File name: Pandora282s1_Ilo-UNAM_20251104_L2Fit_fout2c3d20250118p1-8.txt File generation date: 20251105T043329.7Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 282 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora282_OF_v2d20240118.txt Instrument calibration file used: Pandora282s1_CF_v3d20250118.txt Level 1 file used: Pandora282s1_Ilo-UNAM_20251104_L1_smca1c3d20250118p1-8.txt Full location name: Grupo de Investigacion en Ciencias de la Atmosfera, UNAM, Peru Short location name: Ilo-UNAM Country of location: Peru Location latitude [deg]: -17.6020 Location longitude [deg]: -71.3389 Location altitude [m]: 85 Local noon date: 20251104 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 202 344 Nominal wavelengths inside fitting window [nm]: 305.0533 305.1939 305.3345 305.4751 305.6156 305.7562 305.8968 306.0373 306.1778 306.3184 306.4589 306.5994 306.7399 306.8803 307.0208 307.1613 307.3017 307.4421 307.5825 307.7230 307.8634 308.0037 308.1441 308.2845 308.4248 308.5652 308.7055 308.8458 308.9861 309.1264 309.2667 309.4070 309.5473 309.6875 309.8278 309.9680 310.1082 310.2484 310.3886 310.5288 310.6690 310.8091 310.9493 311.0894 311.2296 311.3697 311.5098 311.6499 311.7900 311.9300 312.0701 312.2102 312.3502 312.4902 312.6302 312.7702 312.9102 313.0502 313.1902 313.3301 313.4701 313.6100 313.7500 313.8899 314.0298 314.1697 314.3095 314.4494 314.5893 314.7291 314.8690 315.0088 315.1486 315.2884 315.4282 315.5680 315.7077 315.8475 315.9872 316.1269 316.2667 316.4064 316.5461 316.6858 316.8254 316.9651 317.1048 317.2444 317.3840 317.5236 317.6632 317.8028 317.9424 318.0820 318.2216 318.3611 318.5006 318.6402 318.7797 318.9192 319.0587 319.1982 319.3376 319.4771 319.6165 319.7560 319.8954 320.0348 320.1742 320.3136 320.4530 320.5923 320.7317 320.8710 321.0104 321.1497 321.2890 321.4283 321.5676 321.7068 321.8461 321.9854 322.1246 322.2638 322.4030 322.5422 322.6814 322.8206 322.9598 323.0990 323.2381 323.3772 323.5164 323.6555 323.7946 323.9337 324.0727 324.2118 324.3509 324.4899 324.6289 324.7679 324.9070 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20251104T123525.5Z 9439.524600 291 1 29.95 2 55.78 97.13 139.20 271.06 0.00 1 0.00 1 0 17 9.070e-03 6.676e-03 1.634e-03 9.801e-04 2.114132e-01 4.925055e-04 2.223943e-03 -6.000000e+00 5.078670e-03 228.36 -2.00 3.04 -2.00 315.54 0.00e+00 3.587876e-04 4.831612e-05 5.922962e-05 -6.000000e+00 2.317042e-04 291.69 -2.00 20.00 -2.00 314.77 0.00e+00 1.772 0.000 302.00 328.00 3 3.6754e+00 1.2688e-03 1.9816e-02 -6.0000e+00 1.2609e-02 2.0042e-02 1.4131e-03 9.4472e-03 -6.0000e+00 1.3658e-02 2.5823e-04 8.1185e-04 4.5916e-03 -6.0000e+00 8.1725e-03 -3.8009e-03 3.7395e-04 1.2873e-03 -6.0000e+00 3.5449e-03 1.8493e-03 3.2126e-05 2.5969e-05 1.4709e-05 -6.0000e+00 2.2672e-04 8.5201e-03 0.0000e+00 11 8 0 10 0 0 99.96 25.55 0.43 0.00852 0.00876 123 123 1 5 0 243.480 33.50 20.00 25.55 30.13 3.8 1014.48 331 17 -464 -2277 -2401 -2481 97 1214 311 88 -1446 -1300 -906 -31 960 884 214 329 465 1329 611 569 1133 973 709 789 -283 -441 -732 -100 985 1194 1292 -703 -2788 -3382 -2801 -1268 -662 175 -593 -507 -370 -551 8 -65 -265 -712 -1019 -513 560 550 807 973 597 1009 620 323 375 117 593 1167 1553 2063 737 74 -666 -867 312 682 572 727 406 636 370 -149 -875 -1540 -1039 -1148 -1116 -1036 -1798 -1740 -1045 -434 -88 283 768 647 516 -91 -359 -283 -168 -186 310 996 485 88 -146 -797 -895 -393 -719 -865 -665 -678 -167 414 633 586 545 359 -106 -211 -170 -131 80 198 -68 221 471 430 637 291 65 493 413 196 173 -113 -185 -158 -69 -9 81 317 372 -91 -278 -675 -692 88 5 -137 -633 -578 -566 23 319 92 25 -443 -397 -284 -11 354 356 89 140 205 601 285 259 520 441 339 392 -142 -206 -337 -44 453 546 639 -367 -1363 -1590 -1426 -693 -409 119 -443 -372 -279 -420 6 -49 -195 -536 -747 -369 418 417 642 813 489 835 527 274 311 96 497 1043 1431 1930 701 68 -584 -729 271 645 570 758 427 646 354 -135 -746 -1291 -885 -1047 -1090 -1067 -1909 -1916 -1171 -501 -107 357 934 795 613 -103 -384 -285 -176 -205 360 1227 621 113 -183 -958 -1047 -448 -869 -1113 -856 -912 -224 586 912 860 772 491 -138 -263 -209 -167 105 271 -97 312 648 592 828 377 83 609 520 255 237 -160 -254 -223 -100 -15 123 492 588 -142 -419 -1022 -1014 SS 20251104T131016.7Z 9439.548805 313 1 30.29 2 47.52 95.21 147.12 268.75 0.00 1 0.00 1 0 17 9.114e-03 6.974e-03 1.793e-03 1.253e-03 1.777683e-01 6.326501e-04 1.877147e-03 -6.000000e+00 5.103062e-03 228.36 -2.00 3.04 -2.00 314.84 0.00e+00 3.252593e-04 5.417564e-05 2.365316e-05 -6.000000e+00 2.328085e-04 291.69 -2.00 20.00 -2.00 314.13 0.00e+00 1.478 0.000 302.00 328.00 3 4.5275e+00 1.6184e-03 1.6561e-02 -6.0000e+00 1.2669e-02 3.3671e-02 1.7968e-03 7.9483e-03 -6.0000e+00 1.3724e-02 1.0395e-03 1.0320e-03 3.8686e-03 -6.0000e+00 8.2116e-03 -4.2321e-03 4.6361e-04 1.0932e-03 -6.0000e+00 3.5621e-03 1.1118e-03 6.0263e-06 3.3055e-05 1.2889e-05 -6.0000e+00 2.2780e-04 8.2308e-03 0.0000e+00 11 8 0 10 0 0 99.91 25.74 0.34 0.00823 0.00828 35 35 1 5 0 865.190 33.75 20.00 25.74 30.41 3.9 1015.85 -311 365 523 -2111 -3134 -2200 -276 918 834 -154 -1051 -1368 -622 86 930 702 324 417 366 1815 976 441 933 1091 778 657 -10 270 -782 488 873 1174 2126 -369 -2111 -2914 -2825 -1514 -927 -381 -446 -756 -463 -673 -150 -440 -892 -577 -860 -483 707 447 812 941 679 592 705 679 549 -118 600 1090 1688 2018 535 -73 -641 -1283 149 675 537 587 545 763 225 -167 -570 -1549 -890 -1069 -1289 -975 -1832 -1604 -892 -415 -106 365 732 743 615 19 -301 -268 -45 34 106 1098 723 322 -292 -689 -1103 -337 -678 -870 -797 -630 -244 295 679 463 603 142 -204 -316 -133 -208 -67 235 3 335 354 334 611 437 159 309 394 235 45 31 -240 -232 -86 133 46 384 418 -154 -239 -512 -810 -111 129 187 -769 -994 -652 -85 313 318 -57 -408 -528 -244 38 424 348 164 215 182 917 507 225 478 587 440 385 -6 147 -418 247 457 609 1173 -215 -1143 -1618 -1597 -922 -638 -289 -349 -615 -385 -564 -124 -365 -722 -447 -677 -372 560 360 683 828 585 516 626 601 475 -101 527 1018 1618 1962 527 -68 -572 -1150 131 642 539 618 576 782 227 -159 -511 -1293 -748 -960 -1241 -986 -1992 -1728 -1019 -489 -127 452 910 896 715 21 -312 -272 -47 38 123 1340 914 405 -360 -817 -1228 -381 -812 -1069 -1018 -838 -324 410 956 663 829 189 -255 -380 -163 -255 -85 309 4 458 472 445 797 545 194 367 494 302 59 41 -322 -320 -120 190 68 578 617 -234 -351 -729 -1161 SS 20251104T131526.6Z 9439.552391 316 1 29.38 2 46.29 94.92 148.30 268.37 0.00 1 0.00 1 0 17 1.070e-02 7.581e-03 3.600e-03 2.387e-03 1.788429e-01 1.202771e-03 1.888973e-03 -6.000000e+00 5.989230e-03 228.36 -2.00 3.04 -2.00 315.08 0.00e+00 4.989889e-04 1.083701e-04 2.206296e-05 -6.000000e+00 2.732359e-04 291.69 -2.00 20.00 -2.00 314.35 0.00e+00 1.445 0.000 302.00 328.00 3 5.5848e+00 3.0863e-03 1.6313e-02 -6.0000e+00 1.4869e-02 6.0121e-02 3.4292e-03 8.0195e-03 -6.0000e+00 1.6107e-02 -5.9579e-03 1.9691e-03 3.8934e-03 -6.0000e+00 9.6376e-03 -4.2799e-03 8.9223e-04 1.1213e-03 -6.0000e+00 4.1806e-03 3.9480e-04 3.3784e-05 6.3056e-05 1.3146e-05 -6.0000e+00 2.6736e-04 8.2103e-03 0.0000e+00 12 9 1 12 1 1 99.72 25.76 0.35 0.00821 0.00846 7 8 1 5 0 3672.130 33.75 20.00 25.76 30.22 3.9 1014.68 -867 702 606 392 -3549 -3320 -458 354 705 -1761 -1208 -1075 254 -288 1623 485 -385 787 1849 1878 399 585 835 909 1216 365 571 1058 -740 -877 2232 961 2897 -1322 -2938 -3062 -4462 -1449 -676 -752 -433 -778 -438 -214 -676 -458 -927 -538 -766 -415 1637 -317 537 363 524 996 534 229 469 413 647 1075 1415 1919 563 -366 -551 -985 280 700 1051 896 180 852 300 -33 -285 -2121 -402 -605 -1191 -1090 -1669 -1637 -590 -222 142 299 860 565 455 -203 136 -364 -85 -818 151 949 998 467 -255 -842 -1150 -780 -503 -699 -860 -559 -162 41 811 676 339 523 -578 -394 -469 -99 -155 366 -224 469 245 341 867 340 53 452 384 34 99 -192 -60 19 -174 -153 58 605 504 -133 -151 -673 -759 -272 233 204 122 -1076 -945 -133 105 233 -623 -407 -358 92 -118 677 222 -180 372 890 931 205 292 419 479 668 194 301 556 -361 -411 1053 486 1544 -758 -1559 -1550 -2488 -844 -438 -570 -333 -622 -358 -176 -551 -372 -735 -408 -598 -317 1273 -252 443 314 463 885 486 208 415 362 579 965 1367 1854 550 -347 -500 -853 250 668 1040 929 188 860 303 -30 -246 -1830 -346 -547 -1142 -1150 -1783 -1810 -654 -264 169 370 1066 682 535 -230 146 -367 -89 -887 170 1168 1252 583 -316 -966 -1303 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