File name: Pandora282s1_Ilo-UNAM_20251207_L2Fit_fout2c3d20250118p1-8.txt File generation date: 20251208T044705.5Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 282 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora282_OF_v2d20240118.txt Instrument calibration file used: Pandora282s1_CF_v3d20250118.txt Level 1 file used: Pandora282s1_Ilo-UNAM_20251207_L1_smca1c3d20250118p1-8.txt Full location name: Grupo de Investigacion en Ciencias de la Atmosfera, UNAM, Peru Short location name: Ilo-UNAM Country of location: Peru Location latitude [deg]: -17.6020 Location longitude [deg]: -71.3389 Location altitude [m]: 85 Local noon date: 20251207 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 202 344 Nominal wavelengths inside fitting window [nm]: 305.0533 305.1939 305.3345 305.4751 305.6156 305.7562 305.8968 306.0373 306.1778 306.3184 306.4589 306.5994 306.7399 306.8803 307.0208 307.1613 307.3017 307.4421 307.5825 307.7230 307.8634 308.0037 308.1441 308.2845 308.4248 308.5652 308.7055 308.8458 308.9861 309.1264 309.2667 309.4070 309.5473 309.6875 309.8278 309.9680 310.1082 310.2484 310.3886 310.5288 310.6690 310.8091 310.9493 311.0894 311.2296 311.3697 311.5098 311.6499 311.7900 311.9300 312.0701 312.2102 312.3502 312.4902 312.6302 312.7702 312.9102 313.0502 313.1902 313.3301 313.4701 313.6100 313.7500 313.8899 314.0298 314.1697 314.3095 314.4494 314.5893 314.7291 314.8690 315.0088 315.1486 315.2884 315.4282 315.5680 315.7077 315.8475 315.9872 316.1269 316.2667 316.4064 316.5461 316.6858 316.8254 316.9651 317.1048 317.2444 317.3840 317.5236 317.6632 317.8028 317.9424 318.0820 318.2216 318.3611 318.5006 318.6402 318.7797 318.9192 319.0587 319.1982 319.3376 319.4771 319.6165 319.7560 319.8954 320.0348 320.1742 320.3136 320.4530 320.5923 320.7317 320.8710 321.0104 321.1497 321.2890 321.4283 321.5676 321.7068 321.8461 321.9854 322.1246 322.2638 322.4030 322.5422 322.6814 322.8206 322.9598 323.0990 323.2381 323.3772 323.5164 323.6555 323.7946 323.9337 324.0727 324.2118 324.3509 324.4899 324.6289 324.7679 324.9070 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20251207T111444.2Z 9472.468567 261 1 29.71 2 74.87 109.44 74.35 304.87 0.00 1 0.00 1 0 17 1.052e-01 1.210e-02 7.469e-02 5.835e-03 4.097704e-01 2.911973e-03 4.222434e-03 -6.000000e+00 5.860620e-02 227.12 -2.00 3.04 -2.00 319.33 0.00e+00 3.818679e-03 7.837555e-04 8.274303e-04 -6.000000e+00 2.695625e-03 292.47 -2.00 20.00 -2.00 318.47 0.00e+00 3.757 0.000 302.00 328.00 3 4.6120e+00 8.2405e-03 4.1142e-02 -6.0000e+00 1.4503e-01 6.5667e-02 9.7368e-03 1.8475e-02 -6.0000e+00 1.5724e-01 -1.9576e-02 7.2625e-03 9.8702e-03 -6.0000e+00 9.4228e-02 -5.3393e-04 3.8685e-03 4.2023e-03 -6.0000e+00 4.1002e-02 7.9723e-05 3.5759e-05 1.5827e-04 3.8284e-05 -6.0000e+00 2.6283e-03 1.0394e-02 0.0000e+00 12 9 8 11 8 0 99.26 25.09 0.52 0.01039 0.01066 9 9 1 5 0 3300.750 33.50 20.00 25.09 29.20 3.9 1008.43 -61594 60978 -18808 -3378 -34293 -7354 -17237 -44091 20560 -22072 9832 -9936 -6098 4920 3177 -7910 -10234 5247 7609 -1076 5035 -8322 -13011 -7345 3704 -11533 -1155 22379 10088 -6937 7028 1928 8448 -13288 -7662 -6053 -4264 -15058 -354 -3109 2339 -7365 1742 7578 36 -4591 -1605 -181 -632 2484 12593 -713 2492 200 801 233 2088 2518 4151 1098 2011 2651 1088 3144 4 2590 3727 71 -1633 1329 -678 854 1071 738 1468 -641 -2414 -499 -1613 -5295 -542 -2121 -2235 -1312 -1242 266 505 920 405 2440 267 -1409 518 -1643 381 -3289 614 578 -167 373 -466 -196 -1787 -2125 -152 248 -1287 -513 83 83 1665 355 430 -674 -741 -385 -666 1016 879 696 -716 1000 583 457 10 321 -498 858 611 188 -221 -34 352 108 91 -133 293 611 194 -691 -134 -732 -722 -2419 798 -578 -85 -1034 -163 -451 -1706 468 -816 263 -345 -246 218 174 -558 -798 376 567 -92 415 -772 -1296 -740 354 -1345 -123 1796 873 -730 728 239 1111 -2306 -1169 -878 -667 -3085 -76 -819 647 -2157 536 2251 12 -1437 -537 -60 -211 824 4085 -264 959 84 350 105 948 1136 1795 484 906 1295 602 1880 2 1509 2019 39 -988 903 -477 620 776 514 1026 -409 -1424 -278 -970 -3838 -431 -1765 -2021 -1229 -1244 282 521 980 436 2499 281 -1384 461 -1458 357 -3618 678 723 -230 509 -602 -230 -1946 -2348 -181 312 -1715 -717 114 124 2659 598 712 -1067 -1085 -566 -974 1525 1313 1113 -1184 1588 903 684 14 473 -701 1187 926 294 -372 -60 633 190 171 -264 596 1265 382 -1433 -263 -1381 -1311 SS 20251207T130800.6Z 9472.547229 328 1 30.16 2 49.07 105.07 96.79 295.04 0.00 1 0.00 1 0 17 8.699e-03 6.807e-03 1.158e-03 8.317e-04 1.779928e-01 4.184331e-04 1.892473e-03 -6.000000e+00 4.849942e-03 227.12 -2.00 3.04 -2.00 314.72 0.00e+00 5.172944e-04 3.548988e-05 1.715958e-05 -6.000000e+00 2.229388e-04 292.47 -2.00 20.00 -2.00 314.03 0.00e+00 1.523 0.000 302.00 328.00 3 3.7201e+00 1.0665e-03 1.6917e-02 -6.0000e+00 1.2002e-02 2.9041e-02 1.1842e-03 7.9660e-03 -6.0000e+00 1.3010e-02 -1.5931e-03 6.8111e-04 3.8736e-03 -6.0000e+00 7.7963e-03 -3.6033e-03 3.0625e-04 1.1239e-03 -6.0000e+00 3.3950e-03 2.3988e-03 -1.1565e-05 2.1872e-05 1.3244e-05 -6.0000e+00 2.1736e-04 5.9860e-03 0.0000e+00 11 9 0 11 8 0 99.68 25.37 0.38 0.00599 0.00590 76 76 1 5 0 396.830 33.50 20.00 25.37 31.00 3.9 1018.95 286 474 114 -1473 -3000 -2337 -795 577 652 19 -1364 -1282 -396 146 927 492 220 610 787 1284 755 466 993 1031 562 377 374 -187 -766 -106 912 1101 1834 -389 -2616 -2832 -2345 -1270 -410 -249 -499 -660 -384 -519 -280 -494 -533 -467 -798 -430 561 502 838 867 714 826 571 500 451 189 720 1050 1443 1838 715 -112 -680 -1089 180 552 497 677 659 746 529 6 -508 -1647 -1063 -1036 -1123 -1217 -1865 -1737 -1015 -413 -179 174 693 723 365 157 -263 -357 -169 -86 167 938 740 226 -291 -769 -918 -476 -796 -887 -667 -539 -202 413 653 618 415 443 -223 -114 -254 -210 54 323 36 162 458 353 595 386 6 541 477 357 118 -4 -247 -132 10 24 121 306 184 -165 -290 -619 -732 103 183 45 -542 -1034 -753 -265 213 251 8 -537 -499 -169 65 435 252 115 306 405 679 409 248 528 576 313 218 215 -106 -399 -56 493 594 1056 -224 -1486 -1534 -1371 -806 -281 -190 -398 -546 -311 -425 -227 -400 -439 -369 -637 -336 450 413 689 747 632 738 501 437 402 167 649 968 1378 1793 706 -105 -627 -956 163 523 501 714 698 768 533 6 -448 -1412 -917 -958 -1077 -1238 -1968 -1896 -1134 -479 -220 214 855 866 434 176 -275 -364 -178 -95 189 1130 930 283 -355 -898 -1037 -548 -943 -1119 -846 -690 -267 558 899 865 576 588 -279 -141 -308 -255 68 427 49 222 613 469 772 478 7 655 589 455 153 -6 -332 -177 14 35 175 454 278 -246 -420 -896 -1026 SS 20251207T133637.1Z 9472.567096 347 1 16.99 2 42.48 104.61 102.72 293.32 0.00 1 0.00 1 0 17 8.655e-03 6.973e-03 1.492e-03 1.153e-03 1.587922e-01 5.831634e-04 1.689651e-03 -6.000000e+00 4.825597e-03 227.12 -2.00 3.04 -2.00 314.26 0.00e+00 4.996205e-04 4.545339e-05 1.094846e-05 -6.000000e+00 2.218171e-04 292.47 -2.00 20.00 -2.00 313.63 0.00e+00 1.354 0.000 302.00 328.00 3 3.9628e+00 1.4815e-03 1.5049e-02 -6.0000e+00 1.1942e-02 3.4736e-02 1.6407e-03 7.1082e-03 -6.0000e+00 1.2945e-02 -8.0748e-04 9.4523e-04 3.4499e-03 -6.0000e+00 7.7571e-03 -4.0580e-03 4.1999e-04 1.0048e-03 -6.0000e+00 3.3780e-03 2.3003e-03 -1.4206e-05 3.0221e-05 1.2199e-05 -6.0000e+00 2.1626e-04 5.8716e-03 0.0000e+00 12 9 1 12 1 1 99.57 25.45 0.44 0.00587 0.00576 20 37 1 5 0 808.630 33.75 20.00 25.45 31.30 3.9 1021.11 -161 146 -91 -1470 -2882 -2228 -6 673 1161 791 -1559 -1024 -412 162 878 361 430 642 849 1774 717 480 696 607 506 375 -163 51 -800 67 1150 968 1664 -371 -2350 -2746 -2487 -1408 -642 -353 -446 -588 -382 -581 -160 -264 -657 -346 -976 -586 386 568 885 945 676 648 860 437 272 179 851 961 1274 1915 727 -176 -669 -1177 318 637 573 684 541 642 375 -37 -323 -1544 -1084 -1272 -1021 -1043 -1897 -1812 -1071 -446 -71 106 912 655 416 324 -354 -253 -248 -333 255 958 622 331 -238 -596 -977 -484 -567 -811 -617 -710 -139 484 768 632 435 220 -37 -180 -373 -19 108 331 -21 127 409 275 522 397 47 465 300 240 37 -53 -133 -165 -199 211 41 397 281 -2 -251 -692 -756 -68 66 -41 -627 -1139 -820 -2 283 510 364 -702 -451 -186 82 466 197 239 360 488 1041 433 284 413 359 313 240 -105 30 -458 38 670 565 1032 -230 -1425 -1588 -1554 -915 -475 -281 -370 -505 -324 -495 -139 -230 -559 -292 -796 -465 315 474 769 826 607 587 792 402 245 160 775 899 1238 1963 727 -172 -614 -1065 283 622 577 720 575 662 378 -35 -292 -1347 -949 -1153 -996 -1081 -2043 -1953 -1223 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