File name: Pandora282s1_Ilo-UNAM_20251108_L2Fit_fout2c3d20250118p1-8.txt File generation date: 20251110T172039.4Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 282 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora282_OF_v2d20240118.txt Instrument calibration file used: Pandora282s1_CF_v3d20250118.txt Level 1 file used: Pandora282s1_Ilo-UNAM_20251108_L1_smca1c3d20250118p1-8.txt Full location name: Grupo de Investigacion en Ciencias de la Atmosfera, UNAM, Peru Short location name: Ilo-UNAM Country of location: Peru Location latitude [deg]: -17.6020 Location longitude [deg]: -71.3389 Location altitude [m]: 85 Local noon date: 20251108 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 202 344 Nominal wavelengths inside fitting window [nm]: 305.0533 305.1939 305.3345 305.4751 305.6156 305.7562 305.8968 306.0373 306.1778 306.3184 306.4589 306.5994 306.7399 306.8803 307.0208 307.1613 307.3017 307.4421 307.5825 307.7230 307.8634 308.0037 308.1441 308.2845 308.4248 308.5652 308.7055 308.8458 308.9861 309.1264 309.2667 309.4070 309.5473 309.6875 309.8278 309.9680 310.1082 310.2484 310.3886 310.5288 310.6690 310.8091 310.9493 311.0894 311.2296 311.3697 311.5098 311.6499 311.7900 311.9300 312.0701 312.2102 312.3502 312.4902 312.6302 312.7702 312.9102 313.0502 313.1902 313.3301 313.4701 313.6100 313.7500 313.8899 314.0298 314.1697 314.3095 314.4494 314.5893 314.7291 314.8690 315.0088 315.1486 315.2884 315.4282 315.5680 315.7077 315.8475 315.9872 316.1269 316.2667 316.4064 316.5461 316.6858 316.8254 316.9651 317.1048 317.2444 317.3840 317.5236 317.6632 317.8028 317.9424 318.0820 318.2216 318.3611 318.5006 318.6402 318.7797 318.9192 319.0587 319.1982 319.3376 319.4771 319.6165 319.7560 319.8954 320.0348 320.1742 320.3136 320.4530 320.5923 320.7317 320.8710 321.0104 321.1497 321.2890 321.4283 321.5676 321.7068 321.8461 321.9854 322.1246 322.2638 322.4030 322.5422 322.6814 322.8206 322.9598 323.0990 323.2381 323.3772 323.5164 323.6555 323.7946 323.9337 324.0727 324.2118 324.3509 324.4899 324.6289 324.7679 324.9070 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20251108T153304.2Z 9443.647965 427 1 30.33 2 13.42 88.52 124.87 292.78 0.00 1 0.00 1 0 17 8.892e-03 7.542e-03 1.664e-03 1.366e-03 1.283815e-01 6.979390e-04 1.370279e-03 -6.000000e+00 4.978646e-03 228.32 -2.00 3.04 -2.00 313.81 0.00e+00 3.665143e-04 4.984478e-05 1.268147e-05 -6.000000e+00 2.272357e-04 291.78 -2.00 20.00 -2.00 313.25 0.00e+00 1.028 0.000 302.00 328.00 3 5.2366e+00 1.7718e-03 1.1633e-02 -6.0000e+00 1.2359e-02 4.5988e-02 1.9553e-03 5.7652e-03 -6.0000e+00 1.3387e-02 -2.1257e-03 1.1293e-03 2.7968e-03 -6.0000e+00 8.0110e-03 -2.6205e-03 4.9509e-04 7.9646e-04 -6.0000e+00 3.4760e-03 9.3915e-04 2.6375e-06 3.5583e-05 1.0517e-05 -6.0000e+00 2.2226e-04 7.6863e-03 0.0000e+00 11 8 0 10 0 0 99.91 25.86 0.39 0.00769 0.00771 16 16 1 5 0 1895.370 33.75 20.00 25.86 30.23 4.0 1016.39 -319 799 31 -1224 -2102 -2101 -245 1043 890 242 -745 -1078 -221 87 1012 263 155 430 849 1378 1000 438 827 797 424 226 194 -265 -919 -71 907 1519 1793 -617 -2564 -2897 -2822 -1635 -493 -145 -612 -684 -483 -837 -243 -355 -556 -859 -1048 -662 530 114 737 1063 723 1026 684 533 518 311 720 1055 1508 2194 901 -100 -565 -1198 143 770 471 641 536 1009 565 86 -713 -1553 -1097 -1342 -1216 -1263 -1897 -1618 -776 -278 -100 206 616 638 738 -91 -234 -419 -128 -473 -18 1281 868 178 -300 -859 -992 -568 -617 -654 -794 -644 -122 126 635 720 634 365 -341 -342 -158 -204 15 129 -121 104 391 550 708 231 86 393 444 239 66 40 31 -23 47 2 -2 436 238 132 -362 -681 -896 -157 412 16 -591 -940 -879 -105 495 439 125 -368 -521 -115 47 599 158 94 261 525 869 644 276 521 524 291 160 136 -173 -582 -42 546 949 1186 -403 -1647 -1773 -1868 -1162 -392 -121 -551 -605 -436 -761 -217 -315 -503 -743 -867 -558 455 99 663 994 658 939 638 496 471 295 663 1033 1508 2300 948 -100 -534 -1073 130 759 490 695 560 1068 566 81 -633 -1339 -945 -1223 -1175 -1276 -2050 -1802 -875 -323 -123 252 755 792 846 -99 -250 -415 -131 -500 -19 1539 1074 219 -349 -963 -1092 -640 -732 -791 -1000 -810 -158 164 858 982 827 458 -405 -389 -184 -236 19 166 -157 135 495 696 880 275 101 443 525 287 82 48 38 -28 62 2 -2 594 331 181 -503 -922 -1179 SS 20251108T154158.0Z 9443.654144 433 1 30.26 2 11.30 87.52 126.72 292.68 0.00 1 0.00 1 0 17 8.206e-03 7.007e-03 9.376e-04 7.853e-04 1.257383e-01 4.012493e-04 1.343432e-03 -6.000000e+00 4.594910e-03 228.32 -2.00 3.04 -2.00 313.66 0.00e+00 3.795340e-04 2.807285e-05 7.694624e-06 -6.000000e+00 2.097114e-04 291.78 -2.00 20.00 -2.00 313.11 0.00e+00 1.020 0.000 302.00 328.00 3 4.1994e+00 1.0170e-03 1.1505e-02 -6.0000e+00 1.1406e-02 3.7658e-02 1.1222e-03 5.6576e-03 -6.0000e+00 1.2355e-02 9.5390e-05 6.4882e-04 2.7418e-03 -6.0000e+00 7.3935e-03 -4.3371e-03 2.8361e-04 7.8739e-04 -6.0000e+00 3.2082e-03 2.6928e-03 -2.2284e-05 2.0389e-05 1.0124e-05 -6.0000e+00 2.0512e-04 7.3741e-03 0.0000e+00 11 8 0 10 0 0 99.97 25.88 0.45 0.00737 0.00721 55 55 1 5 0 550.030 33.75 20.01 25.88 30.45 4.0 1017.63 249 246 322 -1666 -2093 -1600 271 907 1151 379 -1072 -746 -445 121 709 42 373 515 709 1159 714 516 783 814 328 414 95 -178 -643 -105 1099 883 1611 -352 -2432 -2692 -2494 -1280 -688 -160 -787 -670 -478 -998 -56 -400 -404 -671 -823 -504 437 494 848 880 817 893 799 479 302 243 627 1056 1356 1848 760 -119 -634 -1006 323 487 688 687 611 738 544 50 -497 -1485 -1052 -1085 -1129 -1149 -1849 -1647 -923 -502 -62 225 699 600 554 207 -238 -276 -181 -77 344 1015 681 195 -194 -695 -948 -407 -798 -872 -727 -816 -246 360 568 618 513 226 -71 -150 -215 -132 46 252 -56 90 431 431 658 369 54 498 394 321 131 -184 -197 -163 88 24 15 414 181 -22 -270 -629 -681 129 129 169 -862 -986 -701 122 453 603 208 -566 -383 -247 70 430 26 232 323 453 757 477 337 510 553 222 289 66 -120 -415 -64 675 567 1038 -237 -1592 -1678 -1680 -893 -546 -135 -697 -610 -444 -901 -52 -367 -359 -592 -694 -428 364 437 748 808 766 842 738 459 284 226 596 1026 1360 1881 776 -118 -589 -917 301 477 715 721 645 785 547 49 -450 -1292 -915 -1006 -1122 -1162 -2000 -1774 -1020 -578 -75 273 855 713 650 228 -252 -282 -183 -82 383 1195 833 237 -230 -787 -1046 -443 -928 -1045 -904 -1025 -317 469 751 824 675 283 -87 -173 -243 -155 56 322 -72 116 545 541 802 445 61 564 452 377 161 -231 -248 -203 112 33 20 569 254 -31 -364 -853 -896 SS 20251108T154644.8Z 9443.657464 436 1 31.10 2 10.16 86.87 127.71 292.65 0.00 1 0.00 1 0 17 9.838e-03 8.010e-03 2.292e-03 1.851e-03 1.273599e-01 9.420082e-04 1.348547e-03 -6.000000e+00 5.508326e-03 228.32 -2.00 3.04 -2.00 313.94 0.00e+00 3.896324e-04 6.876618e-05 1.230363e-05 -6.000000e+00 2.513911e-04 291.78 -2.00 20.00 -2.00 313.35 0.00e+00 1.016 0.000 302.00 328.00 3 5.8223e+00 2.3937e-03 1.1496e-02 -6.0000e+00 1.3674e-02 5.0600e-02 2.6454e-03 5.6974e-03 -6.0000e+00 1.4811e-02 -9.5907e-04 1.5249e-03 2.7610e-03 -6.0000e+00 8.8631e-03 -4.2629e-03 6.7012e-04 7.9076e-04 -6.0000e+00 3.8461e-03 5.2940e-04 7.6945e-05 4.8249e-05 9.8407e-06 -6.0000e+00 2.4589e-04 7.1484e-03 0.0000e+00 11 8 0 10 0 0 99.66 25.89 0.41 0.00715 0.00773 9 9 1 5 0 3455.160 33.75 20.00 25.89 30.64 4.0 1019.44 -527 139 41 -1218 -2101 -1678 886 1457 1585 -651 -827 -1871 -438 389 900 93 -43 498 990 1516 880 1189 590 1130 307 578 -211 468 -1371 81 1362 1474 2463 -973 -3030 -3479 -3561 -1141 -501 -349 -621 -704 -355 -289 -400 -149 -419 -945 -1030 -719 569 303 512 557 677 932 871 874 96 87 570 1112 1551 2079 746 -171 -952 -1366 145 463 571 1074 687 1020 564 157 -1161 -1534 -1423 -1149 -1053 -1042 -1552 -1735 -774 -255 -225 244 1042 1017 494 -262 -144 -430 -144 -882 388 1000 711 402 -222 -503 -1172 -1098 -684 -616 -1008 -724 -117 581 704 720 655 358 -324 -361 -343 -91 -242 294 -14 223 365 280 834 416 -181 520 437 64 -86 132 -31 -196 -42 168 64 432 313 167 -293 -923 -682 -258 67 20 -587 -875 -705 350 641 773 -313 -408 -908 -227 206 526 55 -25 296 598 934 555 728 365 724 206 399 -146 296 -858 48 805 907 1594 -622 -1924 -2107 -2182 -788 -386 -294 -535 -625 -321 -262 -359 -133 -362 -828 -862 -582 469 266 467 499 618 854 812 811 87 79 526 1089 1539 2166 781 -172 -861 -1235 133 457 588 1151 744 1070 591 149 -1043 -1343 -1249 -1051 -1013 -1098 -1654 -1915 -858 -303 -270 303 1294 1227 582 -296 -153 -425 -146 -927 441 1182 859 505 -263 -580 -1276 -1227 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