File name: Pandora282s1_Ilo-UNAM_20251123_L2Fit_fout2c3d20250118p1-8.txt File generation date: 20251124T044252.9Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 282 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora282_OF_v2d20240118.txt Instrument calibration file used: Pandora282s1_CF_v3d20250118.txt Level 1 file used: Pandora282s1_Ilo-UNAM_20251123_L1_smca1c3d20250118p1-8.txt Full location name: Grupo de Investigacion en Ciencias de la Atmosfera, UNAM, Peru Short location name: Ilo-UNAM Country of location: Peru Location latitude [deg]: -17.6020 Location longitude [deg]: -71.3389 Location altitude [m]: 85 Local noon date: 20251123 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 202 344 Nominal wavelengths inside fitting window [nm]: 305.0533 305.1939 305.3345 305.4751 305.6156 305.7562 305.8968 306.0373 306.1778 306.3184 306.4589 306.5994 306.7399 306.8803 307.0208 307.1613 307.3017 307.4421 307.5825 307.7230 307.8634 308.0037 308.1441 308.2845 308.4248 308.5652 308.7055 308.8458 308.9861 309.1264 309.2667 309.4070 309.5473 309.6875 309.8278 309.9680 310.1082 310.2484 310.3886 310.5288 310.6690 310.8091 310.9493 311.0894 311.2296 311.3697 311.5098 311.6499 311.7900 311.9300 312.0701 312.2102 312.3502 312.4902 312.6302 312.7702 312.9102 313.0502 313.1902 313.3301 313.4701 313.6100 313.7500 313.8899 314.0298 314.1697 314.3095 314.4494 314.5893 314.7291 314.8690 315.0088 315.1486 315.2884 315.4282 315.5680 315.7077 315.8475 315.9872 316.1269 316.2667 316.4064 316.5461 316.6858 316.8254 316.9651 317.1048 317.2444 317.3840 317.5236 317.6632 317.8028 317.9424 318.0820 318.2216 318.3611 318.5006 318.6402 318.7797 318.9192 319.0587 319.1982 319.3376 319.4771 319.6165 319.7560 319.8954 320.0348 320.1742 320.3136 320.4530 320.5923 320.7317 320.8710 321.0104 321.1497 321.2890 321.4283 321.5676 321.7068 321.8461 321.9854 322.1246 322.2638 322.4030 322.5422 322.6814 322.8206 322.9598 323.0990 323.2381 323.3772 323.5164 323.6555 323.7946 323.9337 324.0727 324.2118 324.3509 324.4899 324.6289 324.7679 324.9070 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20251123T103914.5Z 9458.443918 57 1 31.03 2 82.27 109.06 111.20 129.98 0.00 1 0.00 1 0 25 5.250e-01 2.919e-02 3.584e-01 1.348e-02 7.112674e-01 7.445185e-03 1.025492e-02 -6.000000e+00 2.978662e-01 227.84 -2.00 3.04 -2.00 321.61 0.00e+00 2.100420e-02 4.142113e-03 1.300039e-02 -6.000000e+00 1.532488e-02 292.13 -2.00 20.00 -2.00 321.01 0.00e+00 6.913 0.001 302.00 328.00 3 2.5038e+00 2.8756e-02 9.3487e-02 -6.0000e+00 7.4131e-01 6.3378e-01 3.8001e-02 7.0661e-02 -6.0000e+00 8.0549e-01 -8.1091e-01 3.2331e-02 3.4952e-02 -6.0000e+00 4.7875e-01 3.2327e-01 1.5428e-02 1.1333e-02 -6.0000e+00 2.0972e-01 2.2181e-05 -7.5256e-04 3.5883e-04 3.4651e-04 -6.0000e+00 1.3858e-02 1.0567e-02 0.0000e+00 12 8 8 10 0 0 -60.83 24.83 0.82 0.01057 0.00491 12 12 1 5 0 2585.520 33.25 20.00 24.83 26.12 4.0 989.79 -179572 900000 900000 900000 -199388 -65225 -153913 900000 900000 -51667 42373 93781 32708 -96118 253185 -39984 146959 75496 122003 900000 900000 23360 -14607 -67641 13951 900000 -67399 900000 86837 900000 77064 24100 31515 16783 33852 31327 17002 -40222 41101 33509 31649 -41947 134375 176044 23272 8196 16561 -2738 29007 26135 128371 -25727 51257 -3186 17327 -2080 8365 41153 34540 26009 31394 28333 7293 27481 13914 15209 28740 10338 10296 16513 7288 3982 10493 4051 7563 8194 13128 -2286 -747 -15436 1415 -2024 2775 2285 2810 4338 4327 1216 5336 4615 266 -8462 -2035 -1982 -6134 -11745 -5376 -1522 -964 -954 -2033 -2093 -3154 -5803 -102 -3471 -1980 -681 -570 -3024 1384 -164 -2127 387 -2219 -2672 507 2927 1195 2469 1368 4041 1903 205 1997 3400 -1308 1435 930 -1 -412 557 738 59 -232 1174 -408 606 1006 -775 -1331 -1675 -991 -7709 900000 900000 900000 -10224 -856 -4221 900000 900000 -678 556 1230 429 -2865 3321 -1097 1928 990 1600 900000 900000 418 -366 -2823 250 900000 -2652 900000 1139 900000 1112 727 1033 682 1066 945 624 -2954 1563 1582 1661 -4842 2820 2540 1587 677 1303 -273 2207 2160 4210 -4387 4370 -501 2295 -336 1218 4210 3624 2934 3500 3642 1339 4758 2975 3132 5052 2224 2404 4202 2247 1316 3193 1227 2004 1913 2704 -558 -204 -5953 548 -934 1350 1175 1526 2475 2600 780 3304 2796 157 -5073 -1092 -1087 -3967 -8655 -4385 -1399 -990 -998 -2029 -1872 -2785 -5168 -85 -3175 -1882 -690 -636 -3933 1952 -254 -3420 592 -3308 -3821 706 4192 1860 4005 2237 6158 2848 303 2790 4540 -1755 1917 1429 -2 -758 1093 1524 130 -551 2926 -975 1458 2433 -1998 -3235 -3812 -2124 SS 20251123T105502.2Z 9458.454887 62 1 30.19 2 78.70 108.07 108.39 128.03 0.00 1 0.00 1 0 25 2.541e-01 9.899e-03 9.629e-02 3.792e-03 5.387662e-01 1.926614e-03 5.726889e-03 -6.000000e+00 1.420008e-01 227.84 -2.00 3.04 -2.00 320.23 0.00e+00 1.332253e-02 7.103217e-04 1.648444e-03 -6.000000e+00 6.503533e-03 292.13 -2.00 20.00 -2.00 319.47 0.00e+00 4.928 0.000 302.00 328.00 3 2.7180e+00 5.8723e-03 5.4053e-02 -6.0000e+00 3.5205e-01 5.4921e-02 7.3060e-03 2.5002e-02 -6.0000e+00 3.8149e-01 -1.1302e-01 6.3551e-03 1.9404e-02 -6.0000e+00 2.2842e-01 4.6264e-02 3.2820e-03 1.4731e-02 -6.0000e+00 9.9225e-02 1.5455e-04 -9.9237e-06 9.8526e-05 1.2648e-04 -6.0000e+00 6.3513e-03 9.2259e-03 0.0000e+00 12 8 8 10 0 0 47.98 24.85 0.61 0.00923 0.00915 27 27 1 5 0 1117.920 33.25 20.00 24.85 27.86 4.0 1001.85 -115871 14272 -90627 -80401 -112367 -114263 -90494 -15657 -33234 -32551 -102019 -21762 -69984 -36935 22994 -17756 -7101 -10921 -12509 -29292 12610 -27925 -11877 -14164 -8945 -18437 -7179 19463 -31091 -11799 5305 -7977 5338 -6706 -8179 -13068 -3887 -6808 5630 936 1521 -5401 2877 4610 4847 466 -792 2293 3589 5743 1856 422 1032 1738 5010 2317 1749 2973 2335 -1156 1478 3144 1378 5437 2492 1228 -128 -901 -1140 1670 931 1875 1070 726 1129 -1108 374 -3446 -1040 -2172 -1897 -1261 -1136 -1889 -1406 -954 65 900 1659 2336 1818 -378 -731 -173 -555 -2301 -89 395 167 -258 -69 -1156 -1437 -862 -681 -1349 -1142 -765 19 -413 704 251 222 250 -160 -759 127 -54 159 575 69 386 769 811 240 202 -255 822 575 750 346 150 -81 79 42 -48 465 122 57 -118 -526 -693 -622 -2399 95 -1877 -1457 -2493 -2451 -1573 -139 -381 -385 -2414 -258 -1760 -888 391 -552 -223 -396 -500 -1462 424 -1373 -501 -634 -390 -914 -324 662 -1759 -602 277 -569 389 -595 -690 -1116 -331 -695 612 126 226 -919 481 793 857 90 -159 460 737 1208 447 104 275 496 1445 700 543 905 699 -357 467 1086 554 2376 1187 568 -58 -412 -565 859 536 1118 640 414 591 -579 177 -1682 -546 -1262 -1285 -968 -881 -1550 -1227 -890 64 840 1551 2272 1656 -326 -592 -139 -494 -2241 -97 464 218 -341 -85 -1402 -1580 -942 -812 -1607 -1427 -1016 25 -616 1081 410 362 391 -249 -1124 187 -84 246 943 114 620 1191 1292 368 299 -361 1160 909 1253 636 275 -155 158 86 -105 978 263 124 -251 -1119 -1398 -1268 SS 20251123T110026.8Z 9458.458643 65 1 29.96 2 77.48 107.75 107.41 127.40 0.00 1 0.00 1 0 17 1.631e-01 7.361e-03 5.113e-02 2.659e-03 4.959432e-01 1.343523e-03 5.175415e-03 -6.000000e+00 9.114790e-02 227.84 -2.00 3.04 -2.00 319.86 0.00e+00 1.205039e-02 4.360820e-04 1.277014e-03 -6.000000e+00 4.174658e-03 292.13 -2.00 20.00 -2.00 319.05 0.00e+00 4.481 0.000 302.00 328.00 3 2.5309e+00 3.9646e-03 4.9299e-02 -6.0000e+00 2.2597e-01 2.4290e-02 4.8081e-03 2.3118e-02 -6.0000e+00 2.4487e-01 -4.8129e-02 3.9946e-03 1.6989e-02 -6.0000e+00 1.4662e-01 1.4255e-02 2.0981e-03 1.2973e-02 -6.0000e+00 6.3689e-02 2.9590e-04 -1.5739e-04 6.9897e-05 1.0635e-04 -6.0000e+00 4.0770e-03 9.4803e-03 0.0000e+00 11 8 0 10 0 0 51.65 24.86 0.42 0.00948 0.00830 69 69 1 5 0 434.160 33.25 20.01 24.86 28.50 3.9 1005.24 -87722 -30353 -39640 -44170 -77763 -6194 -67010 -29795 -64480 -20198 -50902 -34562 -54272 -2251 -8635 -14668 -13631 -8190 -6525 -1906 -4965 -7196 -2948 -5553 1824 -2478 -5713 1162 -7227 -8832 -7790 -2182 -543 -3464 -6313 -8181 1400 -5709 3124 3424 1884 967 5538 938 2811 2320 1714 1400 963 4681 -1079 -3 590 2029 2359 -290 936 21 895 -1167 1369 1245 957 2635 536 841 372 -1626 271 1488 689 1573 956 397 -241 -841 -1392 -3487 -1944 -1844 -1403 -1450 -1284 -1333 -1328 193 66 687 990 1615 753 -266 -455 -405 -679 -851 -156 790 592 418 -428 -895 -1174 -387 -610 -1125 -465 -328 -382 257 1088 642 584 -15 -382 -478 58 62 -23 307 -55 117 379 248 504 338 -406 259 443 31 112 33 -431 -114 -143 -195 75 367 403 -80 -102 -276 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