File name: Pandora282s1_Ilo-UNAM_20251226_L2Fit_fout2c3d20250118p1-8.txt File generation date: 20251227T045259.6Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: Mario Roman Flores Roque Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 282 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora282_OF_v3d20240118.txt Instrument calibration file used: Pandora282s1_CF_v3d20250118.txt Level 1 file used: Pandora282s1_Ilo-UNAM_20251226_L1_smca1c3d20250118p1-8.txt Full location name: Grupo de Investigacion en Ciencias de la Atmosfera, UNAM, Peru Short location name: Ilo-UNAM Country of location: Peru Location latitude [deg]: -17.6020 Location longitude [deg]: -71.3389 Location altitude [m]: 85 Local noon date: 20251226 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 202 344 Nominal wavelengths inside fitting window [nm]: 305.0533 305.1939 305.3345 305.4751 305.6156 305.7562 305.8968 306.0373 306.1778 306.3184 306.4589 306.5994 306.7399 306.8803 307.0208 307.1613 307.3017 307.4421 307.5825 307.7230 307.8634 308.0037 308.1441 308.2845 308.4248 308.5652 308.7055 308.8458 308.9861 309.1264 309.2667 309.4070 309.5473 309.6875 309.8278 309.9680 310.1082 310.2484 310.3886 310.5288 310.6690 310.8091 310.9493 311.0894 311.2296 311.3697 311.5098 311.6499 311.7900 311.9300 312.0701 312.2102 312.3502 312.4902 312.6302 312.7702 312.9102 313.0502 313.1902 313.3301 313.4701 313.6100 313.7500 313.8899 314.0298 314.1697 314.3095 314.4494 314.5893 314.7291 314.8690 315.0088 315.1486 315.2884 315.4282 315.5680 315.7077 315.8475 315.9872 316.1269 316.2667 316.4064 316.5461 316.6858 316.8254 316.9651 317.1048 317.2444 317.3840 317.5236 317.6632 317.8028 317.9424 318.0820 318.2216 318.3611 318.5006 318.6402 318.7797 318.9192 319.0587 319.1982 319.3376 319.4771 319.6165 319.7560 319.8954 320.0348 320.1742 320.3136 320.4530 320.5923 320.7317 320.8710 321.0104 321.1497 321.2890 321.4283 321.5676 321.7068 321.8461 321.9854 322.1246 322.2638 322.4030 322.5422 322.6814 322.8206 322.9598 323.0990 323.2381 323.3772 323.5164 323.6555 323.7946 323.9337 324.0727 324.2118 324.3509 324.4899 324.6289 324.7679 324.9070 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20251226T133552.3Z 9491.566577 151 1 55.72 2 44.73 105.68 120.24 104.44 0.00 1 0.00 1 0 17 9.029e-03 7.161e-03 1.981e-03 1.392e-03 1.628672e-01 6.977228e-04 1.724831e-03 -6.000000e+00 5.017917e-03 226.25 -2.00 3.04 -2.00 314.79 0.00e+00 6.110655e-04 5.990879e-05 1.386980e-05 -6.000000e+00 2.318486e-04 292.91 -2.00 20.00 -2.00 314.08 0.00e+00 1.406 0.000 302.00 328.00 3 5.4003e+00 1.7772e-03 1.5547e-02 -6.0000e+00 1.2391e-02 3.7413e-02 1.9756e-03 7.2639e-03 -6.0000e+00 1.3439e-02 -2.1011e-03 1.1375e-03 3.5298e-03 -6.0000e+00 8.0612e-03 -3.7549e-03 5.1352e-04 1.0606e-03 -6.0000e+00 3.5184e-03 5.1604e-04 1.6273e-04 3.6623e-05 1.2205e-05 -6.0000e+00 2.2558e-04 6.2481e-03 0.0000e+00 11 9 0 11 8 0 99.96 25.26 0.39 0.00625 0.00747 26 2 1 5 0 2142.950 33.50 20.00 25.26 31.98 4.0 1026.55 -632 429 -208 -348 -2529 -2523 -793 717 1139 -341 -1178 -1296 -553 290 1558 -60 52 412 1047 863 641 939 972 823 557 552 -154 447 -618 470 1458 704 1622 -612 -3037 -2828 -1975 -1766 -404 -346 -572 -1043 -343 -449 -354 -558 -693 -929 -862 -149 989 483 506 928 872 825 607 704 188 181 750 960 1434 2020 779 -169 -822 -1263 148 742 596 1043 498 480 905 -148 -362 -1757 -1085 -1442 -1426 -1289 -1708 -1462 -993 -416 76 422 635 674 682 -11 -490 -572 -45 -633 237 907 715 488 -99 -768 -1342 -563 -537 -722 -769 -585 110 439 832 384 423 129 -78 -271 -395 -64 8 365 -67 104 442 325 716 369 -205 473 336 291 34 -223 -26 -23 25 144 40 384 212 9 -130 -680 -908 -231 154 -76 -127 -810 -758 -246 246 433 -137 -457 -496 -213 124 738 -29 25 204 530 450 342 487 507 451 319 327 -92 245 -312 241 767 366 894 -355 -1644 -1454 -1092 -1127 -285 -267 -452 -857 -287 -378 -295 -465 -562 -724 -685 -115 783 386 423 807 776 743 558 643 169 161 679 876 1407 1981 771 -161 -753 -1100 132 710 597 1088 525 492 917 -136 -314 -1510 -936 -1313 -1372 -1362 -1830 -1618 -1110 -499 92 526 797 822 808 -12 -529 -577 -46 -684 266 1116 901 611 -123 -882 -1524 -650 -647 -884 -981 -777 143 602 1195 537 594 175 -96 -326 -466 -78 10 493 -90 139 606 429 933 460 -254 567 403 373 43 -292 -34 -31 35 207 60 558 314 13 -192 -980 -1273 SS 20251226T141236.7Z 9491.592091 175 1 27.38 2 36.30 105.67 112.06 100.70 0.00 1 0.00 1 0 17 9.965e-03 8.068e-03 3.126e-03 2.321e-03 1.461847e-01 1.166676e-03 1.555576e-03 -6.000000e+00 5.538602e-03 226.25 -2.00 3.04 -2.00 314.48 0.00e+00 5.968008e-04 9.491125e-05 2.489360e-05 -6.000000e+00 2.558792e-04 292.91 -2.00 20.00 -2.00 313.81 0.00e+00 1.240 0.000 302.00 328.00 3 5.7442e+00 2.9667e-03 1.3768e-02 -6.0000e+00 1.3677e-02 3.4420e-02 3.2929e-03 6.5213e-03 -6.0000e+00 1.4833e-02 -4.0595e-03 1.8932e-03 3.1635e-03 -6.0000e+00 8.8974e-03 -3.9211e-03 8.4722e-04 9.3548e-04 -6.0000e+00 3.8839e-03 4.4590e-04 1.8115e-04 6.1080e-05 1.1180e-05 -6.0000e+00 2.4895e-04 5.4972e-03 0.0000e+00 12 9 1 12 1 1 99.61 25.35 0.37 0.00550 0.00686 6 1 1 5 0 3910.070 33.50 20.00 25.35 32.88 3.9 1029.47 -508 810 -1453 -978 -2620 -1232 -1237 1251 1067 -50 -1257 -1429 501 16 538 573 -120 881 663 1398 1431 788 420 1436 604 197 -628 746 -962 -683 2675 942 1344 -400 -2626 -3373 -2480 -1661 -769 -142 -59 -1155 -542 -385 -519 -569 -390 -922 -1116 -870 1449 765 724 174 852 1397 407 1158 517 376 206 1406 1481 2015 1100 76 -735 -1950 -379 1061 495 801 957 484 461 -261 -687 -2392 -967 -1578 -1255 -1216 -1721 -1226 -914 46 -5 24 716 767 412 -261 -369 -474 -407 -645 57 889 632 569 -84 -633 -1388 -839 -822 -505 -760 -419 -358 472 1315 679 592 135 -475 -219 -273 -389 9 416 -241 330 540 819 954 613 -348 450 4 256 -201 16 -213 298 146 -275 415 207 370 -239 -553 -555 -721 -196 330 -610 -375 -950 -413 -434 479 455 -21 -503 -608 211 8 282 300 -64 470 363 782 815 441 236 836 369 125 -399 433 -517 -376 1462 511 774 -241 -1471 -1948 -1428 -1096 -563 -113 -48 -976 -467 -332 -444 -486 -322 -779 -905 -685 1154 653 607 153 761 1252 375 1054 463 334 188 1353 1450 2077 1139 72 -666 -1685 -334 1052 513 822 987 515 462 -251 -624 -2028 -814 -1401 -1241 -1246 -1888 -1311 -1041 53 -6 31 914 951 474 -289 -386 -488 -408 -707 65 1047 800 714 -99 -731 -1594 -930 -1004 -622 -976 -532 -470 648 1790 941 825 175 -588 -262 -320 -474 11 558 -324 440 704 1075 1179 762 -410 539 5 326 -256 21 -277 395 195 -392 605 296 537 -344 -812 -789 -997 SS 20251226T142212.7Z 9491.598758 178 1 54.02 2 34.10 105.83 109.91 99.81 0.00 1 0.00 1 0 17 9.101e-03 7.299e-03 1.512e-03 1.161e-03 1.408945e-01 5.835536e-04 1.497748e-03 -6.000000e+00 5.057865e-03 226.25 -2.00 3.04 -2.00 314.28 0.00e+00 5.239379e-04 4.602977e-05 1.300624e-05 -6.000000e+00 2.336924e-04 292.91 -2.00 20.00 -2.00 313.64 0.00e+00 1.207 0.000 302.00 328.00 3 5.2904e+00 1.4794e-03 1.3370e-02 -6.0000e+00 1.2490e-02 2.6794e-02 1.6401e-03 6.2809e-03 -6.0000e+00 1.3546e-02 -1.6690e-03 9.4458e-04 3.0496e-03 -6.0000e+00 8.1253e-03 -4.0867e-03 4.2237e-04 9.0072e-04 -6.0000e+00 3.5465e-03 7.3468e-04 1.1109e-04 3.0377e-05 1.0676e-05 -6.0000e+00 2.2737e-04 6.1403e-03 0.0000e+00 11 9 0 11 8 0 99.89 25.33 0.41 0.00614 0.00698 31 3 1 5 0 1742.460 33.50 19.99 25.33 32.36 3.9 1027.52 36 945 -40 -1316 -2686 -2002 -47 1323 1668 435 -1119 -1127 -1235 -107 1153 253 -140 442 703 1240 694 472 1065 624 83 559 413 338 -1001 -196 1421 985 1858 -636 -2523 -3256 -2278 -1462 -718 -283 -620 -664 -585 -820 -239 -505 -734 -678 -939 -220 496 606 657 878 941 848 649 501 371 344 725 1104 1461 2252 595 19 -870 -1156 -141 606 516 852 603 843 609 -150 -557 -1828 -1001 -1297 -1267 -1033 -1590 -1457 -947 -380 -27 461 832 654 607 -209 -181 -466 -247 -567 136 1052 674 343 -72 -684 -1262 -342 -618 -835 -801 -798 -193 368 902 653 617 194 -215 -270 -304 -203 81 331 -119 203 506 408 645 203 -117 315 328 122 -64 -103 -102 -97 -129 111 145 448 281 -112 -39 -656 -772 15 415 -18 -545 -1042 -722 -17 541 703 193 -480 -510 -566 -54 598 142 -80 253 412 743 426 283 637 367 51 354 260 211 -574 -106 778 568 1131 -408 -1499 -1851 -1389 -958 -527 -228 -514 -568 -512 -723 -207 -438 -618 -576 -765 -173 401 521 558 776 849 772 602 464 337 310 665 1024 1454 2241 599 18 -795 -1055 -125 577 542 890 636 862 618 -144 -506 -1542 -843 -1156 -1260 -1068 -1676 -1587 -1046 -451 -32 571 1037 794 713 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