File name: Pandora282s1_Ilo-UNAM_20251031_L2Fit_fout2c3d20250118p1-8.txt File generation date: 20251101T043325.2Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 282 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora282_OF_v2d20240118.txt Instrument calibration file used: Pandora282s1_CF_v3d20250118.txt Level 1 file used: Pandora282s1_Ilo-UNAM_20251031_L1_smca1c3d20250118p1-8.txt Full location name: Grupo de Investigacion en Ciencias de la Atmosfera, UNAM, Peru Short location name: Ilo-UNAM Country of location: Peru Location latitude [deg]: -17.6020 Location longitude [deg]: -71.3389 Location altitude [m]: 85 Local noon date: 20251031 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 202 344 Nominal wavelengths inside fitting window [nm]: 305.0533 305.1939 305.3345 305.4751 305.6156 305.7562 305.8968 306.0373 306.1778 306.3184 306.4589 306.5994 306.7399 306.8803 307.0208 307.1613 307.3017 307.4421 307.5825 307.7230 307.8634 308.0037 308.1441 308.2845 308.4248 308.5652 308.7055 308.8458 308.9861 309.1264 309.2667 309.4070 309.5473 309.6875 309.8278 309.9680 310.1082 310.2484 310.3886 310.5288 310.6690 310.8091 310.9493 311.0894 311.2296 311.3697 311.5098 311.6499 311.7900 311.9300 312.0701 312.2102 312.3502 312.4902 312.6302 312.7702 312.9102 313.0502 313.1902 313.3301 313.4701 313.6100 313.7500 313.8899 314.0298 314.1697 314.3095 314.4494 314.5893 314.7291 314.8690 315.0088 315.1486 315.2884 315.4282 315.5680 315.7077 315.8475 315.9872 316.1269 316.2667 316.4064 316.5461 316.6858 316.8254 316.9651 317.1048 317.2444 317.3840 317.5236 317.6632 317.8028 317.9424 318.0820 318.2216 318.3611 318.5006 318.6402 318.7797 318.9192 319.0587 319.1982 319.3376 319.4771 319.6165 319.7560 319.8954 320.0348 320.1742 320.3136 320.4530 320.5923 320.7317 320.8710 321.0104 321.1497 321.2890 321.4283 321.5676 321.7068 321.8461 321.9854 322.1246 322.2638 322.4030 322.5422 322.6814 322.8206 322.9598 323.0990 323.2381 323.3772 323.5164 323.6555 323.7946 323.9337 324.0727 324.2118 324.3509 324.4899 324.6289 324.7679 324.9070 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20251031T134631.5Z 9435.573976 238 1 30.08 2 39.12 91.18 143.69 142.92 0.00 1 0.00 1 0 17 8.585e-03 6.866e-03 1.400e-03 1.059e-03 1.574259e-01 5.370466e-04 1.675458e-03 -6.000000e+00 4.807737e-03 228.40 -2.00 3.04 -2.00 314.39 0.00e+00 3.695167e-04 4.244402e-05 1.894739e-05 -6.000000e+00 2.192114e-04 291.61 -2.00 20.00 -2.00 313.75 0.00e+00 1.288 0.000 302.00 328.00 3 4.4169e+00 1.3683e-03 1.4499e-02 -6.0000e+00 1.1937e-02 3.6020e-02 1.5153e-03 7.0671e-03 -6.0000e+00 1.2931e-02 -1.3575e-03 8.7187e-04 3.4355e-03 -6.0000e+00 7.7365e-03 -3.1259e-03 3.8708e-04 9.7443e-04 -6.0000e+00 3.3556e-03 1.5567e-03 -2.1654e-05 2.7780e-05 1.1989e-05 -6.0000e+00 2.1458e-04 7.8819e-03 0.0000e+00 11 9 0 11 8 0 99.92 25.62 0.45 0.00788 0.00772 60 60 1 5 0 501.300 33.75 20.01 25.62 29.70 3.9 1012.88 -77 199 291 -1805 -2370 -2051 -319 1596 979 -21 -1080 -1177 -927 175 1229 382 -38 322 714 1660 542 350 1313 875 682 622 338 -122 -914 245 685 739 1600 -304 -2419 -2493 -2736 -1227 -605 -267 -743 -799 -413 -827 -187 -235 -569 -709 -750 -537 528 494 786 797 739 663 602 493 524 75 764 1185 1582 1712 788 -275 -640 -1064 196 817 610 769 426 705 461 20 -529 -1334 -1134 -1013 -1041 -1292 -1779 -1535 -1120 -487 11 235 667 523 398 26 -247 -220 -270 -243 395 1122 431 231 -119 -611 -1032 -426 -779 -833 -890 -714 -117 470 667 544 575 283 -159 -250 -266 -158 169 138 -77 179 417 497 502 345 174 555 295 329 101 13 -12 -104 -82 53 -54 249 190 -34 -185 -588 -784 -32 82 121 -752 -853 -744 -120 612 421 -10 -472 -506 -406 85 617 209 -21 181 410 972 308 194 772 510 415 392 213 -71 -521 132 378 429 928 -185 -1452 -1425 -1601 -818 -431 -210 -608 -675 -356 -720 -160 -200 -474 -593 -603 -420 424 424 669 708 672 609 537 439 478 68 706 1111 1523 1747 808 -270 -593 -936 177 798 629 795 444 743 459 19 -464 -1139 -976 -925 -1015 -1328 -1875 -1670 -1245 -580 13 294 840 640 470 29 -258 -225 -285 -267 455 1360 542 289 -146 -719 -1141 -480 -931 -1018 -1133 -910 -154 624 927 767 777 368 -195 -295 -320 -189 208 178 -104 240 546 649 643 422 208 644 361 412 127 17 -15 -138 -111 74 -77 362 272 -50 -262 -811 -1091 SS 20251031T135128.2Z 9435.577410 241 1 2.46 2 37.94 90.84 143.01 141.35 0.00 1 0.00 1 0 17 9.072e-03 7.201e-03 3.101e-03 2.454e-03 1.530862e-01 1.246808e-03 1.621376e-03 -6.000000e+00 5.085886e-03 228.40 -2.00 3.04 -2.00 314.11 0.00e+00 5.607667e-04 9.427951e-05 1.076879e-05 -6.000000e+00 2.315694e-04 291.61 -2.00 20.00 -2.00 313.51 0.00e+00 1.267 0.000 302.00 328.00 3 3.4621e+00 3.1720e-03 1.4220e-02 -6.0000e+00 1.2629e-02 2.6948e-02 3.5074e-03 6.8896e-03 -6.0000e+00 1.3674e-02 5.2731e-04 2.0203e-03 3.3228e-03 -6.0000e+00 8.1809e-03 -3.6096e-03 8.9172e-04 9.7924e-04 -6.0000e+00 3.5541e-03 4.1728e-03 1.1742e-03 6.4138e-05 1.1616e-05 -6.0000e+00 2.2663e-04 -1.8492e-03 0.0000e+00 12 9 1 12 1 1 62.18 25.64 0.37 -0.00185 0.00697 4 61 1 5 0 490.960 33.75 20.00 25.64 29.84 3.9 1013.86 629 -79 1248 -1518 -1864 -2694 -2453 1521 1309 -976 -861 -1319 -207 110 1131 453 -181 805 538 714 541 1087 -16 1043 890 761 358 378 -779 -640 1443 747 1441 66 -2052 -2969 -2438 -1211 -474 334 -870 -529 -176 -736 -560 -257 -913 -508 -1113 -516 549 780 773 1535 842 511 674 258 188 -285 380 1273 1949 2142 602 13 -172 -1063 161 286 729 786 648 613 -86 -158 -791 -1795 -1168 -1148 -987 -1066 -1807 -1450 -1074 -394 37 -119 603 808 88 398 -174 -401 -55 -497 272 1023 374 184 -271 -805 -825 -278 -436 -520 -693 -594 -294 230 555 835 371 342 144 22 -252 -174 250 225 -178 215 224 487 854 473 258 496 391 235 -69 -142 -239 -36 -343 -153 60 324 266 55 -196 -601 -790 285 -37 576 -698 -780 -1066 -1016 642 617 -466 -392 -624 -101 57 616 257 -105 466 321 437 324 660 -10 638 569 483 236 231 -458 -375 853 448 916 42 -1266 -1757 -1556 -812 -351 267 -737 -461 -152 -641 -482 -220 -789 -419 -916 -412 449 656 679 1353 764 470 610 233 172 -259 352 1211 1925 2174 618 12 -159 -965 145 276 749 821 682 645 -86 -151 -719 -1566 -1021 -1047 -974 -1088 -1923 -1591 -1219 -454 44 -147 746 969 103 435 -181 -402 -56 -529 308 1201 462 226 -321 -933 -920 -315 -517 -639 -865 -752 -384 307 759 1151 505 441 178 27 -297 -207 309 288 -238 287 293 625 1058 576 303 582 469 293 -87 -180 -304 -47 -462 -214 84 462 378 79 -274 -835 -1067 SS 20251031T135618.7Z 9435.580772 244 1 30.07 2 36.79 90.49 142.33 139.86 0.00 1 0.00 1 0 17 8.323e-03 6.804e-03 7.086e-04 5.618e-04 1.524234e-01 2.855047e-04 1.621010e-03 -6.000000e+00 4.661241e-03 228.40 -2.00 3.04 -2.00 314.10 0.00e+00 5.413499e-04 2.142475e-05 1.123371e-05 -6.000000e+00 2.125264e-04 291.61 -2.00 20.00 -2.00 313.50 0.00e+00 1.248 0.000 302.00 328.00 3 3.2581e+00 7.2606e-04 1.4047e-02 -6.0000e+00 1.1574e-02 2.8581e-02 8.0307e-04 6.8676e-03 -6.0000e+00 1.2537e-02 -6.8991e-04 4.6280e-04 3.3204e-03 -6.0000e+00 7.5007e-03 -3.7834e-03 2.0392e-04 9.7881e-04 -6.0000e+00 3.2534e-03 5.2203e-03 -2.7111e-05 1.4666e-05 1.1743e-05 -6.0000e+00 2.0803e-04 7.7064e-03 0.0000e+00 11 9 0 11 8 0 99.49 25.67 0.40 0.00771 0.00750 97 97 1 5 0 309.890 33.75 20.01 25.67 30.26 4.0 1017.71 146 284 266 -1664 -2428 -1627 -191 1137 1142 361 -1413 -907 -589 115 898 318 213 606 680 1351 720 436 815 894 373 593 146 -330 -604 325 1069 1166 1537 -432 -2413 -2754 -2433 -1419 -610 -272 -726 -740 -502 -734 -325 -299 -656 -573 -938 -428 474 562 853 1024 659 916 804 593 387 213 613 1142 1407 1831 617 -105 -727 -974 326 588 592 656 492 741 456 -40 -574 -1335 -876 -960 -1123 -1144 -1837 -1555 -1041 -546 -93 154 682 570 498 238 -213 -228 -121 -57 253 864 602 105 -150 -713 -787 -438 -673 -875 -668 -706 -188 348 673 541 432 291 -87 -151 -100 -160 64 271 -117 152 439 427 579 294 97 512 332 267 187 -67 -162 -121 -98 40 41 359 148 -17 -188 -614 -744 66 132 124 -767 -1022 -637 -77 483 540 170 -681 -427 -287 60 490 180 122 351 404 820 448 265 497 546 239 391 96 -203 -353 188 632 693 972 -274 -1486 -1692 -1545 -950 -450 -217 -611 -643 -445 -635 -286 -263 -562 -485 -765 -351 386 486 743 901 594 832 744 548 350 191 563 1078 1385 1847 627 -103 -667 -875 300 577 603 699 514 772 462 -39 -515 -1147 -755 -894 -1098 -1191 -1991 -1689 -1168 -641 -112 187 834 696 577 264 -226 -232 -123 -62 283 1031 752 130 -180 -814 -866 -492 -790 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