File name: Pandora282s1_Ilo-UNAM_20260115_L2Fit_fout2c3d20250118p1-8.txt File generation date: 20260116T050032.0Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: Mario Roman Flores Roque Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 282 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora282_OF_v3d20240118.txt Instrument calibration file used: Pandora282s1_CF_v3d20250118.txt Level 1 file used: Pandora282s1_Ilo-UNAM_20260115_L1_smca1c3d20250118p1-8.txt Full location name: Grupo de Investigacion en Ciencias de la Atmosfera, UNAM, Peru Short location name: Ilo-UNAM Country of location: Peru Location latitude [deg]: -17.6020 Location longitude [deg]: -71.3389 Location altitude [m]: 85 Local noon date: 20260115 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 202 344 Nominal wavelengths inside fitting window [nm]: 305.0533 305.1939 305.3345 305.4751 305.6156 305.7562 305.8968 306.0373 306.1778 306.3184 306.4589 306.5994 306.7399 306.8803 307.0208 307.1613 307.3017 307.4421 307.5825 307.7230 307.8634 308.0037 308.1441 308.2845 308.4248 308.5652 308.7055 308.8458 308.9861 309.1264 309.2667 309.4070 309.5473 309.6875 309.8278 309.9680 310.1082 310.2484 310.3886 310.5288 310.6690 310.8091 310.9493 311.0894 311.2296 311.3697 311.5098 311.6499 311.7900 311.9300 312.0701 312.2102 312.3502 312.4902 312.6302 312.7702 312.9102 313.0502 313.1902 313.3301 313.4701 313.6100 313.7500 313.8899 314.0298 314.1697 314.3095 314.4494 314.5893 314.7291 314.8690 315.0088 315.1486 315.2884 315.4282 315.5680 315.7077 315.8475 315.9872 316.1269 316.2667 316.4064 316.5461 316.6858 316.8254 316.9651 317.1048 317.2444 317.3840 317.5236 317.6632 317.8028 317.9424 318.0820 318.2216 318.3611 318.5006 318.6402 318.7797 318.9192 319.0587 319.1982 319.3376 319.4771 319.6165 319.7560 319.8954 320.0348 320.1742 320.3136 320.4530 320.5923 320.7317 320.8710 321.0104 321.1497 321.2890 321.4283 321.5676 321.7068 321.8461 321.9854 322.1246 322.2638 322.4030 322.5422 322.6814 322.8206 322.9598 323.0990 323.2381 323.3772 323.5164 323.6555 323.7946 323.9337 324.0727 324.2118 324.3509 324.4899 324.6289 324.7679 324.9070 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20260115T114833.9Z 9511.492059 161 1 54.46 2 71.61 106.97 34.85 114.02 0.00 1 0.00 1 0 17 2.492e-02 6.761e-03 6.527e-03 1.471e-03 3.391344e-01 7.244068e-04 3.528008e-03 -6.000000e+00 1.380286e-02 225.44 -2.00 3.04 -2.00 317.88 0.00e+00 1.428114e-03 1.276701e-04 2.462037e-04 -6.000000e+00 6.411945e-04 293.36 -2.00 20.00 -2.00 316.95 0.00e+00 3.128 0.000 302.00 328.00 3 3.5666e+00 1.9335e-03 3.4086e-02 -6.0000e+00 3.4014e-02 7.8931e-03 2.2014e-03 1.5136e-02 -6.0000e+00 3.6915e-02 -1.1743e-02 1.3872e-03 7.4447e-03 -6.0000e+00 2.2164e-02 2.2689e-03 7.2417e-04 2.3060e-03 -6.0000e+00 9.6903e-03 4.7085e-04 -1.2805e-04 3.9494e-05 2.1977e-05 -6.0000e+00 6.2259e-04 9.3556e-03 0.0000e+00 11 8 0 10 0 0 89.73 25.25 0.37 0.00936 0.00839 58 6 1 5 0 938.890 33.50 20.00 25.25 31.07 3.9 1019.22 -8683 1894 -7360 -3607 -17035 -10335 -4553 -1149 -4291 -6017 -5985 -5431 -5720 -151 830 58 -1675 -117 1386 1408 1426 258 1583 -1706 -209 881 648 1618 -2693 -303 267 589 2492 -1715 -2926 -4283 -1480 -2232 456 41 -791 -523 639 108 -60 725 343 -97 -562 337 1314 187 640 974 1117 1209 634 561 439 -514 697 1359 2058 1604 840 486 -503 -1164 308 489 765 799 306 555 517 -420 -887 -1902 -1365 -1354 -1111 -1411 -1843 -1298 -1135 -534 -31 603 886 593 796 -40 -504 -495 -295 -504 64 964 329 183 -671 -1071 -1288 -548 -748 -836 -809 -675 -173 589 641 660 662 350 -144 -244 -161 56 179 195 -65 183 547 514 703 567 -202 467 406 374 140 46 -264 -34 31 -5 -112 423 188 -141 -322 -585 -699 -624 137 -607 -270 -1280 -697 -310 -86 -374 -567 -556 -521 -643 -19 122 9 -276 -20 247 261 272 49 303 -362 -46 203 151 353 -574 -63 60 148 685 -519 -830 -1186 -436 -713 173 17 -368 -255 320 55 -31 373 175 -49 -285 171 708 104 375 607 723 800 405 358 293 -342 471 922 1531 1228 663 358 -371 -844 234 401 653 716 276 480 443 -326 -666 -1370 -1026 -1096 -964 -1374 -1842 -1347 -1191 -601 -37 700 1034 709 882 -44 -501 -502 -300 -545 78 1234 439 244 -847 -1301 -1521 -652 -930 -1106 -1064 -935 -240 877 982 1046 1026 512 -204 -337 -219 80 259 290 -100 275 835 757 983 797 -271 645 579 556 213 72 -428 -55 53 -10 -201 774 336 -257 -564 -1026 -1184 SS 20260115T115402.9Z 9511.495867 165 1 54.99 2 70.36 106.69 33.69 114.40 0.00 1 0.00 1 0 17 3.636e-02 8.182e-03 1.599e-02 3.072e-03 3.232151e-01 1.510831e-03 3.340518e-03 -6.000000e+00 2.014112e-02 225.44 -2.00 3.04 -2.00 318.13 0.00e+00 1.759286e-03 2.845190e-04 1.828606e-04 -6.000000e+00 9.354378e-04 293.36 -2.00 20.00 -2.00 317.21 0.00e+00 2.941 0.000 302.00 328.00 3 4.9989e+00 4.0657e-03 3.2135e-02 -6.0000e+00 4.9634e-02 3.9083e-02 4.6507e-03 1.4455e-02 -6.0000e+00 5.3863e-02 -8.0497e-03 2.9797e-03 7.1296e-03 -6.0000e+00 3.2339e-02 -2.3395e-03 1.5698e-03 2.4443e-03 -6.0000e+00 1.4143e-02 1.3446e-04 1.1464e-04 8.3041e-05 2.2443e-05 -6.0000e+00 9.0828e-04 7.8595e-03 0.0000e+00 11 9 0 11 8 0 99.55 25.26 0.62 0.00786 0.00872 16 2 1 5 0 3436.750 33.50 20.00 25.26 31.44 3.9 1022.15 -4018 13749 -8082 11499 -21189 -15670 2402 7174 1310 -4377 399 6556 6354 4559 2215 -2291 -3596 2303 5796 2859 240 5364 -69 -10463 -217 -4873 1305 8775 -508 -634 1784 -2216 4680 -1699 -7006 -5556 -707 -2439 -976 -1278 -113 -2040 935 2239 -684 -1740 -50 -395 -332 311 3774 -640 137 -116 802 275 459 1798 1108 -1371 1263 1011 1395 2496 218 35 -478 -562 -684 1252 490 240 638 473 465 -160 490 -1622 -483 -1479 -920 -1161 -1068 -1121 -1116 7 110 676 746 684 1298 -946 -432 -407 160 -1816 245 734 607 509 -679 -587 -1281 -1149 18 -612 -1363 -522 -341 75 1137 495 718 109 -818 -418 -119 -649 481 467 -387 314 1060 102 533 233 92 187 439 163 -301 -11 194 30 245 -274 407 473 174 -47 -327 -795 -567 -247 787 -598 658 -1473 -986 135 434 95 -354 30 483 546 473 276 -337 -566 359 918 486 43 897 -12 -2232 -44 -1089 276 1625 -97 -120 361 -517 1130 -460 -1849 -1390 -184 -688 -330 -513 -49 -955 441 1059 -333 -864 -24 -188 -157 147 1843 -326 73 -66 473 166 284 1096 663 -831 766 665 1007 1941 163 27 -336 -384 -497 948 414 213 565 404 371 -124 341 -1092 -336 -1192 -774 -1094 -1086 -1104 -1174 8 130 827 919 818 1430 -974 -436 -394 163 -1965 291 909 817 683 -866 -731 -1481 -1347 23 -777 -1819 -726 -500 111 1779 804 1136 163 -1209 -572 -161 -916 719 704 -605 479 1564 156 773 325 121 242 613 249 -462 -18 313 50 410 -489 741 881 329 -88 -586 -1369 -998 SS 20260115T120258.3Z 9511.502064 171 1 54.65 2 68.32 106.24 31.80 115.12 0.00 1 0.00 1 0 17 1.637e-02 6.946e-03 6.570e-03 1.914e-03 2.954796e-01 9.422245e-04 3.078503e-03 -6.000000e+00 9.066387e-03 225.44 -2.00 3.04 -2.00 317.45 0.00e+00 1.252753e-03 1.473295e-04 1.681831e-04 -6.000000e+00 4.210908e-04 293.36 -2.00 20.00 -2.00 316.53 0.00e+00 2.682 0.000 302.00 328.00 3 4.5108e+00 2.4864e-03 2.9310e-02 -6.0000e+00 2.2342e-02 1.7661e-02 2.8168e-03 1.3158e-02 -6.0000e+00 2.4246e-02 -5.1184e-03 1.7138e-03 6.4465e-03 -6.0000e+00 1.4557e-02 -2.0257e-03 8.7532e-04 1.9978e-03 -6.0000e+00 6.3661e-03 2.9546e-04 1.3783e-04 5.1367e-05 1.9433e-05 -6.0000e+00 4.0887e-04 8.0146e-03 0.0000e+00 11 9 0 11 8 0 85.92 25.27 0.46 0.00801 0.00905 26 2 1 5 0 2101.780 33.50 20.00 25.27 31.85 3.9 1024.23 -2536 3552 -3920 732 -10347 -4788 -4263 475 213 -859 -2233 -2259 -2670 -3075 2914 -24 329 1527 481 1855 -793 1599 1957 -1629 -128 1827 976 1208 -2708 97 1721 1195 1685 -1658 -4182 -4062 -2529 -2600 -135 -399 -427 -1091 377 299 -264 -1 -454 -956 -87 -87 1758 375 856 1298 934 67 463 826 228 -761 1377 1327 1509 2333 507 76 -634 -1270 -147 865 1003 621 765 807 125 -80 -184 -2147 -843 -1260 -1299 -1217 -1666 -1592 -859 -59 -234 191 733 604 833 -331 -15 -517 214 -621 14 1026 686 62 -267 -560 -1333 -700 -549 -946 -1073 -696 -73 364 838 644 261 124 -215 -299 -166 -55 210 338 -213 245 874 481 653 494 -206 294 411 174 61 -157 -122 -49 19 -38 21 418 446 -62 -418 -693 -587 -247 360 -443 74 -1020 -426 -403 49 25 -106 -273 -283 -387 -524 495 -5 67 323 108 426 -192 371 461 -424 -35 508 275 319 -692 24 451 345 535 -570 -1360 -1268 -850 -937 -57 -202 -219 -591 209 168 -149 0 -255 -528 -47 -47 994 234 562 836 625 46 326 578 156 -522 950 989 1149 1912 430 60 -496 -969 -118 735 883 575 709 721 112 -64 -143 -1603 -646 -1033 -1210 -1183 -1753 -1641 -939 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