File name: Pandora282s1_Ilo-UNAM_20260214_L2Fit_fout2c3d20250118p1-8.txt File generation date: 20260216T184958.6Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: Mario Roman Flores Roque Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 282 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora282_OF_v3d20240118.txt Instrument calibration file used: Pandora282s1_CF_v3d20250118.txt Level 1 file used: Pandora282s1_Ilo-UNAM_20260214_L1_smca1c3d20250118p1-8.txt Full location name: Grupo de Investigacion en Ciencias de la Atmosfera, UNAM, Peru Short location name: Ilo-UNAM Country of location: Peru Location latitude [deg]: -17.6020 Location longitude [deg]: -71.3389 Location altitude [m]: 85 Local noon date: 20260214 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 202 344 Nominal wavelengths inside fitting window [nm]: 305.0533 305.1939 305.3345 305.4751 305.6156 305.7562 305.8968 306.0373 306.1778 306.3184 306.4589 306.5994 306.7399 306.8803 307.0208 307.1613 307.3017 307.4421 307.5825 307.7230 307.8634 308.0037 308.1441 308.2845 308.4248 308.5652 308.7055 308.8458 308.9861 309.1264 309.2667 309.4070 309.5473 309.6875 309.8278 309.9680 310.1082 310.2484 310.3886 310.5288 310.6690 310.8091 310.9493 311.0894 311.2296 311.3697 311.5098 311.6499 311.7900 311.9300 312.0701 312.2102 312.3502 312.4902 312.6302 312.7702 312.9102 313.0502 313.1902 313.3301 313.4701 313.6100 313.7500 313.8899 314.0298 314.1697 314.3095 314.4494 314.5893 314.7291 314.8690 315.0088 315.1486 315.2884 315.4282 315.5680 315.7077 315.8475 315.9872 316.1269 316.2667 316.4064 316.5461 316.6858 316.8254 316.9651 317.1048 317.2444 317.3840 317.5236 317.6632 317.8028 317.9424 318.0820 318.2216 318.3611 318.5006 318.6402 318.7797 318.9192 319.0587 319.1982 319.3376 319.4771 319.6165 319.7560 319.8954 320.0348 320.1742 320.3136 320.4530 320.5923 320.7317 320.8710 321.0104 321.1497 321.2890 321.4283 321.5676 321.7068 321.8461 321.9854 322.1246 322.2638 322.4030 322.5422 322.6814 322.8206 322.9598 323.0990 323.2381 323.3772 323.5164 323.6555 323.7946 323.9337 324.0727 324.2118 324.3509 324.4899 324.6289 324.7679 324.9070 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20260214T122705.6Z 9541.518815 167 1 54.44 2 65.54 96.50 32.23 110.67 0.00 1 0.00 1 0 17 1.925e-02 7.132e-03 8.928e-03 2.633e-03 2.760742e-01 1.294510e-03 2.871107e-03 -6.000000e+00 1.066975e-02 225.64 -2.00 3.04 -2.00 317.46 0.00e+00 1.085771e-03 2.031853e-04 1.634683e-04 -6.000000e+00 4.955945e-04 293.55 -2.00 20.00 -2.00 316.53 0.00e+00 2.399 0.000 302.00 328.00 3 5.2924e+00 3.4214e-03 2.6450e-02 -6.0000e+00 2.6304e-02 2.1039e-02 3.8767e-03 1.2272e-02 -6.0000e+00 2.8540e-02 -5.1368e-03 2.3480e-03 6.0168e-03 -6.0000e+00 1.7135e-02 -2.5205e-03 1.1991e-03 1.8244e-03 -6.0000e+00 7.4916e-03 1.8200e-04 2.1723e-04 7.1250e-05 1.7806e-05 -6.0000e+00 4.8082e-04 7.8641e-03 0.0000e+00 11 8 0 10 0 0 99.83 25.48 0.63 0.00786 0.00950 32 3 1 5 0 1701.210 33.50 20.00 25.48 32.83 3.9 1028.91 -4475 8081 -4771 3383 -10375 -4492 2608 2 3876 901 -1406 -6887 -2378 132 2375 -1774 368 2047 2372 650 342 3469 1429 38 567 -757 -40 4472 -897 -2460 1906 1122 1763 -4136 -4527 -1646 -3342 -1672 -1620 241 -385 -1403 -107 -587 -590 -683 -1208 46 244 -444 749 436 910 -91 -126 739 695 895 524 57 371 830 1825 1542 1275 -452 -1062 -566 490 818 1141 499 -99 936 1204 -209 -637 -1272 -863 -970 -1171 -1177 -1391 -1133 -573 -114 490 587 669 659 863 -879 -544 -554 -279 -1315 54 1365 390 481 -623 -1041 -1313 -274 -816 -625 -951 -644 -391 519 871 635 413 1 -296 -359 -96 -20 -191 275 79 378 482 355 789 64 73 485 151 -181 204 417 -324 -432 -183 140 87 462 463 41 -30 -970 -669 -464 813 -562 343 -1052 -409 236 0 440 111 -173 -912 -344 22 441 -383 81 461 557 161 79 840 359 9 147 -207 -11 1202 -236 -647 515 303 520 -1353 -1367 -464 -1046 -601 -705 121 -197 -756 -59 -328 -329 -383 -671 25 128 -234 414 261 575 -61 -88 521 503 644 369 40 266 589 1403 1285 1080 -358 -778 -432 360 690 1060 453 -91 883 1059 -167 -498 -938 -657 -777 -1064 -1104 -1406 -1189 -639 -128 576 715 821 785 1018 -962 -540 -564 -278 -1467 62 1723 538 658 -809 -1242 -1559 -327 -1007 -818 -1304 -866 -549 775 1301 975 618 1 -405 -487 -127 -28 -266 412 122 576 716 510 1139 89 95 622 208 -254 304 639 -507 -700 -295 239 153 829 843 73 -51 -1623 -1079 SS 20260214T123332.7Z 9541.523295 172 1 4.12 2 64.02 96.09 30.82 111.05 0.00 1 0.00 1 0 17 1.182e-02 6.665e-03 6.418e-03 3.138e-03 2.559480e-01 1.553090e-03 2.693358e-03 -6.000000e+00 6.554787e-03 225.64 -2.00 3.04 -2.00 316.26 0.00e+00 1.285908e-03 1.805323e-04 4.346398e-05 -6.000000e+00 3.044863e-04 293.55 -2.00 20.00 -2.00 315.39 0.00e+00 2.269 0.000 302.00 328.00 3 3.3501e+00 4.0146e-03 2.4912e-02 -6.0000e+00 1.6159e-02 -1.4201e-03 4.5048e-03 1.1442e-02 -6.0000e+00 1.7533e-02 -1.7800e-03 2.6088e-03 5.5646e-03 -6.0000e+00 1.0527e-02 -2.5148e-03 1.2485e-03 1.7900e-03 -6.0000e+00 4.6020e-03 1.4991e-03 9.5336e-05 8.3236e-05 1.7708e-05 -6.0000e+00 2.9541e-04 8.4762e-03 0.0000e+00 12 9 1 12 1 1 55.19 25.50 0.44 0.00848 0.00919 5 8 1 5 0 685.360 33.50 20.00 25.50 33.25 4.0 1032.45 -881 -2610 2982 -1546 -4423 -4424 -1546 3664 -1540 -730 -148 -2225 -2060 1874 1743 -299 243 1375 1991 1833 427 1072 2150 1136 16 533 -113 614 -281 430 380 -415 562 -796 -2310 -4406 -2057 -2169 -559 -461 -1111 -662 -613 352 -406 73 -1329 -598 291 -193 257 599 302 -41 1734 1301 1209 265 219 225 379 589 1789 2024 633 -230 -749 -1001 433 712 1025 401 829 -141 165 -72 -64 -1034 -220 -928 -629 -1223 -1443 -1371 -746 -296 -63 356 777 674 335 -411 -492 -585 -336 -520 60 745 368 -357 -454 -588 -721 -779 -519 -529 -659 -589 64 659 261 1006 772 244 -46 -34 -231 -211 -67 231 -67 -186 624 330 482 136 -174 530 306 401 225 -144 -151 41 -261 -251 -142 525 855 -111 -456 -465 -777 -169 -557 618 -313 -801 -762 -274 697 -346 -171 -33 -522 -507 513 512 -99 83 484 727 649 157 384 773 437 6 226 -48 245 -105 156 148 -176 243 -363 -984 -1959 -914 -1059 -307 -282 -713 -441 -422 243 -281 50 -918 -400 189 -125 176 419 224 -31 1320 1012 963 212 172 174 302 482 1581 1843 591 -199 -622 -839 360 651 991 393 812 -140 153 -66 -54 -832 -181 -836 -588 -1227 -1501 -1482 -827 -340 -76 432 947 799 382 -462 -521 -590 -355 -587 69 929 482 -468 -577 -709 -837 -924 -630 -684 -860 -780 88 937 384 1507 1123 344 -62 -44 -300 -276 -91 327 -98 -271 882 465 663 180 -224 689 412 546 325 -210 -222 60 -398 -394 -228 862 1383 -183 -727 -734 -1190 SS 20260214T123814.0Z 9541.526550 175 1 11.92 2 62.91 95.79 29.80 111.37 0.00 1 0.00 1 0 17 1.150e-02 7.116e-03 4.516e-03 2.226e-03 2.516680e-01 1.101743e-03 2.652313e-03 -6.000000e+00 6.372265e-03 225.64 -2.00 3.04 -2.00 316.21 0.00e+00 1.177004e-03 1.272391e-04 3.867797e-05 -6.000000e+00 2.960574e-04 293.55 -2.00 20.00 -2.00 315.35 0.00e+00 2.183 0.000 302.00 328.00 3 3.8734e+00 2.8489e-03 2.4094e-02 -6.0000e+00 1.5709e-02 1.4188e-02 3.1942e-03 1.1243e-02 -6.0000e+00 1.7046e-02 -7.5857e-03 1.8496e-03 5.4747e-03 -6.0000e+00 1.0234e-02 4.4115e-05 8.8583e-04 1.7280e-03 -6.0000e+00 4.4732e-03 9.6403e-04 -1.3916e-04 5.9016e-05 1.7664e-05 -6.0000e+00 2.8723e-04 9.6984e-03 0.0000e+00 12 9 1 12 1 1 98.80 25.50 0.28 0.00970 0.00865 10 5 1 5 0 1083.650 33.75 20.01 25.50 33.76 3.9 1035.91 -3029 872 204 -722 -5370 -4282 -296 1443 1204 -616 -919 -2241 -1772 1738 49 317 -193 1563 504 809 1455 396 618 1614 167 340 83 877 -792 40 406 579 2370 -1438 -3330 -2956 -2678 -1546 -535 -740 -650 -638 -416 -556 219 109 -430 -633 -1190 350 1216 921 963 996 908 1280 485 425 551 -131 1110 991 1424 2451 949 -660 -967 -743 290 288 635 896 245 123 683 16 -706 -1719 -1660 -1274 -1507 -1106 -1893 -1430 -913 -280 -383 306 843 878 567 -10 -173 -268 -342 -124 367 819 484 292 -185 -937 -1463 -44 -734 -1018 -864 -287 2 361 795 822 576 213 -367 -296 -92 -65 21 132 115 182 268 198 749 222 16 509 368 84 60 90 -216 51 -43 19 180 435 108 14 -212 -690 -787 -578 175 42 -141 -1040 -778 -55 296 254 -139 -202 -506 -452 494 15 107 -68 562 177 294 537 144 228 625 69 146 36 352 -298 15 158 243 1069 -655 -1420 -1288 -1184 -788 -306 -470 -426 -436 -293 -376 154 77 -301 -432 -798 230 835 648 716 742 699 997 389 341 431 -102 876 842 1253 2195 872 -592 -836 -616 250 259 603 888 245 119 645 14 -597 -1373 -1367 -1128 -1442 -1119 -1986 -1552 -1012 -320 -464 368 1017 1067 666 -11 -184 -270 -363 -140 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