File name: Pandora282s1_Ilo-UNAM_20251205_L2Fit_fout2c3d20250118p1-8.txt File generation date: 20251206T044318.8Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 282 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora282_OF_v2d20240118.txt Instrument calibration file used: Pandora282s1_CF_v3d20250118.txt Level 1 file used: Pandora282s1_Ilo-UNAM_20251205_L1_smca1c3d20250118p1-8.txt Full location name: Grupo de Investigacion en Ciencias de la Atmosfera, UNAM, Peru Short location name: Ilo-UNAM Country of location: Peru Location latitude [deg]: -17.6020 Location longitude [deg]: -71.3389 Location altitude [m]: 85 Local noon date: 20251205 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 202 344 Nominal wavelengths inside fitting window [nm]: 305.0533 305.1939 305.3345 305.4751 305.6156 305.7562 305.8968 306.0373 306.1778 306.3184 306.4589 306.5994 306.7399 306.8803 307.0208 307.1613 307.3017 307.4421 307.5825 307.7230 307.8634 308.0037 308.1441 308.2845 308.4248 308.5652 308.7055 308.8458 308.9861 309.1264 309.2667 309.4070 309.5473 309.6875 309.8278 309.9680 310.1082 310.2484 310.3886 310.5288 310.6690 310.8091 310.9493 311.0894 311.2296 311.3697 311.5098 311.6499 311.7900 311.9300 312.0701 312.2102 312.3502 312.4902 312.6302 312.7702 312.9102 313.0502 313.1902 313.3301 313.4701 313.6100 313.7500 313.8899 314.0298 314.1697 314.3095 314.4494 314.5893 314.7291 314.8690 315.0088 315.1486 315.2884 315.4282 315.5680 315.7077 315.8475 315.9872 316.1269 316.2667 316.4064 316.5461 316.6858 316.8254 316.9651 317.1048 317.2444 317.3840 317.5236 317.6632 317.8028 317.9424 318.0820 318.2216 318.3611 318.5006 318.6402 318.7797 318.9192 319.0587 319.1982 319.3376 319.4771 319.6165 319.7560 319.8954 320.0348 320.1742 320.3136 320.4530 320.5923 320.7317 320.8710 321.0104 321.1497 321.2890 321.4283 321.5676 321.7068 321.8461 321.9854 322.1246 322.2638 322.4030 322.5422 322.6814 322.8206 322.9598 323.0990 323.2381 323.3772 323.5164 323.6555 323.7946 323.9337 324.0727 324.2118 324.3509 324.4899 324.6289 324.7679 324.9070 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20251205T104735.5Z 9470.449717 240 1 30.09 2 80.81 110.74 95.72 297.96 0.00 1 0.00 1 0 25 4.693e-01 2.322e-02 2.698e-01 1.150e-02 6.166066e-01 6.192515e-03 7.052886e-03 -6.000000e+00 2.707202e-01 227.23 -2.00 3.04 -2.00 321.07 0.00e+00 9.041130e-03 3.005782e-03 4.932145e-03 -6.000000e+00 1.402633e-02 292.42 -2.00 20.00 -2.00 320.38 0.00e+00 5.942 0.001 302.00 328.00 3 3.3243e+00 2.1553e-02 6.7132e-02 -6.0000e+00 6.7522e-01 2.6363e-01 2.8608e-02 3.5708e-02 -6.0000e+00 7.3595e-01 -2.4372e-01 2.6576e-02 2.0319e-02 -6.0000e+00 4.3131e-01 7.8841e-02 1.3008e-02 7.6091e-03 -6.0000e+00 1.8689e-01 2.8338e-05 -7.7911e-04 3.1604e-04 1.2968e-04 -6.0000e+00 1.2704e-02 1.1062e-02 0.0000e+00 12 8 8 10 0 0 93.95 24.90 0.83 0.01106 0.00521 10 10 1 5 0 3007.950 33.25 20.00 24.90 27.14 3.9 994.83 -198843 900000 -227322 900000 -189978 900000 900000 900000 900000 78442 900000 -88943 900000 -63761 900000 -51222 -19233 900000 -21082 223801 -18294 223321 -14804 -36401 27762 4546 -18926 900000 58157 31370 25018 -8232 64194 -1581 -7903 -14084 41955 1786 2859 594 14692 -4885 27210 23840 23029 6395 -22759 11092 10117 18554 80188 -17054 5205 1358 13238 1305 11249 22489 9831 -8373 13360 -6131 1519 16772 4454 7511 2861 1693 481 5806 -1723 -140 191 1874 7588 6536 3558 -9805 -4548 -7815 -2808 -2308 -284 -1202 -651 -1639 3307 2104 2236 1780 3873 -6245 -3102 -2406 -2233 -8523 -1136 1566 556 1147 -1201 691 -6285 426 550 2270 -2316 836 -1990 -735 4402 884 -1457 -446 -2922 1289 -267 479 -189 1193 -456 3693 1456 -507 618 1476 -3020 -1705 -796 1445 818 -399 808 381 -205 80 -631 887 66 -854 -126 121 -810 -4653 900000 -9021 900000 -4446 900000 900000 900000 900000 878 900000 -1086 900000 -1038 900000 -1147 -352 900000 -519 2505 -471 2499 -365 -1181 497 107 -572 900000 781 597 616 -341 1509 -78 -389 -709 1315 98 189 48 1151 -498 2132 2001 1985 673 -3286 1179 1132 2014 5205 -3283 874 257 2341 267 2140 3801 1827 -1837 2437 -1503 394 4261 1366 2160 836 508 159 2119 -754 -63 85 778 2726 2114 1091 -3424 -1670 -3551 -1427 -1338 -178 -800 -460 -1139 2308 1539 1642 1275 2783 -4606 -2097 -1627 -1675 -7198 -1033 1601 638 1326 -1338 680 -5947 374 524 2263 -2538 949 -2528 -1033 6562 1337 -2271 -665 -4202 1836 -385 719 -279 1839 -717 5861 2278 -784 906 2074 -4234 -2389 -1245 2302 1447 -763 1594 798 -463 177 -1442 2034 154 -1955 -271 264 -1700 SS 20251205T111827.9Z 9470.471156 257 1 30.84 2 73.90 108.96 101.97 296.19 0.00 1 0.00 1 0 17 6.557e-02 8.671e-03 3.160e-02 3.932e-03 3.857858e-01 1.953779e-03 3.980907e-03 -6.000000e+00 3.655624e-02 227.22 -2.00 3.04 -2.00 318.85 0.00e+00 3.181275e-03 4.532567e-04 6.238651e-04 -6.000000e+00 1.680307e-03 292.42 -2.00 20.00 -2.00 317.96 0.00e+00 3.543 0.000 302.00 328.00 3 4.2684e+00 5.3983e-03 3.8776e-02 -6.0000e+00 9.0488e-02 5.2361e-02 6.2611e-03 1.7369e-02 -6.0000e+00 9.8099e-02 -2.1683e-02 4.3735e-03 8.8876e-03 -6.0000e+00 5.8779e-02 1.4246e-03 2.3323e-03 3.4227e-03 -6.0000e+00 2.5572e-02 1.4336e-04 -2.7431e-04 1.0621e-04 3.1462e-05 -6.0000e+00 1.6387e-03 9.8467e-03 0.0000e+00 11 9 0 11 8 0 99.46 24.96 0.38 0.00985 0.00779 14 14 1 5 0 2202.520 33.25 20.00 24.96 28.31 3.9 1002.91 -45587 -8640 -12087 -8632 -29857 -22329 -15866 7280 -7163 -28178 -8046 -13871 -6699 -6200 1448 -345 102 1180 4489 -1667 426 -3212 -6972 7662 7462 -3361 -2763 10756 -2580 -2724 2888 2563 2784 -40 -4790 -4402 -3946 -7182 -88 -1633 936 -1827 -184 1726 1175 -209 1013 -56 -1066 1313 3847 -347 -183 -211 1551 -745 -9 1500 1296 -48 1729 1060 2090 1910 1111 72 1135 -1138 -172 640 1654 941 1469 783 -133 464 -1167 -2467 -733 -2773 -1010 -958 -1600 -1702 -1268 -188 874 809 974 1759 192 -1199 -219 -913 -545 -1222 -75 470 702 -366 -636 -780 -1751 -1202 -960 -352 -1378 -682 169 39 999 681 38 -32 -113 -672 -121 663 41 433 48 1270 457 479 667 391 -471 727 229 1 466 -69 39 10 -106 268 26 436 286 -622 -51 -667 -823 -2237 -331 -505 -331 -1248 -830 -590 243 -310 -1599 -370 -713 -383 -428 111 -31 10 119 466 -193 50 -382 -880 893 924 -486 -401 1299 -337 -362 406 409 498 -8 -913 -805 -787 -1735 -24 -491 304 -644 -67 626 431 -79 378 -21 -405 497 1527 -158 -89 -110 824 -380 -5 768 707 -26 955 588 1274 1283 776 47 694 -700 -111 477 1249 750 1166 601 -103 322 -745 -1528 -473 -2110 -800 -851 -1553 -1605 -1272 -201 978 940 1138 1979 204 -1183 -212 -865 -551 -1301 -90 585 952 -501 -822 -917 -2043 -1410 -1149 -445 -1839 -954 234 58 1608 1076 60 -50 -164 -976 -173 980 62 689 78 2011 709 718 948 571 -656 992 342 1 769 -113 65 18 -196 496 50 846 564 -1210 -94 -1252 -1491 SS 20251205T112746.7Z 9470.477624 260 1 29.09 2 71.79 108.48 103.87 295.72 0.00 1 0.00 1 0 17 3.415e-02 7.429e-03 1.889e-02 3.371e-03 3.490386e-01 1.667703e-03 3.596277e-03 -6.000000e+00 1.904174e-02 227.22 -2.00 3.04 -2.00 318.24 0.00e+00 1.662620e-03 3.232006e-04 1.763858e-04 -6.000000e+00 8.752161e-04 292.42 -2.00 20.00 -2.00 317.34 0.00e+00 3.158 0.000 302.00 328.00 3 4.3962e+00 4.5088e-03 3.4671e-02 -6.0000e+00 4.7134e-02 3.9490e-02 5.1589e-03 1.5746e-02 -6.0000e+00 5.1098e-02 -1.1747e-02 3.3521e-03 7.7194e-03 -6.0000e+00 3.0617e-02 3.3701e-04 1.7636e-03 2.5311e-03 -6.0000e+00 1.3321e-02 1.9187e-04 -1.7746e-04 9.0636e-05 2.3700e-05 -6.0000e+00 8.5355e-04 9.5198e-03 0.0000e+00 11 8 0 10 0 0 77.40 24.99 0.33 0.00952 0.00819 10 10 1 5 0 2908.710 33.25 20.00 24.99 28.70 3.9 1005.35 -29429 788 -3784 1697 -7621 -12994 -1817 7211 -5104 -7371 -1755 -5964 2795 -2113 2942 -4491 -4944 -421 2346 -465 3019 -807 3441 -1474 1852 -1099 1220 2295 -2047 -3064 4955 3533 2551 -1031 -2798 -5926 -2972 -2080 30 -69 1186 -686 34 756 -949 -358 996 -1931 -495 772 3229 -662 -254 544 1026 -322 264 1074 567 -830 696 912 1389 2584 523 333 928 -1813 -632 1255 1480 318 402 121 706 -1136 -754 -2357 -1175 -1325 -704 -1551 -1403 -1952 -1204 365 529 686 1174 488 1007 -859 -375 -597 -199 -589 552 515 453 358 -279 -304 -1602 -653 -314 -309 -706 -661 -618 339 1038 838 303 -169 -135 -370 -513 -269 77 512 -328 255 501 411 626 421 -115 530 38 -85 47 9 69 -74 -442 228 214 751 105 -273 -190 -409 -722 -2012 45 -234 94 -406 -701 -94 386 -349 -548 -122 -449 226 -214 335 -625 -733 -63 361 -77 495 -135 566 -273 353 -226 247 435 -380 -575 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