File name: Pandora282s1_Ilo-UNAM_20260213_L2Fit_fout2c3d20250118p1-8.txt File generation date: 20260216T185047.7Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: Mario Roman Flores Roque Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 282 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora282_OF_v3d20240118.txt Instrument calibration file used: Pandora282s1_CF_v3d20250118.txt Level 1 file used: Pandora282s1_Ilo-UNAM_20260213_L1_smca1c3d20250118p1-8.txt Full location name: Grupo de Investigacion en Ciencias de la Atmosfera, UNAM, Peru Short location name: Ilo-UNAM Country of location: Peru Location latitude [deg]: -17.6020 Location longitude [deg]: -71.3389 Location altitude [m]: 85 Local noon date: 20260213 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 202 344 Nominal wavelengths inside fitting window [nm]: 305.0533 305.1939 305.3345 305.4751 305.6156 305.7562 305.8968 306.0373 306.1778 306.3184 306.4589 306.5994 306.7399 306.8803 307.0208 307.1613 307.3017 307.4421 307.5825 307.7230 307.8634 308.0037 308.1441 308.2845 308.4248 308.5652 308.7055 308.8458 308.9861 309.1264 309.2667 309.4070 309.5473 309.6875 309.8278 309.9680 310.1082 310.2484 310.3886 310.5288 310.6690 310.8091 310.9493 311.0894 311.2296 311.3697 311.5098 311.6499 311.7900 311.9300 312.0701 312.2102 312.3502 312.4902 312.6302 312.7702 312.9102 313.0502 313.1902 313.3301 313.4701 313.6100 313.7500 313.8899 314.0298 314.1697 314.3095 314.4494 314.5893 314.7291 314.8690 315.0088 315.1486 315.2884 315.4282 315.5680 315.7077 315.8475 315.9872 316.1269 316.2667 316.4064 316.5461 316.6858 316.8254 316.9651 317.1048 317.2444 317.3840 317.5236 317.6632 317.8028 317.9424 318.0820 318.2216 318.3611 318.5006 318.6402 318.7797 318.9192 319.0587 319.1982 319.3376 319.4771 319.6165 319.7560 319.8954 320.0348 320.1742 320.3136 320.4530 320.5923 320.7317 320.8710 321.0104 321.1497 321.2890 321.4283 321.5676 321.7068 321.8461 321.9854 322.1246 322.2638 322.4030 322.5422 322.6814 322.8206 322.9598 323.0990 323.2381 323.3772 323.5164 323.6555 323.7946 323.9337 324.0727 324.2118 324.3509 324.4899 324.6289 324.7679 324.9070 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20260213T120854.2Z 9540.506183 189 1 20.39 2 69.77 98.01 25.48 118.35 0.00 1 0.00 1 0 25 1.276e-02 6.344e-03 3.575e-03 1.153e-03 3.180001e-01 5.682696e-04 3.313338e-03 -6.000000e+00 7.071068e-03 225.64 -2.00 3.04 -2.00 317.25 0.00e+00 1.862661e-03 8.377177e-05 1.132051e-04 -6.000000e+00 3.285333e-04 293.55 -2.00 20.00 -2.00 316.33 0.00e+00 2.861 0.000 302.00 328.00 3 2.4672e+00 1.4945e-03 3.1314e-02 -6.0000e+00 1.7431e-02 -1.8812e-02 1.6881e-03 1.4222e-02 -6.0000e+00 1.8915e-02 -1.0568e-02 1.0110e-03 6.9511e-03 -6.0000e+00 1.1356e-02 1.5514e-03 5.1056e-04 2.3655e-03 -6.0000e+00 4.9637e-03 1.9001e-03 -2.5879e-05 3.0586e-05 2.2107e-05 -6.0000e+00 3.1875e-04 9.8815e-03 0.0000e+00 12 1 1 12 1 1 10.38 25.46 0.34 0.00988 0.00969 58 15 1 5 0 345.470 33.50 20.00 25.46 32.38 3.9 1026.20 -764 -855 290 -4125 -5018 -4898 -460 -1603 119 -1273 -2707 -5676 -3225 -704 1120 -187 482 1042 230 1362 1149 -190 590 521 388 958 7 -794 -1480 -1151 503 993 993 72 -3722 -3521 -2865 -1634 -433 405 -304 -345 364 366 181 102 -278 317 -883 -210 594 573 679 1013 878 764 551 516 242 -71 691 1111 1672 2101 1007 -322 -526 -699 422 374 852 766 448 843 316 -172 -787 -1724 -1134 -976 -1363 -1252 -1866 -1800 -1109 -420 -37 279 750 403 414 41 -242 -238 -300 -150 119 932 530 98 -364 -834 -1184 -412 -723 -795 -723 -521 -180 259 816 567 409 298 -125 -130 -125 13 62 267 -14 181 520 565 548 328 -130 449 491 299 214 -17 -125 -162 -151 40 -10 369 219 -181 -249 -516 -720 -80 -100 35 -486 -523 -488 -47 -187 15 -176 -372 -832 -537 -124 227 -43 117 245 57 349 303 -50 157 148 117 300 2 -240 -422 -326 153 333 343 26 -1311 -1192 -1054 -649 -194 200 -167 -188 204 209 103 59 -160 179 -499 -119 356 354 446 670 603 538 398 373 171 -50 495 818 1348 1754 867 -260 -414 -537 340 317 764 721 424 766 281 -144 -627 -1313 -899 -846 -1237 -1217 -1896 -1907 -1202 -470 -44 330 888 482 476 45 -253 -239 -308 -165 142 1155 692 129 -464 -1011 -1376 -484 -903 -1021 -939 -711 -249 374 1223 854 620 437 -175 -175 -166 17 88 398 -21 274 767 829 764 453 -177 597 682 440 325 -27 -196 -255 -247 68 -17 636 383 -312 -423 -867 -1171 SS 20260213T121348.5Z 9540.509589 192 1 54.86 2 68.61 97.70 24.47 119.17 0.00 1 0.00 1 0 17 1.354e-02 6.687e-03 2.720e-03 9.087e-04 3.034068e-01 4.477669e-04 3.157222e-03 -6.000000e+00 7.503964e-03 225.64 -2.00 3.04 -2.00 317.16 0.00e+00 1.576914e-03 6.513769e-05 1.312835e-04 -6.000000e+00 3.486549e-04 293.55 -2.00 20.00 -2.00 316.25 0.00e+00 2.716 0.000 302.00 328.00 3 3.1213e+00 1.1766e-03 2.9753e-02 -6.0000e+00 1.8499e-02 -9.5688e-03 1.3286e-03 1.3514e-02 -6.0000e+00 2.0074e-02 -1.1319e-02 7.9245e-04 6.5989e-03 -6.0000e+00 1.2052e-02 2.1466e-03 3.9889e-04 2.1326e-03 -6.0000e+00 5.2674e-03 1.1522e-03 -6.4494e-05 2.4144e-05 2.0648e-05 -6.0000e+00 3.3827e-04 1.0059e-02 0.0000e+00 11 8 0 10 0 0 38.67 25.47 0.41 0.01006 0.00957 115 11 1 5 0 477.020 33.50 20.00 25.47 32.67 3.9 1028.55 -2596 1407 -302 -4195 -5386 -4599 -3402 367 -899 -2245 -3739 -4307 -3059 -767 1429 561 369 597 1241 1611 1444 38 1334 789 505 1478 289 -517 -1847 -1105 -230 470 1715 -928 -3590 -3502 -2803 -1898 -482 193 -196 -324 -88 -237 582 390 -16 -440 -637 45 621 673 778 1056 752 824 859 602 91 -153 559 1114 1907 2290 717 -57 -936 -956 72 686 712 620 608 782 311 -162 -736 -1971 -1345 -1300 -1257 -1244 -1834 -1651 -1064 -359 140 339 925 729 499 -77 -632 -573 -306 -223 264 954 665 -21 -342 -889 -1205 -457 -864 -855 -592 -520 45 376 816 571 668 225 -196 -113 -46 -19 104 222 -2 158 526 502 459 348 -16 494 242 155 95 -178 -275 -173 -32 22 82 473 210 -31 -276 -472 -760 -287 166 -37 -507 -576 -513 -400 43 -119 -319 -528 -629 -510 -147 287 127 88 149 324 436 401 10 372 235 148 447 89 -151 -552 -326 -73 150 600 -350 -1282 -1202 -1045 -762 -216 102 -107 -186 -52 -143 347 236 -10 -260 -372 26 384 425 521 708 524 585 625 438 65 -109 405 822 1534 1894 613 -48 -732 -726 58 595 650 594 585 723 283 -133 -576 -1557 -1044 -1096 -1146 -1209 -1932 -1731 -1187 -411 162 407 1112 853 565 -84 -659 -573 -323 -251 317 1178 859 -27 -433 -1078 -1412 -541 -1084 -1097 -791 -703 64 549 1229 859 1011 332 -276 -154 -62 -26 151 333 -3 233 779 717 645 469 -22 644 328 221 144 -271 -426 -269 -53 37 138 812 367 -53 -471 -774 -1249 SS 20260213T121858.4Z 9540.513175 195 1 12.71 2 67.39 97.37 23.42 120.13 0.00 1 0.00 1 0 17 1.266e-02 6.627e-03 4.835e-03 1.876e-03 2.894394e-01 9.254220e-04 3.018593e-03 -6.000000e+00 7.016940e-03 225.64 -2.00 3.04 -2.00 316.87 0.00e+00 1.544954e-03 1.249251e-04 7.073152e-05 -6.000000e+00 3.260202e-04 293.55 -2.00 20.00 -2.00 315.98 0.00e+00 2.580 0.000 302.00 328.00 3 3.2178e+00 2.4148e-03 2.8283e-02 -6.0000e+00 1.7298e-02 -7.9348e-03 2.7208e-03 1.2918e-02 -6.0000e+00 1.8771e-02 -7.0141e-03 1.6015e-03 6.2886e-03 -6.0000e+00 1.1270e-02 2.9231e-04 7.9220e-04 2.0714e-03 -6.0000e+00 4.9256e-03 1.2128e-03 -3.9197e-05 4.9753e-05 1.9858e-05 -6.0000e+00 3.1631e-04 9.9205e-03 0.0000e+00 12 9 1 12 1 1 39.75 25.48 0.35 0.00992 0.00963 18 8 1 5 0 668.700 33.50 20.00 25.48 32.94 3.9 1029.62 -3645 -482 -2200 -2605 -6000 -3323 -3312 458 -429 -1818 -3734 -2210 -2642 1655 572 49 -637 1771 1220 2404 1337 980 1512 1192 668 803 -147 -213 -828 756 -81 806 1447 -642 -2924 -3162 -2321 -1891 -385 47 -777 -527 -178 -117 -239 366 207 -1387 -538 -102 991 190 856 979 1128 1035 404 335 419 -33 982 1067 1643 2034 407 -176 -816 -1434 208 925 1033 729 538 920 387 -341 -833 -1895 -974 -953 -1068 -1091 -1864 -1542 -973 -428 21 93 762 454 515 182 -423 -564 -101 -350 169 737 466 289 -444 -908 -982 -187 -518 -839 -744 -658 55 301 850 512 468 431 -113 36 -238 -42 -106 313 -194 205 559 480 759 255 126 176 676 122 -5 -236 -1 -309 29 -141 108 473 283 -29 -136 -796 -696 -510 -72 -346 -385 -801 -412 -437 66 -70 -317 -648 -387 -491 345 140 13 -171 485 352 713 411 296 463 390 232 270 -50 -74 -268 238 -28 280 550 -261 -1120 -1167 -929 -822 -187 25 -464 -310 -108 -72 -148 226 126 -843 -320 -64 617 129 582 705 839 747 301 249 304 -24 720 845 1352 1724 356 -150 -644 -1158 166 808 954 707 525 863 357 -297 -689 -1493 -791 -841 -1022 -1067 -1978 -1631 -1096 -497 24 114 933 541 592 199 -442 -564 -106 -394 204 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