 75 -1185 -496 -431 -376 -302 -305 -1161 -530 -602 165 273 -17 -417 181 36 483 169 -594 -249 74 416 -678 -355 141 -855 -448 167 -93 -85 -401 -946 -1120 -1456 -808 102 6 -209 -578 815 106 411 -111 9 289 -379 61 644 466 279 834 747 456 480 451 364 266 715 1087 1387 1338 1263 296 -440 -544 -39 710 743 833 154 1167 405 -662 -720 -1493 -1020 -1391 -1581 -965 -1968 -1886 -1277 -464 287 571 1349 994 1124 -177 -2 -547 -606 -741 -9 819 671 73 -688 -913 -1726 -490 -882 -1460 -1267 -835 -209 311 1099 825 874 553 -661 -444 -72 179 238 950 299 524 939 267 538 605 -426 589 1007 563 727 38 -291 -159 -271 -212 -121 875 633 -154 -610 -1231 -1268 SS 20250923T115948.6Z 9397.499868 77 1 30.43 2 70.37 83.82 83.83 98.45 0.00 1 0.00 1 0 25 2.770e-02 7.056e-03 1.004e-02 2.152e-03 3.525561e-01 1.068650e-03 3.648070e-03 -6.000000e+00 1.550599e-02 228.18 -2.00 3.04 -2.00 317.89 0.00e+00 8.360704e-04 1.862665e-04 2.860696e-04 -6.000000e+00 7.042654e-04 290.66 -2.00 20.00 -2.00 317.01 0.00e+00 2.943 0.000 302.00 328.00 3 3.8116e+00 2.8651e-03 3.3015e-02 -6.0000e+00 3.8496e-02 2.8455e-02 3.2512e-03 1.5879e-02 -6.0000e+00 4.1704e-02 -6.6899e-03 2.0645e-03 7.7444e-03 -6.0000e+00 2.4941e-02 -4.9298e-04 1.0754e-03 2.2064e-03 -6.0000e+00 1.0820e-02 4.1593e-04 -1.3026e-04 5.7341e-05 2.1824e-05 -6.0000e+00 6.9203e-04 3.5939e-03 0.0000e+00 11 8 0 10 0 0 99.91 24.92 0.47 0.00359 0.00262 23 23 1 5 0 1322.890 33.25 20.01 24.92 24.89 3.9 982.59 -13786 4841 -8871 -4863 -9496 -10972 -14089 -2425 -657 -5668 -7989 -4102 -4450 -1083 3078 -1743 -2139 1215 -387 1022 2688 -39 1814 239 1589 -1189 1118 2009 -1267 -486 1 1180 2611 -401 -2657 -4818 -5341 -2602 -364 375 -105 -305 -196 -210 861 -614 -123 -298 10 1150 1754 1091 804 88 676 571 728 259 689 620 860 1621 1854 1813 1331 281 -453 -1877 -201 1232 817 417 460 826 260 -243 -1253 -2252 -1257 -1320 -1187 -960 -1863 -1747 -1075 -195 108 124 676 517 532 -56 -497 -742 -456 -643 130 775 722 45 -349 -670 -1080 -724 -545 -952 -701 -468 145 419 1036 642 610 253 30 -236 27 -303 127 298 -269 442 622 455 548 262 -536 633 487 -8 257 -204 -161 -455 123 60 -147 541 322 -34 -373 -428 -707 -963 315 -692 -346 -622 -698 -990 -173 -52 -507 -724 -370 -470 -131 422 -259 -339 197 -67 183 488 -7 335 48 338 -273 254 428 -260 -99 0 288 700 -118 -741 -1316 -1602 -816 -136 153 -48 -147 -98 -107 432 -316 -62 -150 5 574 929 591 466 55 437 379 496 177 458 406 576 1084 1366 1370 1040 221 -333 -1365 -152 995 736 373 413 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