File name: Pandora282s1_Ilo-UNAM_20251028_L2Fit_fout2c3d20250118p1-8.txt File generation date: 20251029T212050.6Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 282 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora282_OF_v2d20240118.txt Instrument calibration file used: Pandora282s1_CF_v3d20250118.txt Level 1 file used: Pandora282s1_Ilo-UNAM_20251028_L1_smca1c3d20250118p1-8.txt Full location name: Grupo de Investigacion en Ciencias de la Atmosfera, UNAM, Peru Short location name: Ilo-UNAM Country of location: Peru Location latitude [deg]: -17.6020 Location longitude [deg]: -71.3389 Location altitude [m]: 85 Local noon date: 20251028 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 202 344 Nominal wavelengths inside fitting window [nm]: 305.0533 305.1939 305.3345 305.4751 305.6156 305.7562 305.8968 306.0373 306.1778 306.3184 306.4589 306.5994 306.7399 306.8803 307.0208 307.1613 307.3017 307.4421 307.5825 307.7230 307.8634 308.0037 308.1441 308.2845 308.4248 308.5652 308.7055 308.8458 308.9861 309.1264 309.2667 309.4070 309.5473 309.6875 309.8278 309.9680 310.1082 310.2484 310.3886 310.5288 310.6690 310.8091 310.9493 311.0894 311.2296 311.3697 311.5098 311.6499 311.7900 311.9300 312.0701 312.2102 312.3502 312.4902 312.6302 312.7702 312.9102 313.0502 313.1902 313.3301 313.4701 313.6100 313.7500 313.8899 314.0298 314.1697 314.3095 314.4494 314.5893 314.7291 314.8690 315.0088 315.1486 315.2884 315.4282 315.5680 315.7077 315.8475 315.9872 316.1269 316.2667 316.4064 316.5461 316.6858 316.8254 316.9651 317.1048 317.2444 317.3840 317.5236 317.6632 317.8028 317.9424 318.0820 318.2216 318.3611 318.5006 318.6402 318.7797 318.9192 319.0587 319.1982 319.3376 319.4771 319.6165 319.7560 319.8954 320.0348 320.1742 320.3136 320.4530 320.5923 320.7317 320.8710 321.0104 321.1497 321.2890 321.4283 321.5676 321.7068 321.8461 321.9854 322.1246 322.2638 322.4030 322.5422 322.6814 322.8206 322.9598 323.0990 323.2381 323.3772 323.5164 323.6555 323.7946 323.9337 324.0727 324.2118 324.3509 324.4899 324.6289 324.7679 324.9070 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20251028T124309.8Z 9432.529974 122 1 9.96 2 54.44 94.01 121.30 135.76 0.00 1 0.00 1 0 17 1.037e-02 7.403e-03 4.867e-03 2.988e-03 2.055424e-01 1.495970e-03 2.148892e-03 -6.000000e+00 5.811982e-03 228.43 -2.00 3.04 -2.00 315.43 0.00e+00 8.022234e-04 1.448541e-04 2.158677e-05 -6.000000e+00 2.648315e-04 291.54 -2.00 20.00 -2.00 314.67 0.00e+00 1.714 0.000 302.00 328.00 3 4.6285e+00 3.8543e-03 1.9196e-02 -6.0000e+00 1.4433e-02 3.4672e-02 4.2942e-03 9.2245e-03 -6.0000e+00 1.5632e-02 2.9253e-03 2.4605e-03 4.4583e-03 -6.0000e+00 9.3521e-03 -5.5022e-03 1.1294e-03 1.3494e-03 -6.0000e+00 4.0568e-03 7.5468e-04 3.8203e-04 7.8778e-05 1.4547e-05 -6.0000e+00 2.5930e-04 6.2887e-03 0.0000e+00 12 9 1 12 1 1 54.33 25.38 0.36 0.00629 0.00916 4 15 1 5 0 1991.040 33.50 20.00 25.38 29.34 4.0 1010.90 232 399 -1056 -342 -1091 -3149 -3011 -651 2519 1308 -2003 -2049 -1764 859 604 521 -71 595 2084 1670 1201 -403 996 956 938 724 -294 759 -969 557 -443 476 1123 -445 -1890 -3792 -2998 -1545 247 -720 -577 -1148 -1089 -296 479 -33 -725 -1315 -1613 55 1157 594 534 1063 1216 487 1043 583 384 101 1014 565 1592 1914 874 -564 -409 -1167 804 436 444 511 780 815 533 -239 -1056 -1378 -992 -1093 -880 -1363 -1493 -1742 -1366 -188 -32 343 883 1242 585 -106 -764 -171 -238 -277 550 1031 537 43 -700 -546 -1142 -474 -787 -376 -1084 -592 -150 331 768 408 530 142 158 -88 -197 -464 110 319 -15 111 352 396 564 -21 146 887 713 -69 190 -91 -337 -213 21 -30 142 363 227 147 -70 -836 -738 65 112 -306 -99 -274 -764 -771 -183 768 389 -594 -607 -582 314 233 220 -31 264 942 783 539 -180 474 448 461 370 -152 360 -460 252 -213 225 572 -238 -938 -1833 -1566 -866 154 -503 -438 -861 -841 -228 365 -25 -545 -1013 -1208 40 870 456 431 896 999 408 886 496 320 83 853 512 1475 1888 834 -520 -359 -984 695 413 442 533 815 824 531 -227 -946 -1148 -841 -991 -852 -1397 -1567 -1900 -1521 -223 -38 427 1103 1501 686 -118 -809 -177 -245 -301 629 1248 702 56 -862 -642 -1313 -554 -973 -472 -1428 -780 -205 459 1080 585 759 197 208 -112 -246 -579 146 440 -21 152 490 530 741 -26 179 1105 904 -91 252 -124 -465 -301 31 -45 215 562 359 228 -105 -1267 -1081 SS 20251028T124851.1Z 9432.533924 126 1 30.15 2 53.08 93.65 120.39 134.80 0.00 1 0.00 1 0 17 9.316e-03 6.694e-03 1.424e-03 9.356e-04 1.999275e-01 4.707127e-04 2.101517e-03 -6.000000e+00 5.217756e-03 228.43 -2.00 3.04 -2.00 315.16 0.00e+00 9.060103e-04 4.300219e-05 2.253064e-05 -6.000000e+00 2.378367e-04 291.54 -2.00 20.00 -2.00 314.43 0.00e+00 1.661 0.000 302.00 328.00 3 3.7422e+00 1.2089e-03 1.8621e-02 -6.0000e+00 1.2957e-02 3.4570e-02 1.3439e-03 9.0099e-03 -6.0000e+00 1.4035e-02 -9.1512e-04 7.7066e-04 4.3431e-03 -6.0000e+00 8.3967e-03 -3.2718e-03 3.5014e-04 1.3494e-03 -6.0000e+00 3.6410e-03 1.9507e-03 4.6931e-05 2.4645e-05 1.4646e-05 -6.0000e+00 2.3288e-04 8.6126e-03 0.0000e+00 11 8 0 10 0 0 99.86 25.41 0.43 0.00861 0.00897 71 71 1 5 0 424.540 33.50 20.00 25.41 29.86 4.0 1014.66 -293 -133 -517 -2045 -3247 -2641 -920 562 836 -446 -2113 -1507 -649 123 1746 422 286 447 1034 1753 1041 899 1392 1084 615 645 159 -16 -590 64 1049 1028 1725 -491 -2617 -2855 -2748 -1289 -714 -179 -741 -615 -331 -556 110 -320 -621 -630 -870 -227 356 500 709 778 557 854 758 556 361 11 682 1259 1318 1900 731 -295 -681 -999 398 540 586 601 484 658 342 -7 -544 -1542 -982 -890 -1184 -1207 -1863 -1647 -1031 -491 -121 324 687 538 507 65 -257 -166 -49 -214 277 883 677 69 -232 -753 -949 -274 -762 -773 -627 -646 -75 366 633 529 475 162 -98 8 -133 -101 195 206 -5 66 379 472 646 350 30 528 335 214 86 -112 -162 -173 22 -29 114 288 289 -69 -229 -665 -716 -88 -43 -171 -634 -947 -723 -261 177 272 -153 -710 -502 -239 48 753 189 131 210 498 866 529 447 695 538 321 348 86 -8 -292 30 517 541 916 -276 -1371 -1521 -1497 -759 -477 -132 -571 -468 -258 -438 86 -250 -498 -487 -652 -167 272 389 578 666 469 725 657 482 306 9 586 1152 1252 1839 717 -277 -606 -850 349 519 596 615 499 681 334 -7 -487 -1290 -834 -812 -1165 -1258 -2009 -1769 -1176 -579 -145 403 858 654 590 72 -275 -167 -51 -238 325 1063 849 86 -283 -876 -1069 -314 -931 -969 -818 -851 -99 509 898 764 660 216 -127 9 -163 -128 256 284 -6 91 526 629 840 451 37 646 420 277 113 -152 -222 -243 31 -42 168 434 442 -104 -346 -973 -1047 SS 20251028T125403.5Z 9432.537540 129 1 29.74 2 51.84 93.32 119.55 133.95 0.00 1 0.00 1 0 17 9.589e-03 7.154e-03 2.933e-03 1.842e-03 1.943417e-01 9.245085e-04 2.038518e-03 -6.000000e+00 5.370655e-03 228.43 -2.00 3.04 -2.00 315.32 0.00e+00 9.584871e-04 8.710165e-05 2.340226e-05 -6.000000e+00 2.447986e-04 291.54 -2.00 20.00 -2.00 314.57 0.00e+00 1.615 0.000 302.00 328.00 3 5.0582e+00 2.3800e-03 1.8108e-02 -6.0000e+00 1.3336e-02 4.2544e-02 2.6506e-03 8.7733e-03 -6.0000e+00 1.4446e-02 1.6441e-03 1.5174e-03 4.2277e-03 -6.0000e+00 8.6427e-03 -4.5571e-03 6.9272e-04 1.3383e-03 -6.0000e+00 3.7478e-03 5.5030e-04 8.0598e-05 4.8679e-05 1.3841e-05 -6.0000e+00 2.3969e-04 8.3851e-03 0.0000e+00 11 8 0 10 0 0 99.91 25.44 0.35 0.00839 0.00899 12 12 1 5 0 2477.820 33.50 20.01 25.44 30.30 4.0 1017.41 -552 806 -411 -1165 -3004 -1529 -1242 897 1493 -1225 -435 -1409 -232 66 996 598 -794 765 329 977 770 1383 1880 784 598 -146 826 456 -1628 -466 1143 592 2249 -382 -3426 -2678 -3446 -1396 -10 -513 -321 -857 -341 -311 -355 -460 -361 -584 -719 -396 668 513 461 957 508 1039 658 391 390 299 889 848 1253 2129 727 -294 -424 -1066 412 546 497 799 556 764 299 -239 -989 -1766 -1184 -1202 -1045 -872 -1890 -1612 -1214 -187 -132 374 849 1054 668 6 -377 -367 146 -684 120 1039 330 397 -299 -615 -965 -651 -579 -821 -992 -556 21 416 784 797 403 213 -301 -438 -260 -202 210 55 8 275 486 357 485 224 -156 299 393 406 -120 160 108 42 -28 -101 102 492 305 -139 -112 -763 -857 -158 247 -129 -341 -773 -399 -312 248 457 -403 -136 -444 -80 24 403 265 -364 354 147 447 360 628 857 380 304 -77 432 223 -744 -219 552 284 1147 -207 -1744 -1292 -1822 -783 -6 -377 -241 -669 -272 -250 -284 -368 -281 -440 -524 -300 493 406 383 784 428 882 571 339 331 251 762 779 1176 2114 733 -271 -375 -904 359 515 492 825 577 767 298 -227 -843 -1487 -1009 -1087 -1003 -875 -2047 -1804 -1376 -216 -161 473 1076 1294 798 6 -389 -375 154 -760 139 1263 415 517 -367 -730 -1126 -737 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