File name: Pandora282s1_Ilo-UNAM_20251102_L2Fit_fout2c3d20250118p1-8.txt File generation date: 20251103T043517.2Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 282 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora282_OF_v2d20240118.txt Instrument calibration file used: Pandora282s1_CF_v3d20250118.txt Level 1 file used: Pandora282s1_Ilo-UNAM_20251102_L1_smca1c3d20250118p1-8.txt Full location name: Grupo de Investigacion en Ciencias de la Atmosfera, UNAM, Peru Short location name: Ilo-UNAM Country of location: Peru Location latitude [deg]: -17.6020 Location longitude [deg]: -71.3389 Location altitude [m]: 85 Local noon date: 20251102 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 202 344 Nominal wavelengths inside fitting window [nm]: 305.0533 305.1939 305.3345 305.4751 305.6156 305.7562 305.8968 306.0373 306.1778 306.3184 306.4589 306.5994 306.7399 306.8803 307.0208 307.1613 307.3017 307.4421 307.5825 307.7230 307.8634 308.0037 308.1441 308.2845 308.4248 308.5652 308.7055 308.8458 308.9861 309.1264 309.2667 309.4070 309.5473 309.6875 309.8278 309.9680 310.1082 310.2484 310.3886 310.5288 310.6690 310.8091 310.9493 311.0894 311.2296 311.3697 311.5098 311.6499 311.7900 311.9300 312.0701 312.2102 312.3502 312.4902 312.6302 312.7702 312.9102 313.0502 313.1902 313.3301 313.4701 313.6100 313.7500 313.8899 314.0298 314.1697 314.3095 314.4494 314.5893 314.7291 314.8690 315.0088 315.1486 315.2884 315.4282 315.5680 315.7077 315.8475 315.9872 316.1269 316.2667 316.4064 316.5461 316.6858 316.8254 316.9651 317.1048 317.2444 317.3840 317.5236 317.6632 317.8028 317.9424 318.0820 318.2216 318.3611 318.5006 318.6402 318.7797 318.9192 319.0587 319.1982 319.3376 319.4771 319.6165 319.7560 319.8954 320.0348 320.1742 320.3136 320.4530 320.5923 320.7317 320.8710 321.0104 321.1497 321.2890 321.4283 321.5676 321.7068 321.8461 321.9854 322.1246 322.2638 322.4030 322.5422 322.6814 322.8206 322.9598 323.0990 323.2381 323.3772 323.5164 323.6555 323.7946 323.9337 324.0727 324.2118 324.3509 324.4899 324.6289 324.7679 324.9070 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20251102T144730.6Z 9437.616326 327 1 28.93 2 24.47 87.49 158.94 140.01 0.00 1 0.00 1 0 17 1.016e-02 8.025e-03 3.093e-03 2.364e-03 1.398554e-01 1.202715e-03 1.483950e-03 -6.000000e+00 5.692682e-03 228.38 -2.00 3.04 -2.00 314.29 0.00e+00 3.388510e-04 9.356053e-05 2.016467e-05 -6.000000e+00 2.596012e-04 291.65 -2.00 20.00 -2.00 313.68 0.00e+00 1.098 0.000 302.00 328.00 3 6.0699e+00 3.0630e-03 1.2488e-02 -6.0000e+00 1.4134e-02 5.5892e-02 3.3887e-03 6.2547e-03 -6.0000e+00 1.5310e-02 -1.8078e-03 1.9497e-03 3.0415e-03 -6.0000e+00 9.1601e-03 -4.9073e-03 8.6440e-04 8.6193e-04 -6.0000e+00 3.9739e-03 3.7005e-04 2.6770e-05 6.1998e-05 1.0669e-05 -6.0000e+00 2.5406e-04 7.1547e-03 0.0000e+00 11 8 0 10 0 0 99.77 25.81 0.37 0.00715 0.00736 8 8 1 5 0 3615.870 33.75 20.01 25.81 30.97 3.9 1021.86 -139 1066 -456 -1511 -2771 -1767 -606 760 99 -146 -1192 -1759 879 1419 1516 -224 503 700 627 1074 242 830 395 1247 317 117 -36 840 -1078 -253 2085 1484 2476 -697 -2265 -3999 -3541 -1701 -861 193 -238 -1358 -337 -418 133 -200 -649 -513 -1710 -573 918 124 728 346 442 669 560 541 79 385 765 1400 1479 2247 629 195 -839 -1013 -54 394 629 1102 314 598 1362 -183 -1275 -1552 -930 -1533 -1326 -842 -1944 -1778 -538 -232 -86 507 658 877 661 -315 -549 -328 343 -728 228 864 774 765 -112 -413 -1451 -530 -579 -808 -1079 -791 -102 171 873 598 415 322 -442 -213 -602 -454 -87 387 84 493 608 559 501 140 -345 493 253 83 82 -4 147 -178 214 256 11 408 93 74 -459 -516 -859 -59 476 -207 -637 -1015 -655 -213 295 43 -66 -520 -754 400 714 781 -126 283 398 365 639 148 492 236 771 191 73 -23 515 -611 -135 1115 835 1470 -438 -1314 -2242 -2140 -1082 -651 157 -198 -1175 -295 -368 115 -173 -545 -439 -1414 -455 743 108 654 305 398 605 516 496 71 342 694 1345 1438 2292 648 193 -752 -914 -50 388 641 1168 337 623 1410 -173 -1150 -1285 -769 -1420 -1281 -888 -2074 -1958 -624 -274 -108 619 809 1103 770 -355 -588 -326 348 -766 261 1022 982 960 -133 -479 -1593 -591 -672 -999 -1391 -1003 -133 233 1238 816 571 409 -541 -254 -704 -550 -107 512 111 645 821 725 613 173 -403 553 299 104 101 -5 186 -231 292 351 15 589 138 108 -651 -710 -1150 SS 20251102T145157.7Z 9437.619418 330 1 1.49 2 23.41 87.05 158.29 137.71 0.00 1 0.00 1 0 17 8.369e-03 7.126e-03 1.574e-03 1.309e-03 1.356075e-01 6.681578e-04 1.450366e-03 -6.000000e+00 4.686792e-03 228.38 -2.00 3.04 -2.00 313.74 0.00e+00 3.814755e-04 4.732472e-05 1.400044e-05 -6.000000e+00 2.137619e-04 291.65 -2.00 20.00 -2.00 313.19 0.00e+00 1.089 0.000 302.00 328.00 3 2.0812e+00 1.6949e-03 1.2323e-02 -6.0000e+00 1.1636e-02 2.4123e-02 1.8699e-03 6.0956e-03 -6.0000e+00 1.2605e-02 -1.0697e-03 1.0802e-03 2.9570e-03 -6.0000e+00 7.5419e-03 -3.6532e-03 4.7323e-04 8.4009e-04 -6.0000e+00 3.2713e-03 2.0541e-02 -1.1453e-04 3.4076e-05 1.0822e-05 -6.0000e+00 2.0920e-04 8.1576e-03 0.0000e+00 12 9 1 12 1 1 90.57 25.84 0.40 0.00816 0.00730 13 282 1 5 0 106.120 33.75 20.00 25.84 31.24 4.0 1023.41 615 273 -12 -1444 -2347 -1593 -254 1178 936 228 -839 -828 -466 442 696 351 -32 381 812 1301 634 241 866 988 370 467 -55 -168 -644 228 1037 1131 1659 -862 -2323 -2653 -2454 -1226 -675 -537 -507 -799 -719 -751 -192 -423 -883 -678 -1067 -451 521 938 691 1084 1038 1153 754 321 382 345 589 1248 1603 1820 796 -167 -725 -709 142 620 576 721 744 595 559 -226 -492 -1261 -916 -1016 -1306 -1202 -1820 -1506 -1102 -687 -5 360 670 403 334 108 -185 -291 -261 -285 259 854 704 168 -51 -582 -892 -310 -796 -944 -632 -795 -175 547 526 623 570 153 -107 -140 -37 -230 103 178 41 109 592 426 779 352 -24 732 178 194 53 -82 1 -235 -162 55 84 310 211 -74 -260 -581 -711 306 146 -6 -721 -1101 -726 -114 561 478 122 -432 -416 -254 246 413 217 -20 239 520 852 411 158 567 652 248 322 -38 -111 -401 138 640 730 1094 -578 -1486 -1676 -1619 -863 -517 -452 -438 -713 -656 -671 -173 -380 -774 -581 -901 -378 436 808 622 986 965 1051 702 299 357 320 544 1191 1599 1872 821 -164 -678 -641 128 604 590 754 782 624 567 -218 -444 -1113 -809 -945 -1290 -1238 -1958 -1631 -1241 -796 -6 435 816 488 391 120 -194 -290 -268 -303 287 992 858 204 -60 -657 -991 -343 -933 -1152 -783 -1007 -223 712 705 841 752 195 -129 -162 -43 -272 125 224 53 141 761 538 945 417 -28 843 206 234 65 -104 1 -297 -212 75 116 426 296 -102 -357 -793 -944 SS 20251102T150116.7Z 9437.625888 333 1 9.09 2 21.19 86.02 156.84 133.30 0.00 1 0.00 1 0 17 9.940e-03 8.169e-03 3.788e-03 3.046e-03 1.338957e-01 1.548084e-03 1.428023e-03 -6.000000e+00 5.566935e-03 228.38 -2.00 3.04 -2.00 313.97 0.00e+00 5.910952e-04 1.143323e-04 1.141831e-05 -6.000000e+00 2.538784e-04 291.65 -2.00 20.00 -2.00 313.39 0.00e+00 1.072 0.000 302.00 328.00 3 5.2878e+00 3.9366e-03 1.2147e-02 -6.0000e+00 1.3822e-02 4.2067e-02 4.3523e-03 6.0643e-03 -6.0000e+00 1.4972e-02 4.1835e-04 2.5065e-03 2.9213e-03 -6.0000e+00 8.9579e-03 -5.2902e-03 1.1022e-03 8.8318e-04 -6.0000e+00 3.8859e-03 8.4298e-04 -3.5629e-05 7.9392e-05 1.0462e-05 -6.0000e+00 2.4846e-04 7.4454e-03 0.0000e+00 12 9 1 12 1 1 99.93 25.89 0.41 0.00745 0.00718 3 13 1 5 0 2270.220 33.75 20.01 25.89 32.11 3.8 1027.37 283 1774 348 -1840 -2844 -1954 -618 -683 1617 346 -1097 -1553 -89 1226 735 -188 645 365 543 804 1255 753 579 1003 -23 816 401 459 -985 401 1259 678 2197 -964 -2611 -2697 -3655 -1141 -1452 -440 -471 -1094 -310 -852 -70 -371 -1053 -553 -351 -50 410 812 430 853 714 1253 -309 274 120 480 740 1049 1661 2174 250 -436 -548 -716 661 712 800 1211 1016 864 1401 -665 -516 -1990 -928 -1465 -1448 -1820 -1673 -1914 -853 294 50 391 1001 656 754 -237 -567 59 -362 -555 42 617 733 352 -697 -873 -1290 -735 -316 -628 -630 -75 -692 -18 887 554 1170 181 -13 -269 -440 -132 325 -134 41 336 338 -21 565 38 193 307 155 530 260 18 -305 -42 209 -66 384 162 506 45 -177 -771 -967 135 829 166 -879 -1176 -807 -263 -302 777 164 -535 -744 -42 645 405 -112 384 220 335 508 804 473 365 656 -15 539 264 298 -588 240 763 405 1376 -639 -1598 -1569 -2325 -769 -1110 -367 -404 -974 -280 -777 -62 -333 -919 -483 -292 -41 340 712 375 772 660 1160 -295 259 111 440 692 994 1683 2211 258 -426 -504 -654 585 684 808 1274 1078 893 1422 -650 -470 -1682 -780 -1376 -1440 -1898 -1768 -2096 -944 347 60 486 1249 799 885 -265 -596 60 -362 -607 47 735 896 427 -836 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