File name: Pandora282s1_Ilo-UNAM_20251206_L2Fit_fout2c3d20250118p1-8.txt File generation date: 20251207T060617.7Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 282 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora282_OF_v2d20240118.txt Instrument calibration file used: Pandora282s1_CF_v3d20250118.txt Level 1 file used: Pandora282s1_Ilo-UNAM_20251206_L1_smca1c3d20250118p1-8.txt Full location name: Grupo de Investigacion en Ciencias de la Atmosfera, UNAM, Peru Short location name: Ilo-UNAM Country of location: Peru Location latitude [deg]: -17.6020 Location longitude [deg]: -71.3389 Location altitude [m]: 85 Local noon date: 20251206 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 202 344 Nominal wavelengths inside fitting window [nm]: 305.0533 305.1939 305.3345 305.4751 305.6156 305.7562 305.8968 306.0373 306.1778 306.3184 306.4589 306.5994 306.7399 306.8803 307.0208 307.1613 307.3017 307.4421 307.5825 307.7230 307.8634 308.0037 308.1441 308.2845 308.4248 308.5652 308.7055 308.8458 308.9861 309.1264 309.2667 309.4070 309.5473 309.6875 309.8278 309.9680 310.1082 310.2484 310.3886 310.5288 310.6690 310.8091 310.9493 311.0894 311.2296 311.3697 311.5098 311.6499 311.7900 311.9300 312.0701 312.2102 312.3502 312.4902 312.6302 312.7702 312.9102 313.0502 313.1902 313.3301 313.4701 313.6100 313.7500 313.8899 314.0298 314.1697 314.3095 314.4494 314.5893 314.7291 314.8690 315.0088 315.1486 315.2884 315.4282 315.5680 315.7077 315.8475 315.9872 316.1269 316.2667 316.4064 316.5461 316.6858 316.8254 316.9651 317.1048 317.2444 317.3840 317.5236 317.6632 317.8028 317.9424 318.0820 318.2216 318.3611 318.5006 318.6402 318.7797 318.9192 319.0587 319.1982 319.3376 319.4771 319.6165 319.7560 319.8954 320.0348 320.1742 320.3136 320.4530 320.5923 320.7317 320.8710 321.0104 321.1497 321.2890 321.4283 321.5676 321.7068 321.8461 321.9854 322.1246 322.2638 322.4030 322.5422 322.6814 322.8206 322.9598 323.0990 323.2381 323.3772 323.5164 323.6555 323.7946 323.9337 324.0727 324.2118 324.3509 324.4899 324.6289 324.7679 324.9070 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20251206T140638.0Z 9471.587940 205 1 30.01 2 35.46 104.38 122.77 292.27 0.00 1 0.00 1 0 17 8.327e-03 6.839e-03 1.599e-04 1.296e-04 1.431998e-01 6.570885e-05 1.536208e-03 -6.000000e+00 4.644896e-03 227.17 -2.00 3.04 -2.00 313.94 0.00e+00 3.659767e-04 4.840737e-06 1.179206e-05 -6.000000e+00 2.133637e-04 292.45 -2.00 20.00 -2.00 313.34 0.00e+00 1.227 0.000 302.00 328.00 3 4.1182e-01 1.6650e-04 1.3628e-02 -6.0000e+00 1.1497e-02 1.0043e-02 1.8416e-04 6.4223e-03 -6.0000e+00 1.2460e-02 -2.3185e-03 1.0631e-04 3.1247e-03 -6.0000e+00 7.4661e-03 -3.4610e-03 4.6857e-05 8.9288e-04 -6.0000e+00 3.2523e-03 9.4708e-02 -1.2390e-04 3.3797e-06 1.1332e-05 -6.0000e+00 2.0801e-04 3.1825e-03 0.0000e+00 11 8 0 10 0 0 89.78 25.40 0.41 0.00318 0.00225 1619 1619 1 5 0 18.530 32.75 19.80 25.40 32.03 4.9 1035.89 252 184 237 -1649 -2493 -1790 -193 851 1370 320 -1146 -1038 -455 208 864 394 275 555 681 1358 791 470 910 869 415 501 149 -238 -776 54 867 988 1534 -279 -2415 -2785 -2423 -1372 -594 -213 -626 -701 -525 -722 -288 -285 -494 -587 -901 -436 321 544 822 1042 728 891 728 522 314 229 622 1020 1436 1879 754 -111 -599 -959 149 550 612 701 528 730 410 -10 -562 -1496 -1081 -1095 -1118 -1106 -1807 -1648 -1046 -544 -153 184 693 581 457 227 -132 -271 -202 -60 215 908 648 194 -99 -614 -926 -439 -672 -816 -716 -645 -207 336 600 588 514 286 -112 -184 -184 -189 107 262 -5 126 436 388 600 311 86 501 344 306 171 -77 -184 -198 -59 50 25 289 224 -52 -216 -559 -729 119 89 116 -792 -1131 -752 -83 390 668 158 -572 -505 -230 112 495 236 167 339 412 837 500 292 563 562 272 339 101 -155 -479 32 512 612 972 -179 -1497 -1698 -1536 -930 -450 -173 -538 -606 -464 -643 -252 -249 -432 -491 -744 -359 264 462 726 934 653 804 669 480 283 210 567 963 1419 1914 776 -107 -560 -870 134 534 625 734 559 750 418 -10 -512 -1295 -934 -997 -1082 -1119 -1920 -1767 -1163 -636 -182 222 839 699 533 251 -138 -275 -205 -65 242 1076 793 236 -119 -698 -1033 -487 -787 -998 -892 -821 -266 443 811 805 690 371 -138 -217 -212 -226 131 335 -6 166 571 500 744 377 102 576 406 377 215 -98 -234 -258 -78 69 34 410 317 -74 -301 -771 -997 SS 20251206T141142.2Z 9471.591461 208 1 30.01 2 34.29 104.43 123.82 292.17 0.00 1 0.00 1 0 17 8.310e-03 6.844e-03 1.669e-04 1.356e-04 1.413121e-01 6.871547e-05 1.514178e-03 -6.000000e+00 4.635357e-03 227.17 -2.00 3.04 -2.00 313.93 0.00e+00 3.466797e-04 5.060871e-06 1.312214e-05 -6.000000e+00 2.129241e-04 292.45 -2.00 20.00 -2.00 313.34 0.00e+00 1.209 0.000 302.00 328.00 3 5.1963e-01 1.7405e-04 1.3437e-02 -6.0000e+00 1.1473e-02 1.0923e-02 1.9240e-04 6.3310e-03 -6.0000e+00 1.2434e-02 -2.4551e-03 1.1113e-04 3.0813e-03 -6.0000e+00 7.4508e-03 -3.3665e-03 4.9056e-05 8.7810e-04 -6.0000e+00 3.2457e-03 8.6806e-02 -6.6794e-05 3.5324e-06 1.1249e-05 -6.0000e+00 2.0758e-04 3.1305e-03 0.0000e+00 11 8 0 10 0 0 99.72 25.51 0.40 0.00313 0.00263 1695 1695 1 5 0 17.700 33.50 20.01 25.51 33.56 4.4 1041.14 309 120 268 -1644 -2398 -1843 -144 867 1314 332 -1171 -1033 -492 179 800 419 276 572 720 1343 760 458 914 858 439 540 158 -258 -728 51 859 957 1586 -302 -2401 -2768 -2427 -1390 -532 -168 -608 -769 -556 -752 -282 -314 -521 -585 -870 -438 356 571 796 988 767 913 763 561 335 261 668 1068 1421 1872 765 -156 -620 -965 172 552 587 703 531 705 433 -45 -527 -1469 -1097 -1075 -1123 -1103 -1810 -1614 -1028 -538 -163 202 671 572 444 228 -162 -266 -196 -67 216 912 673 188 -134 -608 -946 -444 -675 -794 -730 -650 -185 317 594 596 506 303 -94 -178 -199 -188 107 274 -21 134 409 373 576 318 91 526 359 299 148 -102 -168 -170 -79 46 34 317 211 -69 -217 -568 -727 147 59 132 -796 -1049 -784 -63 401 645 165 -588 -506 -249 97 458 250 167 348 448 823 478 282 562 552 285 362 106 -167 -446 31 524 588 995 -199 -1528 -1673 -1580 -963 -397 -138 -527 -671 -495 -675 -249 -277 -447 -493 -726 -354 295 488 688 890 689 826 703 517 303 240 610 1009 1405 1903 785 -154 -565 -854 155 536 599 732 559 739 440 -43 -481 -1277 -953 -980 -1085 -1140 -1910 -1759 -1133 -624 -196 245 819 696 513 250 -168 -270 -199 -72 242 1069 831 231 -159 -700 -1046 -500 -800 -959 -897 -833 -238 419 805 819 683 386 -116 -208 -232 -222 132 353 -27 177 528 474 721 388 108 613 429 363 184 -129 -214 -217 -105 63 47 449 299 -96 -303 -785 -977 SS 20251206T141647.1Z 9471.594990 211 1 30.00 2 33.11 104.50 124.89 292.09 0.00 1 0.00 1 0 17 8.273e-03 6.843e-03 1.600e-04 1.308e-04 1.394609e-01 6.637750e-05 1.495077e-03 -6.000000e+00 4.614304e-03 227.17 -2.00 3.04 -2.00 313.88 0.00e+00 3.636608e-04 4.844828e-06 1.069863e-05 -6.000000e+00 2.119686e-04 292.45 -2.00 20.00 -2.00 313.30 0.00e+00 1.193 0.000 302.00 328.00 3 4.6870e-01 1.6805e-04 1.3259e-02 -6.0000e+00 1.1421e-02 1.1177e-02 1.8569e-04 6.2530e-03 -6.0000e+00 1.2378e-02 -2.4947e-03 1.0733e-04 3.0400e-03 -6.0000e+00 7.4171e-03 -3.4820e-03 4.7322e-05 8.6938e-04 -6.0000e+00 3.2308e-03 9.3165e-02 -7.2560e-05 3.3982e-06 1.1120e-05 -6.0000e+00 2.0666e-04 3.4932e-03 0.0000e+00 11 8 0 10 0 0 98.17 25.60 0.40 0.00349 0.00295 1687 1687 1 5 0 17.780 33.75 20.00 25.60 34.21 4.2 1042.43 220 233 280 -1604 -2452 -1764 -127 791 1366 322 -1175 -1015 -380 204 847 405 307 558 692 1402 765 409 855 848 409 528 136 -268 -792 81 828 964 1522 -282 -2420 -2745 -2396 -1402 -573 -166 -629 -754 -557 -729 -279 -301 -542 -572 -893 -414 337 542 806 1028 738 907 770 545 371 238 602 1039 1441 1898 757 -162 -564 -977 188 521 586 699 568 741 433 -28 -503 -1434 -1052 -1054 -1080 -1106 -1851 -1619 -1033 -525 -164 187 680 598 437 227 -182 -251 -176 -46 244 915 637 201 -158 -602 -930 -434 -621 -802 -753 -649 -220 330 601 588 511 279 -86 -190 -176 -170 106 256 -15 149 407 369 577 286 62 521 361 272 188 -83 -166 -163 -85 42 45 305 206 -74 -208 -547 -734 105 119 144 -774 -1116 -780 -55 364 668 166 -587 -494 -200 110 484 242 185 339 430 890 481 261 544 545 275 354 91 -173 -484 48 502 590 985 -185 -1531 -1710 -1550 -967 -441 -136 -546 -659 -497 -655 -247 -266 -465 -482 -744 -343 278 463 716 925 663 820 710 502 335 219 550 983 1425 1932 777 -159 -526 -886 169 505 597 729 597 776 440 -28 -457 -1240 -908 -984 -1039 -1141 -1952 -1762 -1165 -608 -197 228 831 712 505 249 -192 -253 -182 -49 273 1071 786 247 -187 -691 -1026 -488 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